Loading...
HomeMy WebLinkAbout20250940 48 Lincoln Ave The Green House Saratoga Special Use Permit Structure Monitoring New York State Department of Environmental Conservation Division of Environmental Remediation Remedial Bureau A, 12th Floor 625 Broadway, Albany, New York 12233-7015 Phone: (518) 402-9620 • Fax: (518) 402-9627 Website: www.dec.ny.gov MEMORANDUM TO: FILE FROM: Hayley Frank, Environmental Engineering Technician 1 SUBJECT: Structure Monitoring 2017 Site Name: Sharon Cleaners Site Code: 546052 City: Saratoga Springs County: Saratoga DATE: 6/20/17 The Sharon Cleaners site is located in Saratoga Springs, New York, see Figure 1. Structure monitoring was performed at the above-referenced site by the New York State Department of Environmental Conservation (NYSDEC). Monitoring was performed in accordance with the Site Management Plan (SMP) dated July 2010 for this site. Details of the monitoring activities are present below. Site Inspections On March 7, 2017, a site inspection was performed at the site, also known as Structure 9. The site is still an active dry cleaner and no potable wells were identified on the site. The on-site sub-slab depressurization system (SSDS) was evaluated and found to be working appropriately. See Appendix A for completed field forms. An exterior inspection was performed on the off-site systems. The fan for Structure 7 was humming. The exterior piping for passive system at Structure 8 was still present. The locations of the structures are identified on Figure 1. Structure Monitoring Procedures Structure monitoring was performed at Structure 10 on March 7, 2017. The location of the structure is identified on Figure 1. The sub-slab sampling point was inspected for cracks and purged 300 milliliters at a rate less than 200 milliliters per minute using a syringe. Following purging activities a summa canister was immediately connected to the tubing and one summa canister was set up to obtain an indoor air sample at breathing height (approximately 4 feet). Prior to leaving the site an ambient air sample was setup outside of Structure 10 (approximately 6 feet). Starting regulator vacuum measurements for the canisters were recorded when the canisters were opened and checked again fifteen minutes later to verify that the regulators were operating accordingly. The field crew returned the next day to retrieve the canisters approximately 24 hours after setup. At that time the vacuum on the canisters were recorded and valves closed. Field logs are provided in Appendix A. The samples were managed in accordance with the SMP. A duplicate indoor air sample was collected for Quality Assurance/Quality Control (QA/QC) at Structure 10. After obtaining all of the samples, they were delivered to Test America Laboratories, Inc., a New York State Department of Health ELAP-certified laboratory. All samples were analyzed for volatile organic compounds (VOCs) by TO-15 analysis. Structure Monitoring Results The analytical results from the March 2017 sampling event are presented in Table 1. The laboratory results from the 2017 sampling event are included in Appendix B. A Data Review Report was prepared and included in Appendix C. The analytical results are considered to be acceptable based on the review of the QA/QC samples and laboratory methods. The primary site contaminants are tetrachloroethylene (PCE) and trichloroethylene (TCE). Sample results from Structure 10 are discussed below. Structure 10 indoor air concentrations of PCE were non-detect. Sub-slab soil vapor detected PCE at 630 micrograms per cubic meter (µg/m3). Application of the PCE indoor and sub-slab soil vapor concentrations to NYSDOH Soil Vapor/Indoor Air Matrix B in the NYSDOH Guidance for Evaluating Soil Vapor Intrusion in New York State indicated that no additional actions are recommended to address human exposure. For TCE, the indoor air concentration was found to be 3.0 µg/m3 and the sub-slab soil vapor concentration was non-detect. This resulted in a recommendation from the NYSDOH Soil Vapor/Indoor Air Matrix A to identify the source(s) and resample or mitigate. Summary and Recommendations The ROD, dated March 2009, required structure monitoring to be conducted for a minimum of three years at Structure 10. This was the eighth sampling event at this structure since the ROD. The indoor air and sub-slab soil vapor analytical results from 2008 to 2017 for PCE and TCE are presented on Table 2. A summary and recommendation for Structure 10 is provided below. The analytical results for Structure 10 have resulted in the recommendation of no further action. The data demonstrates presence of PCE in the sub-slab vapors. However, the concentration of PCE has remained stable over time. Since 2014, PCE has not been detected within the indoor air, and the indoor air levels have not exceeded the guidance value of 30 µg/l for any sampling events. TCE has remained non-detect in sub-slab vapor, excluding one low detection in 2010. This indicates that the low levels of TCE detected in the indoor air are not due to soil vapor intrusion, and have been attributed to an indoor source, for which the owner has been instructed on how to mitigate. For these reasons, the New York State Department of Health (NYSDOH) has agreed to the action of discontinuation of monitoring at this location. Figures XW XW XW !? !? Structure 10 Structure 9 Structure 8 Structure 7 OA IA-10, SS-10 Sources: Esri, HERE, DeLorme, Intermap, increment P Corp., GEBCO,USGS, FAO, NPS, NRCAN, GeoBase, IGN, Kadaster NL, Ordnance Survey,Esri Japan, METI, Esri China (Hong Kong), swisstopo, MapmyIndia, ©OpenStreetMap contributors, and the GIS User Community, Source: Esri,DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA,USGS, AeroGRID, IGN, and the GIS User Community Figure 1: Site PlanSharon Cleaners Site No. 546052Saratoga Springs, Saratoga County, New York !(SARATOGA RENSSELAER ALBANY WASHINGTON SCHENECTADY 1 inch = 50 feet 0 40 80 12020Feet Key Plan1 inch = 20 miles Ü Legend !?Monitoring Location XW Sub-Slab Depressurization System Site Boundary Tables Location ID Sample Date Chemical Value Q Value Q Value Q Value Q Ethylbenzene 6.8 6.7 0.35 U 3.5 U Styrene 1.7 U 1.7 U 0.34 U 3.4 U Benzyl Chloride 4.1 U 4.1 U 0.83 U 8.3 U Cis-1,3-Dichloropropene 1.8 U 1.8 U 0.36 U 3.6 U Trans-1,3-Dichloropropene 1.8 U 1.8 U 0.36 U 3.6 U 1,4-Dichlorobenzene 2.4 U 2.4 U 0.48 U 4.8 U 1,2-Dibromoethane (Ethylene Dibromide)3.1 U 3.1 U 0.61 U 6.1 U 1,2-Dichloroethane 1.6 U 1.6 U 0.32 U 3.2 U Methyl Isobutyl Ketone (4-Methyl-2-Pentanone)4.1 U 4.1 U 0.82 U 8.2 U 1,3,5-Trimethylbenzene (Mesitylene)2.0 U 2.0 U 0.39 U 3.9 U Toluene 64 62 1.2 4.5 U Chlorobenzene 1.8 U 1.8 U 0.37 U 3.7 U N-Hexane 41 40 0.70 U 7.0 Cyclohexane 13 13 0.69 U 6.9 U 1,2,4-Trichlorobenzene 3.0 U 3.0 U 0.59 U 5.9 U 1,4-Dioxane (P-Dioxane)3.6 U 3.6 U 0.72 U 7.2 U Dibromochloromethane 3.4 U 3.4 U 0.68 U 6.8 U Tetrachloroethylene (PCE)2.7 U 2.7 U 0.54 U 630 Cis-1,2-Dichloroethylene 1.6 U 1.6 U 0.32 U 3.2 U Trans-1,2-Dichloroethene 1.6 U 1.6 U 0.32 U 3.2 U Tert-Butyl Methyl Ether 2.9 U 2.9 U 0.58 U 5.8 U m,p-Xylene 26 25 0.66 3.5 U 2,2,4-Trimethylpentane 8.7 8.6 0.93 U 9.3 U 1,3-Dichlorobenzene 2.4 U 2.4 U 0.48 U 4.8 U Carbon Tetrachloride 1.3 U 1.3 U 0.48 2.5 U Ethanol 2400 1600 D E 2400 1500 D E 10 38 U Chloroform 2.0 U 2.0 U 0.39 U 3.9 U Benzene 18 18 0.94 2.6 U 1,1,1-Trichloroethane (TCA)2.2 U 2.2 U 0.44 U 4.4 U Bromomethane 1.6 U 1.6 U 0.31 U 3.1 U Chloromethane 6.5 7.6 1.2 4.1 U Chloroethane 1.1 U T 1.1 U T 0.21 U T 2.1 U T Vinyl Chloride 0.51 U 0.51 U 0.10 U 1.0 U Methylene Chloride 150 150 0.82 6.9 U Bromoform 4.1 U 4.1 U 0.83 U 8.3 U Bromodichloromethane 2.7 U 2.7 U 0.54 U 5.4 U 1,1-Dichloroethane 1.6 U 1.6 U 0.32 U 3.2 U 1,1-Dichloroethene 1.6 U 1.6 U 0.32 U 3.2 U Tert-Butyl Alcohol 4.9 U 4.9 U 0.97 U 9.7 U Trichlorofluoromethane 2.2 U 2.2 U 0.93 4.5 U Dichlorodifluoromethane 2.0 2.3 0.89 4.0 U 1,1,2-Trichloro-1,2,2-Trifluoroethane 3.1 U 3.1 U 0.61 U 6.1 U 1,2-Dichlorotetrafluoroethane 2.8 U 2.8 U 0.56 U 5.6 U 1,2-Dichloropropane 1.8 U 1.8 U 0.37 U 3.7 U Methyl Ethyl Ketone (2-Butanone)7.4 8.8 1.5 9.4 U 1,1,2-Trichloroethane 2.2 U 2.2 U 0.44 U 4.4 U Trichloroethylene (TCE)2.9 3.0 U 0.21 U 2.1 U 1,1,2,2-Tetrachloroethane 2.7 U 2.7 U 0.55 U 5.5 U Hexachlorobutadiene 4.3 U 4.3 U 0.85 U 8.5 U O-Xylene (1,2-Dimethylbenzene)7.1 7.1 0.35 U 3.5 U 1,2-Dichlorobenzene 2.4 U 2.4 U 0.48 U 4.8 U 1,2,4-Trimethylbenzene 6.2 6.1 0.39 U 3.9 U Notes: 1. Units: micrograms per cubic meter 2. Analysis: TO-15 3. *Duplicate of IA-10 4. U: undetect (not detected above the laboratory method detection limit) 5. D: indicates diluted sample 6. E: indicates estimated sample 7. T: indicates that a quality control parameter has exceeded laboratory limits 3/6/2017 3/6/2017 3/6/2017 3/6/2017 Table 1 Sharon Cleaners Saratoga Springs, New York Site Number 546052 Structure Monitoring Results March 2017 IA-10 IA-10*OA SS-10 Date Sample ID IA-10 SS-10 IA-10 SS-10 IA-10 SS-10 IA-10 SS-10 IA-10 SS-10 IA-10 SS-10 tetrachloroethylene (PCE)1.5 740 ND 11 0.93 680 0.9 790 21 650 ND 500 trichloroethylene (TCE)0.49 ND ND 7.0 1.2 ND ND ND ND ND ND ND Date Sample ID IA-10 SS-10 IA-10 SS-10 IA-10 SS-10 tetrachloroethene (PCE)ND 520 ND 730 ND 630 trichloroethene (TCE)ND ND ND ND 3.0 ND Notes: 1.Units micrograms per cubic meter (ug/m3). 2.IA - Indoor air sample. 3.SS - Sub-slab soil vapor sample. TABLE 2 Sharon Cleaners Saratoga Springs, New York Site Number 546052 Structure Monitoring Results 2/12/2015 3/24/2016 Structure 10 3/31/2008 2/16/20112/1/2010 3/22/2012 2/27/20143/6/2013 3/7/2017 Appendix A Field Forms March 2017 Sharon Cleaners Site-Wide lnsPection List Sharon e leaners Site 48 Lincoln Avenue, Saratoga Springs, h*lY Date of Inspection: Inspection by Site-wide inspections will be performed to assess the following: 5 ß.r'* J.* or***.-( *}¡.t É1. Reason for inspection? 2. Is the Site Management Plan present at the site?€"5 -. I $æi-*q* ¿r 5 j+Ë" e-3. Verify owner contact information for the site? 4. Is the site occupied and if so used for?e I.ee"a P{I 5. Has the building footprint changed?(.) 6. Is the on-site vapor mitigation system working as designed?ät 7. Are the twó off-site vapor mitigation systems working as designed? B. Is a potable well present on site?oüp 9. Condition of monitoring wells?,4jf\ 10. Any sampling or testing performed?&.Å-,,ç,jo*( " f ßp,'Á- I 1. Provide any details regarding site conditions and attach photographs as needed Page 2 of 2 Feriodãe tpenations VisüÈ F mnr*m - !F System ID: Owner System Address:- Date of Visit: Date In stalled: Telepho ne: Alt. Telephone'- Site No: Site Na rne Import Sys,Data' Check box if new sys infot- City zip: Perlormed BY: Compan'v: -- do ú. Ttl þ.z Structural Review Change in building footprint since last inspection? Basement occuPied (>4 hrs Per daY)? Heating/ventilation system modifications? CrawlsPace insPected? Large cracks in floor or near sumPs? Wall Penetrations or cracks noted? Piping, Slab & Wall Are sYstem suction Points sealed? is PiPing system in need of rePair? Miscellaneous Are manometer levels equal? C Yes Are system labels accurate and applied correctly? ptves C Yes \#* rt:o Å/4 lU TN Notes Þ*o þv". C No ) lë* No CNo C Yes (- Yes C'Yes (-' Yes c, Yes C Yes CNo f-.No (-No ffiruo CNo úo d. tU t--X IJJ Fan Model No(s)' Is Fan OPerating (arrival)? Confirmation Method Is Fan OPerating (deParture)? CYes CNo CYes CNo f-' Yes C No (ìYes CNo C, Yes C' No CYes CNo Fan #1.Fan #3Fan #2 Requested to inspect interior system compónents? C Yes 61 Date: No Fan OPeration Confirmation If yes, when and bY whom? Maintenance completed (checl< all that apply): [- Replace fan [- seal pipe f- Ëlectrical l- other irs made and any proposed actions requiring a subsequent visit (if necessary) Submit:by Email Describe rePa Periodic OPeratíons Visit Form Air Sampling Form Sharon Cleaners Site 546052 48 Lincoln Avenue, Saratoga Springs, NY ¿¿5- L.4 'a'1 ;X,Åt\> (ppb) PID 7ðt Purge Volume (ml) -) À .) Final Vacuum ("Hg) 7i'tù r{û Ð ¿{l\-} End Time " fil '1-\' .- "t(-: ¡ Initial Vacuum ("Hg) t.' .ø ) If 4t-\ f/tz {I"a'iî Start Time >f 6- -4 (<> ')l I Date /üé"7 / l{"t Y {, d Itz,Aç I / ¡:: x4v ID Regulator {; t. \s, r_- Summa Size (L) r:-/w / s7 ta7 I *)V{-¿*" I I Ð, ï"'-. ID Summa SS-10 DUP OA Sample ID 1 'TSjf IA-10 >1 I.. . . #s-to t ID Structure A.{$-1"tt'" í AS-iO Notes f.e f q {-¡ r lþ*-*o-.-".+ {-"{1'. { å"c -e & ,-^ a ri i*d¿-"lS'' _*.:." *n {n.V {-Í -ln f( :t:,{*'!(*t4ej'¿<*Ì< Units t 2 J. 1. Sample Analysis TO-15. 2. Detection limits 1 microgram per cubic meter (ug/m3) for all except TCE and VC, which is 0.25 ug/m3 3. Duplicate collected from sub-slab soil vapor. 4. Purge rate <200 milliliters per minute. 5. Indoor air (IA) and outdoor air (OA) samples are set approximately 4 feet above ground surface. 6. Sub-slab soil vapor (SS) points are existing sample points from the remedial investigation. 7. Ðuplicates (DUP) are collected with a Í'T" connection. I- - liter "Hg - inches of mercury ppb - parts per billion Appendix B Laboratory Results Sampled March 2017 Sharon Cleaners ANALYTICAL REPORT Job Number: 140-7345-1 Job Description: Sharon Cleaners # 546052 Contract Number: C008010 For: New York State D.E.C. 625 Broadway 12th Floor Albany, NY 12233-7017 Attention: Mr. Brian Jankauskas _____________________________________________ Approved for release. Jamie A McKinney Senior Project Manager 3/21/2017 4:12 PM Jamie A McKinney, Senior Project Manager 5815 Middlebrook Pike, Knoxville, TN, 37921 (865)291-3000 jamie.mckinney@testamericainc.com 03/21/2017 The test results in this report meet all 2003 NELAC and 2003 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. TestAmerica Laboratories, Inc. TestAmerica Knoxville 5815 Middlebrook Pike, Knoxville, TN 37921 Tel (865) 291-3000 Fax (865) 584-4315 www.testamericainc.com 03/21/2017Page 1 of 377 Table of Contents Cover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1 Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5 Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9 Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19 Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21 QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22 QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .28 Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .29 Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .31 Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .32 Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .33 Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .34 Air - GC/MS VOA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .34 Method TO15 Low Level . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .34 Method TO15 Low Level QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .35 Method TO15 Low Level Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .49 Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .136 Method TO15 Low Level ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .136 Method TO15 Low Level CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .267 Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .295 Method TO15 Low Level Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .295 Method TO15 Low Level Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .313 Method TO15 Low Level LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .325 03/21/2017Page 2 of 377 Table of Contents Method TO15 Low Level Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .338 Clean Canister Certification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .350 Clean Canister Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .350 Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . .374 Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .375 Sample Receipt Checklist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .377 03/21/2017Page 3 of 377 Definitions/Glossary TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Qualifiers Air - GC/MS VOA Qualifier Description *LCS or LCSD is outside acceptance limits. Qualifier E Result exceeded calibration range. D Sample results are obtained from a dilution; the surrogate or matrix spike recoveries reported are calculated from diluted samples. Glossary These commonly used abbreviations may or may not be present in this report. ¤Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation %R Percent Recovery CFL Contains Free Liquid CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference) Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin) NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown) PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TestAmerica Knoxville 03/21/2017Page 4 of 377 Job Narrative 140-7345-1 Comments No additional comments. Receipt The samples were received on 3/8/2017 10:10 AM; the samples arrived in good condition, properly preserved and, where required, on ice. Air - GC/MS VOA Method(s) TO 15 LL, TO-14A, TO-15: EPA methods TO-14A and TO-15 specify the use of humidified “zero air” as the blank reagent for canister cleaning, instrument calibration and sample analysis. Ultra-high purity humidified nitrogen from a cryogenic reservoir is used in place of “zero air” by TestAmerica Knoxville. Method(s) TO 15 LL: The continuing calibration verification (CCV) associated with batch 140-9156 exhibited % difference of > 30% for the following analyte(s) Chloroethane and/or ethanol; however, the results were within the LCS acceptance limits. The EPA method requires that all target analytes in the continuing calibration verification standard be within 30% difference from the initial calibration. According to the laboratory standard operating procedure, the continuing calibration is acceptable if it meets the laboratory control sample acceptance criteria. Method(s) TO 15 LL: The following analyte recovered outside control limits for the LCS associated with analytical batch 140-9156: Chloroethane. This is not indicative of a systematic control problem because these were random marginal exceedances. Qualified results have been reported. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. 03/21/2017Page 5 of 377 Detection Summary TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Client Sample ID: SS-10-2017 Lab Sample ID: 140-7345-1 Tetrachloroethene RL 0.80 ppb v/v MDLAnalyteResultQualifier Unit Dil Fac D Method Prep Type Total/NA192TO 15 LL Tetrachloroethene RL 5.4 ug/m3 MDLAnalyteResultQualifier Unit Dil Fac D Method Prep Type Total/NA1630TO 15 LL Client Sample ID: AS-10-2017 Lab Sample ID: 140-7345-2 1,2,4-Trimethylbenzene RL 0.40 ppb v/v MDLAnalyteResultQualifier Unit Dil Fac D Method Prep Type Total/NA11.3 TO 15 LL 2,2,4-Trimethylpentane 1.0 ppb v/v Total/NA11.9 TO 15 LL 2-Butanone 1.6 ppb v/v Total/NA12.5 TO 15 LL Benzene 0.40 ppb v/v Total/NA15.6 TO 15 LL Chloromethane 1.0 ppb v/v Total/NA13.2 TO 15 LL Cyclohexane 1.0 ppb v/v Total/NA13.6 TO 15 LL Dichlorodifluoromethane 0.40 ppb v/v Total/NA10.40 TO 15 LL Ethanol 10 ppb v/v Total/NA1850ETO 15 LL Ethylbenzene 0.40 ppb v/v Total/NA11.6 TO 15 LL Hexane 1.0 ppb v/v Total/NA112TO 15 LL Methylene Chloride 1.0 ppb v/v Total/NA144TO 15 LL m-Xylene & p-Xylene 0.40 ppb v/v Total/NA15.9 TO 15 LL o-Xylene 0.40 ppb v/v Total/NA11.6 TO 15 LL Toluene 0.60 ppb v/v Total/NA117TO 15 LL Trichloroethene 0.20 ppb v/v Total/NA10.55 TO 15 LL Ethanol - DL 40 ppb v/v Total/NA11200DTO 15 LL 1,2,4-Trimethylbenzene RL 2.0 ug/m3 MDLAnalyteResultQualifier Unit Dil Fac D Method Prep Type Total/NA16.2 TO 15 LL 2,2,4-Trimethylpentane 4.7 ug/m3 Total/NA18.7 TO 15 LL 2-Butanone 4.7 ug/m3 Total/NA17.4 TO 15 LL Benzene 1.3 ug/m3 Total/NA118TO 15 LL Chloromethane 2.1 ug/m3 Total/NA16.5 TO 15 LL Cyclohexane 3.4 ug/m3 Total/NA113TO 15 LL Dichlorodifluoromethane 2.0 ug/m3 Total/NA12.0 TO 15 LL Ethanol 19 ug/m3 Total/NA11600ETO 15 LL Ethylbenzene 1.7 ug/m3 Total/NA16.8 TO 15 LL Hexane 3.5 ug/m3 Total/NA141TO 15 LL Methylene Chloride 3.5 ug/m3 Total/NA1150TO 15 LL m-Xylene & p-Xylene 1.7 ug/m3 Total/NA126TO 15 LL o-Xylene 1.7 ug/m3 Total/NA17.1 TO 15 LL Toluene 2.3 ug/m3 Total/NA164TO 15 LL Trichloroethene 1.1 ug/m3 Total/NA12.9 TO 15 LL Ethanol - DL 75 ug/m3 Total/NA12400DTO 15 LL Client Sample ID: DUP-2017 Lab Sample ID: 140-7345-3 1,2,4-Trimethylbenzene RL 0.40 ppb v/v MDLAnalyteResultQualifier Unit Dil Fac D Method Prep Type Total/NA11.2 TO 15 LL 2,2,4-Trimethylpentane 1.0 ppb v/v Total/NA11.8 TO 15 LL 2-Butanone 1.6 ppb v/v Total/NA13.0 TO 15 LL Benzene 0.40 ppb v/v Total/NA15.6 TO 15 LL Chloromethane 1.0 ppb v/v Total/NA13.7 TO 15 LL Cyclohexane 1.0 ppb v/v Total/NA13.8 TO 15 LL TestAmerica Knoxville This Detection Summary does not include radiochemical test results. 03/21/2017Page 6 of 377 Detection Summary TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Client Sample ID: DUP-2017 (Continued)Lab Sample ID: 140-7345-3 Dichlorodifluoromethane RL 0.40 ppb v/v MDLAnalyteResultQualifier Unit Dil Fac D Method Prep Type Total/NA10.47 TO 15 LL Ethanol 10 ppb v/v Total/NA1820ETO 15 LL Ethylbenzene 0.40 ppb v/v Total/NA11.5 TO 15 LL Hexane 1.0 ppb v/v Total/NA111TO 15 LL Methylene Chloride 1.0 ppb v/v Total/NA144TO 15 LL m-Xylene & p-Xylene 0.40 ppb v/v Total/NA15.8 TO 15 LL o-Xylene 0.40 ppb v/v Total/NA11.6 TO 15 LL Toluene 0.60 ppb v/v Total/NA116TO 15 LL Trichloroethene 0.20 ppb v/v Total/NA10.56 TO 15 LL Ethanol - DL 40 ppb v/v Total/NA11300DTO 15 LL 1,2,4-Trimethylbenzene RL 2.0 ug/m3 MDLAnalyteResultQualifier Unit Dil Fac D Method Prep Type Total/NA16.1 TO 15 LL 2,2,4-Trimethylpentane 4.7 ug/m3 Total/NA18.6 TO 15 LL 2-Butanone 4.7 ug/m3 Total/NA18.8 TO 15 LL Benzene 1.3 ug/m3 Total/NA118TO 15 LL Chloromethane 2.1 ug/m3 Total/NA17.6 TO 15 LL Cyclohexane 3.4 ug/m3 Total/NA113TO 15 LL Dichlorodifluoromethane 2.0 ug/m3 Total/NA12.3 TO 15 LL Ethanol 19 ug/m3 Total/NA11500ETO 15 LL Ethylbenzene 1.7 ug/m3 Total/NA16.7 TO 15 LL Hexane 3.5 ug/m3 Total/NA140TO 15 LL Methylene Chloride 3.5 ug/m3 Total/NA1150TO 15 LL m-Xylene & p-Xylene 1.7 ug/m3 Total/NA125TO 15 LL o-Xylene 1.7 ug/m3 Total/NA17.1 TO 15 LL Toluene 2.3 ug/m3 Total/NA162TO 15 LL Trichloroethene 1.1 ug/m3 Total/NA13.0 TO 15 LL Ethanol - DL 75 ug/m3 Total/NA12400DTO 15 LL Client Sample ID: OA-10-2017 Lab Sample ID: 140-7345-4 2-Butanone RL 0.32 ppb v/v MDLAnalyteResultQualifier Unit Dil Fac D Method Prep Type Total/NA10.52 TO 15 LL Benzene 0.080 ppb v/v Total/NA10.29 TO 15 LL Carbon tetrachloride 0.040 ppb v/v Total/NA10.076 TO 15 LL Chloromethane 0.20 ppb v/v Total/NA10.57 TO 15 LL Dichlorodifluoromethane 0.080 ppb v/v Total/NA10.18 TO 15 LL Ethanol 2.0 ppb v/v Total/NA15.4 TO 15 LL Methylene Chloride 0.20 ppb v/v Total/NA10.24 TO 15 LL m-Xylene & p-Xylene 0.080 ppb v/v Total/NA10.15 TO 15 LL Toluene 0.12 ppb v/v Total/NA10.31 TO 15 LL Trichlorofluoromethane 0.080 ppb v/v Total/NA10.17 TO 15 LL 2-Butanone RL 0.94 ug/m3 MDLAnalyteResultQualifier Unit Dil Fac D Method Prep Type Total/NA11.5 TO 15 LL Benzene 0.26 ug/m3 Total/NA10.94 TO 15 LL Carbon tetrachloride 0.25 ug/m3 Total/NA10.48 TO 15 LL Chloromethane 0.41 ug/m3 Total/NA11.2 TO 15 LL Dichlorodifluoromethane 0.40 ug/m3 Total/NA10.89 TO 15 LL Ethanol 3.8 ug/m3 Total/NA110TO 15 LL Methylene Chloride 0.69 ug/m3 Total/NA10.82 TO 15 LL m-Xylene & p-Xylene 0.35 ug/m3 Total/NA10.66 TO 15 LL TestAmerica Knoxville This Detection Summary does not include radiochemical test results. 03/21/2017Page 7 of 377 Detection Summary TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Client Sample ID: OA-10-2017 (Continued)Lab Sample ID: 140-7345-4 Toluene RL 0.45 ug/m3 MDLAnalyteResultQualifier Unit Dil Fac D Method Prep Type Total/NA11.2 TO 15 LL Trichlorofluoromethane 0.45 ug/m3 Total/NA10.93 TO 15 LL TestAmerica Knoxville This Detection Summary does not include radiochemical test results. 03/21/2017Page 8 of 377 Client Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Lab Sample ID: 140-7345-1Client Sample ID: SS-10-2017 Matrix: AirDate Collected: 03/06/17 11:10 Date Received: 03/08/17 10:10 Sample Container: Summa Canister 6L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) RL MDL 1,1,1-Trichloroethane ND 0.80 ppb v/v 03/09/17 20:00 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 0.80 ppb v/v 03/09/17 20:00 11,1,2,2-Tetrachloroethane ND 0.80 ppb v/v 03/09/17 20:00 11,1,2-Trichloroethane ND 0.80 ppb v/v 03/09/17 20:00 11,1,2-Trichlorotrifluoroethane ND 0.80 ppb v/v 03/09/17 20:00 11,1-Dichloroethane ND 0.80 ppb v/v 03/09/17 20:00 11,1-Dichloroethene ND 0.80 ppb v/v 03/09/17 20:00 11,2,4-Trichlorobenzene ND 0.80 ppb v/v 03/09/17 20:00 11,2,4-Trimethylbenzene ND 0.80 ppb v/v 03/09/17 20:00 11,2-Dibromoethane ND 0.80 ppb v/v 03/09/17 20:00 11,2-Dichlorobenzene ND 0.80 ppb v/v 03/09/17 20:00 11,2-Dichloroethane ND 0.80 ppb v/v 03/09/17 20:00 11,2-Dichloropropane ND 0.80 ppb v/v 03/09/17 20:00 11,2-Dichlorotetrafluoroethane ND 0.80 ppb v/v 03/09/17 20:00 11,3,5-Trimethylbenzene ND 0.80 ppb v/v 03/09/17 20:00 11,3-Dichlorobenzene ND 0.80 ppb v/v 03/09/17 20:00 11,4-Dichlorobenzene ND 2.0 ppb v/v 03/09/17 20:00 11,4-Dioxane ND 2.0 ppb v/v 03/09/17 20:00 12,2,4-Trimethylpentane ND 3.2 ppb v/v 03/09/17 20:00 12-Butanone ND 2.0 ppb v/v 03/09/17 20:00 14-Methyl-2-pentanone (MIBK)ND 0.80 ppb v/v 03/09/17 20:00 1BenzeneND 1.6 ppb v/v 03/09/17 20:00 1Benzyl chloride ND 0.80 ppb v/v 03/09/17 20:00 1BromodichloromethaneND 0.80 ppb v/v 03/09/17 20:00 1BromoformND 0.80 ppb v/v 03/09/17 20:00 1BromomethaneND 0.40 ppb v/v 03/09/17 20:00 1Carbon tetrachloride ND 0.80 ppb v/v 03/09/17 20:00 1ChlorobenzeneND 0.80 ppb v/v 03/09/17 20:00 1ChloroethaneND* 0.80 ppb v/v 03/09/17 20:00 1ChloroformND 2.0 ppb v/v 03/09/17 20:00 1ChloromethaneND 0.80 ppb v/v 03/09/17 20:00 1cis-1,2-Dichloroethene ND 0.80 ppb v/v 03/09/17 20:00 1cis-1,3-Dichloropropene ND 2.0 ppb v/v 03/09/17 20:00 1CyclohexaneND 0.80 ppb v/v 03/09/17 20:00 1DibromochloromethaneND 0.80 ppb v/v 03/09/17 20:00 1DichlorodifluoromethaneND 20 ppb v/v 03/09/17 20:00 1EthanolND 0.80 ppb v/v 03/09/17 20:00 1EthylbenzeneND 0.80 ppb v/v 03/09/17 20:00 1HexachlorobutadieneND 2.0 ppb v/v 03/09/17 20:00 1HexaneND 1.6 ppb v/v 03/09/17 20:00 1Methyl tert-butyl ether ND 2.0 ppb v/v 03/09/17 20:00 1Methylene Chloride ND 0.80 ppb v/v 03/09/17 20:00 1m-Xylene & p-Xylene ND 0.80 ppb v/v 03/09/17 20:00 1o-Xylene ND 0.80 ppb v/v 03/09/17 20:00 1StyreneND 3.2 ppb v/v 03/09/17 20:00 1t-Butyl alcohol ND 0.80 ppb v/v 03/09/17 20:00 1Tetrachloroethene92 1.2 ppb v/v 03/09/17 20:00 1TolueneND 0.80 ppb v/v 03/09/17 20:00 1trans-1,2-Dichloroethene ND TestAmerica Knoxville 03/21/2017Page 9 of 377 Client Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Lab Sample ID: 140-7345-1Client Sample ID: SS-10-2017 Matrix: AirDate Collected: 03/06/17 11:10 Date Received: 03/08/17 10:10 Sample Container: Summa Canister 6L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) RL MDL trans-1,3-Dichloropropene ND 0.80 ppb v/v 03/09/17 20:00 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 0.40 ppb v/v 03/09/17 20:00 1TrichloroetheneND 0.80 ppb v/v 03/09/17 20:00 1TrichlorofluoromethaneND 0.40 ppb v/v 03/09/17 20:00 1Vinyl chloride ND RL MDL 1,1,1-Trichloroethane ND 4.4 ug/m3 03/09/17 20:00 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 5.5 ug/m3 03/09/17 20:00 11,1,2,2-Tetrachloroethane ND 4.4 ug/m3 03/09/17 20:00 11,1,2-Trichloroethane ND 6.1 ug/m3 03/09/17 20:00 11,1,2-Trichlorotrifluoroethane ND 3.2 ug/m3 03/09/17 20:00 11,1-Dichloroethane ND 3.2 ug/m3 03/09/17 20:00 11,1-Dichloroethene ND 5.9 ug/m3 03/09/17 20:00 11,2,4-Trichlorobenzene ND 3.9 ug/m3 03/09/17 20:00 11,2,4-Trimethylbenzene ND 6.1 ug/m3 03/09/17 20:00 11,2-Dibromoethane ND 4.8 ug/m3 03/09/17 20:00 11,2-Dichlorobenzene ND 3.2 ug/m3 03/09/17 20:00 11,2-Dichloroethane ND 3.7 ug/m3 03/09/17 20:00 11,2-Dichloropropane ND 5.6 ug/m3 03/09/17 20:00 11,2-Dichlorotetrafluoroethane ND 3.9 ug/m3 03/09/17 20:00 11,3,5-Trimethylbenzene ND 4.8 ug/m3 03/09/17 20:00 11,3-Dichlorobenzene ND 4.8 ug/m3 03/09/17 20:00 11,4-Dichlorobenzene ND 7.2 ug/m3 03/09/17 20:00 11,4-Dioxane ND 9.3 ug/m3 03/09/17 20:00 12,2,4-Trimethylpentane ND 9.4 ug/m3 03/09/17 20:00 12-Butanone ND 8.2 ug/m3 03/09/17 20:00 14-Methyl-2-pentanone (MIBK)ND 2.6 ug/m3 03/09/17 20:00 1BenzeneND 8.3 ug/m3 03/09/17 20:00 1Benzyl chloride ND 5.4 ug/m3 03/09/17 20:00 1BromodichloromethaneND 8.3 ug/m3 03/09/17 20:00 1BromoformND 3.1 ug/m3 03/09/17 20:00 1BromomethaneND 2.5 ug/m3 03/09/17 20:00 1Carbon tetrachloride ND 3.7 ug/m3 03/09/17 20:00 1ChlorobenzeneND 2.1 ug/m3 03/09/17 20:00 1ChloroethaneND* 3.9 ug/m3 03/09/17 20:00 1ChloroformND 4.1 ug/m3 03/09/17 20:00 1ChloromethaneND 3.2 ug/m3 03/09/17 20:00 1cis-1,2-Dichloroethene ND 3.6 ug/m3 03/09/17 20:00 1cis-1,3-Dichloropropene ND 6.9 ug/m3 03/09/17 20:00 1CyclohexaneND 6.8 ug/m3 03/09/17 20:00 1DibromochloromethaneND 4.0 ug/m3 03/09/17 20:00 1DichlorodifluoromethaneND 38 ug/m3 03/09/17 20:00 1EthanolND 3.5 ug/m3 03/09/17 20:00 1EthylbenzeneND 8.5 ug/m3 03/09/17 20:00 1HexachlorobutadieneND 7.0 ug/m3 03/09/17 20:00 1HexaneND 5.8 ug/m3 03/09/17 20:00 1Methyl tert-butyl ether ND 6.9 ug/m3 03/09/17 20:00 1Methylene Chloride ND 3.5 ug/m3 03/09/17 20:00 1m-Xylene & p-Xylene ND 3.5 ug/m3 03/09/17 20:00 1o-Xylene ND TestAmerica Knoxville 03/21/2017Page 10 of 377 Client Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Lab Sample ID: 140-7345-1Client Sample ID: SS-10-2017 Matrix: AirDate Collected: 03/06/17 11:10 Date Received: 03/08/17 10:10 Sample Container: Summa Canister 6L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) RL MDL Styrene ND 3.4 ug/m3 03/09/17 20:00 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 9.7 ug/m3 03/09/17 20:00 1t-Butyl alcohol ND 5.4 ug/m3 03/09/17 20:00 1Tetrachloroethene630 4.5 ug/m3 03/09/17 20:00 1TolueneND 3.2 ug/m3 03/09/17 20:00 1trans-1,2-Dichloroethene ND 3.6 ug/m3 03/09/17 20:00 1trans-1,3-Dichloropropene ND 2.1 ug/m3 03/09/17 20:00 1TrichloroetheneND 4.5 ug/m3 03/09/17 20:00 1TrichlorofluoromethaneND 1.0 ug/m3 03/09/17 20:00 1Vinyl chloride ND 4-Bromofluorobenzene (Surr)113 60 -140 03/09/17 20:00 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Lab Sample ID: 140-7345-2Client Sample ID: AS-10-2017 Matrix: AirDate Collected: 03/06/17 11:10 Date Received: 03/08/17 10:10 Sample Container: Summa Canister 6L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) RL MDL 1,1,1-Trichloroethane ND 0.40 ppb v/v 03/09/17 20:48 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 0.40 ppb v/v 03/09/17 20:48 11,1,2,2-Tetrachloroethane ND 0.40 ppb v/v 03/09/17 20:48 11,1,2-Trichloroethane ND 0.40 ppb v/v 03/09/17 20:48 11,1,2-Trichlorotrifluoroethane ND 0.40 ppb v/v 03/09/17 20:48 11,1-Dichloroethane ND 0.40 ppb v/v 03/09/17 20:48 11,1-Dichloroethene ND 0.40 ppb v/v 03/09/17 20:48 11,2,4-Trichlorobenzene ND 0.40 ppb v/v 03/09/17 20:48 11,2,4-Trimethylbenzene 1.3 0.40 ppb v/v 03/09/17 20:48 11,2-Dibromoethane ND 0.40 ppb v/v 03/09/17 20:48 11,2-Dichlorobenzene ND 0.40 ppb v/v 03/09/17 20:48 11,2-Dichloroethane ND 0.40 ppb v/v 03/09/17 20:48 11,2-Dichloropropane ND 0.40 ppb v/v 03/09/17 20:48 11,2-Dichlorotetrafluoroethane ND 0.40 ppb v/v 03/09/17 20:48 11,3,5-Trimethylbenzene ND 0.40 ppb v/v 03/09/17 20:48 11,3-Dichlorobenzene ND 0.40 ppb v/v 03/09/17 20:48 11,4-Dichlorobenzene ND 1.0 ppb v/v 03/09/17 20:48 11,4-Dioxane ND 1.0 ppb v/v 03/09/17 20:48 12,2,4-Trimethylpentane 1.9 1.6 ppb v/v 03/09/17 20:48 12-Butanone 2.5 1.0 ppb v/v 03/09/17 20:48 14-Methyl-2-pentanone (MIBK)ND 0.40 ppb v/v 03/09/17 20:48 1Benzene5.6 0.80 ppb v/v 03/09/17 20:48 1Benzyl chloride ND 0.40 ppb v/v 03/09/17 20:48 1BromodichloromethaneND 0.40 ppb v/v 03/09/17 20:48 1BromoformND 0.40 ppb v/v 03/09/17 20:48 1BromomethaneND 0.20 ppb v/v 03/09/17 20:48 1Carbon tetrachloride ND 0.40 ppb v/v 03/09/17 20:48 1ChlorobenzeneND 0.40 ppb v/v 03/09/17 20:48 1ChloroethaneND* 0.40 ppb v/v 03/09/17 20:48 1ChloroformND TestAmerica Knoxville 03/21/2017Page 11 of 377 Client Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Lab Sample ID: 140-7345-2Client Sample ID: AS-10-2017 Matrix: AirDate Collected: 03/06/17 11:10 Date Received: 03/08/17 10:10 Sample Container: Summa Canister 6L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) RL MDL Chloromethane 3.2 1.0 ppb v/v 03/09/17 20:48 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 0.40 ppb v/v 03/09/17 20:48 1cis-1,2-Dichloroethene ND 0.40 ppb v/v 03/09/17 20:48 1cis-1,3-Dichloropropene ND 1.0 ppb v/v 03/09/17 20:48 1Cyclohexane3.6 0.40 ppb v/v 03/09/17 20:48 1DibromochloromethaneND 0.40 ppb v/v 03/09/17 20:48 1Dichlorodifluoromethane0.40 10 ppb v/v 03/09/17 20:48 1Ethanol850E 0.40 ppb v/v 03/09/17 20:48 1Ethylbenzene1.6 0.40 ppb v/v 03/09/17 20:48 1HexachlorobutadieneND 1.0 ppb v/v 03/09/17 20:48 1Hexane12 0.80 ppb v/v 03/09/17 20:48 1Methyl tert-butyl ether ND 1.0 ppb v/v 03/09/17 20:48 1Methylene Chloride 44 0.40 ppb v/v 03/09/17 20:48 1m-Xylene & p-Xylene 5.9 0.40 ppb v/v 03/09/17 20:48 1o-Xylene 1.6 0.40 ppb v/v 03/09/17 20:48 1StyreneND 1.6 ppb v/v 03/09/17 20:48 1t-Butyl alcohol ND 0.40 ppb v/v 03/09/17 20:48 1TetrachloroetheneND 0.60 ppb v/v 03/09/17 20:48 1Toluene17 0.40 ppb v/v 03/09/17 20:48 1trans-1,2-Dichloroethene ND 0.40 ppb v/v 03/09/17 20:48 1trans-1,3-Dichloropropene ND 0.20 ppb v/v 03/09/17 20:48 1Trichloroethene0.55 0.40 ppb v/v 03/09/17 20:48 1TrichlorofluoromethaneND 0.20 ppb v/v 03/09/17 20:48 1Vinyl chloride ND RL MDL 1,1,1-Trichloroethane ND 2.2 ug/m3 03/09/17 20:48 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 2.7 ug/m3 03/09/17 20:48 11,1,2,2-Tetrachloroethane ND 2.2 ug/m3 03/09/17 20:48 11,1,2-Trichloroethane ND 3.1 ug/m3 03/09/17 20:48 11,1,2-Trichlorotrifluoroethane ND 1.6 ug/m3 03/09/17 20:48 11,1-Dichloroethane ND 1.6 ug/m3 03/09/17 20:48 11,1-Dichloroethene ND 3.0 ug/m3 03/09/17 20:48 11,2,4-Trichlorobenzene ND 2.0 ug/m3 03/09/17 20:48 11,2,4-Trimethylbenzene 6.2 3.1 ug/m3 03/09/17 20:48 11,2-Dibromoethane ND 2.4 ug/m3 03/09/17 20:48 11,2-Dichlorobenzene ND 1.6 ug/m3 03/09/17 20:48 11,2-Dichloroethane ND 1.8 ug/m3 03/09/17 20:48 11,2-Dichloropropane ND 2.8 ug/m3 03/09/17 20:48 11,2-Dichlorotetrafluoroethane ND 2.0 ug/m3 03/09/17 20:48 11,3,5-Trimethylbenzene ND 2.4 ug/m3 03/09/17 20:48 11,3-Dichlorobenzene ND 2.4 ug/m3 03/09/17 20:48 11,4-Dichlorobenzene ND 3.6 ug/m3 03/09/17 20:48 11,4-Dioxane ND 4.7 ug/m3 03/09/17 20:48 12,2,4-Trimethylpentane 8.7 4.7 ug/m3 03/09/17 20:48 12-Butanone 7.4 4.1 ug/m3 03/09/17 20:48 14-Methyl-2-pentanone (MIBK)ND 1.3 ug/m3 03/09/17 20:48 1Benzene18 4.1 ug/m3 03/09/17 20:48 1Benzyl chloride ND 2.7 ug/m3 03/09/17 20:48 1BromodichloromethaneND 4.1 ug/m3 03/09/17 20:48 1BromoformND TestAmerica Knoxville 03/21/2017Page 12 of 377 Client Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Lab Sample ID: 140-7345-2Client Sample ID: AS-10-2017 Matrix: AirDate Collected: 03/06/17 11:10 Date Received: 03/08/17 10:10 Sample Container: Summa Canister 6L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) RL MDL Bromomethane ND 1.6 ug/m3 03/09/17 20:48 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 1.3 ug/m3 03/09/17 20:48 1Carbon tetrachloride ND 1.8 ug/m3 03/09/17 20:48 1ChlorobenzeneND 1.1 ug/m3 03/09/17 20:48 1ChloroethaneND* 2.0 ug/m3 03/09/17 20:48 1ChloroformND 2.1 ug/m3 03/09/17 20:48 1Chloromethane6.5 1.6 ug/m3 03/09/17 20:48 1cis-1,2-Dichloroethene ND 1.8 ug/m3 03/09/17 20:48 1cis-1,3-Dichloropropene ND 3.4 ug/m3 03/09/17 20:48 1Cyclohexane13 3.4 ug/m3 03/09/17 20:48 1DibromochloromethaneND 2.0 ug/m3 03/09/17 20:48 1Dichlorodifluoromethane2.0 19 ug/m3 03/09/17 20:48 1Ethanol1600E 1.7 ug/m3 03/09/17 20:48 1Ethylbenzene6.8 4.3 ug/m3 03/09/17 20:48 1HexachlorobutadieneND 3.5 ug/m3 03/09/17 20:48 1Hexane41 2.9 ug/m3 03/09/17 20:48 1Methyl tert-butyl ether ND 3.5 ug/m3 03/09/17 20:48 1Methylene Chloride 150 1.7 ug/m3 03/09/17 20:48 1m-Xylene & p-Xylene 26 1.7 ug/m3 03/09/17 20:48 1o-Xylene 7.1 1.7 ug/m3 03/09/17 20:48 1StyreneND 4.9 ug/m3 03/09/17 20:48 1t-Butyl alcohol ND 2.7 ug/m3 03/09/17 20:48 1TetrachloroetheneND 2.3 ug/m3 03/09/17 20:48 1Toluene64 1.6 ug/m3 03/09/17 20:48 1trans-1,2-Dichloroethene ND 1.8 ug/m3 03/09/17 20:48 1trans-1,3-Dichloropropene ND 1.1 ug/m3 03/09/17 20:48 1Trichloroethene2.9 2.2 ug/m3 03/09/17 20:48 1TrichlorofluoromethaneND 0.51 ug/m3 03/09/17 20:48 1Vinyl chloride ND 4-Bromofluorobenzene (Surr)106 60 -140 03/09/17 20:48 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) - DL RL MDL Ethanol 1200 D 40 ppb v/v 03/10/17 14:09 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier RL MDL Ethanol 2400 D 75 ug/m3 03/10/17 14:09 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 4-Bromofluorobenzene (Surr)103 60 -140 03/10/17 14:09 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Lab Sample ID: 140-7345-3Client Sample ID: DUP-2017 Matrix: AirDate Collected: 03/06/17 00:00 Date Received: 03/08/17 10:10 Sample Container: Summa Canister 6L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) RL MDL 1,1,1-Trichloroethane ND 0.40 ppb v/v 03/09/17 21:35 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier TestAmerica Knoxville 03/21/2017Page 13 of 377 Client Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Lab Sample ID: 140-7345-3Client Sample ID: DUP-2017 Matrix: AirDate Collected: 03/06/17 00:00 Date Received: 03/08/17 10:10 Sample Container: Summa Canister 6L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) RL MDL 1,1,2,2-Tetrachloroethane ND 0.40 ppb v/v 03/09/17 21:35 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 0.40 ppb v/v 03/09/17 21:35 11,1,2-Trichloroethane ND 0.40 ppb v/v 03/09/17 21:35 11,1,2-Trichlorotrifluoroethane ND 0.40 ppb v/v 03/09/17 21:35 11,1-Dichloroethane ND 0.40 ppb v/v 03/09/17 21:35 11,1-Dichloroethene ND 0.40 ppb v/v 03/09/17 21:35 11,2,4-Trichlorobenzene ND 0.40 ppb v/v 03/09/17 21:35 11,2,4-Trimethylbenzene 1.2 0.40 ppb v/v 03/09/17 21:35 11,2-Dibromoethane ND 0.40 ppb v/v 03/09/17 21:35 11,2-Dichlorobenzene ND 0.40 ppb v/v 03/09/17 21:35 11,2-Dichloroethane ND 0.40 ppb v/v 03/09/17 21:35 11,2-Dichloropropane ND 0.40 ppb v/v 03/09/17 21:35 11,2-Dichlorotetrafluoroethane ND 0.40 ppb v/v 03/09/17 21:35 11,3,5-Trimethylbenzene ND 0.40 ppb v/v 03/09/17 21:35 11,3-Dichlorobenzene ND 0.40 ppb v/v 03/09/17 21:35 11,4-Dichlorobenzene ND 1.0 ppb v/v 03/09/17 21:35 11,4-Dioxane ND 1.0 ppb v/v 03/09/17 21:35 12,2,4-Trimethylpentane 1.8 1.6 ppb v/v 03/09/17 21:35 12-Butanone 3.0 1.0 ppb v/v 03/09/17 21:35 14-Methyl-2-pentanone (MIBK)ND 0.40 ppb v/v 03/09/17 21:35 1Benzene5.6 0.80 ppb v/v 03/09/17 21:35 1Benzyl chloride ND 0.40 ppb v/v 03/09/17 21:35 1BromodichloromethaneND 0.40 ppb v/v 03/09/17 21:35 1BromoformND 0.40 ppb v/v 03/09/17 21:35 1BromomethaneND 0.20 ppb v/v 03/09/17 21:35 1Carbon tetrachloride ND 0.40 ppb v/v 03/09/17 21:35 1ChlorobenzeneND 0.40 ppb v/v 03/09/17 21:35 1ChloroethaneND* 0.40 ppb v/v 03/09/17 21:35 1ChloroformND 1.0 ppb v/v 03/09/17 21:35 1Chloromethane3.7 0.40 ppb v/v 03/09/17 21:35 1cis-1,2-Dichloroethene ND 0.40 ppb v/v 03/09/17 21:35 1cis-1,3-Dichloropropene ND 1.0 ppb v/v 03/09/17 21:35 1Cyclohexane3.8 0.40 ppb v/v 03/09/17 21:35 1DibromochloromethaneND 0.40 ppb v/v 03/09/17 21:35 1Dichlorodifluoromethane0.47 10 ppb v/v 03/09/17 21:35 1Ethanol820E 0.40 ppb v/v 03/09/17 21:35 1Ethylbenzene1.5 0.40 ppb v/v 03/09/17 21:35 1HexachlorobutadieneND 1.0 ppb v/v 03/09/17 21:35 1Hexane11 0.80 ppb v/v 03/09/17 21:35 1Methyl tert-butyl ether ND 1.0 ppb v/v 03/09/17 21:35 1Methylene Chloride 44 0.40 ppb v/v 03/09/17 21:35 1m-Xylene & p-Xylene 5.8 0.40 ppb v/v 03/09/17 21:35 1o-Xylene 1.6 0.40 ppb v/v 03/09/17 21:35 1StyreneND 1.6 ppb v/v 03/09/17 21:35 1t-Butyl alcohol ND 0.40 ppb v/v 03/09/17 21:35 1TetrachloroetheneND 0.60 ppb v/v 03/09/17 21:35 1Toluene16 0.40 ppb v/v 03/09/17 21:35 1trans-1,2-Dichloroethene ND 0.40 ppb v/v 03/09/17 21:35 1trans-1,3-Dichloropropene ND TestAmerica Knoxville 03/21/2017Page 14 of 377 Client Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Lab Sample ID: 140-7345-3Client Sample ID: DUP-2017 Matrix: AirDate Collected: 03/06/17 00:00 Date Received: 03/08/17 10:10 Sample Container: Summa Canister 6L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) RL MDL Trichloroethene 0.56 0.20 ppb v/v 03/09/17 21:35 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 0.40 ppb v/v 03/09/17 21:35 1TrichlorofluoromethaneND 0.20 ppb v/v 03/09/17 21:35 1Vinyl chloride ND RL MDL 1,1,1-Trichloroethane ND 2.2 ug/m3 03/09/17 21:35 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 2.7 ug/m3 03/09/17 21:35 11,1,2,2-Tetrachloroethane ND 2.2 ug/m3 03/09/17 21:35 11,1,2-Trichloroethane ND 3.1 ug/m3 03/09/17 21:35 11,1,2-Trichlorotrifluoroethane ND 1.6 ug/m3 03/09/17 21:35 11,1-Dichloroethane ND 1.6 ug/m3 03/09/17 21:35 11,1-Dichloroethene ND 3.0 ug/m3 03/09/17 21:35 11,2,4-Trichlorobenzene ND 2.0 ug/m3 03/09/17 21:35 11,2,4-Trimethylbenzene 6.1 3.1 ug/m3 03/09/17 21:35 11,2-Dibromoethane ND 2.4 ug/m3 03/09/17 21:35 11,2-Dichlorobenzene ND 1.6 ug/m3 03/09/17 21:35 11,2-Dichloroethane ND 1.8 ug/m3 03/09/17 21:35 11,2-Dichloropropane ND 2.8 ug/m3 03/09/17 21:35 11,2-Dichlorotetrafluoroethane ND 2.0 ug/m3 03/09/17 21:35 11,3,5-Trimethylbenzene ND 2.4 ug/m3 03/09/17 21:35 11,3-Dichlorobenzene ND 2.4 ug/m3 03/09/17 21:35 11,4-Dichlorobenzene ND 3.6 ug/m3 03/09/17 21:35 11,4-Dioxane ND 4.7 ug/m3 03/09/17 21:35 12,2,4-Trimethylpentane 8.6 4.7 ug/m3 03/09/17 21:35 12-Butanone 8.8 4.1 ug/m3 03/09/17 21:35 14-Methyl-2-pentanone (MIBK)ND 1.3 ug/m3 03/09/17 21:35 1Benzene18 4.1 ug/m3 03/09/17 21:35 1Benzyl chloride ND 2.7 ug/m3 03/09/17 21:35 1BromodichloromethaneND 4.1 ug/m3 03/09/17 21:35 1BromoformND 1.6 ug/m3 03/09/17 21:35 1BromomethaneND 1.3 ug/m3 03/09/17 21:35 1Carbon tetrachloride ND 1.8 ug/m3 03/09/17 21:35 1ChlorobenzeneND 1.1 ug/m3 03/09/17 21:35 1ChloroethaneND* 2.0 ug/m3 03/09/17 21:35 1ChloroformND 2.1 ug/m3 03/09/17 21:35 1Chloromethane7.6 1.6 ug/m3 03/09/17 21:35 1cis-1,2-Dichloroethene ND 1.8 ug/m3 03/09/17 21:35 1cis-1,3-Dichloropropene ND 3.4 ug/m3 03/09/17 21:35 1Cyclohexane13 3.4 ug/m3 03/09/17 21:35 1DibromochloromethaneND 2.0 ug/m3 03/09/17 21:35 1Dichlorodifluoromethane2.3 19 ug/m3 03/09/17 21:35 1Ethanol1500E 1.7 ug/m3 03/09/17 21:35 1Ethylbenzene6.7 4.3 ug/m3 03/09/17 21:35 1HexachlorobutadieneND 3.5 ug/m3 03/09/17 21:35 1Hexane40 2.9 ug/m3 03/09/17 21:35 1Methyl tert-butyl ether ND 3.5 ug/m3 03/09/17 21:35 1Methylene Chloride 150 1.7 ug/m3 03/09/17 21:35 1m-Xylene & p-Xylene 25 1.7 ug/m3 03/09/17 21:35 1o-Xylene 7.1 1.7 ug/m3 03/09/17 21:35 1StyreneND TestAmerica Knoxville 03/21/2017Page 15 of 377 Client Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Lab Sample ID: 140-7345-3Client Sample ID: DUP-2017 Matrix: AirDate Collected: 03/06/17 00:00 Date Received: 03/08/17 10:10 Sample Container: Summa Canister 6L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) RL MDL t-Butyl alcohol ND 4.9 ug/m3 03/09/17 21:35 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 2.7 ug/m3 03/09/17 21:35 1TetrachloroetheneND 2.3 ug/m3 03/09/17 21:35 1Toluene62 1.6 ug/m3 03/09/17 21:35 1trans-1,2-Dichloroethene ND 1.8 ug/m3 03/09/17 21:35 1trans-1,3-Dichloropropene ND 1.1 ug/m3 03/09/17 21:35 1Trichloroethene3.0 2.2 ug/m3 03/09/17 21:35 1TrichlorofluoromethaneND 0.51 ug/m3 03/09/17 21:35 1Vinyl chloride ND 4-Bromofluorobenzene (Surr)106 60 -140 03/09/17 21:35 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) - DL RL MDL Ethanol 1300 D 40 ppb v/v 03/10/17 14:51 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier RL MDL Ethanol 2400 D 75 ug/m3 03/10/17 14:51 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 4-Bromofluorobenzene (Surr)103 60 -140 03/10/17 14:51 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery Lab Sample ID: 140-7345-4Client Sample ID: OA-10-2017 Matrix: AirDate Collected: 03/06/17 11:25 Date Received: 03/08/17 10:10 Sample Container: Summa Canister 6L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) RL MDL 1,1,1-Trichloroethane ND 0.080 ppb v/v 03/09/17 22:28 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 0.080 ppb v/v 03/09/17 22:28 11,1,2,2-Tetrachloroethane ND 0.080 ppb v/v 03/09/17 22:28 11,1,2-Trichloroethane ND 0.080 ppb v/v 03/09/17 22:28 11,1,2-Trichlorotrifluoroethane ND 0.080 ppb v/v 03/09/17 22:28 11,1-Dichloroethane ND 0.080 ppb v/v 03/09/17 22:28 11,1-Dichloroethene ND 0.080 ppb v/v 03/09/17 22:28 11,2,4-Trichlorobenzene ND 0.080 ppb v/v 03/09/17 22:28 11,2,4-Trimethylbenzene ND 0.080 ppb v/v 03/09/17 22:28 11,2-Dibromoethane ND 0.080 ppb v/v 03/09/17 22:28 11,2-Dichlorobenzene ND 0.080 ppb v/v 03/09/17 22:28 11,2-Dichloroethane ND 0.080 ppb v/v 03/09/17 22:28 11,2-Dichloropropane ND 0.080 ppb v/v 03/09/17 22:28 11,2-Dichlorotetrafluoroethane ND 0.080 ppb v/v 03/09/17 22:28 11,3,5-Trimethylbenzene ND 0.080 ppb v/v 03/09/17 22:28 11,3-Dichlorobenzene ND 0.080 ppb v/v 03/09/17 22:28 11,4-Dichlorobenzene ND 0.20 ppb v/v 03/09/17 22:28 11,4-Dioxane ND 0.20 ppb v/v 03/09/17 22:28 12,2,4-Trimethylpentane ND 0.32 ppb v/v 03/09/17 22:28 12-Butanone 0.52 0.20 ppb v/v 03/09/17 22:28 14-Methyl-2-pentanone (MIBK)ND 0.080 ppb v/v 03/09/17 22:28 1Benzene0.29 TestAmerica Knoxville 03/21/2017Page 16 of 377 Client Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Lab Sample ID: 140-7345-4Client Sample ID: OA-10-2017 Matrix: AirDate Collected: 03/06/17 11:25 Date Received: 03/08/17 10:10 Sample Container: Summa Canister 6L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) RL MDL Benzyl chloride ND 0.16 ppb v/v 03/09/17 22:28 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 0.080 ppb v/v 03/09/17 22:28 1BromodichloromethaneND 0.080 ppb v/v 03/09/17 22:28 1BromoformND 0.080 ppb v/v 03/09/17 22:28 1BromomethaneND 0.040 ppb v/v 03/09/17 22:28 1Carbon tetrachloride 0.076 0.080 ppb v/v 03/09/17 22:28 1ChlorobenzeneND 0.080 ppb v/v 03/09/17 22:28 1ChloroethaneND* 0.080 ppb v/v 03/09/17 22:28 1ChloroformND 0.20 ppb v/v 03/09/17 22:28 1Chloromethane0.57 0.080 ppb v/v 03/09/17 22:28 1cis-1,2-Dichloroethene ND 0.080 ppb v/v 03/09/17 22:28 1cis-1,3-Dichloropropene ND 0.20 ppb v/v 03/09/17 22:28 1CyclohexaneND 0.080 ppb v/v 03/09/17 22:28 1DibromochloromethaneND 0.080 ppb v/v 03/09/17 22:28 1Dichlorodifluoromethane0.18 2.0 ppb v/v 03/09/17 22:28 1Ethanol5.4 0.080 ppb v/v 03/09/17 22:28 1EthylbenzeneND 0.080 ppb v/v 03/09/17 22:28 1HexachlorobutadieneND 0.20 ppb v/v 03/09/17 22:28 1HexaneND 0.16 ppb v/v 03/09/17 22:28 1Methyl tert-butyl ether ND 0.20 ppb v/v 03/09/17 22:28 1Methylene Chloride 0.24 0.080 ppb v/v 03/09/17 22:28 1m-Xylene & p-Xylene 0.15 0.080 ppb v/v 03/09/17 22:28 1o-Xylene ND 0.080 ppb v/v 03/09/17 22:28 1StyreneND 0.32 ppb v/v 03/09/17 22:28 1t-Butyl alcohol ND 0.080 ppb v/v 03/09/17 22:28 1TetrachloroetheneND 0.12 ppb v/v 03/09/17 22:28 1Toluene0.31 0.080 ppb v/v 03/09/17 22:28 1trans-1,2-Dichloroethene ND 0.080 ppb v/v 03/09/17 22:28 1trans-1,3-Dichloropropene ND 0.040 ppb v/v 03/09/17 22:28 1TrichloroetheneND 0.080 ppb v/v 03/09/17 22:28 1Trichlorofluoromethane0.17 0.040 ppb v/v 03/09/17 22:28 1Vinyl chloride ND RL MDL 1,1,1-Trichloroethane ND 0.44 ug/m3 03/09/17 22:28 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 0.55 ug/m3 03/09/17 22:28 11,1,2,2-Tetrachloroethane ND 0.44 ug/m3 03/09/17 22:28 11,1,2-Trichloroethane ND 0.61 ug/m3 03/09/17 22:28 11,1,2-Trichlorotrifluoroethane ND 0.32 ug/m3 03/09/17 22:28 11,1-Dichloroethane ND 0.32 ug/m3 03/09/17 22:28 11,1-Dichloroethene ND 0.59 ug/m3 03/09/17 22:28 11,2,4-Trichlorobenzene ND 0.39 ug/m3 03/09/17 22:28 11,2,4-Trimethylbenzene ND 0.61 ug/m3 03/09/17 22:28 11,2-Dibromoethane ND 0.48 ug/m3 03/09/17 22:28 11,2-Dichlorobenzene ND 0.32 ug/m3 03/09/17 22:28 11,2-Dichloroethane ND 0.37 ug/m3 03/09/17 22:28 11,2-Dichloropropane ND 0.56 ug/m3 03/09/17 22:28 11,2-Dichlorotetrafluoroethane ND 0.39 ug/m3 03/09/17 22:28 11,3,5-Trimethylbenzene ND 0.48 ug/m3 03/09/17 22:28 11,3-Dichlorobenzene ND 0.48 ug/m3 03/09/17 22:28 11,4-Dichlorobenzene ND TestAmerica Knoxville 03/21/2017Page 17 of 377 Client Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Lab Sample ID: 140-7345-4Client Sample ID: OA-10-2017 Matrix: AirDate Collected: 03/06/17 11:25 Date Received: 03/08/17 10:10 Sample Container: Summa Canister 6L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) RL MDL 1,4-Dioxane ND 0.72 ug/m3 03/09/17 22:28 1 Analyte Dil FacAnalyzedPreparedUnitDResultQualifier 0.93 ug/m3 03/09/17 22:28 12,2,4-Trimethylpentane ND 0.94 ug/m3 03/09/17 22:28 12-Butanone 1.5 0.82 ug/m3 03/09/17 22:28 14-Methyl-2-pentanone (MIBK)ND 0.26 ug/m3 03/09/17 22:28 1Benzene0.94 0.83 ug/m3 03/09/17 22:28 1Benzyl chloride ND 0.54 ug/m3 03/09/17 22:28 1BromodichloromethaneND 0.83 ug/m3 03/09/17 22:28 1BromoformND 0.31 ug/m3 03/09/17 22:28 1BromomethaneND 0.25 ug/m3 03/09/17 22:28 1Carbon tetrachloride 0.48 0.37 ug/m3 03/09/17 22:28 1ChlorobenzeneND 0.21 ug/m3 03/09/17 22:28 1ChloroethaneND* 0.39 ug/m3 03/09/17 22:28 1ChloroformND 0.41 ug/m3 03/09/17 22:28 1Chloromethane1.2 0.32 ug/m3 03/09/17 22:28 1cis-1,2-Dichloroethene ND 0.36 ug/m3 03/09/17 22:28 1cis-1,3-Dichloropropene ND 0.69 ug/m3 03/09/17 22:28 1CyclohexaneND 0.68 ug/m3 03/09/17 22:28 1DibromochloromethaneND 0.40 ug/m3 03/09/17 22:28 1Dichlorodifluoromethane0.89 3.8 ug/m3 03/09/17 22:28 1Ethanol10 0.35 ug/m3 03/09/17 22:28 1EthylbenzeneND 0.85 ug/m3 03/09/17 22:28 1HexachlorobutadieneND 0.70 ug/m3 03/09/17 22:28 1HexaneND 0.58 ug/m3 03/09/17 22:28 1Methyl tert-butyl ether ND 0.69 ug/m3 03/09/17 22:28 1Methylene Chloride 0.82 0.35 ug/m3 03/09/17 22:28 1m-Xylene & p-Xylene 0.66 0.35 ug/m3 03/09/17 22:28 1o-Xylene ND 0.34 ug/m3 03/09/17 22:28 1StyreneND 0.97 ug/m3 03/09/17 22:28 1t-Butyl alcohol ND 0.54 ug/m3 03/09/17 22:28 1TetrachloroetheneND 0.45 ug/m3 03/09/17 22:28 1Toluene1.2 0.32 ug/m3 03/09/17 22:28 1trans-1,2-Dichloroethene ND 0.36 ug/m3 03/09/17 22:28 1trans-1,3-Dichloropropene ND 0.21 ug/m3 03/09/17 22:28 1TrichloroetheneND 0.45 ug/m3 03/09/17 22:28 1Trichlorofluoromethane0.93 0.10 ug/m3 03/09/17 22:28 1Vinyl chloride ND 4-Bromofluorobenzene (Surr)100 60 -140 03/09/17 22:28 1 Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery TestAmerica Knoxville 03/21/2017Page 18 of 377 Default Detection Limits Client: New York State D.E.C.TestAmerica Job ID: 140-7345-1 Project/Site: Sharon Cleaners # 546052 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) 0.0801,1,1-Trichloroethane ppb v/v Analyte Units MethodMDLRL 0.012 TO 15 LL 0.441,1,1-Trichloroethane ug/m30.065 TO 15 LL 0.0801,1,2,2-Tetrachloroethane ppb v/v0.024 TO 15 LL 0.551,1,2,2-Tetrachloroethane ug/m30.16 TO 15 LL 0.0801,1,2-Trichloroethane ppb v/v0.021 TO 15 LL 0.441,1,2-Trichloroethane ug/m30.11 TO 15 LL 0.0801,1,2-Trichlorotrifluoroethane ppb v/v0.012 TO 15 LL 0.611,1,2-Trichlorotrifluoroethane ug/m30.092 TO 15 LL 0.0801,1-Dichloroethane ppb v/v0.010 TO 15 LL 0.321,1-Dichloroethane ug/m30.040 TO 15 LL 0.0801,1-Dichloroethene ppb v/v0.014 TO 15 LL 0.321,1-Dichloroethene ug/m30.056 TO 15 LL 0.0801,2,4-Trichlorobenzene ppb v/v0.039 TO 15 LL 0.591,2,4-Trichlorobenzene ug/m30.29 TO 15 LL 0.0801,2,4-Trimethylbenzene ppb v/v0.025 TO 15 LL 0.391,2,4-Trimethylbenzene ug/m30.12 TO 15 LL 0.0801,2-Dibromoethane ppb v/v0.018 TO 15 LL 0.611,2-Dibromoethane ug/m30.14 TO 15 LL 0.0801,2-Dichlorobenzene ppb v/v0.028 TO 15 LL 0.481,2-Dichlorobenzene ug/m30.17 TO 15 LL 0.0801,2-Dichloroethane ppb v/v0.019 TO 15 LL 0.321,2-Dichloroethane ug/m30.077 TO 15 LL 0.0801,2-Dichloropropane ppb v/v0.021 TO 15 LL 0.371,2-Dichloropropane ug/m30.097 TO 15 LL 0.0801,2-Dichlorotetrafluoroethane ppb v/v0.013 TO 15 LL 0.561,2-Dichlorotetrafluoroethane ug/m30.091 TO 15 LL 0.0801,3,5-Trimethylbenzene ppb v/v0.026 TO 15 LL 0.391,3,5-Trimethylbenzene ug/m30.13 TO 15 LL 0.0801,3-Dichlorobenzene ppb v/v0.026 TO 15 LL 0.481,3-Dichlorobenzene ug/m30.16 TO 15 LL 0.0801,4-Dichlorobenzene ppb v/v0.026 TO 15 LL 0.481,4-Dichlorobenzene ug/m30.16 TO 15 LL 0.201,4-Dioxane ppb v/v0.032 TO 15 LL 0.721,4-Dioxane ug/m30.12 TO 15 LL 0.202,2,4-Trimethylpentane ppb v/v0.016 TO 15 LL 0.932,2,4-Trimethylpentane ug/m30.075 TO 15 LL 0.322-Butanone ppb v/v0.080 TO 15 LL 0.942-Butanone ug/m30.24 TO 15 LL 0.204-Methyl-2-pentanone (MIBK)ppb v/v0.018 TO 15 LL 0.824-Methyl-2-pentanone (MIBK)ug/m30.074 TO 15 LL 0.080Benzene ppb v/v0.023 TO 15 LL 0.26Benzene ug/m30.073 TO 15 LL 0.16Benzyl chloride ppb v/v0.031 TO 15 LL 0.83Benzyl chloride ug/m30.16 TO 15 LL 0.080Bromodichloromethane ppb v/v0.018 TO 15 LL 0.54Bromodichloromethane ug/m30.12 TO 15 LL 0.080Bromoform ppb v/v0.019 TO 15 LL 0.83Bromoform ug/m30.20 TO 15 LL 0.080Bromomethane ppb v/v0.013 TO 15 LL 0.31Bromomethane ug/m30.050 TO 15 LL 0.040Carbon tetrachloride ppb v/v0.015 TO 15 LL 0.25Carbon tetrachloride ug/m30.094 TO 15 LL TestAmerica Knoxville 03/21/2017Page 19 of 377 Default Detection Limits Client: New York State D.E.C.TestAmerica Job ID: 140-7345-1 Project/Site: Sharon Cleaners # 546052 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) 0.080Chlorobenzene ppb v/v Analyte Units MethodMDLRL 0.020 TO 15 LL 0.37Chlorobenzene ug/m30.092 TO 15 LL 0.080Chloroethane ppb v/v0.014 TO 15 LL 0.21Chloroethane ug/m30.037 TO 15 LL 0.080Chloroform ppb v/v0.015 TO 15 LL 0.39Chloroform ug/m30.073 TO 15 LL 0.20Chloromethane ppb v/v0.064 TO 15 LL 0.41Chloromethane ug/m30.13 TO 15 LL 0.080cis-1,2-Dichloroethene ppb v/v0.024 TO 15 LL 0.32cis-1,2-Dichloroethene ug/m30.095 TO 15 LL 0.080cis-1,3-Dichloropropene ppb v/v0.029 TO 15 LL 0.36cis-1,3-Dichloropropene ug/m30.13 TO 15 LL 0.20Cyclohexane ppb v/v0.016 TO 15 LL 0.69Cyclohexane ug/m30.055 TO 15 LL 0.080Dibromochloromethane ppb v/v0.017 TO 15 LL 0.68Dibromochloromethane ug/m30.14 TO 15 LL 0.080Dichlorodifluoromethane ppb v/v0.027 TO 15 LL 0.40Dichlorodifluoromethane ug/m30.13 TO 15 LL 2.0Ethanol ppb v/v0.64 TO 15 LL 3.8Ethanol ug/m31.2 TO 15 LL 0.080Ethylbenzene ppb v/v0.027 TO 15 LL 0.35Ethylbenzene ug/m30.12 TO 15 LL 0.080Hexachlorobutadiene ppb v/v0.049 TO 15 LL 0.85Hexachlorobutadiene ug/m30.52 TO 15 LL 0.20Hexane ppb v/v0.013 TO 15 LL 0.70Hexane ug/m30.046 TO 15 LL 0.16Methyl tert-butyl ether ppb v/v0.068 TO 15 LL 0.58Methyl tert-butyl ether ug/m30.25 TO 15 LL 0.20Methylene Chloride ppb v/v0.13 TO 15 LL 0.69Methylene Chloride ug/m30.45 TO 15 LL 0.080m-Xylene & p-Xylene ppb v/v0.053 TO 15 LL 0.35m-Xylene & p-Xylene ug/m30.23 TO 15 LL 0.080o-Xylene ppb v/v0.024 TO 15 LL 0.35o-Xylene ug/m30.10 TO 15 LL 0.080Styrene ppb v/v0.023 TO 15 LL 0.34Styrene ug/m30.098 TO 15 LL 0.32t-Butyl alcohol ppb v/v0.015 TO 15 LL 0.97t-Butyl alcohol ug/m30.045 TO 15 LL 0.080Tetrachloroethene ppb v/v0.016 TO 15 LL 0.54Tetrachloroethene ug/m30.11 TO 15 LL 0.12Toluene ppb v/v0.12 TO 15 LL 0.45Toluene ug/m30.45 TO 15 LL 0.080trans-1,2-Dichloroethene ppb v/v0.020 TO 15 LL 0.32trans-1,2-Dichloroethene ug/m30.079 TO 15 LL 0.080trans-1,3-Dichloropropene ppb v/v0.019 TO 15 LL 0.36trans-1,3-Dichloropropene ug/m30.086 TO 15 LL 0.040Trichloroethene ppb v/v0.014 TO 15 LL 0.21Trichloroethene ug/m30.075 TO 15 LL 0.080Trichlorofluoromethane ppb v/v0.010 TO 15 LL 0.45Trichlorofluoromethane ug/m30.056 TO 15 LL 0.040Vinyl chloride ppb v/v0.029 TO 15 LL 0.10Vinyl chloride ug/m30.074 TO 15 LL TestAmerica Knoxville 03/21/2017Page 20 of 377 Surrogate Summary TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Prep Type: Total/NAMatrix: Air Lab Sample ID Client Sample ID (60-140) BFB 113140-7345-1 Percent Surrogate Recovery (Acceptance Limits) SS-10-2017 106140-7345-2 AS-10-2017 103140-7345-2 - DL AS-10-2017 106140-7345-3 DUP-2017 103140-7345-3 - DL DUP-2017 100140-7345-4 OA-10-2017 98LCS 140-9156/1002 Lab Control Sample 107LCS 140-9158/1002 Lab Control Sample 98MB 140-9156/4 Method Blank 103MB 140-9158/4 Method Blank Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) TestAmerica Knoxville 03/21/2017Page 21 of 377 QC Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Client Sample ID: Method BlankLab Sample ID: MB 140-9156/4 Matrix: Air Prep Type: Total/NA Analysis Batch: 9156 RL MDL 1,1,1-Trichloroethane ND 0.080 ppb v/v 03/09/17 12:38 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier ND 0.080 ppb v/v 03/09/17 12:38 11,1,2,2-Tetrachloroethane ND 0.080 ppb v/v 03/09/17 12:38 11,1,2-Trichloroethane ND 0.080 ppb v/v 03/09/17 12:38 11,1,2-Trichlorotrifluoroethane ND 0.080 ppb v/v 03/09/17 12:38 11,1-Dichloroethane ND 0.080 ppb v/v 03/09/17 12:38 11,1-Dichloroethene ND 0.080 ppb v/v 03/09/17 12:38 11,2,4-Trichlorobenzene ND 0.080 ppb v/v 03/09/17 12:38 11,2,4-Trimethylbenzene ND 0.080 ppb v/v 03/09/17 12:38 11,2-Dibromoethane ND 0.080 ppb v/v 03/09/17 12:38 11,2-Dichlorobenzene ND 0.080 ppb v/v 03/09/17 12:38 11,2-Dichloroethane ND 0.080 ppb v/v 03/09/17 12:38 11,2-Dichloropropane ND 0.080 ppb v/v 03/09/17 12:38 11,2-Dichlorotetrafluoroethane ND 0.080 ppb v/v 03/09/17 12:38 11,3,5-Trimethylbenzene ND 0.080 ppb v/v 03/09/17 12:38 11,3-Dichlorobenzene ND 0.080 ppb v/v 03/09/17 12:38 11,4-Dichlorobenzene ND 0.20 ppb v/v 03/09/17 12:38 11,4-Dioxane ND 0.20 ppb v/v 03/09/17 12:38 12,2,4-Trimethylpentane ND 0.32 ppb v/v 03/09/17 12:38 12-Butanone ND 0.20 ppb v/v 03/09/17 12:38 14-Methyl-2-pentanone (MIBK) ND 0.080 ppb v/v 03/09/17 12:38 1Benzene ND 0.16 ppb v/v 03/09/17 12:38 1Benzyl chloride ND 0.080 ppb v/v 03/09/17 12:38 1Bromodichloromethane ND 0.080 ppb v/v 03/09/17 12:38 1Bromoform ND 0.080 ppb v/v 03/09/17 12:38 1Bromomethane ND 0.040 ppb v/v 03/09/17 12:38 1Carbon tetrachloride ND 0.080 ppb v/v 03/09/17 12:38 1Chlorobenzene ND 0.080 ppb v/v 03/09/17 12:38 1Chloroethane ND 0.080 ppb v/v 03/09/17 12:38 1Chloroform ND 0.20 ppb v/v 03/09/17 12:38 1Chloromethane ND 0.080 ppb v/v 03/09/17 12:38 1cis-1,2-Dichloroethene ND 0.080 ppb v/v 03/09/17 12:38 1cis-1,3-Dichloropropene ND 0.20 ppb v/v 03/09/17 12:38 1Cyclohexane ND 0.080 ppb v/v 03/09/17 12:38 1Dibromochloromethane ND 0.080 ppb v/v 03/09/17 12:38 1Dichlorodifluoromethane ND 2.0 ppb v/v 03/09/17 12:38 1Ethanol ND 0.080 ppb v/v 03/09/17 12:38 1Ethylbenzene ND 0.080 ppb v/v 03/09/17 12:38 1Hexachlorobutadiene ND 0.20 ppb v/v 03/09/17 12:38 1Hexane ND 0.16 ppb v/v 03/09/17 12:38 1Methyl tert-butyl ether ND 0.20 ppb v/v 03/09/17 12:38 1Methylene Chloride ND 0.080 ppb v/v 03/09/17 12:38 1m-Xylene & p-Xylene ND 0.080 ppb v/v 03/09/17 12:38 1o-Xylene ND 0.080 ppb v/v 03/09/17 12:38 1Styrene ND 0.32 ppb v/v 03/09/17 12:38 1t-Butyl alcohol ND 0.080 ppb v/v 03/09/17 12:38 1Tetrachloroethene ND 0.12 ppb v/v 03/09/17 12:38 1Toluene ND 0.080 ppb v/v 03/09/17 12:38 1trans-1,2-Dichloroethene TestAmerica Knoxville 03/21/2017Page 22 of 377 QC Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) Client Sample ID: Method BlankLab Sample ID: MB 140-9156/4 Matrix: Air Prep Type: Total/NA Analysis Batch: 9156 RL MDL trans-1,3-Dichloropropene ND 0.080 ppb v/v 03/09/17 12:38 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier ND 0.040 ppb v/v 03/09/17 12:38 1Trichloroethene ND 0.080 ppb v/v 03/09/17 12:38 1Trichlorofluoromethane ND 0.040 ppb v/v 03/09/17 12:38 1Vinyl chloride RL MDL 1,1,1-Trichloroethane ND 0.44 ug/m3 03/09/17 12:38 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier ND 0.55 ug/m3 03/09/17 12:38 11,1,2,2-Tetrachloroethane ND 0.44 ug/m3 03/09/17 12:38 11,1,2-Trichloroethane ND 0.61 ug/m3 03/09/17 12:38 11,1,2-Trichlorotrifluoroethane ND 0.32 ug/m3 03/09/17 12:38 11,1-Dichloroethane ND 0.32 ug/m3 03/09/17 12:38 11,1-Dichloroethene ND 0.59 ug/m3 03/09/17 12:38 11,2,4-Trichlorobenzene ND 0.39 ug/m3 03/09/17 12:38 11,2,4-Trimethylbenzene ND 0.61 ug/m3 03/09/17 12:38 11,2-Dibromoethane ND 0.48 ug/m3 03/09/17 12:38 11,2-Dichlorobenzene ND 0.32 ug/m3 03/09/17 12:38 11,2-Dichloroethane ND 0.37 ug/m3 03/09/17 12:38 11,2-Dichloropropane ND 0.56 ug/m3 03/09/17 12:38 11,2-Dichlorotetrafluoroethane ND 0.39 ug/m3 03/09/17 12:38 11,3,5-Trimethylbenzene ND 0.48 ug/m3 03/09/17 12:38 11,3-Dichlorobenzene ND 0.48 ug/m3 03/09/17 12:38 11,4-Dichlorobenzene ND 0.72 ug/m3 03/09/17 12:38 11,4-Dioxane ND 0.93 ug/m3 03/09/17 12:38 12,2,4-Trimethylpentane ND 0.94 ug/m3 03/09/17 12:38 12-Butanone ND 0.82 ug/m3 03/09/17 12:38 14-Methyl-2-pentanone (MIBK) ND 0.26 ug/m3 03/09/17 12:38 1Benzene ND 0.83 ug/m3 03/09/17 12:38 1Benzyl chloride ND 0.54 ug/m3 03/09/17 12:38 1Bromodichloromethane ND 0.83 ug/m3 03/09/17 12:38 1Bromoform ND 0.31 ug/m3 03/09/17 12:38 1Bromomethane ND 0.25 ug/m3 03/09/17 12:38 1Carbon tetrachloride ND 0.37 ug/m3 03/09/17 12:38 1Chlorobenzene ND 0.21 ug/m3 03/09/17 12:38 1Chloroethane ND 0.39 ug/m3 03/09/17 12:38 1Chloroform ND 0.41 ug/m3 03/09/17 12:38 1Chloromethane ND 0.32 ug/m3 03/09/17 12:38 1cis-1,2-Dichloroethene ND 0.36 ug/m3 03/09/17 12:38 1cis-1,3-Dichloropropene ND 0.69 ug/m3 03/09/17 12:38 1Cyclohexane ND 0.68 ug/m3 03/09/17 12:38 1Dibromochloromethane ND 0.40 ug/m3 03/09/17 12:38 1Dichlorodifluoromethane ND 3.8 ug/m3 03/09/17 12:38 1Ethanol ND 0.35 ug/m3 03/09/17 12:38 1Ethylbenzene ND 0.85 ug/m3 03/09/17 12:38 1Hexachlorobutadiene ND 0.70 ug/m3 03/09/17 12:38 1Hexane ND 0.58 ug/m3 03/09/17 12:38 1Methyl tert-butyl ether ND 0.69 ug/m3 03/09/17 12:38 1Methylene Chloride TestAmerica Knoxville 03/21/2017Page 23 of 377 QC Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) Client Sample ID: Method BlankLab Sample ID: MB 140-9156/4 Matrix: Air Prep Type: Total/NA Analysis Batch: 9156 RL MDL m-Xylene & p-Xylene ND 0.35 ug/m3 03/09/17 12:38 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier ND 0.35 ug/m3 03/09/17 12:38 1o-Xylene ND 0.34 ug/m3 03/09/17 12:38 1Styrene ND 0.97 ug/m3 03/09/17 12:38 1t-Butyl alcohol ND 0.54 ug/m3 03/09/17 12:38 1Tetrachloroethene ND 0.45 ug/m3 03/09/17 12:38 1Toluene ND 0.32 ug/m3 03/09/17 12:38 1trans-1,2-Dichloroethene ND 0.36 ug/m3 03/09/17 12:38 1trans-1,3-Dichloropropene ND 0.21 ug/m3 03/09/17 12:38 1Trichloroethene ND 0.45 ug/m3 03/09/17 12:38 1Trichlorofluoromethane ND 0.10 ug/m3 03/09/17 12:38 1Vinyl chloride 4-Bromofluorobenzene (Surr)98 60 -140 03/09/17 12:38 1 MB MB Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-9156/1002 Matrix: Air Prep Type: Total/NA Analysis Batch: 9156 1,1,1-Trichloroethane 2.00 2.02 ppb v/v 101 70 -130 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec. Limits 1,1,2,2-Tetrachloroethane 2.00 2.21 ppb v/v 110 70 -130 1,1,2-Trichloroethane 2.00 2.17 ppb v/v 109 70 -130 1,1,2-Trichlorotrifluoroethane 2.00 2.10 ppb v/v 105 70 -130 1,1-Dichloroethane 2.00 2.08 ppb v/v 104 70 -130 1,1-Dichloroethene 2.00 2.11 ppb v/v 106 70 -130 1,2,4-Trichlorobenzene 2.00 2.25 ppb v/v 112 60 -140 1,2,4-Trimethylbenzene 2.00 2.29 ppb v/v 115 70 -130 1,2-Dibromoethane 2.00 2.26 ppb v/v 113 70 -130 1,2-Dichlorobenzene 2.00 2.21 ppb v/v 110 70 -130 1,2-Dichloroethane 2.00 1.95 ppb v/v 98 70 -130 1,2-Dichloropropane 2.00 2.22 ppb v/v 111 70 -130 1,2-Dichlorotetrafluoroethane 2.00 1.95 ppb v/v 97 60 -140 1,3,5-Trimethylbenzene 2.00 2.21 ppb v/v 111 70 -130 1,3-Dichlorobenzene 2.00 2.15 ppb v/v 108 70 -130 1,4-Dichlorobenzene 2.00 2.15 ppb v/v 108 70 -130 1,4-Dioxane 2.00 2.14 ppb v/v 107 60 -140 2,2,4-Trimethylpentane 2.00 2.24 ppb v/v 112 70 -130 2-Butanone 2.00 2.14 ppb v/v 107 60 -140 4-Methyl-2-pentanone (MIBK)2.00 2.45 ppb v/v 122 60 -140 Benzene 2.00 2.11 ppb v/v 106 70 -130 Benzyl chloride 2.00 2.40 ppb v/v 120 70 -130 Bromodichloromethane 2.00 2.12 ppb v/v 106 70 -130 Bromoform 2.00 2.17 ppb v/v 109 60 -140 Bromomethane 2.00 1.47 ppb v/v 73 70 -130 Carbon tetrachloride 2.00 1.99 ppb v/v 99 70 -130 Chlorobenzene 2.00 2.11 ppb v/v 105 70 -130 TestAmerica Knoxville 03/21/2017Page 24 of 377 QC Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-9156/1002 Matrix: Air Prep Type: Total/NA Analysis Batch: 9156 Chloroethane 2.00 1.36 *ppb v/v 68 70 -130 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec. Limits Chloroform 2.00 2.02 ppb v/v 101 70 -130 Chloromethane 2.00 2.21 ppb v/v 111 60 -140 cis-1,2-Dichloroethene 2.00 2.12 ppb v/v 106 70 -130 cis-1,3-Dichloropropene 2.00 2.24 ppb v/v 112 70 -130 Cyclohexane 2.00 2.24 ppb v/v 112 70 -130 Dibromochloromethane 2.00 2.36 ppb v/v 118 70 -130 Dichlorodifluoromethane 2.00 1.55 ppb v/v 77 60 -140 Ethanol 10.0 6.84 ppb v/v 68 60 -140 Ethylbenzene 2.00 2.22 ppb v/v 111 70 -130 Hexachlorobutadiene 2.00 2.12 ppb v/v 106 60 -140 Hexane 2.00 2.08 ppb v/v 104 70 -130 Methyl tert-butyl ether 2.00 2.09 ppb v/v 104 60 -140 Methylene Chloride 2.00 1.99 ppb v/v 100 70 -130 m-Xylene & p-Xylene 4.00 4.58 ppb v/v 114 70 -130 o-Xylene 2.00 2.17 ppb v/v 108 70 -130 Styrene 2.00 2.46 ppb v/v 123 70 -130 t-Butyl alcohol 2.00 2.02 ppb v/v 101 60 -140 Tetrachloroethene 2.00 2.17 ppb v/v 109 70 -130 Toluene 2.00 2.24 ppb v/v 112 70 -130 trans-1,2-Dichloroethene 2.00 2.13 ppb v/v 107 70 -130 trans-1,3-Dichloropropene 2.00 2.22 ppb v/v 111 70 -130 Trichloroethene 2.00 2.07 ppb v/v 104 70 -130 Trichlorofluoromethane 2.00 1.71 ppb v/v 85 60 -140 Vinyl chloride 2.00 1.90 ppb v/v 95 70 -130 1,1,1-Trichloroethane 11 11.0 ug/m3 101 70 -130 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec. Limits 1,1,2,2-Tetrachloroethane 14 15.1 ug/m3 110 70 -130 1,1,2-Trichloroethane 11 11.9 ug/m3 109 70 -130 1,1,2-Trichlorotrifluoroethane 15 16.1 ug/m3 105 70 -130 1,1-Dichloroethane 8.1 8.40 ug/m3 104 70 -130 1,1-Dichloroethene 7.9 8.38 ug/m3 106 70 -130 1,2,4-Trichlorobenzene 15 16.7 ug/m3 112 60 -140 1,2,4-Trimethylbenzene 9.8 11.3 ug/m3 115 70 -130 1,2-Dibromoethane 15 17.4 ug/m3 113 70 -130 1,2-Dichlorobenzene 12 13.3 ug/m3 110 70 -130 1,2-Dichloroethane 8.1 7.91 ug/m3 98 70 -130 1,2-Dichloropropane 9.2 10.3 ug/m3 111 70 -130 1,2-Dichlorotetrafluoroethane 14 13.6 ug/m3 97 60 -140 1,3,5-Trimethylbenzene 9.8 10.9 ug/m3 111 70 -130 1,3-Dichlorobenzene 12 12.9 ug/m3 108 70 -130 1,4-Dichlorobenzene 12 12.9 ug/m3 108 70 -130 1,4-Dioxane 7.2 7.73 ug/m3 107 60 -140 2,2,4-Trimethylpentane 9.3 10.5 ug/m3 112 70 -130 2-Butanone 5.9 6.31 ug/m3 107 60 -140 4-Methyl-2-pentanone (MIBK)8.2 10.0 ug/m3 122 60 -140 TestAmerica Knoxville 03/21/2017Page 25 of 377 QC Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-9156/1002 Matrix: Air Prep Type: Total/NA Analysis Batch: 9156 Benzene 6.4 6.75 ug/m3 106 70 -130 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec. Limits Benzyl chloride 10 12.4 ug/m3 120 70 -130 Bromodichloromethane 13 14.2 ug/m3 106 70 -130 Bromoform 21 22.5 ug/m3 109 60 -140 Bromomethane 7.8 5.71 ug/m3 73 70 -130 Carbon tetrachloride 13 12.5 ug/m3 99 70 -130 Chlorobenzene 9.2 9.70 ug/m3 105 70 -130 Chloroethane 5.3 3.60 *ug/m3 68 70 -130 Chloroform 9.8 9.84 ug/m3 101 70 -130 Chloromethane 4.1 4.57 ug/m3 111 60 -140 cis-1,2-Dichloroethene 7.9 8.40 ug/m3 106 70 -130 cis-1,3-Dichloropropene 9.1 10.1 ug/m3 112 70 -130 Cyclohexane 6.9 7.71 ug/m3 112 70 -130 Dibromochloromethane 17 20.1 ug/m3 118 70 -130 Dichlorodifluoromethane 9.9 7.65 ug/m3 77 60 -140 Ethanol 19 12.9 ug/m3 68 60 -140 Ethylbenzene 8.7 9.65 ug/m3 111 70 -130 Hexachlorobutadiene 21 22.6 ug/m3 106 60 -140 Hexane 7.1 7.34 ug/m3 104 70 -130 Methyl tert-butyl ether 7.2 7.54 ug/m3 104 60 -140 Methylene Chloride 7.0 6.93 ug/m3 100 70 -130 m-Xylene & p-Xylene 17 19.9 ug/m3 114 70 -130 o-Xylene 8.7 9.42 ug/m3 108 70 -130 Styrene 8.5 10.5 ug/m3 123 70 -130 t-Butyl alcohol 6.1 6.11 ug/m3 101 60 -140 Tetrachloroethene 14 14.7 ug/m3 109 70 -130 Toluene 7.5 8.45 ug/m3 112 70 -130 trans-1,2-Dichloroethene 7.9 8.45 ug/m3 107 70 -130 trans-1,3-Dichloropropene 9.1 10.1 ug/m3 111 70 -130 Trichloroethene 11 11.1 ug/m3 104 70 -130 Trichlorofluoromethane 11 9.60 ug/m3 85 60 -140 Vinyl chloride 5.1 4.85 ug/m3 95 70 -130 4-Bromofluorobenzene (Surr)60 -140 Surrogate 98 LCS LCS Qualifier Limits%Recovery Client Sample ID: Method BlankLab Sample ID: MB 140-9158/4 Matrix: Air Prep Type: Total/NA Analysis Batch: 9158 RL MDL Ethanol ND 2.0 ppb v/v 03/10/17 10:04 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier RL MDL Ethanol ND 3.8 ug/m3 03/10/17 10:04 1 MB MB Analyte Dil FacAnalyzedPreparedDUnitResultQualifier TestAmerica Knoxville 03/21/2017Page 26 of 377 QC Sample Results TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) (Continued) Client Sample ID: Method BlankLab Sample ID: MB 140-9158/4 Matrix: Air Prep Type: Total/NA Analysis Batch: 9158 4-Bromofluorobenzene (Surr)103 60 -140 03/10/17 10:04 1 MB MB Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-9158/1002 Matrix: Air Prep Type: Total/NA Analysis Batch: 9158 Ethanol 10.0 10.5 ppb v/v 105 60 -140 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec. Limits Ethanol 19 19.8 ug/m3 105 60 -140 Analyte LCS LCS DUnitResultQualifier %Rec Spike Added %Rec. Limits 4-Bromofluorobenzene (Surr)60 -140 Surrogate 107 LCS LCS Qualifier Limits%Recovery TestAmerica Knoxville 03/21/2017Page 27 of 377 QC Association Summary TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Air - GC/MS VOA Analysis Batch: 9156 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Air TO 15 LL140-7345-1 SS-10-2017 Total/NA Air TO 15 LL140-7345-2 AS-10-2017 Total/NA Air TO 15 LL140-7345-3 DUP-2017 Total/NA Air TO 15 LL140-7345-4 OA-10-2017 Total/NA Air TO 15 LLMB 140-9156/4 Method Blank Total/NA Air TO 15 LLLCS 140-9156/1002 Lab Control Sample Total/NA Analysis Batch: 9158 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Air TO 15 LL140-7345-2 - DL AS-10-2017 Total/NA Air TO 15 LL140-7345-3 - DL DUP-2017 Total/NA Air TO 15 LLMB 140-9158/4 Method Blank Total/NA Air TO 15 LLLCS 140-9158/1002 Lab Control Sample Total/NA TestAmerica Knoxville 03/21/2017Page 28 of 377 Lab Chronicle Client: New York State D.E.C.TestAmerica Job ID: 140-7345-1 Project/Site: Sharon Cleaners # 546052 Client Sample ID: SS-10-2017 Lab Sample ID: 140-7345-1 Matrix: AirDate Collected: 03/06/17 11:10 Date Received: 03/08/17 10:10 Analysis TO 15 LL HMT03/09/17 20:001 TAL KNX9156 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 50 mL 500 mL MRInstrument ID: Client Sample ID: AS-10-2017 Lab Sample ID: 140-7345-2 Matrix: AirDate Collected: 03/06/17 11:10 Date Received: 03/08/17 10:10 Analysis TO 15 LL HMT03/10/17 14:091DL TAL KNX9158 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 25 mL 500 mL MGInstrument ID: Analysis TO 15 LL 1 9156 03/09/17 20:48 HMT TAL KNXTotal/NA 100 mL 500 mL MRInstrument ID: Client Sample ID: DUP-2017 Lab Sample ID: 140-7345-3 Matrix: AirDate Collected: 03/06/17 00:00 Date Received: 03/08/17 10:10 Analysis TO 15 LL HMT03/10/17 14:511DL TAL KNX9158 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 25 mL 500 mL MGInstrument ID: Analysis TO 15 LL 1 9156 03/09/17 21:35 HMT TAL KNXTotal/NA 100 mL 500 mL MRInstrument ID: Client Sample ID: OA-10-2017 Lab Sample ID: 140-7345-4 Matrix: AirDate Collected: 03/06/17 11:25 Date Received: 03/08/17 10:10 Analysis TO 15 LL HMT03/09/17 22:281 TAL KNX9156 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 500 mL 500 mL MRInstrument ID: Client Sample ID: Method Blank Lab Sample ID: MB 140-9156/4 Matrix: AirDate Collected: N/A Date Received: N/A Analysis TO 15 LL HMT03/09/17 12:381 TAL KNX9156 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 500 mL 500 mL MRInstrument ID: TestAmerica Knoxville 03/21/2017Page 29 of 377 Lab Chronicle Client: New York State D.E.C.TestAmerica Job ID: 140-7345-1 Project/Site: Sharon Cleaners # 546052 Client Sample ID: Method Blank Lab Sample ID: MB 140-9158/4 Matrix: AirDate Collected: N/A Date Received: N/A Analysis TO 15 LL HMT03/10/17 10:041 TAL KNX9158 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 500 mL 500 mL MGInstrument ID: Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-9156/1002 Matrix: AirDate Collected: N/A Date Received: N/A Analysis TO 15 LL HMT03/09/17 09:421 TAL KNX9156 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 500 mL 500 mL MRInstrument ID: Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-9158/1002 Matrix: AirDate Collected: N/A Date Received: N/A Analysis TO 15 LL HMT03/10/17 08:211 TAL KNX9158 Type Batch Method Batch Prep Type LabAnalystRun Prepared or Analyzed Initial Amount Amount Final Batch NumberFactor Dil Total/NA 500 mL 500 mL MGInstrument ID: Laboratory References: TAL KNX = TestAmerica Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000 TestAmerica Knoxville 03/21/2017Page 30 of 377 Certification Summary Client: New York State D.E.C.TestAmerica Job ID: 140-7345-1 Project/Site: Sharon Cleaners # 546052 Laboratory: TestAmerica Knoxville Unless otherwise noted, all analytes for this laboratory were covered under each certification below. Authority Program EPA Region Certification ID Expiration Date New York 107812NELAP 03-31-17 Analysis Method Prep Method Matrix Analyte The following analytes are included in this report, but are not certified under this certification: TO 15 LL Air 1,1,2-Trichlorotrifluoroethane TO 15 LL Air 1,2,4-Trimethylbenzene TO 15 LL Air 1,2-Dichlorotetrafluoroethane TO 15 LL Air 1,3,5-Trimethylbenzene TO 15 LL Air Dichlorodifluoromethane TO 15 LL Air o-Xylene TO 15 LL Air Trichlorofluoromethane Analysis Method Prep Method Matrix Analyte The following analytes are included in this report, but certification is not offered by the governing authority: TO 15 LL Air Ethanol TestAmerica Knoxville 03/21/2017Page 31 of 377 Method Summary TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Method Method Description LaboratoryProtocol EPATO 15 LL Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS)TAL KNX Protocol References: EPA = US Environmental Protection Agency Laboratory References: TAL KNX = TestAmerica Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000 TestAmerica Knoxville 03/21/2017Page 32 of 377 Sample Summary TestAmerica Job ID: 140-7345-1Client: New York State D.E.C. Project/Site: Sharon Cleaners # 546052 Lab Sample ID Client Sample ID ReceivedCollectedMatrix 140-7345-1 SS-10-2017 Air 03/06/17 11:10 03/08/17 10:10 140-7345-2 AS-10-2017 Air 03/06/17 11:10 03/08/17 10:10 140-7345-3 DUP-2017 Air 03/06/17 00:00 03/08/17 10:10 140-7345-4 OA-10-2017 Air 03/06/17 11:25 03/08/17 10:10 TestAmerica Knoxville 03/21/2017Page 33 of 377 Method TO15 Low Level Volatile Organic Compounds - Low level (GC/MS) by Method TO 15 03/21/2017Page 34 of 377 FORM II AIR - GC/MS VOA SURROGATE RECOVERY Lab Name:Job No.:140-7345-1 SDG No.: Matrix:Air Level:Low TestAmerica Knoxville GC Column (1):RTX-5 ID:0.32(mm) Lab Sample IDClient Sample ID #BFB 140-7345-1SS-10-2017 113 140-7345-2AS-10-2017 106 140-7345-2 DLAS-10-2017 DL 103 140-7345-3DUP-2017 106 140-7345-3 DLDUP-2017 DL 103 140-7345-4OA-10-2017 100 MB 140-9156/4 98 MB 140-9158/4 103 LCS 140-9156/1002 98 LCS 140-9158/1002 107 QC LIMITS BFB = 4-Bromofluorobenzene (Surr)60-140 FORM II TO 15 LL # Column to be used to flag recovery values 03/21/2017Page 35 of 377 AIR - GC/MS VOA LAB CONTROL SAMPLE RECOVERY FORM III Job No.:Lab Name: SDG No.: Level:Matrix:Low 140-7345-1 Lab File ID:RC09CCV-LCS.dAir Lab ID:LCS 140-9156/1002 Client ID: TestAmerica Knoxville REC % REC QC LIMITSCONCENTRATION (ppb v/v) SPIKE ADDED (ppb v/v) # LCS LCS COMPOUND 1,1,1-Trichloroethane 2.00 2.02 70-130101 1,1,2,2-Tetrachloroethane 2.00 2.21 70-130110 1,1,2-Trichloroethane 2.00 2.17 70-130109 1,1,2-Trichlorotrifluoroethane 2.00 2.10 70-130105 1,1-Dichloroethane 2.00 2.08 70-130104 1,1-Dichloroethene 2.00 2.11 70-130106 1,2,4-Trichlorobenzene 2.00 2.25 60-140112 1,2,4-Trimethylbenzene 2.00 2.29 70-130115 1,2-Dibromoethane 2.00 2.26 70-130113 1,2-Dichlorobenzene 2.00 2.21 70-130110 1,2-Dichloroethane 2.00 1.95 70-13098 1,2-Dichloropropane 2.00 2.22 70-130111 1,2-Dichlorotetrafluoroethane 2.00 1.95 60-14097 1,3,5-Trimethylbenzene 2.00 2.21 70-130111 1,3-Dichlorobenzene 2.00 2.15 70-130108 1,4-Dichlorobenzene 2.00 2.15 70-130108 1,4-Dioxane 2.00 2.14 60-140107 2,2,4-Trimethylpentane 2.00 2.24 70-130112 2-Butanone 2.00 2.14 60-140107 4-Methyl-2-pentanone (MIBK)2.00 2.45 60-140122 Benzene 2.00 2.11 70-130106 Benzyl chloride 2.00 2.40 70-130120 Bromodichloromethane 2.00 2.12 70-130106 Bromoform 2.00 2.17 60-140109 Bromomethane 2.00 1.47 70-13073 Carbon tetrachloride 2.00 1.99 70-13099 Chlorobenzene 2.00 2.11 70-130105 Chloroethane 2.00 1.36 70-13068 * Chloroform 2.00 2.02 70-130101 Chloromethane 2.00 2.21 60-140111 cis-1,2-Dichloroethene 2.00 2.12 70-130106 cis-1,3-Dichloropropene 2.00 2.24 70-130112 Cyclohexane 2.00 2.24 70-130112 Dibromochloromethane 2.00 2.36 70-130118 Dichlorodifluoromethane 2.00 1.55 60-14077 Ethanol 10.0 6.84 60-14068 Ethylbenzene 2.00 2.22 70-130111 Hexachlorobutadiene 2.00 2.12 60-140106 Hexane 2.00 2.08 70-130104 Methyl tert-butyl ether 2.00 2.09 60-140104 Methylene Chloride 2.00 1.99 70-130100 m-Xylene & p-Xylene 4.00 4.58 70-130114 FORM III TO 15 LL # Column to be used to flag recovery and RPD values 03/21/2017Page 36 of 377 AIR - GC/MS VOA LAB CONTROL SAMPLE RECOVERY FORM III Job No.:Lab Name: SDG No.: Level:Matrix:Low 140-7345-1 Lab File ID:RC09CCV-LCS.dAir Lab ID:LCS 140-9156/1002 Client ID: TestAmerica Knoxville REC % REC QC LIMITSCONCENTRATION (ppb v/v) SPIKE ADDED (ppb v/v) # LCS LCS COMPOUND o-Xylene 2.00 2.17 70-130108 Styrene 2.00 2.46 70-130123 t-Butyl alcohol 2.00 2.02 60-140101 Tetrachloroethene 2.00 2.17 70-130109 Toluene 2.00 2.24 70-130112 trans-1,2-Dichloroethene 2.00 2.13 70-130107 trans-1,3-Dichloropropene 2.00 2.22 70-130111 Trichloroethene 2.00 2.07 70-130104 Trichlorofluoromethane 2.00 1.71 60-14085 Vinyl chloride 2.00 1.90 70-13095 FORM III TO 15 LL # Column to be used to flag recovery and RPD values 03/21/2017Page 37 of 377 AIR - GC/MS VOA LAB CONTROL SAMPLE RECOVERY FORM III Job No.:Lab Name: SDG No.: Level:Matrix:Low 140-7345-1 Lab File ID:GCCVC10-LCS.dAir Lab ID:LCS 140-9158/1002 Client ID: TestAmerica Knoxville REC % REC QC LIMITSCONCENTRATION (ppb v/v) SPIKE ADDED (ppb v/v) # LCS LCS COMPOUND Ethanol 10.0 10.5 60-140105 FORM III TO 15 LL # Column to be used to flag recovery and RPD values 03/21/2017Page 38 of 377 FORM IV AIR - GC/MS VOA METHOD BLANK SUMMARY Lab Name: SDG No.: Job No.:140-7345-1TestAmerica Knoxville Date Analyzed: GC Column:ID: Instrument ID:03/10/2017 10:04 RTX-5 NHeated Purge:(Y/N) MG GMB500C10.DLab File ID:Lab Sample ID:MB 140-9158/4 AirMatrix: 0.32(mm) THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES: LAB SAMPLE ID LAB FILE ID DATE ANALYZEDCLIENT SAMPLE ID 03/10/2017 08:21GCCVC10-LCS .d LCS 140-9158/1002 03/10/2017 14:09GC10P104.D140-7345-2 DLAS-10-2017 DL 03/10/2017 14:51GC10P105.D140-7345-3 DLDUP-2017 DL FORM IV TO 15 LL 03/21/2017Page 39 of 377 FORM IV AIR - GC/MS VOA METHOD BLANK SUMMARY Lab Name: SDG No.: Job No.:140-7345-1TestAmerica Knoxville Date Analyzed: GC Column:ID: Instrument ID:03/09/2017 12:38 RTX-5 NHeated Purge:(Y/N) MR RC09BLK.DLab File ID:Lab Sample ID:MB 140-9156/4 AirMatrix: 0.32(mm) THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES: LAB SAMPLE ID LAB FILE ID DATE ANALYZEDCLIENT SAMPLE ID 03/09/2017 09:42RC09CCV-LCS .d LCS 140-9156/1002 03/09/2017 20:00RC09P107.D140-7345-1SS-10-2017 03/09/2017 20:48RC09P108.D140-7345-2AS-10-2017 03/09/2017 21:35RC09P109.D140-7345-3DUP-2017 03/09/2017 22:28RC09P110.D140-7345-4OA-10-2017 FORM IV TO 15 LL 03/21/2017Page 40 of 377 FORM V Lab Name: SDG No.: Job No.:140-7345-1 Lab File ID: Instrument ID: GBFBC02.D MG 03/02/2017 12:22 BFB Injection Date: BFB Injection Time: M/E ION ABUNDANCE CRITERIA % RELATIVE ABUNDANCE Analysis Batch No.:9079 50 15.0 - 40.0 % of mass 95 18.4 75 30.0 - 60.0 % of mass 95 55.3 95 Base Peak, 100% relative abundance 100.0 96 5.0 - 9.0 % of mass 95 6.8 173 Less than 2.0 % of mass 174 0.5 (0.6)1 174 50.0 - 120.00 % of mass 95 90.3 175 5.0 - 9.0 % of mass 174 6.1 (6.8)1 176 95.0 - 101.0 % of mass 174 87.4 (96.7)1 177 5.0 - 9.0 % of mass 176 5.5 (6.3)2 1-Value is % mass 174 THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS: 2-Value is % mass 176 AIR - GC/MS VOA INSTRUMENT PERFORMANCE CHECK TestAmerica Knoxville CLIENT SAMPLE ID LAB FILE IDLAB SAMPLE ID DATE ANALYZED TIME ANALYZED GC02IC01.D 03/02/2017 13:34IC 140-9079/3 GC02IC03.D 03/02/2017 14:57IC 140-9079/5 GC02IC04.D 03/02/2017 15:39IC 140-9079/6 GC02IC05.D 03/02/2017 16:20IC 140-9079/7 GC02IC06.D 03/02/2017 17:02ICIS 140-9079/8 GC02IC07.D 03/02/2017 17:44IC 140-9079/9 GC02IC08.D 03/02/2017 18:26IC 140-9079/10 GC02IC09.D 03/02/2017 19:08IC 140-9079/11 GC02IC02R.D 03/02/2017 20:31IC 140-9079/20 GLCSC02.D 03/02/2017 23:17ICV 140-9079/15 FORM V TO 15 LL 03/21/2017Page 41 of 377 FORM V Lab Name: SDG No.: Job No.:140-7345-1 Lab File ID: Instrument ID: GBFBC10.D MG 03/10/2017 07:50 BFB Injection Date: BFB Injection Time: M/E ION ABUNDANCE CRITERIA % RELATIVE ABUNDANCE Analysis Batch No.:9158 50 15.0 - 40.0 % of mass 95 18.6 75 30.0 - 60.0 % of mass 95 55.4 95 Base Peak, 100% relative abundance 100.0 96 5.0 - 9.0 % of mass 95 7.0 173 Less than 2.0 % of mass 174 0.4 (0.5)1 174 50.0 - 120.00 % of mass 95 88.2 175 5.0 - 9.0 % of mass 174 6.1 (6.9)1 176 95.0 - 101.0 % of mass 174 85.2 (96.6)1 177 5.0 - 9.0 % of mass 176 5.4 (6.4)2 1-Value is % mass 174 THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS: 2-Value is % mass 176 AIR - GC/MS VOA INSTRUMENT PERFORMANCE CHECK TestAmerica Knoxville CLIENT SAMPLE ID LAB FILE IDLAB SAMPLE ID DATE ANALYZED TIME ANALYZED GCCVC10.D 03/10/2017 08:21CCVIS 140-9158/2 GCCVC10-LCS. d 03/10/2017 08:21LCS 140-9158/1002 GMB500C10.D 03/10/2017 10:04MB 140-9158/4 AS-10-2017 DL GC10P104.D 03/10/2017 14:09140-7345-2 DL DUP-2017 DL GC10P105.D 03/10/2017 14:51140-7345-3 DL FORM V TO 15 LL 03/21/2017Page 42 of 377 FORM V Lab Name: SDG No.: Job No.:140-7345-1 Lab File ID: Instrument ID: RXBFBB23.D MR 02/23/2017 21:41 BFB Injection Date: BFB Injection Time: M/E ION ABUNDANCE CRITERIA % RELATIVE ABUNDANCE Analysis Batch No.:8740 50 15.0 - 40.0 % of mass 95 23.3 75 30.0 - 60.0 % of mass 95 48.6 95 Base Peak, 100% relative abundance 100.0 96 5.0 - 9.0 % of mass 95 6.4 173 Less than 2.0 % of mass 174 0.7 (0.7)1 174 50.0 - 120.00 % of mass 95 101.5 175 5.0 - 9.0 % of mass 174 6.8 (6.7)1 176 95.0 - 101.0 % of mass 174 98.2 (96.8)1 177 5.0 - 9.0 % of mass 176 6.2 (6.3)2 1-Value is % mass 174 THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS: 2-Value is % mass 176 AIR - GC/MS VOA INSTRUMENT PERFORMANCE CHECK TestAmerica Knoxville CLIENT SAMPLE ID LAB FILE IDLAB SAMPLE ID DATE ANALYZED TIME ANALYZED RB23IC01.D 02/23/2017 22:59IC 140-8740/3 RB23IC02.D 02/23/2017 23:47IC 140-8740/4 RB23IC03.D 02/24/2017 00:35IC 140-8740/5 RB23IC04.D 02/24/2017 01:23IC 140-8740/6 RB23IC05.D 02/24/2017 02:09IC 140-8740/7 RB23IC06.D 02/24/2017 02:57ICIS 140-8740/8 RB23IC07.D 02/24/2017 03:45IC 140-8740/9 RB23IC08.D 02/24/2017 04:33IC 140-8740/10 RB23IC09.D 02/24/2017 05:21IC 140-8740/11 RB23LCS.D 02/24/2017 09:49ICV 140-8740/17 FORM V TO 15 LL 03/21/2017Page 43 of 377 FORM V Lab Name: SDG No.: Job No.:140-7345-1 Lab File ID: Instrument ID: RC09BFB.D MR 03/09/2017 09:10 BFB Injection Date: BFB Injection Time: M/E ION ABUNDANCE CRITERIA % RELATIVE ABUNDANCE Analysis Batch No.:9156 50 15.0 - 40.0 % of mass 95 22.0 75 30.0 - 60.0 % of mass 95 46.7 95 Base Peak, 100% relative abundance 100.0 96 5.0 - 9.0 % of mass 95 6.8 173 Less than 2.0 % of mass 174 0.5 (0.6)1 174 50.0 - 120.00 % of mass 95 97.9 175 5.0 - 9.0 % of mass 174 7.1 (7.3)1 176 95.0 - 101.0 % of mass 174 95.2 (97.2)1 177 5.0 - 9.0 % of mass 176 6.3 (6.6)2 1-Value is % mass 174 THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS AND STANDARDS: 2-Value is % mass 176 AIR - GC/MS VOA INSTRUMENT PERFORMANCE CHECK TestAmerica Knoxville CLIENT SAMPLE ID LAB FILE IDLAB SAMPLE ID DATE ANALYZED TIME ANALYZED RC09CCV.D 03/09/2017 09:42CCVIS 140-9156/2 RC09CCV-LCS. d 03/09/2017 09:42LCS 140-9156/1002 RC09BLK.D 03/09/2017 12:38MB 140-9156/4 SS-10-2017 RC09P107.D 03/09/2017 20:00140-7345-1 AS-10-2017 RC09P108.D 03/09/2017 20:48140-7345-2 DUP-2017 RC09P109.D 03/09/2017 21:35140-7345-3 OA-10-2017 RC09P110.D 03/09/2017 22:28140-7345-4 FORM V TO 15 LL 03/21/2017Page 44 of 377 AIR - GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY Lab Name:Job No.: SDG No.: FORM VIII TestAmerica Knoxville 140-7345-1 Sample No.:ICIS 140-9079/8 Date Analyzed:03/02/2017 17:02 Lab File ID (Standard):GC02IC06.D Instrument ID:MG GC Column:RTX-5 ID:0.32(mm) Heated Purge: (Y/N)N Calibration ID:934 #RT #RT ##RT ## CBM DFBZ CBZd5 AREA AREA AREA UPPER LIMIT LOWER LIMIT 555828 238212 1197214 2793500 1228615 2866767 8.01 10.18 15.04INITIAL CALIBRATION MID-POINT 8.34 7.68 10.51 9.85 15.37 14.71 397020 1995357 2047691 LAB SAMPLE ID CLIENT SAMPLE ID ICV 140-9079/15 386596 1963711 2019239 8.01 10.18 15.04 CBM = Chlorobromomethane (IS) DFBZ = 1,4-Difluorobenzene CBZd5 = Chlorobenzene-d5 (IS) Area Limit = 60%-140% of internal standard area RT Limit = ± 0.33 minutes of internal standard RT # Column used to flag values outside QC limits FORM VIII TO 15 LL 03/21/2017Page 45 of 377 AIR - GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY Lab Name:Job No.: SDG No.: FORM VIII TestAmerica Knoxville 140-7345-1 Sample No.:CCVIS 140-9158/2 Date Analyzed:03/10/2017 08:21 Lab File ID (Standard):GCCVC10.D Instrument ID:MG GC Column:RTX-5 ID:0.32(mm) Heated Purge: (Y/N)N Calibration ID:934 #RT #RT ##RT ## CBM DFBZ CBZd5 AREA AREA AREA UPPER LIMIT LOWER LIMIT 398145 170633 884626 2064128 883847 2062311 8.00 10.17 15.0412/24 HOUR STD 8.33 7.67 10.50 9.84 15.37 14.71 284389 1474377 1473079 LAB SAMPLE ID CLIENT SAMPLE ID LCS 140-9158/1002 284389 1474377 1473079 8.00 10.17 15.04 MB 140-9158/4 280896 1418032 1398041 7.99 10.16 15.03 140-7345-2 DL AS-10-2017 DL 288463 1340420 1361295 7.99 10.16 15.03 140-7345-3 DL DUP-2017 DL 300843 1427589 1440175 8.00 10.17 15.04 CBM = Chlorobromomethane (IS) DFBZ = 1,4-Difluorobenzene CBZd5 = Chlorobenzene-d5 (IS) Area Limit = 60%-140% of internal standard area RT Limit = ± 0.33 minutes of internal standard RT # Column used to flag values outside QC limits FORM VIII TO 15 LL 03/21/2017Page 46 of 377 AIR - GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY Lab Name:Job No.: SDG No.: FORM VIII TestAmerica Knoxville 140-7345-1 Sample No.:ICIS 140-8740/8 Date Analyzed:02/24/2017 02:57 Lab File ID (Standard):RB23IC06.D Instrument ID:MR GC Column:RTX-5 ID:0.32(mm) Heated Purge: (Y/N)N Calibration ID:919 #RT #RT ##RT ## CBM DFBZ CBZd5 AREA AREA AREA UPPER LIMIT LOWER LIMIT 581122 249052 1216870 2839362 986252 2301256 8.23 10.39 15.28INITIAL CALIBRATION MID-POINT 8.56 7.90 10.72 10.06 15.61 14.95 415087 2028116 1643754 LAB SAMPLE ID CLIENT SAMPLE ID ICV 140-8740/17 429501 2158241 1765346 8.23 10.39 15.28 CBM = Chlorobromomethane (IS) DFBZ = 1,4-Difluorobenzene CBZd5 = Chlorobenzene-d5 (IS) Area Limit = 60%-140% of internal standard area RT Limit = ± 0.33 minutes of internal standard RT # Column used to flag values outside QC limits FORM VIII TO 15 LL 03/21/2017Page 47 of 377 AIR - GC/MS VOA INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY Lab Name:Job No.: SDG No.: FORM VIII TestAmerica Knoxville 140-7345-1 Sample No.:CCVIS 140-9156/2 Date Analyzed:03/09/2017 09:42 Lab File ID (Standard):RC09CCV.D Instrument ID:MR GC Column:RTX-5 ID:0.32(mm) Heated Purge: (Y/N)N Calibration ID:919 #RT #RT ##RT ## CBM DFBZ CBZd5 AREA AREA AREA UPPER LIMIT LOWER LIMIT 555639 238131 1163302 2714372 936176 2184412 8.22 10.38 15.2712/24 HOUR STD 8.55 7.89 10.71 10.05 15.60 14.94 396885 1938837 1560294 LAB SAMPLE ID CLIENT SAMPLE ID LCS 140-9156/1002 396885 1938837 1560294 8.22 10.38 15.27 MB 140-9156/4 436115 2108497 1621976 8.20 10.37 15.27 140-7345-1 SS-10-2017 456214 2213338 1698973 8.21 10.38 15.27 140-7345-2 AS-10-2017 438724 2126996 1642109 8.22 10.38 15.27 140-7345-3 DUP-2017 435909 2100341 1672298 8.21 10.37 15.27 140-7345-4 OA-10-2017 420420 2052213 1564423 8.20 10.37 15.27 CBM = Chlorobromomethane (IS) DFBZ = 1,4-Difluorobenzene CBZd5 = Chlorobenzene-d5 (IS) Area Limit = 60%-140% of internal standard area RT Limit = ± 0.33 minutes of internal standard RT # Column used to flag values outside QC limits FORM VIII TO 15 LL 03/21/2017Page 48 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: SS-10-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-1 TestAmerica Knoxville Matrix:RC09P107.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:10 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 50(mL) 0.32(mm) Date Analyzed:03/09/2017 20:00 ID:RTX-5 Analysis Batch No.:9156 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 133.4171-55-6 1,1,1-Trichloroethane ND 0.80 167.8579-34-5 1,1,2,2-Tetrachloroethan e ND 0.80 133.4179-00-5 1,1,2-Trichloroethane ND 0.80 187.3876-13-1 1,1,2-Trichlorotrifluoro ethane ND 0.80 98.9675-34-3 1,1-Dichloroethane ND 0.80 96.9475-35-4 1,1-Dichloroethene ND 0.80 181.45120-82-1 1,2,4-Trichlorobenzene ND 0.80 120.2095-63-6 1,2,4-Trimethylbenzene ND 0.80 187.87106-93-4 1,2-Dibromoethane ND 0.80 147.0095-50-1 1,2-Dichlorobenzene ND 0.80 98.96107-06-2 1,2-Dichloroethane ND 0.80 112.9978-87-5 1,2-Dichloropropane ND 0.80 170.9276-14-2 1,2-Dichlorotetrafluoroe thane ND 0.80 120.20108-67-8 1,3,5-Trimethylbenzene ND 0.80 147.00541-73-1 1,3-Dichlorobenzene ND 0.80 147.00106-46-7 1,4-Dichlorobenzene ND 0.80 88.11123-91-1 1,4-Dioxane ND 2.0 114.23540-84-1 2,2,4-Trimethylpentane ND 2.0 72.1178-93-3 2-Butanone ND 3.2 100.16108-10-1 4-Methyl-2-pentanone (MIBK) ND 2.0 78.1171-43-2 Benzene ND 0.80 126.58100-44-7 Benzyl chloride ND 1.6 163.8375-27-4 Bromodichloromethane ND 0.80 252.7575-25-2 Bromoform ND 0.80 94.9474-83-9 Bromomethane ND 0.80 153.8156-23-5 Carbon tetrachloride ND 0.40 112.56108-90-7 Chlorobenzene ND 0.80 64.5275-00-3 Chloroethane ND *0.80 119.3867-66-3 Chloroform ND 0.80 50.4974-87-3 Chloromethane ND 2.0 96.94156-59-2 cis-1,2-Dichloroethene ND 0.80 110.9710061-01-5 cis-1,3-Dichloropropene ND 0.80 84.16110-82-7 Cyclohexane ND 2.0 FORM I TO 15 LL 03/21/2017Page 49 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: SS-10-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-1 TestAmerica Knoxville Matrix:RC09P107.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:10 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 50(mL) 0.32(mm) Date Analyzed:03/09/2017 20:00 ID:RTX-5 Analysis Batch No.:9156 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 208.29124-48-1 Dibromochloromethane ND 0.80 120.9175-71-8 Dichlorodifluoromethane ND 0.80 46.0764-17-5 Ethanol ND 20 106.17100-41-4 Ethylbenzene ND 0.80 260.7687-68-3 Hexachlorobutadiene ND 0.80 86.17110-54-3 Hexane ND 2.0 88.151634-04-4 Methyl tert-butyl ether ND 1.6 84.9375-09-2 Methylene Chloride ND 2.0 106.17179601-23-1 m-Xylene & p-Xylene ND 0.80 106.1795-47-6 o-Xylene ND 0.80 104.15100-42-5 Styrene ND 0.80 74.1275-65-0 t-Butyl alcohol ND 3.2 165.83127-18-4 Tetrachloroethene 92 0.80 92.14108-88-3 Toluene ND 1.2 96.94156-60-5 trans-1,2-Dichloroethene ND 0.80 110.9710061-02-6 trans-1,3-Dichloropropen e ND 0.80 131.3979-01-6 Trichloroethene ND 0.40 137.3775-69-4 Trichlorofluoromethane ND 0.80 62.5075-01-4 Vinyl chloride ND 0.40 %RECCAS NO.LIMITSQSURROGATE 113 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 50 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: SS-10-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-1 TestAmerica Knoxville Matrix:RC09P107.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:10 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 50(mL) 0.32(mm) Date Analyzed:03/09/2017 20:00 ID:RTX-5 Analysis Batch No.:9156 ug/m3Units: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 133.4171-55-6 1,1,1-Trichloroethane ND 4.4 167.8579-34-5 1,1,2,2-Tetrachloroethan e ND 5.5 133.4179-00-5 1,1,2-Trichloroethane ND 4.4 187.3876-13-1 1,1,2-Trichlorotrifluoro ethane ND 6.1 98.9675-34-3 1,1-Dichloroethane ND 3.2 96.9475-35-4 1,1-Dichloroethene ND 3.2 181.45120-82-1 1,2,4-Trichlorobenzene ND 5.9 120.2095-63-6 1,2,4-Trimethylbenzene ND 3.9 187.87106-93-4 1,2-Dibromoethane ND 6.1 147.0095-50-1 1,2-Dichlorobenzene ND 4.8 98.96107-06-2 1,2-Dichloroethane ND 3.2 112.9978-87-5 1,2-Dichloropropane ND 3.7 170.9276-14-2 1,2-Dichlorotetrafluoroe thane ND 5.6 120.20108-67-8 1,3,5-Trimethylbenzene ND 3.9 147.00541-73-1 1,3-Dichlorobenzene ND 4.8 147.00106-46-7 1,4-Dichlorobenzene ND 4.8 88.11123-91-1 1,4-Dioxane ND 7.2 114.23540-84-1 2,2,4-Trimethylpentane ND 9.3 72.1178-93-3 2-Butanone ND 9.4 100.16108-10-1 4-Methyl-2-pentanone (MIBK) ND 8.2 78.1171-43-2 Benzene ND 2.6 126.58100-44-7 Benzyl chloride ND 8.3 163.8375-27-4 Bromodichloromethane ND 5.4 252.7575-25-2 Bromoform ND 8.3 94.9474-83-9 Bromomethane ND 3.1 153.8156-23-5 Carbon tetrachloride ND 2.5 112.56108-90-7 Chlorobenzene ND 3.7 64.5275-00-3 Chloroethane ND *2.1 119.3867-66-3 Chloroform ND 3.9 50.4974-87-3 Chloromethane ND 4.1 96.94156-59-2 cis-1,2-Dichloroethene ND 3.2 110.9710061-01-5 cis-1,3-Dichloropropene ND 3.6 84.16110-82-7 Cyclohexane ND 6.9 FORM I TO 15 LL 03/21/2017Page 51 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: SS-10-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-1 TestAmerica Knoxville Matrix:RC09P107.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:10 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 50(mL) 0.32(mm) Date Analyzed:03/09/2017 20:00 ID:RTX-5 Analysis Batch No.:9156 ug/m3Units: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 208.29124-48-1 Dibromochloromethane ND 6.8 120.9175-71-8 Dichlorodifluoromethane ND 4.0 46.0764-17-5 Ethanol ND 38 106.17100-41-4 Ethylbenzene ND 3.5 260.7687-68-3 Hexachlorobutadiene ND 8.5 86.17110-54-3 Hexane ND 7.0 88.151634-04-4 Methyl tert-butyl ether ND 5.8 84.9375-09-2 Methylene Chloride ND 6.9 106.17179601-23-1 m-Xylene & p-Xylene ND 3.5 106.1795-47-6 o-Xylene ND 3.5 104.15100-42-5 Styrene ND 3.4 74.1275-65-0 t-Butyl alcohol ND 9.7 165.83127-18-4 Tetrachloroethene 630 5.4 92.14108-88-3 Toluene ND 4.5 96.94156-60-5 trans-1,2-Dichloroethene ND 3.2 110.9710061-02-6 trans-1,3-Dichloropropen e ND 3.6 131.3979-01-6 Trichloroethene ND 2.1 137.3775-69-4 Trichlorofluoromethane ND 4.5 62.5075-01-4 Vinyl chloride ND 1.0 %RECCAS NO.LIMITSQSURROGATE 113 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 52 of 377 Report Date: 10-Mar-2017 08:03:51 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P107.D Lims ID:140-7345-A-1 Client ID:SS-10-2017 Sample Type:Client Inject. Date:09-Mar-2017 20:00:30 ALS Bottle#:7 Worklist Smp#:12 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004226-012 Misc. Info.:140-7345-a-1 Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 08:03:18 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 07:52:41 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.210 8.215 -0.005 96 456214 4.00 * 2 1,4-Difluorobenzene 114 10.377 10.377 0.000 95 2213338 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.268 15.274 -0.006 89 1698973 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.961 16.961 0.000 97 1341987 4.53 8 Dichlorodifluoromethane 85 3.782 3.750 0.032 67 19051 0.0622 15 Bromomethane 94 4.419 4.392 0.027 23 5228 0.0529 21 Trichlorofluoromethane 101 5.017 5.012 0.005 96 7734 0.0207 31 Methylene Chloride 84 5.912 5.907 0.005 96 12218 0.0859 76 Tetrachloroethene 129 14.432 14.432 0.000 94 1556801 9.22 Reagents: 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 53 of 377 Report Date: 10-Mar-2017 08:03:51 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P107.D Injection Date:09-Mar-2017 20:00:30 Instrument ID:MR Operator ID: Lims ID:140-7345-A-1 Lab Sample ID:140-7345-1 Worklist Smp#:12 Client ID:SS-10-2017 Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:7 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 42 45 48 51 54 57 60 63 66 69 72 Y ( X10 0 0 0 0 ) RC09P107[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 1 0 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 7 2 )+ * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 6 8 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 1 ) 03/21/2017Page 54 of 377 Report Date: 10-Mar-2017 08:03:51 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Recovery Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P107.D Lims ID:140-7345-A-1 Client ID:SS-10-2017 Sample Type:Client Inject. Date:09-Mar-2017 20:00:30 ALS Bottle#:7 Worklist Smp#:12 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004226-012 Misc. Info.:140-7345-a-1 Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 08:03:18 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 07:52:41 Compound Amount Added Amount Recovered %Rec. $4 4-Bromofluorobenzene (Surr)4.00 4.53 113.14 03/21/2017Page 55 of 377 Report Date: 10-Mar-2017 08:03:52 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P107.D Injection Date:09-Mar-2017 20:00:30 Instrument ID:MR Lims ID:140-7345-A-1 Lab Sample ID:140-7345-1 Client ID:SS-10-2017 Operator ID:ALS Bottle#:7 Worklist Smp#:12 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 76 Tetrachloroethene, CAS: 127-18-4 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 12 14 Y ( X10 0 0 0 0 ) Raw Spec:Scan 2104(14.43) 166 164 131 168 94 9647 13359 35 17082 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 12 14 Y ( X10 0 0 0 0 ) Enhanced Spec:Scan 2104(14.43) Bgrd 2094(14.37), Qvalue=94 166 164 131 168 94 9647 13359 35 17082 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 76 Tetrachloroethene @ 585.533 min. 166 164 129 131 168 94 96 1334759 17082 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 2104 @ 14.432 min.(Qvalue: 94) 13.9 14.2 14.5 14.8 Min 0 7 14 21 28 35 42 49 56 63 70 77 Y ( X10 0 0 0 ) m/z 129.0 1 4 . 4 3 2 13.9 14.2 14.5 14.8 Min 0 2 4 6 8 10 12 14 Y ( X10 0 0 0 0 ) m/z 166.0 1 4 . 4 3 2 13.9 14.2 14.5 14.8 Min 0 6 12 18 24 30 36 42 48 54 60 Y ( X10 0 0 0 ) m/z 168.0 1 4 . 4 3 2 03/21/2017Page 56 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: AS-10-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-2 TestAmerica Knoxville Matrix:RC09P108.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:10 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 100(mL) 0.32(mm) Date Analyzed:03/09/2017 20:48 ID:RTX-5 Analysis Batch No.:9156 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 133.4171-55-6 1,1,1-Trichloroethane ND 0.40 167.8579-34-5 1,1,2,2-Tetrachloroethan e ND 0.40 133.4179-00-5 1,1,2-Trichloroethane ND 0.40 187.3876-13-1 1,1,2-Trichlorotrifluoro ethane ND 0.40 98.9675-34-3 1,1-Dichloroethane ND 0.40 96.9475-35-4 1,1-Dichloroethene ND 0.40 181.45120-82-1 1,2,4-Trichlorobenzene ND 0.40 120.2095-63-6 1,2,4-Trimethylbenzene 1.3 0.40 187.87106-93-4 1,2-Dibromoethane ND 0.40 147.0095-50-1 1,2-Dichlorobenzene ND 0.40 98.96107-06-2 1,2-Dichloroethane ND 0.40 112.9978-87-5 1,2-Dichloropropane ND 0.40 170.9276-14-2 1,2-Dichlorotetrafluoroe thane ND 0.40 120.20108-67-8 1,3,5-Trimethylbenzene ND 0.40 147.00541-73-1 1,3-Dichlorobenzene ND 0.40 147.00106-46-7 1,4-Dichlorobenzene ND 0.40 88.11123-91-1 1,4-Dioxane ND 1.0 114.23540-84-1 2,2,4-Trimethylpentane 1.9 1.0 72.1178-93-3 2-Butanone 2.5 1.6 100.16108-10-1 4-Methyl-2-pentanone (MIBK) ND 1.0 78.1171-43-2 Benzene 5.6 0.40 126.58100-44-7 Benzyl chloride ND 0.80 163.8375-27-4 Bromodichloromethane ND 0.40 252.7575-25-2 Bromoform ND 0.40 94.9474-83-9 Bromomethane ND 0.40 153.8156-23-5 Carbon tetrachloride ND 0.20 112.56108-90-7 Chlorobenzene ND 0.40 64.5275-00-3 Chloroethane ND *0.40 119.3867-66-3 Chloroform ND 0.40 50.4974-87-3 Chloromethane 3.2 1.0 96.94156-59-2 cis-1,2-Dichloroethene ND 0.40 110.9710061-01-5 cis-1,3-Dichloropropene ND 0.40 84.16110-82-7 Cyclohexane 3.6 1.0 FORM I TO 15 LL 03/21/2017Page 57 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: AS-10-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-2 TestAmerica Knoxville Matrix:RC09P108.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:10 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 100(mL) 0.32(mm) Date Analyzed:03/09/2017 20:48 ID:RTX-5 Analysis Batch No.:9156 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 208.29124-48-1 Dibromochloromethane ND 0.40 120.9175-71-8 Dichlorodifluoromethane 0.40 0.40 46.0764-17-5 Ethanol 850 E 10 106.17100-41-4 Ethylbenzene 1.6 0.40 260.7687-68-3 Hexachlorobutadiene ND 0.40 86.17110-54-3 Hexane 12 1.0 88.151634-04-4 Methyl tert-butyl ether ND 0.80 84.9375-09-2 Methylene Chloride 44 1.0 106.17179601-23-1 m-Xylene & p-Xylene 5.9 0.40 106.1795-47-6 o-Xylene 1.6 0.40 104.15100-42-5 Styrene ND 0.40 74.1275-65-0 t-Butyl alcohol ND 1.6 165.83127-18-4 Tetrachloroethene ND 0.40 92.14108-88-3 Toluene 17 0.60 96.94156-60-5 trans-1,2-Dichloroethene ND 0.40 110.9710061-02-6 trans-1,3-Dichloropropen e ND 0.40 131.3979-01-6 Trichloroethene 0.55 0.20 137.3775-69-4 Trichlorofluoromethane ND 0.40 62.5075-01-4 Vinyl chloride ND 0.20 %RECCAS NO.LIMITSQSURROGATE 106 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 58 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: AS-10-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-2 TestAmerica Knoxville Matrix:RC09P108.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:10 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 100(mL) 0.32(mm) Date Analyzed:03/09/2017 20:48 ID:RTX-5 Analysis Batch No.:9156 ug/m3Units: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 133.4171-55-6 1,1,1-Trichloroethane ND 2.2 167.8579-34-5 1,1,2,2-Tetrachloroethan e ND 2.7 133.4179-00-5 1,1,2-Trichloroethane ND 2.2 187.3876-13-1 1,1,2-Trichlorotrifluoro ethane ND 3.1 98.9675-34-3 1,1-Dichloroethane ND 1.6 96.9475-35-4 1,1-Dichloroethene ND 1.6 181.45120-82-1 1,2,4-Trichlorobenzene ND 3.0 120.2095-63-6 1,2,4-Trimethylbenzene 6.2 2.0 187.87106-93-4 1,2-Dibromoethane ND 3.1 147.0095-50-1 1,2-Dichlorobenzene ND 2.4 98.96107-06-2 1,2-Dichloroethane ND 1.6 112.9978-87-5 1,2-Dichloropropane ND 1.8 170.9276-14-2 1,2-Dichlorotetrafluoroe thane ND 2.8 120.20108-67-8 1,3,5-Trimethylbenzene ND 2.0 147.00541-73-1 1,3-Dichlorobenzene ND 2.4 147.00106-46-7 1,4-Dichlorobenzene ND 2.4 88.11123-91-1 1,4-Dioxane ND 3.6 114.23540-84-1 2,2,4-Trimethylpentane 8.7 4.7 72.1178-93-3 2-Butanone 7.4 4.7 100.16108-10-1 4-Methyl-2-pentanone (MIBK) ND 4.1 78.1171-43-2 Benzene 18 1.3 126.58100-44-7 Benzyl chloride ND 4.1 163.8375-27-4 Bromodichloromethane ND 2.7 252.7575-25-2 Bromoform ND 4.1 94.9474-83-9 Bromomethane ND 1.6 153.8156-23-5 Carbon tetrachloride ND 1.3 112.56108-90-7 Chlorobenzene ND 1.8 64.5275-00-3 Chloroethane ND *1.1 119.3867-66-3 Chloroform ND 2.0 50.4974-87-3 Chloromethane 6.5 2.1 96.94156-59-2 cis-1,2-Dichloroethene ND 1.6 110.9710061-01-5 cis-1,3-Dichloropropene ND 1.8 84.16110-82-7 Cyclohexane 13 3.4 FORM I TO 15 LL 03/21/2017Page 59 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: AS-10-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-2 TestAmerica Knoxville Matrix:RC09P108.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:10 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 100(mL) 0.32(mm) Date Analyzed:03/09/2017 20:48 ID:RTX-5 Analysis Batch No.:9156 ug/m3Units: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 208.29124-48-1 Dibromochloromethane ND 3.4 120.9175-71-8 Dichlorodifluoromethane 2.0 2.0 46.0764-17-5 Ethanol 1600 E 19 106.17100-41-4 Ethylbenzene 6.8 1.7 260.7687-68-3 Hexachlorobutadiene ND 4.3 86.17110-54-3 Hexane 41 3.5 88.151634-04-4 Methyl tert-butyl ether ND 2.9 84.9375-09-2 Methylene Chloride 150 3.5 106.17179601-23-1 m-Xylene & p-Xylene 26 1.7 106.1795-47-6 o-Xylene 7.1 1.7 104.15100-42-5 Styrene ND 1.7 74.1275-65-0 t-Butyl alcohol ND 4.9 165.83127-18-4 Tetrachloroethene ND 2.7 92.14108-88-3 Toluene 64 2.3 96.94156-60-5 trans-1,2-Dichloroethene ND 1.6 110.9710061-02-6 trans-1,3-Dichloropropen e ND 1.8 131.3979-01-6 Trichloroethene 2.9 1.1 137.3775-69-4 Trichlorofluoromethane ND 2.2 62.5075-01-4 Vinyl chloride ND 0.51 %RECCAS NO.LIMITSQSURROGATE 106 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 60 of 377 Report Date: 10-Mar-2017 08:03:53 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Lims ID:140-7345-A-2 Client ID:AS-10-2017 Sample Type:Client Inject. Date:09-Mar-2017 20:48:30 ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004226-013 Misc. Info.:140-7345-a-2 Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 08:03:18 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 07:53:55 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.215 8.215 0.000 98 438724 4.00 * 2 1,4-Difluorobenzene 114 10.377 10.377 0.000 96 2126996 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.274 15.274 0.000 89 1642109 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.961 16.961 0.000 96 1219103 4.25 8 Dichlorodifluoromethane 85 3.777 3.750 0.027 99 23375 0.0793 9 Chloromethane 52 3.923 3.896 0.027 99 32593 0.6343 M 17 Ethanol 31 4.672 4.634 0.038 98 5426842 171.0 E 21 Trichlorofluoromethane 101 5.034 5.012 0.022 99 14026 0.0391 29 2-Methyl-2-propanol 59 5.761 5.718 0.043 77 14869 0.0574 31 Methylene Chloride 84 5.918 5.907 0.011 98 1213017 8.86 39 2-Butanone (MEK) 72 7.514 7.503 0.011 98 33266 0.5044 40 Hexane 56 7.606 7.595 0.011 90 287467 2.34 44 Chloroform 83 8.247 8.247 0.000 92 18661 0.0633 48 1,2-Dichloroethane 62 9.299 9.299 0.000 93 3741 0.0189 50 Benzene 78 9.811 9.806 0.005 98 429960 1.12 51 Cyclohexane 69 9.838 9.833 0.005 91 44782 0.7299 52 Carbon tetrachloride 117 9.849 9.843 0.006 66 8234 0.0282 56 Isooctane 57 10.663 10.663 0.000 98 264262 0.3738 59 Trichloroethene 130 11.111 11.111 0.000 96 20623 0.1094 65 4-Methyl-2-pentanone (MIBK 43 12.335 12.324 0.011 97 20811 0.0602 68 Toluene 91 13.241 13.246 -0.005 93 1521237 3.41 76 Tetrachloroethene 129 14.438 14.432 0.006 89 4881 0.0299 79 Ethylbenzene 91 15.635 15.640 -0.005 99 175286 0.3114 81 m-Xylene & p-Xylene 91 15.807 15.807 0.000 100 502947 1.18 83 Styrene 104 16.277 16.276 0.001 96 17096 0.0604 85 o-Xylene 91 16.341 16.341 0.000 99 148454 0.3283 92 1,3,5-Trimethylbenzene 120 17.786 17.781 0.005 92 17485 0.0616 96 1,2,4-Trimethylbenzene 105 18.245 18.245 0.000 98 134226 0.2540 03/21/2017Page 61 of 377 Report Date: 10-Mar-2017 08:03:53 Chrom Revision: 2.2 05-Mar-2017 11:38:00 QC Flag Legend Processing Flags E - Exceeded Maximum Amount Review Flags M - Manually Integrated Reagents: 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 62 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Operator ID: Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Worklist Smp#:13 Client ID:AS-10-2017 Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:8 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 Y ( X10 0 0 0 0 ) RC09P108[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 1 5 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 7 7 )+ * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 7 4 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 1 ) 03/21/2017Page 63 of 377 Report Date: 10-Mar-2017 08:03:53 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Recovery Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Lims ID:140-7345-A-2 Client ID:AS-10-2017 Sample Type:Client Inject. Date:09-Mar-2017 20:48:30 ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004226-013 Misc. Info.:140-7345-a-2 Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 08:03:18 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 07:53:55 Compound Amount Added Amount Recovered %Rec. $4 4-Bromofluorobenzene (Surr)4.00 4.25 106.34 03/21/2017Page 64 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 96 1,2,4-Trimethylbenzene, CAS: 95-63-6 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 10 20 30 40 50 60 70 80 Y ( X10 0 0 ) Raw Spec:Scan 2811(18.24) 105 120 913951 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 2811(18.24), Qvalue=98 105 120 7739 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 96 1,2,4-Trimethylbenzene @ 159.833 min. 105 120 7739 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 18.250 min.(Qvalue: 98) 17.7 18.0 18.3 18.6 Min 0 7 14 21 28 35 42 49 56 63 70 77 Y ( X10 0 0 ) m/z 105.0 1 8 . 2 4 5 17.7 18.0 18.3 18.6 Min 0 4 8 12 16 20 24 28 32 36 40 Y ( X10 0 0 ) m/z 120.0 1 8 . 2 5 0 17.7 18.0 18.3 18.6 Min 0 2 4 6 8 10 12 14 Y ( X10 0 0 ) m/z 119.0 1 8 . 2 4 5 03/21/2017Page 65 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 56 Isooctane, CAS: 540-84-1 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 0 ) Raw Spec:Scan 1405(10.66) 57 56 41 43 39 70 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 1405(10.66), Qvalue=98 57 56 41 43 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 56 Isooctane @ 129.933 min. 57 56 41 43 99 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 10.670 min.(Qvalue: 98) 56 10.1 10.4 10.7 11.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 Y ( X10 0 0 0 ) m/z 57.0 1 0 . 6 6 3 10.1 10.4 10.7 11.0 Min 0 5 10 15 20 25 30 35 40 45 Y ( X10 0 0 ) m/z 56.0 1 0 . 6 6 9 10.1 10.4 10.7 11.0 Min 0 5 10 15 20 25 30 35 40 45 50 Y ( X10 0 0 ) m/z 41.0 1 0 . 6 6 3 03/21/2017Page 66 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 39 2-Butanone (MEK), CAS: 78-93-3 20 40 60 80 100 120 140 160 180 200 m/z 0 9 18 27 36 45 54 63 Y ( X10 0 0 ) Raw Spec:Scan 821(7.51) 43 72 57 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 821(7.51), Qvalue=98 43 72 5742 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 39 2-Butanone (MEK) @ 10.950 min. 43 72 57 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 7.510 min.(Qvalue: 98) 7.0 7.3 7.6 7.9 Min 0 2 4 6 8 10 12 14 Y ( X10 0 0 ) m/z 72.0 7 . 5 1 4 7.0 7.3 7.6 7.9 Min 0 2 4 6 8 10 12 14 16 18 Y ( X10 0 0 0 ) m/z 43.0 7 . 5 1 4 7.0 7.3 7.6 7.9 Min 0 2 4 6 8 10 12 14 16 18 20 Y ( X10 0 0 ) m/z 29.0 7 . 5 0 9 03/21/2017Page 67 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 50 Benzene, CAS: 71-43-2 20 40 60 80 100 120 140 160 180 200 m/z 0 3 6 9 12 15 18 Y ( X10 0 0 0 ) Raw Spec:Scan 1247(9.81) 78 775239 8474 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 1247(9.81), Qvalue=98 78 775152 79 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 50 Benzene @ 17.083 min. 78 77 51 52 7938 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 9.810 min.(Qvalue: 98) 9.3 9.6 9.9 10.2 Min 0 2 4 6 8 10 12 14 16 18 Y ( X10 0 0 0 ) m/z 78.0 9 . 8 1 1 9.3 9.6 9.9 10.2 Min 0 4 8 12 16 20 24 28 32 36 40 Y ( X10 0 0 ) m/z 77.0 9 . 8 1 1 9.3 9.6 9.9 10.2 Min 0 4 8 12 16 20 24 28 32 36 Y ( X10 0 0 ) m/z 51.0 9 . 8 0 6 03/21/2017Page 68 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 9 Chloromethane, CAS: 74-87-3 20 40 60 80 100 120 140 160 180 200 m/z 0 7 14 21 28 35 42 49 Y ( X10 0 0 ) Raw Spec:Scan 155(3.92) 50 52 32 49 78 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 155(3.92), Qvalue=99 50 52 49 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 9 Chloromethane @ 1.983 min. 50 52 4935 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 3.920 min.(Qvalue: 99) 52 3.4 3.7 4.0 4.3 Min 0 2 4 6 8 10 12 14 16 18 Y ( X10 0 0 ) m/z 52.0 3 . 9 2 3 3.4 3.7 4.0 4.3 Min 0 5 10 15 20 25 30 35 40 45 50 55 Y ( X10 0 0 ) m/z 50.0 3 . 9 1 7 03/21/2017Page 69 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 51 Cyclohexane, CAS: 110-82-7 20 40 60 80 100 120 140 160 180 200 m/z 0 9 18 27 36 45 54 63 Y ( X10 0 0 ) Raw Spec:Scan 1252(9.84) 56 84 41 5539 69 32 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 1252(9.84), Qvalue=91 56 84 41 55 6939 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 51 Cyclohexane @ 24.550 min. 56 84 41 55 69 39 42 8583 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 9.840 min.(Qvalue: 91) 41 9.3 9.6 9.9 10.2 Min 0 2 4 6 8 10 12 14 16 Y ( X10 0 0 ) m/z 69.0 9 . 8 3 8 9.3 9.6 9.9 10.2 Min 0 3 6 9 12 15 18 21 24 Y ( X10 0 0 ) m/z 55.0 9 . 8 3 8 9.3 9.6 9.9 10.2 Min 0 4 8 12 16 20 24 28 32 36 40 Y ( X10 0 0 ) m/z 41.0 9 . 8 3 8 03/21/2017Page 70 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 8 Dichlorodifluoromethane, CAS: 75-71-8 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 12 14 Y ( X10 0 0 ) Raw Spec:Scan 128(3.78) 85 32 87 40 78 207101103 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 128(3.78), Qvalue=99 85 87 50 101 10335 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 8 Dichlorodifluoromethane @ 160.750 min. 85 87 50 10135 103 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 3.780 min.(Qvalue: 99) 3.2 3.5 3.8 4.1 Min 0 2 4 6 8 10 12 14 Y ( X10 0 0 ) m/z 85.0 3 . 7 7 7 3.2 3.5 3.8 4.1 Min 0 4 8 12 16 20 24 28 32 36 40 44 Y ( X10 0 ) m/z 87.0 3 . 7 7 7 3.2 3.5 3.8 4.1 Min 2 6 10 14 18 22 26 30 34 38 42 Y ( X10 0 ) m/z 50.0 3 . 7 7 2 03/21/2017Page 71 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 17 Ethanol, CAS: 64-17-5 20 40 60 80 100 120 140 160 180 200 220 m/z 0 3 6 9 12 15 18 21 Y ( X10 0 0 0 0 ) Raw Spec:Scan 294(4.67) 31 45 46 20 40 60 80 100 120 140 160 180 200 220 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 294(4.67), Qvalue=98 31 45 46 20 40 60 80 100 120 140 160 180 200 220 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 17 Ethanol @ 1.567 min. 31 45 46 20 40 60 80 100 120 140 160 180 200 220 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 4.670 min.(Qvalue: 98) 4.1 4.4 4.7 5.0 Min 0 2 4 6 8 10 12 14 16 18 20 Y ( X10 0 0 0 0 ) m/z 31.0 4 . 6 7 2 4.1 4.4 4.7 5.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 Y ( X10 0 0 0 0 ) m/z 45.0 4 . 6 7 2 03/21/2017Page 72 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 79 Ethylbenzene, CAS: 100-41-4 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 0 0 ) Raw Spec:Scan 2327(15.63) 91 106 51 65 7732 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 2327(15.63), Qvalue=99 91 106 51 65 77 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 79 Ethylbenzene @ 86.183 min. 91 106 51 65 77 105 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 15.640 min.(Qvalue: 99) 106 15.1 15.4 15.7 16.0 Min 0 3 6 9 12 15 18 21 24 Y ( X10 0 0 0 ) m/z 91.0 1 5 . 6 3 5 15.1 15.4 15.7 16.0 Min 0 2 4 6 8 10 12 Y ( X10 0 0 0 ) m/z 106.0 1 5 . 6 4 0 15.1 15.4 15.7 16.0 Min 0 3 6 9 12 15 18 21 24 27 30 Y ( X10 0 0 ) m/z 77.0 1 5 . 6 3 5 03/21/2017Page 73 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 40 Hexane, CAS: 110-54-3 20 40 60 80 100 120 140 160 180 200 m/z 0 3 6 9 12 15 18 21 24 Y ( X10 0 0 0 ) Raw Spec:Scan 838(7.61) 57 41 43 56 86 71 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 838(7.61), Qvalue=90 57 41 43 56 86 71 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 40 Hexane @ 30.683 min. 57 43 56 86 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 7.610 min.(Qvalue: 90) 56 41 7.1 7.4 7.7 8.0 Min 0 2 4 6 8 10 12 14 16 Y ( X10 0 0 0 ) m/z 56.0 7 . 6 0 6 7.1 7.4 7.7 8.0 Min 0 3 6 9 12 15 18 21 24 Y ( X10 0 0 0 ) m/z 57.0 7 . 6 0 6 7.1 7.4 7.7 8.0 Min 0 4 8 12 16 20 24 28 32 Y ( X10 0 0 ) m/z 86.0 7 . 6 0 6 03/21/2017Page 74 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 31 Methylene Chloride, CAS: 75-09-2 20 40 60 80 100 120 140 160 180 200 m/z 0 11 22 33 44 55 66 77 Y ( X10 0 0 0 ) Raw Spec:Scan 525(5.92) 49 84 86 51 47 88 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 525(5.92), Qvalue=98 49 84 86 51 47 88 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 31 Methylene Chloride @ 25.683 min. 49 84 86 51 47 88 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 5.920 min.(Qvalue: 98) 5.4 5.7 6.0 6.3 Min 0 5 10 15 20 25 30 35 40 45 50 Y ( X10 0 0 0 ) m/z 84.0 5 . 9 1 8 5.4 5.7 6.0 6.3 Min 0 8 16 24 32 40 48 56 64 72 80 Y ( X10 0 0 0 ) m/z 49.0 5 . 9 1 8 5.4 5.7 6.0 6.3 Min 0 3 6 9 12 15 18 21 24 27 30 Y ( X10 0 0 0 ) m/z 86.0 5 . 9 1 8 03/21/2017Page 75 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 81 m-Xylene & p-Xylene, CAS: 179601-23-1 20 40 60 80 100 120 140 160 180 200 220 m/z 0 4 8 12 16 20 24 Y ( X10 0 0 0 ) Raw Spec:Scan 2359(15.81) 91 106 105 7751 20 40 60 80 100 120 140 160 180 200 220 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 2359(15.81), Qvalue=100 91 106 105 7751 20 40 60 80 100 120 140 160 180 200 220 m/z 0 13 26 39 52 65 78 91 Y Ref Spec: 81 m-Xylene & p-Xylene @ 15.820 min. 91 106 105 7751 20 40 60 80 100 120 140 160 180 200 220 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 15.810 min.(Qvalue:100) 15.3 15.6 15.9 16.2 Min 0 3 6 9 12 15 18 21 24 Y ( X10 0 0 0 ) m/z 91.0 1 5 . 8 0 7 15.3 15.6 15.9 16.2 Min 0 2 4 6 8 10 12 Y ( X10 0 0 0 ) m/z 106.0 1 5 . 8 0 7 15.3 15.6 15.9 16.2 Min 0 3 6 9 12 15 18 21 24 27 30 Y ( X10 0 0 ) m/z 77.0 1 5 . 8 0 2 03/21/2017Page 76 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 85 o-Xylene, CAS: 95-47-6 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 11 22 33 44 55 66 77 Y ( X10 0 0 ) Raw Spec:Scan 2458(16.34) 91 106 7751 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 2458(16.34), Qvalue=99 91 106 51 77 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 85 o-Xylene @ 86.000 min. 91 106 7751 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 16.340 min.(Qvalue: 99) 15.8 16.1 16.4 16.7 Min 0 8 16 24 32 40 48 56 64 72 80 Y ( X10 0 0 ) m/z 91.0 1 6 . 3 4 1 15.8 16.1 16.4 16.7 Min 0 4 8 12 16 20 24 28 32 36 40 Y ( X10 0 0 ) m/z 106.0 1 6 . 3 3 6 15.8 16.1 16.4 16.7 Min 0 9 18 27 36 45 54 63 72 81 90 Y ( X10 0 ) m/z 77.0 1 6 . 3 3 6 03/21/2017Page 77 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 68 Toluene, CAS: 108-88-3 20 40 60 80 100 120 140 160 180 200 m/z 0 10 20 30 40 50 60 70 Y ( X10 0 0 0 ) Raw Spec:Scan 1883(13.24) 91 92 6539 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 1883(13.24), Qvalue=93 91 92 6539 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 68 Toluene @ 41.267 min. 91 92 6539 93 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 13.240 min.(Qvalue: 93) 12.7 13.0 13.3 13.6 Min 0 7 14 21 28 35 42 49 56 63 70 Y ( X10 0 0 0 ) m/z 91.0 1 3 . 2 4 1 12.7 13.0 13.3 13.6 Min 0 4 8 12 16 20 24 28 32 36 40 44 Y ( X10 0 0 0 ) m/z 92.0 1 3 . 2 4 1 03/21/2017Page 78 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 59 Trichloroethene, CAS: 79-01-6 20 30 40 50 60 70 80 90 100 110 120 130 140 m/z 0 12 24 36 48 60 72 84 Y ( X10 0 ) Raw Spec:Scan 1488(11.11) 13095 132 32 97 60 40 47 62 94 992981 20 30 40 50 60 70 80 90 100 110 120 130 140 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 1488(11.11), Qvalue=96 95 132 97 60 624735 999449 20 30 40 50 60 70 80 90 100 110 120 130 140 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 59 Trichloroethene @ 223.767 min. 130 95 97 60 6247 99943559 20 30 40 50 60 70 80 90 100 110 120 130 140 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 11.120 min.(Qvalue: 96) 95 132 10.6 10.9 11.2 11.5 Min 0 9 18 27 36 45 54 63 72 81 90 Y ( X10 0 ) m/z 130.0 1 1 . 1 1 1 10.6 10.9 11.2 11.5 Min 0 9 18 27 36 45 54 63 72 81 90 99 Y ( X10 0 ) m/z 95.0 1 1 . 1 1 6 10.6 10.9 11.2 11.5 Min 0 9 18 27 36 45 54 63 72 81 90 99 Y ( X10 0 ) m/z 132.0 1 1 . 1 1 6 03/21/2017Page 79 of 377 Report Date: 10-Mar-2017 08:03:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 Manual Integration/User Assign Peak Report TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P108.D Injection Date:09-Mar-2017 20:48:30 Instrument ID:MR Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:ALS Bottle#:8 Worklist Smp#:13 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 9 Chloromethane, CAS: 74-87-3 Signal: 1 Processing Integration Results RT: 3.92 Area: 25504 Amount: 0.496334 Amount Units: ppb v/v 3.7 3.9 4.1 Min 0 2 4 6 8 10 12 14 16 18 Y ( X10 0 0 ) m/z 52.0 3 . 9 2 3 Manual Integration Results RT: 3.92 Area: 32593 Amount: 0.634293 Amount Units: ppb v/v 3.7 3.9 4.1 Min 0 2 4 6 8 10 12 14 16 18 Y ( X10 0 0 ) m/z 52.0 3 . 9 2 3 Reviewer: tajh, 10-Mar-2017 08:03:53 Audit Action: Manually Integrated Audit Reason: Baseline 03/21/2017Page 80 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: AS-10-2017 DL SDG No.: 140-7345-1 Lab Sample ID:140-7345-2 DL TestAmerica Knoxville Matrix:GC10P104.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:10 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 25(mL) 0.32(mm) Date Analyzed:03/10/2017 14:09 ID:RTX-5 Analysis Batch No.:9158 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 46.0764-17-5 Ethanol 1200 D 40 %RECCAS NO.LIMITSQSURROGATE 103 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 81 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: AS-10-2017 DL SDG No.: 140-7345-1 Lab Sample ID:140-7345-2 DL TestAmerica Knoxville Matrix:GC10P104.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:10 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 25(mL) 0.32(mm) Date Analyzed:03/10/2017 14:09 ID:RTX-5 Analysis Batch No.:9158 ug/m3Units: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 46.0764-17-5 Ethanol 2400 D 75 %RECCAS NO.LIMITSQSURROGATE 103 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 82 of 377 Report Date: 13-Mar-2017 11:57:49 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GC10P104.D Lims ID:140-7345-A-2 Client ID:AS-10-2017 Sample Type:Client Inject. Date:10-Mar-2017 14:09:30 ALS Bottle#:4 Worklist Smp#:8 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004228-008 Misc. Info.:140-7345-a-2 Operator ID:7126 Instrument ID:MG Method:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:13-Mar-2017 11:57:48 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK020 First Level Reviewer: barlozhetskayaa Date:13-Mar-2017 11:57:48 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 7.991 8.001 -0.010 86 288463 4.00 * 2 1,4-Difluorobenzene 114 10.158 10.169 -0.011 95 1340420 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.033 15.038 -0.005 88 1361295 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.705 16.710 -0.005 94 1045927 4.13 8 Dichlorodifluoromethane 85 3.510 3.515 -0.005 99 9516 0.0372 9 Chloromethane 52 3.661 3.666 -0.005 100 5630 0.2726 M 17 Ethanol 31 4.356 4.361 -0.005 98 1980697 62.5 21 Trichlorofluoromethane 101 4.739 4.750 -0.011 97 3731 0.0142 31 Methylene Chloride 84 5.650 5.666 -0.016 88 163855 2.36 39 2-Butanone (MEK) 72 7.295 7.284 0.011 45 3278 0.1026 40 Hexane 56 7.333 7.343 -0.010 89 34273 0.5905 44 Chloroform 83 8.012 8.028 -0.016 28 3202 0.0168 49 Benzene 78 9.581 9.592 -0.011 97 53661 0.2556 50 Cyclohexane 69 9.592 9.597 -0.005 91 7202 0.1948 56 Isooctane 57 10.412 10.422 -0.010 96 30614 0.0925 59 Trichloroethene 130 10.897 10.908 -0.011 91 2943 0.0244 65 4-Methyl-2-pentanone (MIBK 43 12.143 12.137 0.006 92 3771 0.0299 68 Toluene 91 13.022 13.027 -0.005 93 147253 0.5960 79 Ethylbenzene 91 15.389 15.394 -0.005 99 18103 0.0558 81 m-Xylene & p-Xylene 91 15.551 15.567 -0.016 99 51224 0.2013 85 o-Xylene 91 16.090 16.090 0.000 97 15580 0.0597 92 1,3,5-Trimethylbenzene 120 17.492 17.492 -0.005 64 1595 0.009526 7 96 1,2,4-Trimethylbenzene 105 17.950 17.956 -0.006 98 13997 0.0450 03/21/2017Page 83 of 377 Report Date: 13-Mar-2017 11:57:49 Chrom Revision: 2.2 05-Mar-2017 11:38:00 QC Flag Legend Processing Flags 7 - Failed Limit of Detection Review Flags M - Manually Integrated Reagents: 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 84 of 377 Report Date: 13-Mar-2017 11:57:49 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GC10P104.D Injection Date:10-Mar-2017 14:09:30 Instrument ID:MG Operator ID:7126 Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Worklist Smp#:8 Client ID:AS-10-2017 Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:4 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 Y ( X10 0 0 0 0 ) GC10P104[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 7 . 9 9 1 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 5 8 )+ * C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 3 3 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 7 0 5 ) 03/21/2017Page 85 of 377 Report Date: 13-Mar-2017 11:57:49 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Recovery Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GC10P104.D Lims ID:140-7345-A-2 Client ID:AS-10-2017 Sample Type:Client Inject. Date:10-Mar-2017 14:09:30 ALS Bottle#:4 Worklist Smp#:8 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004228-008 Misc. Info.:140-7345-a-2 Operator ID:7126 Instrument ID:MG Method:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:13-Mar-2017 11:57:48 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK020 First Level Reviewer: barlozhetskayaa Date:13-Mar-2017 11:57:48 Compound Amount Added Amount Recovered %Rec. $4 4-Bromofluorobenzene (Surr)4.00 4.13 103.17 03/21/2017Page 86 of 377 Report Date: 13-Mar-2017 11:57:49 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GC10P104.D Injection Date:10-Mar-2017 14:09:30 Instrument ID:MG Lims ID:140-7345-A-2 Lab Sample ID:140-7345-2 Client ID:AS-10-2017 Operator ID:7126 ALS Bottle#:4 Worklist Smp#:8 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 17 Ethanol, CAS: 64-17-5 20 40 60 80 100 120 140 160 180 200 m/z 0 10 20 30 40 50 60 70 Y ( X10 0 0 0 ) Raw Spec:Scan 209(4.36) 31 45 46 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 209(4.36), Qvalue=98 31 45 46 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 17 Ethanol @ 1.567 min. 31 45 46 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 4.360 min.(Qvalue: 98) 3.8 4.1 4.4 4.7 Min 0 7 14 21 28 35 42 49 56 63 70 Y ( X10 0 0 0 ) m/z 31.0 4 . 3 5 6 3.8 4.1 4.4 4.7 Min 0 4 8 12 16 20 24 28 32 36 Y ( X10 0 0 0 ) m/z 45.0 4 . 3 5 6 03/21/2017Page 87 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: DUP-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-3 TestAmerica Knoxville Matrix:RC09P109.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 00:00 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 100(mL) 0.32(mm) Date Analyzed:03/09/2017 21:35 ID:RTX-5 Analysis Batch No.:9156 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 133.4171-55-6 1,1,1-Trichloroethane ND 0.40 167.8579-34-5 1,1,2,2-Tetrachloroethan e ND 0.40 133.4179-00-5 1,1,2-Trichloroethane ND 0.40 187.3876-13-1 1,1,2-Trichlorotrifluoro ethane ND 0.40 98.9675-34-3 1,1-Dichloroethane ND 0.40 96.9475-35-4 1,1-Dichloroethene ND 0.40 181.45120-82-1 1,2,4-Trichlorobenzene ND 0.40 120.2095-63-6 1,2,4-Trimethylbenzene 1.2 0.40 187.87106-93-4 1,2-Dibromoethane ND 0.40 147.0095-50-1 1,2-Dichlorobenzene ND 0.40 98.96107-06-2 1,2-Dichloroethane ND 0.40 112.9978-87-5 1,2-Dichloropropane ND 0.40 170.9276-14-2 1,2-Dichlorotetrafluoroe thane ND 0.40 120.20108-67-8 1,3,5-Trimethylbenzene ND 0.40 147.00541-73-1 1,3-Dichlorobenzene ND 0.40 147.00106-46-7 1,4-Dichlorobenzene ND 0.40 88.11123-91-1 1,4-Dioxane ND 1.0 114.23540-84-1 2,2,4-Trimethylpentane 1.8 1.0 72.1178-93-3 2-Butanone 3.0 1.6 100.16108-10-1 4-Methyl-2-pentanone (MIBK) ND 1.0 78.1171-43-2 Benzene 5.6 0.40 126.58100-44-7 Benzyl chloride ND 0.80 163.8375-27-4 Bromodichloromethane ND 0.40 252.7575-25-2 Bromoform ND 0.40 94.9474-83-9 Bromomethane ND 0.40 153.8156-23-5 Carbon tetrachloride ND 0.20 112.56108-90-7 Chlorobenzene ND 0.40 64.5275-00-3 Chloroethane ND *0.40 119.3867-66-3 Chloroform ND 0.40 50.4974-87-3 Chloromethane 3.7 1.0 96.94156-59-2 cis-1,2-Dichloroethene ND 0.40 110.9710061-01-5 cis-1,3-Dichloropropene ND 0.40 84.16110-82-7 Cyclohexane 3.8 1.0 FORM I TO 15 LL 03/21/2017Page 88 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: DUP-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-3 TestAmerica Knoxville Matrix:RC09P109.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 00:00 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 100(mL) 0.32(mm) Date Analyzed:03/09/2017 21:35 ID:RTX-5 Analysis Batch No.:9156 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 208.29124-48-1 Dibromochloromethane ND 0.40 120.9175-71-8 Dichlorodifluoromethane 0.47 0.40 46.0764-17-5 Ethanol 820 E 10 106.17100-41-4 Ethylbenzene 1.5 0.40 260.7687-68-3 Hexachlorobutadiene ND 0.40 86.17110-54-3 Hexane 11 1.0 88.151634-04-4 Methyl tert-butyl ether ND 0.80 84.9375-09-2 Methylene Chloride 44 1.0 106.17179601-23-1 m-Xylene & p-Xylene 5.8 0.40 106.1795-47-6 o-Xylene 1.6 0.40 104.15100-42-5 Styrene ND 0.40 74.1275-65-0 t-Butyl alcohol ND 1.6 165.83127-18-4 Tetrachloroethene ND 0.40 92.14108-88-3 Toluene 16 0.60 96.94156-60-5 trans-1,2-Dichloroethene ND 0.40 110.9710061-02-6 trans-1,3-Dichloropropen e ND 0.40 131.3979-01-6 Trichloroethene 0.56 0.20 137.3775-69-4 Trichlorofluoromethane ND 0.40 62.5075-01-4 Vinyl chloride ND 0.20 %RECCAS NO.LIMITSQSURROGATE 106 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 89 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: DUP-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-3 TestAmerica Knoxville Matrix:RC09P109.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 00:00 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 100(mL) 0.32(mm) Date Analyzed:03/09/2017 21:35 ID:RTX-5 Analysis Batch No.:9156 ug/m3Units: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 133.4171-55-6 1,1,1-Trichloroethane ND 2.2 167.8579-34-5 1,1,2,2-Tetrachloroethan e ND 2.7 133.4179-00-5 1,1,2-Trichloroethane ND 2.2 187.3876-13-1 1,1,2-Trichlorotrifluoro ethane ND 3.1 98.9675-34-3 1,1-Dichloroethane ND 1.6 96.9475-35-4 1,1-Dichloroethene ND 1.6 181.45120-82-1 1,2,4-Trichlorobenzene ND 3.0 120.2095-63-6 1,2,4-Trimethylbenzene 6.1 2.0 187.87106-93-4 1,2-Dibromoethane ND 3.1 147.0095-50-1 1,2-Dichlorobenzene ND 2.4 98.96107-06-2 1,2-Dichloroethane ND 1.6 112.9978-87-5 1,2-Dichloropropane ND 1.8 170.9276-14-2 1,2-Dichlorotetrafluoroe thane ND 2.8 120.20108-67-8 1,3,5-Trimethylbenzene ND 2.0 147.00541-73-1 1,3-Dichlorobenzene ND 2.4 147.00106-46-7 1,4-Dichlorobenzene ND 2.4 88.11123-91-1 1,4-Dioxane ND 3.6 114.23540-84-1 2,2,4-Trimethylpentane 8.6 4.7 72.1178-93-3 2-Butanone 8.8 4.7 100.16108-10-1 4-Methyl-2-pentanone (MIBK) ND 4.1 78.1171-43-2 Benzene 18 1.3 126.58100-44-7 Benzyl chloride ND 4.1 163.8375-27-4 Bromodichloromethane ND 2.7 252.7575-25-2 Bromoform ND 4.1 94.9474-83-9 Bromomethane ND 1.6 153.8156-23-5 Carbon tetrachloride ND 1.3 112.56108-90-7 Chlorobenzene ND 1.8 64.5275-00-3 Chloroethane ND *1.1 119.3867-66-3 Chloroform ND 2.0 50.4974-87-3 Chloromethane 7.6 2.1 96.94156-59-2 cis-1,2-Dichloroethene ND 1.6 110.9710061-01-5 cis-1,3-Dichloropropene ND 1.8 84.16110-82-7 Cyclohexane 13 3.4 FORM I TO 15 LL 03/21/2017Page 90 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: DUP-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-3 TestAmerica Knoxville Matrix:RC09P109.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 00:00 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 100(mL) 0.32(mm) Date Analyzed:03/09/2017 21:35 ID:RTX-5 Analysis Batch No.:9156 ug/m3Units: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 208.29124-48-1 Dibromochloromethane ND 3.4 120.9175-71-8 Dichlorodifluoromethane 2.3 2.0 46.0764-17-5 Ethanol 1500 E 19 106.17100-41-4 Ethylbenzene 6.7 1.7 260.7687-68-3 Hexachlorobutadiene ND 4.3 86.17110-54-3 Hexane 40 3.5 88.151634-04-4 Methyl tert-butyl ether ND 2.9 84.9375-09-2 Methylene Chloride 150 3.5 106.17179601-23-1 m-Xylene & p-Xylene 25 1.7 106.1795-47-6 o-Xylene 7.1 1.7 104.15100-42-5 Styrene ND 1.7 74.1275-65-0 t-Butyl alcohol ND 4.9 165.83127-18-4 Tetrachloroethene ND 2.7 92.14108-88-3 Toluene 62 2.3 96.94156-60-5 trans-1,2-Dichloroethene ND 1.6 110.9710061-02-6 trans-1,3-Dichloropropen e ND 1.8 131.3979-01-6 Trichloroethene 3.0 1.1 137.3775-69-4 Trichlorofluoromethane ND 2.2 62.5075-01-4 Vinyl chloride ND 0.51 %RECCAS NO.LIMITSQSURROGATE 106 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 91 of 377 Report Date: 10-Mar-2017 08:03:56 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Lims ID:140-7345-A-3 Client ID:DUP-2017 Sample Type:Client Inject. Date:09-Mar-2017 21:35:30 ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004226-014 Misc. Info.:140-7345-a-3 Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 08:03:18 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 07:55:24 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.209 8.215 -0.006 99 435909 4.00 * 2 1,4-Difluorobenzene 114 10.372 10.377 -0.005 96 2100341 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.268 15.274 -0.006 89 1672298 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.961 16.961 0.000 96 1235329 4.23 8 Dichlorodifluoromethane 85 3.750 3.750 0.000 100 27226 0.0930 9 Chloromethane 52 3.896 3.896 0.000 99 37818 0.7407 M 17 Ethanol 31 4.661 4.634 0.027 98 5160041 163.6 E 21 Trichlorofluoromethane 101 5.012 5.012 0.000 98 12251 0.0344 29 2-Methyl-2-propanol 59 5.745 5.718 0.027 80 18220 0.0708 30 1,1,2-Trichloro-1,2,2-trif 101 5.794 5.788 0.006 88 4361 0.0145 31 Methylene Chloride 84 5.907 5.907 0.000 98 1190461 8.76 39 2-Butanone (MEK) 72 7.503 7.503 0.000 98 38921 0.5940 40 Hexane 56 7.595 7.595 0.000 91 276707 2.27 44 Chloroform 83 8.242 8.247 -0.005 90 18082 0.0617 50 Benzene 78 9.800 9.806 -0.006 98 423044 1.11 51 Cyclohexane 69 9.833 9.833 0.000 93 45512 0.7512 52 Carbon tetrachloride 117 9.849 9.843 0.006 92 8437 0.0292 56 Isooctane 57 10.658 10.663 -0.005 94 255941 0.3666 59 Trichloroethene 130 11.105 11.111 -0.006 96 20732 0.1114 65 4-Methyl-2-pentanone (MIBK 43 12.329 12.324 0.005 95 10543 0.0309 68 Toluene 91 13.241 13.246 -0.005 93 1492365 3.29 76 Tetrachloroethene 129 14.427 14.432 -0.005 90 4134 0.0249 79 Ethylbenzene 91 15.635 15.640 -0.005 99 176040 0.3071 81 m-Xylene & p-Xylene 91 15.802 15.807 -0.005 100 501284 1.15 83 Styrene 104 16.271 16.276 -0.005 73 16257 0.0564 85 o-Xylene 91 16.336 16.341 -0.005 98 150143 0.3260 92 1,3,5-Trimethylbenzene 120 17.781 17.781 0.000 91 17136 0.0593 96 1,2,4-Trimethylbenzene 105 18.245 18.245 0.000 97 133272 0.2476 03/21/2017Page 92 of 377 Report Date: 10-Mar-2017 08:03:56 Chrom Revision: 2.2 05-Mar-2017 11:38:00 QC Flag Legend Processing Flags E - Exceeded Maximum Amount Review Flags M - Manually Integrated Reagents: 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 93 of 377 Report Date: 10-Mar-2017 08:03:56 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Operator ID: Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Worklist Smp#:14 Client ID:DUP-2017 Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:9 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 Y ( X10 0 0 0 0 ) RC09P109[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 0 9 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 7 2 )+ * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 6 8 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 1 ) 03/21/2017Page 94 of 377 Report Date: 10-Mar-2017 08:03:56 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Recovery Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Lims ID:140-7345-A-3 Client ID:DUP-2017 Sample Type:Client Inject. Date:09-Mar-2017 21:35:30 ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004226-014 Misc. Info.:140-7345-a-3 Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 08:03:18 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 07:55:24 Compound Amount Added Amount Recovered %Rec. $4 4-Bromofluorobenzene (Surr)4.00 4.23 105.81 03/21/2017Page 95 of 377 Report Date: 10-Mar-2017 08:03:57 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 96 1,2,4-Trimethylbenzene, CAS: 95-63-6 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 11 22 33 44 55 66 77 Y ( X10 0 0 ) Raw Spec:Scan 2811(18.24) 105 120 913951 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 2811(18.24), Qvalue=97 105 120 7751 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 96 1,2,4-Trimethylbenzene @ 159.833 min. 105 120 7739 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 18.250 min.(Qvalue: 97) 17.7 18.0 18.3 18.6 Min 0 8 16 24 32 40 48 56 64 72 80 Y ( X10 0 0 ) m/z 105.0 1 8 . 2 4 5 17.7 18.0 18.3 18.6 Min 0 4 8 12 16 20 24 28 32 36 Y ( X10 0 0 ) m/z 120.0 1 8 . 2 4 5 17.7 18.0 18.3 18.6 Min 0 2 4 6 8 10 12 14 Y ( X10 0 0 ) m/z 119.0 1 8 . 2 5 0 03/21/2017Page 96 of 377 Report Date: 10-Mar-2017 08:03:57 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 56 Isooctane, CAS: 540-84-1 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 0 ) Raw Spec:Scan 1404(10.66) 57 56 41 43 39 70 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 1404(10.66), Qvalue=94 57 56 41 43 39 70 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 56 Isooctane @ 129.933 min. 57 56 41 43 99 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 10.660 min.(Qvalue: 94) 56 10.1 10.4 10.7 11.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 Y ( X10 0 0 0 ) m/z 57.0 1 0 . 6 5 8 10.1 10.4 10.7 11.0 Min 0 4 8 12 16 20 24 28 32 36 40 44 Y ( X10 0 0 ) m/z 56.0 1 0 . 6 6 3 10.1 10.4 10.7 11.0 Min 0 5 10 15 20 25 30 35 40 45 Y ( X10 0 0 ) m/z 41.0 1 0 . 6 6 3 03/21/2017Page 97 of 377 Report Date: 10-Mar-2017 08:03:56 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 39 2-Butanone (MEK), CAS: 78-93-3 20 40 60 80 100 120 140 160 180 200 m/z 0 10 20 30 40 50 60 70 Y ( X10 0 0 ) Raw Spec:Scan 819(7.50) 43 72 57 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 819(7.50), Qvalue=98 43 72 5742 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 39 2-Butanone (MEK) @ 10.950 min. 43 72 57 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 7.510 min.(Qvalue: 98) 7.0 7.3 7.6 7.9 Min 0 2 4 6 8 10 12 14 16 Y ( X10 0 0 ) m/z 72.0 7 . 5 0 3 7.0 7.3 7.6 7.9 Min 0 2 4 6 8 10 12 14 16 Y ( X10 0 0 0 ) m/z 43.0 7 . 5 0 3 7.0 7.3 7.6 7.9 Min 0 3 6 9 12 15 18 21 24 Y ( X10 0 0 ) m/z 29.0 7 . 5 0 3 03/21/2017Page 98 of 377 Report Date: 10-Mar-2017 08:03:56 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 50 Benzene, CAS: 71-43-2 20 40 60 80 100 120 140 160 180 200 m/z 0 3 6 9 12 15 18 Y ( X10 0 0 0 ) Raw Spec:Scan 1245(9.80) 78 775152 79 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 1245(9.80), Qvalue=98 78 775152 79 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 50 Benzene @ 17.083 min. 78 77 51 52 7938 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 9.800 min.(Qvalue: 98) 9.2 9.5 9.8 10.1 10.4 Min 0 2 4 6 8 10 12 14 16 18 Y ( X10 0 0 0 ) m/z 78.0 9 . 8 0 0 9.3 9.6 9.9 10.2 Min 0 4 8 12 16 20 24 28 32 36 Y ( X10 0 0 ) m/z 77.0 9 . 8 0 6 9.2 9.5 9.8 10.1 10.4 Min 0 4 8 12 16 20 24 28 32 Y ( X10 0 0 ) m/z 51.0 9 . 8 0 0 03/21/2017Page 99 of 377 Report Date: 10-Mar-2017 08:03:56 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 9 Chloromethane, CAS: 74-87-3 20 40 60 80 100 120 140 160 180 200 m/z 0 9 18 27 36 45 54 63 Y ( X10 0 0 ) Raw Spec:Scan 150(3.90) 50 52 4932 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 150(3.90), Qvalue=99 50 52 49 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 9 Chloromethane @ 1.983 min. 50 52 4935 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 3.900 min.(Qvalue: 99) 52 3.3 3.6 3.9 4.2 Min 0 2 4 6 8 10 12 14 16 18 20 22 Y ( X10 0 0 ) m/z 52.0 3 . 8 9 6 3.3 3.6 3.9 4.2 Min 0 6 12 18 24 30 36 42 48 54 60 66 Y ( X10 0 0 ) m/z 50.0 3 . 8 9 6 03/21/2017Page 100 of 377 Report Date: 10-Mar-2017 08:03:57 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 51 Cyclohexane, CAS: 110-82-7 20 40 60 80 100 120 140 160 180 200 m/z 0 9 18 27 36 45 54 63 Y ( X10 0 0 ) Raw Spec:Scan 1251(9.83) 56 8441 78 55 39 69 32 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 1251(9.83), Qvalue=93 56 84 41 55 69 4239 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 51 Cyclohexane @ 24.550 min. 56 84 41 55 69 39 42 8583 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 9.830 min.(Qvalue: 93) 41 9.3 9.6 9.9 10.2 Min 0 2 4 6 8 10 12 14 16 18 Y ( X10 0 0 ) m/z 69.0 9 . 8 3 3 9.3 9.6 9.9 10.2 Min 0 3 6 9 12 15 18 21 24 Y ( X10 0 0 ) m/z 55.0 9 . 8 3 3 9.3 9.6 9.9 10.2 Min 0 4 8 12 16 20 24 28 32 36 40 Y ( X10 0 0 ) m/z 41.0 9 . 8 2 7 03/21/2017Page 101 of 377 Report Date: 10-Mar-2017 08:03:56 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 8 Dichlorodifluoromethane, CAS: 75-71-8 20 40 60 80 100 120 140 160 180 200 m/z 0 3 6 9 12 15 Y ( X10 0 0 ) Raw Spec:Scan 123(3.75) 85 32 87 40 78 101 207 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 123(3.75), Qvalue=100 85 87 50 101 10335 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 8 Dichlorodifluoromethane @ 160.750 min. 85 87 50 10135 103 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 3.750 min.(Qvalue:100) 87 3.2 3.5 3.8 4.1 Min 0 2 4 6 8 10 12 14 16 Y ( X10 0 0 ) m/z 85.0 3 . 7 5 0 3.2 3.5 3.8 4.1 Min 0 5 10 15 20 25 30 35 40 45 50 55 Y ( X10 0 ) m/z 87.0 3 . 7 5 5 3.2 3.5 3.8 4.1 Min 2 7 12 17 22 27 32 37 42 47 52 Y ( X10 0 ) m/z 50.0 3 . 7 5 0 03/21/2017Page 102 of 377 Report Date: 10-Mar-2017 08:03:56 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 17 Ethanol, CAS: 64-17-5 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 3 6 9 12 15 18 21 Y ( X10 0 0 0 0 ) Raw Spec:Scan 292(4.66) 45 46 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 3 6 9 12 15 18 21 Y ( X10 0 0 0 0 ) Enhanced Spec:Scan 292(4.66) Bgrd 278( 4.58), Qvalue=98 45 46 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 17 Ethanol @ 1.567 min. 45 46 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 292 @ 4.661 min.(Qvalue: 98) 4.1 4.4 4.7 5.0 Min 0 2 4 6 8 10 12 14 16 18 20 Y ( X10 0 0 0 0 ) m/z 31.0 4 . 6 6 1 4.1 4.4 4.7 5.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 Y ( X10 0 0 0 0 ) m/z 45.0 4 . 6 6 1 03/21/2017Page 103 of 377 Report Date: 10-Mar-2017 08:03:57 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 79 Ethylbenzene, CAS: 100-41-4 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 0 0 ) Raw Spec:Scan 2327(15.63) 91 106 51 7765 7839 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 2327(15.63), Qvalue=99 91 106 51 65 77 7839 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 79 Ethylbenzene @ 86.183 min. 91 106 51 65 77 7839 105 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 15.640 min.(Qvalue: 99) 106 15.1 15.4 15.7 16.0 Min 0 3 6 9 12 15 18 21 24 Y ( X10 0 0 0 ) m/z 91.0 1 5 . 6 3 5 15.1 15.4 15.7 16.0 Min 0 2 4 6 8 10 12 Y ( X10 0 0 0 ) m/z 106.0 1 5 . 6 3 5 15.1 15.4 15.7 16.0 Min 0 3 6 9 12 15 18 21 24 27 30 Y ( X10 0 0 ) m/z 77.0 1 5 . 6 3 5 03/21/2017Page 104 of 377 Report Date: 10-Mar-2017 08:03:56 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 40 Hexane, CAS: 110-54-3 20 40 60 80 100 120 140 160 180 200 m/z 0 3 6 9 12 15 18 21 24 Y ( X10 0 0 0 ) Raw Spec:Scan 836(7.59) 57 41 43 56 86 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 836(7.59), Qvalue=91 57 41 43 56 86 71 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 40 Hexane @ 30.683 min. 57 43 56 86 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 7.600 min.(Qvalue: 91) 56 41 7.0 7.3 7.6 7.9 Min 0 2 4 6 8 10 12 14 16 Y ( X10 0 0 0 ) m/z 56.0 7 . 5 9 5 7.0 7.3 7.6 7.9 Min 0 3 6 9 12 15 18 21 24 Y ( X10 0 0 0 ) m/z 57.0 7 . 5 9 5 7.0 7.3 7.6 7.9 Min 0 3 6 9 12 15 18 21 24 27 30 33 Y ( X10 0 0 ) m/z 86.0 7 . 5 9 5 03/21/2017Page 105 of 377 Report Date: 10-Mar-2017 08:03:56 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 31 Methylene Chloride, CAS: 75-09-2 20 40 60 80 100 120 140 160 180 200 m/z 0 10 20 30 40 50 60 70 Y ( X10 0 0 0 ) Raw Spec:Scan 523(5.91) 49 84 86 51 47 88 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 523(5.91), Qvalue=98 49 84 86 51 47 88 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 31 Methylene Chloride @ 25.683 min. 49 84 86 51 47 88 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 5.900 min.(Qvalue: 98) 5.4 5.7 6.0 6.3 Min 0 5 10 15 20 25 30 35 40 45 Y ( X10 0 0 0 ) m/z 84.0 5 . 9 0 7 5.4 5.7 6.0 6.3 Min 0 7 14 21 28 35 42 49 56 63 70 77 Y ( X10 0 0 0 ) m/z 49.0 5 . 9 0 2 5.4 5.7 6.0 6.3 Min 0 3 6 9 12 15 18 21 24 27 30 Y ( X10 0 0 0 ) m/z 86.0 5 . 9 0 2 03/21/2017Page 106 of 377 Report Date: 10-Mar-2017 08:03:57 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 81 m-Xylene & p-Xylene, CAS: 179601-23-1 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 4 8 12 16 20 24 Y ( X10 0 0 0 ) Raw Spec:Scan 2358(15.80) 91 106 7751 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 2358(15.80), Qvalue=100 91 106 7751 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 13 26 39 52 65 78 91 Y Ref Spec: 81 m-Xylene & p-Xylene @ 15.820 min. 91 106 7751 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 15.810 min.(Qvalue:100) 15.3 15.6 15.9 16.2 Min 0 3 6 9 12 15 18 21 24 Y ( X10 0 0 0 ) m/z 91.0 1 5 . 8 0 2 15.3 15.6 15.9 16.2 Min 0 2 4 6 8 10 12 Y ( X10 0 0 0 ) m/z 106.0 1 5 . 8 0 2 15.3 15.6 15.9 16.2 Min 0 3 6 9 12 15 18 21 24 27 30 Y ( X10 0 0 ) m/z 77.0 1 5 . 8 0 2 03/21/2017Page 107 of 377 Report Date: 10-Mar-2017 08:03:57 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 85 o-Xylene, CAS: 95-47-6 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 11 22 33 44 55 66 77 Y ( X10 0 0 ) Raw Spec:Scan 2457(16.34) 91 106 51 77 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 2457(16.34), Qvalue=98 91 106 51 77 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 85 o-Xylene @ 86.000 min. 91 106 7751 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 16.340 min.(Qvalue: 98) 15.8 16.1 16.4 16.7 Min 0 8 16 24 32 40 48 56 64 72 80 Y ( X10 0 0 ) m/z 91.0 1 6 . 3 3 6 15.8 16.1 16.4 16.7 Min 0 4 8 12 16 20 24 28 32 36 40 Y ( X10 0 0 ) m/z 106.0 1 6 . 3 3 6 15.8 16.1 16.4 16.7 Min 0 9 18 27 36 45 54 63 72 81 90 Y ( X10 0 ) m/z 77.0 1 6 . 3 4 1 03/21/2017Page 108 of 377 Report Date: 10-Mar-2017 08:03:57 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 68 Toluene, CAS: 108-88-3 20 40 60 80 100 120 140 160 180 200 m/z 0 10 20 30 40 50 60 70 Y ( X10 0 0 0 ) Raw Spec:Scan 1883(13.24) 91 92 653951 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 1883(13.24), Qvalue=93 91 92 653951 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 68 Toluene @ 41.267 min. 91 92 653951 93 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 13.240 min.(Qvalue: 93) 12.7 13.0 13.3 13.6 Min 0 7 14 21 28 35 42 49 56 63 70 77 Y ( X10 0 0 0 ) m/z 91.0 1 3 . 2 4 1 12.7 13.0 13.3 13.6 Min 0 4 8 12 16 20 24 28 32 36 40 44 Y ( X10 0 0 0 ) m/z 92.0 1 3 . 2 4 1 03/21/2017Page 109 of 377 Report Date: 10-Mar-2017 08:03:57 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 59 Trichloroethene, CAS: 79-01-6 20 30 40 50 60 70 80 90 100 110 120 130 140 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Raw Spec:Scan 1487(11.11) 13095 132 32 97 60 40 62 44 94 992959 20 30 40 50 60 70 80 90 100 110 120 130 140 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 1487(11.11), Qvalue=96 13295 97 60 624735 94 9948 20 30 40 50 60 70 80 90 100 110 120 130 140 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 59 Trichloroethene @ 223.767 min. 130 95 97 60 6247 99943559 20 30 40 50 60 70 80 90 100 110 120 130 140 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 11.110 min.(Qvalue: 96) 95 132 10.6 10.9 11.2 11.5 Min 0 1 2 3 4 5 6 7 8 9 10 11 Y ( X10 0 0 ) m/z 130.0 1 1 . 1 0 5 10.6 10.9 11.2 11.5 Min 0 9 18 27 36 45 54 63 72 81 90 99 Y ( X10 0 ) m/z 95.0 1 1 . 1 0 5 10.6 10.9 11.2 11.5 Min 0 1 2 3 4 5 6 7 8 9 10 11 Y ( X10 0 0 ) m/z 132.0 1 1 . 1 1 1 03/21/2017Page 110 of 377 Report Date: 10-Mar-2017 08:03:56 Chrom Revision: 2.2 05-Mar-2017 11:38:00 Manual Integration/User Assign Peak Report TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P109.D Injection Date:09-Mar-2017 21:35:30 Instrument ID:MR Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:ALS Bottle#:9 Worklist Smp#:14 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 9 Chloromethane, CAS: 74-87-3 Signal: 1 Processing Integration Results RT: 3.90 Area: 29768 Amount: 0.583057 Amount Units: ppb v/v 3.7 3.9 4.1 Min 0 2 4 6 8 10 12 14 16 18 20 22 Y ( X10 0 0 ) m/z 52.0 3 . 8 9 6 Manual Integration Results RT: 3.90 Area: 37818 Amount: 0.740729 Amount Units: ppb v/v 3.7 3.9 4.1 Min 0 2 4 6 8 10 12 14 16 18 20 22 Y ( X10 0 0 ) m/z 52.0 3 . 8 9 6 Reviewer: tajh, 10-Mar-2017 08:03:55 Audit Action: Manually Integrated Audit Reason: Baseline 03/21/2017Page 111 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: DUP-2017 DL SDG No.: 140-7345-1 Lab Sample ID:140-7345-3 DL TestAmerica Knoxville Matrix:GC10P105.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 00:00 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 25(mL) 0.32(mm) Date Analyzed:03/10/2017 14:51 ID:RTX-5 Analysis Batch No.:9158 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 46.0764-17-5 Ethanol 1300 D 40 %RECCAS NO.LIMITSQSURROGATE 103 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 112 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: DUP-2017 DL SDG No.: 140-7345-1 Lab Sample ID:140-7345-3 DL TestAmerica Knoxville Matrix:GC10P105.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 00:00 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 25(mL) 0.32(mm) Date Analyzed:03/10/2017 14:51 ID:RTX-5 Analysis Batch No.:9158 ug/m3Units: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 46.0764-17-5 Ethanol 2400 D 75 %RECCAS NO.LIMITSQSURROGATE 103 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 113 of 377 Report Date: 13-Mar-2017 11:58:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GC10P105.D Lims ID:140-7345-A-3 Client ID:DUP-2017 Sample Type:Client Inject. Date:10-Mar-2017 14:51:30 ALS Bottle#:5 Worklist Smp#:9 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004228-009 Misc. Info.:140-7345-a-3 Operator ID:7126 Instrument ID:MG Method:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:13-Mar-2017 11:58:53 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK020 First Level Reviewer: barlozhetskayaa Date:13-Mar-2017 11:58:53 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.001 8.001 0.000 86 300843 4.00 * 2 1,4-Difluorobenzene 114 10.169 10.169 0.000 95 1427589 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.039 15.038 0.000 88 1440175 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.705 16.710 -0.005 94 1109846 4.14 8 Dichlorodifluoromethane 85 3.520 3.515 0.005 99 9184 0.0344 9 Chloromethane 52 3.666 3.666 0.000 100 5927 0.2752 M 17 Ethanol 31 4.383 4.361 0.022 97 2117701 64.0 21 Trichlorofluoromethane 101 4.755 4.750 0.005 98 3783 0.0138 31 Methylene Chloride 84 5.667 5.666 0.001 89 173031 2.39 39 2-Butanone (MEK) 72 7.311 7.284 0.027 46 3448 0.1035 40 Hexane 56 7.349 7.343 0.006 90 36639 0.6053 44 Chloroform 83 8.018 8.028 -0.010 75 3202 0.0161 49 Benzene 78 9.587 9.592 -0.005 97 49624 0.2219 50 Cyclohexane 69 9.598 9.597 0.001 90 7522 0.1911 56 Isooctane 57 10.423 10.422 0.001 96 31465 0.0893 59 Trichloroethene 130 10.897 10.908 -0.011 92 3184 0.0248 68 Toluene 91 13.027 13.027 0.000 93 145779 0.5577 79 Ethylbenzene 91 15.394 15.394 0.000 99 18263 0.0532 81 m-Xylene & p-Xylene 91 15.556 15.567 -0.011 99 51464 0.1912 85 o-Xylene 91 16.090 16.090 0.000 98 16217 0.0588 96 1,2,4-Trimethylbenzene 105 17.956 17.956 0.000 98 14532 0.0442 QC Flag Legend Review Flags M - Manually Integrated Reagents: 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 114 of 377 Report Date: 13-Mar-2017 11:58:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GC10P105.D Injection Date:10-Mar-2017 14:51:30 Instrument ID:MG Operator ID:7126 Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Worklist Smp#:9 Client ID:DUP-2017 Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:5 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 Y ( X10 0 0 0 0 ) GC10P105[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 0 0 1 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 6 9 )+* C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 3 9 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 7 1 0 ) 03/21/2017Page 115 of 377 Report Date: 13-Mar-2017 11:58:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Recovery Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GC10P105.D Lims ID:140-7345-A-3 Client ID:DUP-2017 Sample Type:Client Inject. Date:10-Mar-2017 14:51:30 ALS Bottle#:5 Worklist Smp#:9 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004228-009 Misc. Info.:140-7345-a-3 Operator ID:7126 Instrument ID:MG Method:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:13-Mar-2017 11:58:53 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK020 First Level Reviewer: barlozhetskayaa Date:13-Mar-2017 11:58:53 Compound Amount Added Amount Recovered %Rec. $4 4-Bromofluorobenzene (Surr)4.00 4.14 103.48 03/21/2017Page 116 of 377 Report Date: 13-Mar-2017 11:58:54 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GC10P105.D Injection Date:10-Mar-2017 14:51:30 Instrument ID:MG Lims ID:140-7345-A-3 Lab Sample ID:140-7345-3 Client ID:DUP-2017 Operator ID:7126 ALS Bottle#:5 Worklist Smp#:9 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 17 Ethanol, CAS: 64-17-5 20 40 60 80 100 120 140 160 180 200 m/z 0 9 18 27 36 45 54 63 Y ( X10 0 0 0 ) Raw Spec:Scan 214(4.38) 31 45 46 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 214(4.38), Qvalue=97 31 45 46 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 17 Ethanol @ 1.567 min. 31 45 46 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 4.380 min.(Qvalue: 97) 3.8 4.1 4.4 4.7 Min 0 6 12 18 24 30 36 42 48 54 60 66 Y ( X10 0 0 0 ) m/z 31.0 4 . 3 8 3 3.8 4.1 4.4 4.7 Min 0 3 6 9 12 15 18 21 24 27 30 Y ( X10 0 0 0 ) m/z 45.0 4 . 3 8 3 03/21/2017Page 117 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: OA-10-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-4 TestAmerica Knoxville Matrix:RC09P110.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:25 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:03/09/2017 22:28 ID:RTX-5 Analysis Batch No.:9156 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 133.4171-55-6 1,1,1-Trichloroethane ND 0.080 167.8579-34-5 1,1,2,2-Tetrachloroethan e ND 0.080 133.4179-00-5 1,1,2-Trichloroethane ND 0.080 187.3876-13-1 1,1,2-Trichlorotrifluoro ethane ND 0.080 98.9675-34-3 1,1-Dichloroethane ND 0.080 96.9475-35-4 1,1-Dichloroethene ND 0.080 181.45120-82-1 1,2,4-Trichlorobenzene ND 0.080 120.2095-63-6 1,2,4-Trimethylbenzene ND 0.080 187.87106-93-4 1,2-Dibromoethane ND 0.080 147.0095-50-1 1,2-Dichlorobenzene ND 0.080 98.96107-06-2 1,2-Dichloroethane ND 0.080 112.9978-87-5 1,2-Dichloropropane ND 0.080 170.9276-14-2 1,2-Dichlorotetrafluoroe thane ND 0.080 120.20108-67-8 1,3,5-Trimethylbenzene ND 0.080 147.00541-73-1 1,3-Dichlorobenzene ND 0.080 147.00106-46-7 1,4-Dichlorobenzene ND 0.080 88.11123-91-1 1,4-Dioxane ND 0.20 114.23540-84-1 2,2,4-Trimethylpentane ND 0.20 72.1178-93-3 2-Butanone 0.52 0.32 100.16108-10-1 4-Methyl-2-pentanone (MIBK) ND 0.20 78.1171-43-2 Benzene 0.29 0.080 126.58100-44-7 Benzyl chloride ND 0.16 163.8375-27-4 Bromodichloromethane ND 0.080 252.7575-25-2 Bromoform ND 0.080 94.9474-83-9 Bromomethane ND 0.080 153.8156-23-5 Carbon tetrachloride 0.076 0.040 112.56108-90-7 Chlorobenzene ND 0.080 64.5275-00-3 Chloroethane ND *0.080 119.3867-66-3 Chloroform ND 0.080 50.4974-87-3 Chloromethane 0.57 0.20 96.94156-59-2 cis-1,2-Dichloroethene ND 0.080 110.9710061-01-5 cis-1,3-Dichloropropene ND 0.080 84.16110-82-7 Cyclohexane ND 0.20 FORM I TO 15 LL 03/21/2017Page 118 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: OA-10-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-4 TestAmerica Knoxville Matrix:RC09P110.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:25 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:03/09/2017 22:28 ID:RTX-5 Analysis Batch No.:9156 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 208.29124-48-1 Dibromochloromethane ND 0.080 120.9175-71-8 Dichlorodifluoromethane 0.18 0.080 46.0764-17-5 Ethanol 5.4 2.0 106.17100-41-4 Ethylbenzene ND 0.080 260.7687-68-3 Hexachlorobutadiene ND 0.080 86.17110-54-3 Hexane ND 0.20 88.151634-04-4 Methyl tert-butyl ether ND 0.16 84.9375-09-2 Methylene Chloride 0.24 0.20 106.17179601-23-1 m-Xylene & p-Xylene 0.15 0.080 106.1795-47-6 o-Xylene ND 0.080 104.15100-42-5 Styrene ND 0.080 74.1275-65-0 t-Butyl alcohol ND 0.32 165.83127-18-4 Tetrachloroethene ND 0.080 92.14108-88-3 Toluene 0.31 0.12 96.94156-60-5 trans-1,2-Dichloroethene ND 0.080 110.9710061-02-6 trans-1,3-Dichloropropen e ND 0.080 131.3979-01-6 Trichloroethene ND 0.040 137.3775-69-4 Trichlorofluoromethane 0.17 0.080 62.5075-01-4 Vinyl chloride ND 0.040 %RECCAS NO.LIMITSQSURROGATE 100 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 119 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: OA-10-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-4 TestAmerica Knoxville Matrix:RC09P110.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:25 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:03/09/2017 22:28 ID:RTX-5 Analysis Batch No.:9156 ug/m3Units: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 133.4171-55-6 1,1,1-Trichloroethane ND 0.44 167.8579-34-5 1,1,2,2-Tetrachloroethan e ND 0.55 133.4179-00-5 1,1,2-Trichloroethane ND 0.44 187.3876-13-1 1,1,2-Trichlorotrifluoro ethane ND 0.61 98.9675-34-3 1,1-Dichloroethane ND 0.32 96.9475-35-4 1,1-Dichloroethene ND 0.32 181.45120-82-1 1,2,4-Trichlorobenzene ND 0.59 120.2095-63-6 1,2,4-Trimethylbenzene ND 0.39 187.87106-93-4 1,2-Dibromoethane ND 0.61 147.0095-50-1 1,2-Dichlorobenzene ND 0.48 98.96107-06-2 1,2-Dichloroethane ND 0.32 112.9978-87-5 1,2-Dichloropropane ND 0.37 170.9276-14-2 1,2-Dichlorotetrafluoroe thane ND 0.56 120.20108-67-8 1,3,5-Trimethylbenzene ND 0.39 147.00541-73-1 1,3-Dichlorobenzene ND 0.48 147.00106-46-7 1,4-Dichlorobenzene ND 0.48 88.11123-91-1 1,4-Dioxane ND 0.72 114.23540-84-1 2,2,4-Trimethylpentane ND 0.93 72.1178-93-3 2-Butanone 1.5 0.94 100.16108-10-1 4-Methyl-2-pentanone (MIBK) ND 0.82 78.1171-43-2 Benzene 0.94 0.26 126.58100-44-7 Benzyl chloride ND 0.83 163.8375-27-4 Bromodichloromethane ND 0.54 252.7575-25-2 Bromoform ND 0.83 94.9474-83-9 Bromomethane ND 0.31 153.8156-23-5 Carbon tetrachloride 0.48 0.25 112.56108-90-7 Chlorobenzene ND 0.37 64.5275-00-3 Chloroethane ND *0.21 119.3867-66-3 Chloroform ND 0.39 50.4974-87-3 Chloromethane 1.2 0.41 96.94156-59-2 cis-1,2-Dichloroethene ND 0.32 110.9710061-01-5 cis-1,3-Dichloropropene ND 0.36 84.16110-82-7 Cyclohexane ND 0.69 FORM I TO 15 LL 03/21/2017Page 120 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: OA-10-2017 SDG No.: 140-7345-1 Lab Sample ID:140-7345-4 TestAmerica Knoxville Matrix:RC09P110.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 03/06/2017 11:25 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:03/09/2017 22:28 ID:RTX-5 Analysis Batch No.:9156 ug/m3Units: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 208.29124-48-1 Dibromochloromethane ND 0.68 120.9175-71-8 Dichlorodifluoromethane 0.89 0.40 46.0764-17-5 Ethanol 10 3.8 106.17100-41-4 Ethylbenzene ND 0.35 260.7687-68-3 Hexachlorobutadiene ND 0.85 86.17110-54-3 Hexane ND 0.70 88.151634-04-4 Methyl tert-butyl ether ND 0.58 84.9375-09-2 Methylene Chloride 0.82 0.69 106.17179601-23-1 m-Xylene & p-Xylene 0.66 0.35 106.1795-47-6 o-Xylene ND 0.35 104.15100-42-5 Styrene ND 0.34 74.1275-65-0 t-Butyl alcohol ND 0.97 165.83127-18-4 Tetrachloroethene ND 0.54 92.14108-88-3 Toluene 1.2 0.45 96.94156-60-5 trans-1,2-Dichloroethene ND 0.32 110.9710061-02-6 trans-1,3-Dichloropropen e ND 0.36 131.3979-01-6 Trichloroethene ND 0.21 137.3775-69-4 Trichlorofluoromethane 0.93 0.45 62.5075-01-4 Vinyl chloride ND 0.10 %RECCAS NO.LIMITSQSURROGATE 100 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 121 of 377 Report Date: 10-Mar-2017 08:03:58 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P110.D Lims ID:140-7345-A-4 Client ID:OA-10-2017 Sample Type:Client Inject. Date:09-Mar-2017 22:28:30 ALS Bottle#:10 Worklist Smp#:15 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004226-015 Misc. Info.:140-7345-a-4 Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 08:03:18 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 07:56:01 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.204 8.215 -0.011 98 420420 4.00 * 2 1,4-Difluorobenzene 114 10.372 10.377 -0.005 96 2052213 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.268 15.274 -0.006 89 1564423 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.961 16.961 0.000 96 1088033 3.98 8 Dichlorodifluoromethane 85 3.761 3.750 0.011 99 50841 0.1801 9 Chloromethane 52 3.901 3.896 0.005 99 28100 0.5707 17 Ethanol 31 4.640 4.634 0.006 98 164281 5.40 21 Trichlorofluoromethane 101 5.012 5.012 0.000 99 57047 0.1660 29 2-Methyl-2-propanol 59 5.735 5.718 0.017 95 14513 0.0584 30 1,1,2-Trichloro-1,2,2-trif 101 5.788 5.788 0.000 96 20297 0.0701 31 Methylene Chloride 84 5.907 5.907 0.000 98 30979 0.2362 39 2-Butanone (MEK) 72 7.509 7.503 0.006 99 32757 0.5183 40 Hexane 56 7.595 7.595 0.000 89 22069 0.1875 44 Chloroform 83 8.237 8.247 -0.010 76 6241 0.0221 50 Benzene 78 9.800 9.806 -0.006 98 108884 0.2930 51 Cyclohexane 69 9.827 9.833 -0.006 65 3721 0.0629 52 Carbon tetrachloride 117 9.844 9.843 0.001 94 21379 0.0758 56 Isooctane 57 10.658 10.663 -0.005 95 51532 0.0755 59 Trichloroethene 130 11.111 11.111 0.000 93 3255 0.0179 65 4-Methyl-2-pentanone (MIBK 43 12.329 12.324 0.005 98 63676 0.1909 68 Toluene 91 13.241 13.246 -0.005 92 133387 0.3141 76 Tetrachloroethene 129 14.427 14.432 -0.005 94 6651 0.0428 79 Ethylbenzene 91 15.635 15.640 -0.005 98 24937 0.0465 81 m-Xylene & p-Xylene 91 15.807 15.807 0.000 100 61841 0.1517 85 o-Xylene 91 16.336 16.341 -0.005 97 24311 0.0564 96 1,2,4-Trimethylbenzene 105 18.245 18.245 0.000 97 20073 0.0399 03/21/2017Page 122 of 377 Report Date: 10-Mar-2017 08:03:58 Chrom Revision: 2.2 05-Mar-2017 11:38:00 Reagents: 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 123 of 377 Report Date: 10-Mar-2017 08:03:58 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P110.D Injection Date:09-Mar-2017 22:28:30 Instrument ID:MR Operator ID: Lims ID:140-7345-A-4 Lab Sample ID:140-7345-4 Worklist Smp#:15 Client ID:OA-10-2017 Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:10 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 Y ( X10 0 0 0 0 ) RC09P110[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 0 4 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 7 2 )+ * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 6 8 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 1 ) 03/21/2017Page 124 of 377 Report Date: 10-Mar-2017 08:03:58 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Recovery Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P110.D Lims ID:140-7345-A-4 Client ID:OA-10-2017 Sample Type:Client Inject. Date:09-Mar-2017 22:28:30 ALS Bottle#:10 Worklist Smp#:15 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004226-015 Misc. Info.:140-7345-a-4 Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 08:03:18 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 07:56:01 Compound Amount Added Amount Recovered %Rec. $4 4-Bromofluorobenzene (Surr)4.00 3.98 99.62 03/21/2017Page 125 of 377 Report Date: 10-Mar-2017 08:03:59 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P110.D Injection Date:09-Mar-2017 22:28:30 Instrument ID:MR Lims ID:140-7345-A-4 Lab Sample ID:140-7345-4 Client ID:OA-10-2017 Operator ID:ALS Bottle#:10 Worklist Smp#:15 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 39 2-Butanone (MEK), CAS: 78-93-3 20 40 60 80 100 120 140 160 180 200 m/z 0 9 18 27 36 45 54 63 Y ( X10 0 0 ) Raw Spec:Scan 820(7.51) 43 72 57 20 40 60 80 100 120 140 160 180 200 m/z 0 8 16 24 32 40 48 56 Y ( X10 0 0 ) Enhanced Spec:Scan 820(7.51) Bgrd 812( 7.46), Qvalue=99 43 72 57 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 39 2-Butanone (MEK) @ 10.950 min. 43 72 57 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 820 @ 7.509 min.(Qvalue: 99) 7.0 7.3 7.6 7.9 Min 0 2 4 6 8 10 12 14 Y ( X10 0 0 ) m/z 72.0 7 . 5 0 9 7.0 7.3 7.6 7.9 Min 0 6 12 18 24 30 36 42 48 54 60 66 Y ( X10 0 0 ) m/z 43.0 7 . 5 0 3 7.0 7.3 7.6 7.9 Min 0 2 4 6 8 10 12 14 16 18 Y ( X10 0 0 ) m/z 29.0 7 . 5 0 9 03/21/2017Page 126 of 377 Report Date: 10-Mar-2017 08:03:59 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P110.D Injection Date:09-Mar-2017 22:28:30 Instrument ID:MR Lims ID:140-7345-A-4 Lab Sample ID:140-7345-4 Client ID:OA-10-2017 Operator ID:ALS Bottle#:10 Worklist Smp#:15 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 50 Benzene, CAS: 71-43-2 29 33 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 m/z 0 6 12 18 24 30 36 42 Y ( X10 0 0 ) Raw Spec:Scan 1245(9.80) 78 77515239 41 797656 29 33 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 1245(9.80), Qvalue=98 78 7752 39 7976 29 33 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 50 Benzene @ 17.083 min. 78 77 51 52 39 7974 29 33 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101 105 109 113 117 121 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 9.800 min.(Qvalue: 98) 9.2 9.5 9.8 10.1 10.4 Min 0 4 8 12 16 20 24 28 32 36 40 44 Y ( X10 0 0 ) m/z 78.0 9 . 8 0 0 9.2 9.5 9.8 10.1 10.4 Min 0 9 18 27 36 45 54 63 72 81 90 99 Y ( X10 0 ) m/z 77.0 9 . 8 0 0 9.2 9.5 9.8 10.1 10.4 Min 0 9 18 27 36 45 54 63 72 81 90 Y ( X10 0 ) m/z 51.0 9 . 8 0 0 03/21/2017Page 127 of 377 Report Date: 10-Mar-2017 08:03:59 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P110.D Injection Date:09-Mar-2017 22:28:30 Instrument ID:MR Lims ID:140-7345-A-4 Lab Sample ID:140-7345-4 Client ID:OA-10-2017 Operator ID:ALS Bottle#:10 Worklist Smp#:15 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 52 Carbon tetrachloride, CAS: 56-23-5 29 33 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101105109113117121 m/z 0 11 22 33 44 55 66 77 Y ( X10 0 ) Raw Spec:Scan 1253(9.84) 117 56 8441 4340 55 6957 77 85 29 33 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101105109113117121 m/z 0 11 22 33 44 55 66 77 Y ( X10 0 ) Enhanced Spec:Scan 1253(9.84) Bgrd 1241( 9.77), Qvalue=94 117 56 84 47 82553569 29 33 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101105109113117121 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 52 Carbon tetrachloride @ 449.767 min. 117 8247 843549 29 33 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 101105109113117121 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1253 @ 9.844 min.(Qvalue: 94) 56 9.3 9.6 9.9 10.2 Min 0 8 16 24 32 40 48 56 64 72 80 Y ( X10 0 ) m/z 117.0 9 . 8 4 4 9.3 9.6 9.9 10.2 Min 0 8 16 24 32 40 48 56 64 72 80 Y ( X10 0 ) m/z 119.0 9 . 8 3 8 9.3 9.6 9.9 10.2 Min 0 3 6 9 12 15 18 21 24 27 Y ( X10 0 ) m/z 121.0 9 . 8 2 7 03/21/2017Page 128 of 377 Report Date: 10-Mar-2017 08:03:58 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P110.D Injection Date:09-Mar-2017 22:28:30 Instrument ID:MR Lims ID:140-7345-A-4 Lab Sample ID:140-7345-4 Client ID:OA-10-2017 Operator ID:ALS Bottle#:10 Worklist Smp#:15 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 9 Chloromethane, CAS: 74-87-3 20 40 60 80 100 120 140 160 180 200 m/z 0 6 12 18 24 30 36 42 Y ( X10 0 0 ) Raw Spec:Scan 151(3.90) 50 52 32 49 78 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 151(3.90), Qvalue=99 50 52 49 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 9 Chloromethane @ 1.983 min. 50 52 4935 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 3.910 min.(Qvalue: 99) 52 3.3 3.6 3.9 4.2 4.5 Min 0 2 4 6 8 10 12 14 16 Y ( X10 0 0 ) m/z 52.0 3 . 9 0 1 3.3 3.6 3.9 4.2 4.5 Min 0 4 8 12 16 20 24 28 32 36 40 44 Y ( X10 0 0 ) m/z 50.0 3 . 9 0 1 03/21/2017Page 129 of 377 Report Date: 10-Mar-2017 08:03:58 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P110.D Injection Date:09-Mar-2017 22:28:30 Instrument ID:MR Lims ID:140-7345-A-4 Lab Sample ID:140-7345-4 Client ID:OA-10-2017 Operator ID:ALS Bottle#:10 Worklist Smp#:15 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 8 Dichlorodifluoromethane, CAS: 75-71-8 20 40 60 80 100 120 140 160 180 200 m/z 0 4 8 12 16 20 24 28 32 Y ( X10 0 0 ) Raw Spec:Scan 125(3.76) 85 32 87 50 10178 103 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 125(3.76), Qvalue=99 85 87 50 10135 103 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 8 Dichlorodifluoromethane @ 160.750 min. 85 87 50 10135 103 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 3.760 min.(Qvalue: 99) 3.2 3.5 3.8 4.1 Min 0 3 6 9 12 15 18 21 24 27 30 Y ( X10 0 0 ) m/z 85.0 3 . 7 6 1 3.2 3.5 3.8 4.1 Min 0 9 18 27 36 45 54 63 72 81 90 Y ( X10 0 ) m/z 87.0 3 . 7 6 1 3.2 3.5 3.8 4.1 Min 2 10 18 26 34 42 50 58 66 74 82 Y ( X10 0 ) m/z 50.0 3 . 7 5 6 03/21/2017Page 130 of 377 Report Date: 10-Mar-2017 08:03:58 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P110.D Injection Date:09-Mar-2017 22:28:30 Instrument ID:MR Lims ID:140-7345-A-4 Lab Sample ID:140-7345-4 Client ID:OA-10-2017 Operator ID:ALS Bottle#:10 Worklist Smp#:15 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 17 Ethanol, CAS: 64-17-5 20 40 60 80 100 120 140 160 180 200 220 m/z 0 9 18 27 36 45 54 63 72 Y ( X10 0 0 ) Raw Spec:Scan 288(4.64) 31 45 46 20 40 60 80 100 120 140 160 180 200 220 m/z 0 9 18 27 36 45 54 63 72 Y ( X10 0 0 ) Enhanced Spec:Scan 288(4.64) Bgrd 278( 4.58), Qvalue=98 31 45 46 20 40 60 80 100 120 140 160 180 200 220 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 17 Ethanol @ 1.567 min. 31 45 46 20 40 60 80 100 120 140 160 180 200 220 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 288 @ 4.640 min.(Qvalue: 98) 45 4.1 4.4 4.7 5.0 Min 0 7 14 21 28 35 42 49 56 63 70 Y ( X10 0 0 ) m/z 31.0 4 . 6 4 0 4.1 4.4 4.7 5.0 Min 0 4 8 12 16 20 24 28 32 36 40 Y ( X10 0 0 ) m/z 45.0 4 . 6 3 5 03/21/2017Page 131 of 377 Report Date: 10-Mar-2017 08:03:59 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P110.D Injection Date:09-Mar-2017 22:28:30 Instrument ID:MR Lims ID:140-7345-A-4 Lab Sample ID:140-7345-4 Client ID:OA-10-2017 Operator ID:ALS Bottle#:10 Worklist Smp#:15 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 31 Methylene Chloride, CAS: 75-09-2 20 40 60 80 100 120 140 160 180 200 m/z 0 3 6 9 12 15 18 21 Y ( X10 0 0 ) Raw Spec:Scan 523(5.91) 49 84 32 86 51 47 71 88 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 523(5.91), Qvalue=98 49 84 86 51 47 8856 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 31 Methylene Chloride @ 25.683 min. 49 84 86 51 47 88 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 5.900 min.(Qvalue: 98) 5.4 5.7 6.0 6.3 Min 0 2 4 6 8 10 12 14 Y ( X10 0 0 ) m/z 84.0 5 . 9 0 7 5.4 5.7 6.0 6.3 Min 0 2 4 6 8 10 12 14 16 18 20 Y ( X10 0 0 ) m/z 49.0 5 . 9 0 2 5.4 5.7 6.0 6.3 Min 0 8 16 24 32 40 48 56 64 72 80 Y ( X10 0 ) m/z 86.0 5 . 9 0 7 03/21/2017Page 132 of 377 Report Date: 10-Mar-2017 08:03:59 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P110.D Injection Date:09-Mar-2017 22:28:30 Instrument ID:MR Lims ID:140-7345-A-4 Lab Sample ID:140-7345-4 Client ID:OA-10-2017 Operator ID:ALS Bottle#:10 Worklist Smp#:15 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 81 m-Xylene & p-Xylene, CAS: 179601-23-1 20 40 60 80 100 120 140 160 180 200 m/z 0 4 8 12 16 20 24 28 Y ( X10 0 0 ) Raw Spec:Scan 2359(15.81) 91 106 32 1057751 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 2359(15.81), Qvalue=100 91 106 105 7751 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y Ref Spec: 81 m-Xylene & p-Xylene @ 15.820 min. 91 106 105 7751 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 15.810 min.(Qvalue:100) 15.3 15.6 15.9 16.2 Min 0 3 6 9 12 15 18 21 24 27 30 Y ( X10 0 0 ) m/z 91.0 1 5 . 8 0 7 15.3 15.6 15.9 16.2 Min 0 2 4 6 8 10 12 14 Y ( X10 0 0 ) m/z 106.0 1 5 . 8 0 2 15.3 15.6 15.9 16.2 Min 0 4 8 12 16 20 24 28 32 36 Y ( X10 0 ) m/z 77.0 1 5 . 8 0 7 03/21/2017Page 133 of 377 Report Date: 10-Mar-2017 08:03:59 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P110.D Injection Date:09-Mar-2017 22:28:30 Instrument ID:MR Lims ID:140-7345-A-4 Lab Sample ID:140-7345-4 Client ID:OA-10-2017 Operator ID:ALS Bottle#:10 Worklist Smp#:15 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 68 Toluene, CAS: 108-88-3 20 40 60 80 100 120 140 160 180 200 m/z 0 9 18 27 36 45 54 63 Y ( X10 0 0 ) Raw Spec:Scan 1883(13.24) 91 92 39 6551 20 40 60 80 100 120 140 160 180 200 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 1883(13.24), Qvalue=92 91 92 653951 20 40 60 80 100 120 140 160 180 200 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 68 Toluene @ 41.267 min. 91 92 653951 93 20 40 60 80 100 120 140 160 180 200 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 13.240 min.(Qvalue: 92) 12.7 13.0 13.3 13.6 Min 0 6 12 18 24 30 36 42 48 54 60 66 Y ( X10 0 0 ) m/z 91.0 1 3 . 2 4 1 12.7 13.0 13.3 13.6 Min 0 4 8 12 16 20 24 28 32 36 Y ( X10 0 0 ) m/z 92.0 1 3 . 2 4 1 03/21/2017Page 134 of 377 Report Date: 10-Mar-2017 08:03:58 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09P110.D Injection Date:09-Mar-2017 22:28:30 Instrument ID:MR Lims ID:140-7345-A-4 Lab Sample ID:140-7345-4 Client ID:OA-10-2017 Operator ID:ALS Bottle#:10 Worklist Smp#:15 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 21 Trichlorofluoromethane, CAS: 75-69-4 20 40 60 80 100 120 140 160 180 200 220 240 m/z 0 4 8 12 16 20 24 28 Y ( X10 0 0 ) Raw Spec:Scan 357(5.01) 101 103 66 10547 20 40 60 80 100 120 140 160 180 200 220 240 m/z 0 13 26 39 52 65 78 91 Y ( X10 ) Amdis Enhanced Spec: Scan 357(5.01), Qvalue=99 101 103 6647 105 20 40 60 80 100 120 140 160 180 200 220 240 m/z 0 2 4 6 8 10 Y ( X10 0 0 ) Ref Spec: 21 Trichlorofluoromethane @ 282.567 min. 101 103 6635 105 20 40 60 80 100 120 140 160 180 200 220 240 m/z -100 -75 -50 -25 0 25 50 75 100 Y Differenc Spec:Scan 1 @ 5.010 min.(Qvalue: 99) 4.5 4.8 5.1 5.4 Min 0 3 6 9 12 15 18 21 24 27 Y ( X10 0 0 ) m/z 101.0 5 . 0 1 2 4.5 4.8 5.1 5.4 Min 0 2 4 6 8 10 12 14 16 18 Y ( X10 0 0 ) m/z 103.0 5 . 0 1 2 4.5 4.8 5.1 5.4 Min 0 4 8 12 16 20 24 28 32 36 40 Y ( X10 0 ) m/z 66.0 5 . 0 0 7 03/21/2017Page 135 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 0.32(mm)RTX-5 ID: CURVE EVALUATION Calibration Files: LEVEL:LAB SAMPLE ID:LAB FILE ID: 1Level IC 140-9079/3 GC02IC01.D 2Level IC 140-9079/20 GC02IC02R.D 3Level IC 140-9079/5 GC02IC03.D 4Level IC 140-9079/6 GC02IC04.D 5Level IC 140-9079/7 GC02IC05.D 6Level ICIS 140-9079/8 GC02IC06.D 7Level IC 140-9079/9 GC02IC07.D 8Level IC 140-9079/10 GC02IC08.D 9Level IC 140-9079/11 GC02IC09.D ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 Chlorodifluoromethane +++++0.4829 0.4517 0.3992 0.3847 Ave 13.4 0.3713 0.3442 0.3643 0.3308 30.00.3912 Propene +++++0.9940 1.0782 0.9663 0.9533 Ave 9.0 0.9150 0.8405 0.8843 0.8262 30.00.9322 Dichlorodifluoromethane 3.9419 3.5597 3.5281 3.6178 3.7080 Ave 6.0 3.5248 3.3346 3.5444 3.1809 30.03.5489 Chloromethane ++++++++++0.3571 0.2844 0.3080 Ave 14.0 0.2879 0.2743 0.2675 0.2253 30.00.2864 1,2-Dichloro-1,1,2,2-tetrafluoroethane 2.4106 2.2539 2.1523 2.1642 2.2985 Ave 6.7 2.2038 1.9847 2.0690 1.9650 30.02.1669 Acetaldehyde +++++++++++++++0.7190 0.4376 Ave 36.1 0.4163 0.3781 0.3327 0.2777 *30.00.4269 Vinyl chloride 1.1787 1.1356 1.1228 1.1236 1.1841 Ave 8.7 1.1377 1.0699 1.0419 0.8737 30.01.0965 1,3-Butadiene 0.9259 0.8142 0.7772 0.7789 0.8550 Ave 10.3 0.8245 0.7719 0.7527 0.6260 30.00.7918 Butane 1.8650 1.7718 1.7079 1.6895 1.7835 Ave 10.5 1.6959 1.6084 1.5631 1.2632 30.01.6609 Bromomethane 1.3004 1.1620 1.1063 1.1238 1.1815 Ave 9.4 1.1299 1.0587 1.0311 0.9237 30.01.1130 Chloroethane 0.6834 0.5898 0.5831 0.6053 0.6310 Ave 9.3 0.5923 0.5611 0.5508 0.4850 30.00.5869 Ethanol +++++0.4648 0.4854 0.4806 0.4276 Ave 8.2 0.4423 0.4163 0.4219 0.3783 30.00.4396 Vinyl bromide 1.2190 1.1164 1.1099 1.0661 1.1409 Ave 9.6 1.0498 0.9598 0.9741 0.8945 30.01.0589 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 136 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 0.32(mm)RTX-5 ID: CURVE EVALUATION ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 2-Methylbutane +++++1.3298 1.3068 1.3375 1.4453 Ave 10.5 1.3221 1.1980 1.1754 1.0110 30.01.2657 Acrolein ++++++++++0.2411 0.1533 0.1508 Ave 22.2 0.1564 0.1564 0.1243 0.1656 30.00.1640 Trichlorofluoromethane 4.0976 3.8225 3.6426 3.6556 3.9200 Ave 7.7 3.6041 3.3210 3.4112 3.2570 30.03.6368 Acetonitrile ++++++++++0.4603 0.4960 0.3843 Ave 13.7 0.3927 0.3686 0.3673 0.3445 30.00.4020 Acetone +++++++++++++++0.6479 0.4238 Ave 27.0 0.4276 0.3854 0.3597 0.3201 30.00.4274 Pentane ++++++++++0.2085 0.2059 0.2314 Ave 8.2 0.2049 0.1908 0.1934 0.1793 30.00.2020 Isopropyl alcohol 1.4098 1.3158 1.4551 1.3749 1.1732 Ave 10.6 1.3008 1.1675 1.1539 1.0588 30.01.2677 Ethyl ether 1.3154 1.1436 1.3702 1.1899 1.1582 Ave 9.4 1.1717 1.1277 1.0627 1.0209 30.01.1734 1,1-Dichloroethene 1.2857 1.0381 1.0194 1.0065 1.1059 Ave 10.3 1.0102 0.9375 0.9857 0.9350 30.01.0360 Acrylonitrile +++++0.4904 0.5108 0.5107 0.5060 Ave 2.7 0.5118 0.5058 0.4989 0.4719 30.00.5008 tert-Butyl alcohol ++++++++++1.6761 1.5633 1.4912 Ave 6.3 1.5862 1.4800 1.5118 1.3704 30.01.5256 1,1,2-Trichloro-1,2,2-trifluoroethane 2.4414 2.2142 2.1355 2.1382 2.3315 Ave 5.5 2.1749 2.0564 2.1477 2.1010 30.02.1934 Methylene Chloride ++++++++++1.4672 1.0531 0.9702 Ave 25.3 0.8715 0.8113 0.8126 0.7603 30.00.9637 3-Chloropropene +++++0.9879 1.1709 0.9895 1.0645 Ave 9.6 1.0547 0.9694 0.9580 0.8404 30.01.0044 Carbon disulfide 3.0834 2.8883 2.7972 2.6507 2.8758 Ave 6.4 2.7502 2.5890 2.7076 2.4966 30.02.7599 trans-1,2-Dichloroethene 1.1555 1.1125 1.0142 1.0120 1.0752 Ave 5.3 1.0341 1.0017 1.0794 0.9936 30.01.0531 2-Methylpentane 2.1575 2.1877 2.0221 2.0371 2.1959 Ave 4.7 2.1113 2.0070 2.2077 1.9323 30.02.0954 Methyl tert-butyl ether 2.8984 2.6226 2.8783 2.8005 2.5675 Ave 4.3 2.6881 2.6579 2.7985 2.8262 30.02.7487 1,1-Dichloroethane 2.1797 2.0450 1.9405 1.9135 1.9760 Ave 5.1 1.9231 1.8450 1.9159 1.8954 30.01.9593 Vinyl acetate 2.1760 1.7777 2.1065 2.1399 1.9326 Ave 7.8 2.1023 2.1308 2.1743 2.3637 30.02.1004 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 137 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 0.32(mm)RTX-5 ID: CURVE EVALUATION ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 2-Butanone (MEK)0.4773 0.4409 0.5050 0.4973 0.3898 Ave 9.2 0.4151 0.4113 0.4233 0.4263 30.00.4429 Hexane +++++0.9073 0.8517 0.7865 0.8271 Ave 7.1 0.7971 0.7509 0.7917 0.7267 30.00.8049 Isopropyl ether 2.8649 2.4694 2.9472 2.9874 2.6842 Ave 5.9 2.7962 2.7735 2.9348 2.9506 30.02.8231 cis-1,2-Dichloroethene 1.2654 1.1590 1.0839 1.0579 1.0952 Ave 6.4 1.0628 1.0398 1.1019 1.0543 30.01.1022 Ethyl acetate +++++1.4608 1.7602 1.7781 1.5752 Ave 7.9 1.7048 1.7318 1.8088 1.8837 30.01.7129 Chloroform 3.0721 2.7021 2.6749 2.6322 2.6656 Ave 6.9 2.5787 2.4795 2.6043 2.4369 30.02.6496 Tert-butyl ethyl ether 2.5945 2.3959 2.6843 2.7006 2.5017 Ave 4.7 2.6139 2.6097 2.7757 2.7784 30.02.6283 Tetrahydrofuran +++++0.9556 1.1108 1.0388 0.8547 Ave 8.1 0.9487 0.9112 0.9744 0.9452 30.00.9674 1,1,1-Trichloroethane 3.2550 2.9134 2.8971 2.8500 2.9650 Ave 4.8 2.8890 2.7739 2.9100 2.7901 30.02.9159 1,2-Dichloroethane 0.3807 0.3428 0.3554 0.3455 0.3545 Ave 3.2 0.3548 0.3440 0.3578 0.3575 30.00.3548 Benzene 0.7029 0.6407 0.6219 0.5993 0.6168 Ave 5.4 0.6314 0.6304 0.6155 0.5796 30.00.6265 Cyclohexane +++++0.1272 0.1120 0.1058 0.1111 Ave 7.7 0.1114 0.1111 0.1072 0.0968 30.00.1103 Carbon tetrachloride 0.5933 0.5551 0.5657 0.4865 0.5936 Ave 7.5 0.6165 0.6034 0.6220 0.6226 30.00.5843 1-Butanol 0.0819 0.0629 0.0740 0.0685 0.0640 Ave 9.4 0.0746 0.0753 0.0820 0.0761 30.00.0732 2,3-Dimethylpentane 0.1825 0.1647 0.1535 0.1459 0.1508 Ave 8.0 0.1517 0.1469 0.1556 0.1410 30.00.1547 Thiophene 0.3794 0.3609 0.3606 0.3445 0.3585 Ave 2.9 0.3576 0.3508 0.3694 0.3517 30.00.3593 Tert-amyl methyl ether +++++0.3783 0.5207 0.5537 0.4922 Ave 12.5 0.5564 0.5498 0.5840 0.5662 30.00.5252 2,2,4-Trimethylpentane 1.0869 1.0077 0.9925 0.9615 0.9842 Ave 5.0 0.9840 0.9554 1.0105 0.9044 30.00.9875 Heptane 0.2616 0.2501 0.2460 0.2323 0.2390 Ave 4.8 0.2393 0.2358 0.2397 0.2199 30.00.2404 1,2-Dichloropropane 0.2489 0.2258 0.2374 0.2223 0.2241 Ave 4.5 0.2339 0.2281 0.2388 0.2147 30.00.2304 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 138 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 0.32(mm)RTX-5 ID: CURVE EVALUATION ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 Trichloroethene 0.3730 0.3777 0.3448 0.3380 0.3755 Ave 3.9 0.3630 0.3562 0.3580 0.3483 30.00.3594 Dibromomethane +++++0.3032 0.2994 0.2784 0.2958 Ave 2.5 0.2941 0.2914 0.2975 0.2914 30.00.2939 Bromodichloromethane 0.4899 0.4618 0.4956 0.4880 0.5223 Ave 6.3 0.5399 0.5409 0.5585 0.5377 30.00.5150 1,4-Dioxane +++++0.0800 0.0832 0.0851 0.0786 Ave 4.0 0.0861 0.0869 0.0880 0.0820 30.00.0837 Methyl methacrylate 0.2194 0.2024 0.2123 0.2136 0.1951 Ave 9.9 0.2298 0.2357 0.2551 0.2591 30.00.2247 Methylcyclohexane 0.5765 0.5274 0.4975 0.4894 0.5057 Ave 5.6 0.5119 0.5052 0.5031 0.4749 30.00.5102 4-Methyl-2-pentanone (MIBK)++++++++++0.3972 0.3922 0.3045 Ave 9.1 0.3758 0.3711 0.4086 0.3864 30.00.3765 cis-1,3-Dichloropropene 0.4225 0.3843 0.3894 0.3884 0.4034 Ave 3.6 0.4126 0.4046 0.4247 0.3977 30.00.4030 trans-1,3-Dichloropropene 0.3773 0.3806 0.3754 0.3646 0.3767 Ave 5.6 0.3973 0.4036 0.4280 0.4205 30.00.3916 Toluene Range +++++++++++++++1.7344 1.7229 Ave 2.8 1.8053 1.7951 1.8537 1.8102 30.01.7869 Toluene 0.7711 0.7162 0.7274 0.6783 0.6716 Ave 4.8 0.7126 0.7433 0.7628 0.7504 30.00.7260 1,1,2-Trichloroethane 0.2346 0.2167 0.2159 0.2117 0.2052 Ave 4.5 0.2200 0.2286 0.2328 0.2272 30.00.2214 2-Methylthiophene 0.6288 0.6323 0.6048 0.6036 0.6088 Ave 4.0 0.6354 0.6581 0.6746 0.6550 30.00.6335 3-Methylthiophene 0.6220 0.6149 0.6149 0.6011 0.6011 Ave 3.8 0.6244 0.6487 0.6739 0.6453 30.00.6274 2-Hexanone ++++++++++0.1851 0.1784 0.1483 Ave 10.3 0.1824 0.1874 0.2087 0.1989 30.00.1842 Octane 0.2808 0.2753 0.2627 0.2561 0.2623 Ave 3.1 0.2637 0.2726 0.2674 0.2585 30.00.2666 C8 Range +++++++++++++++3.8895 4.0217 Ave 23.7 3.3336 2.7089 2.7845 2.0971 30.03.1392 Dibromochloromethane 0.3658 0.4016 0.4242 0.4305 0.4870 Ave 18.5 0.5286 0.5615 0.5887 0.6242 30.00.4903 1,2-Dibromoethane (EDB)0.4195 0.4210 0.4087 0.4123 0.4290 Ave 7.0 0.4523 0.4737 0.4807 0.4860 30.00.4426 Tetrachloroethene 0.3265 0.3269 0.3021 0.2982 0.3054 Ave 5.7 0.3133 0.3179 0.3344 0.3561 30.00.3201 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 139 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 0.32(mm)RTX-5 ID: CURVE EVALUATION ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 Chlorobenzene 0.6378 0.6543 0.6088 0.5969 0.6134 Ave 4.3 0.6263 0.6550 0.6675 0.6724 30.00.6369 2,3-Dimethylheptane 0.7298 0.6528 0.6471 0.6346 0.6399 Ave 6.5 0.6387 0.6720 0.6565 0.5664 30.00.6487 Ethylbenzene 0.9354 0.9245 0.9270 0.9360 0.8787 Ave 5.2 0.9400 0.9958 1.0212 1.0251 30.00.9537 2-Ethylthiophene 0.7774 0.7278 0.7405 0.7507 0.7197 Ave 5.3 0.7653 0.8083 0.8222 0.8282 30.00.7711 m-Xylene & p-Xylene 0.7465 0.6914 0.7334 0.7385 0.6937 Ave 5.6 0.7403 0.7782 0.7900 0.8170 30.00.7477 Bromoform +++++0.3242 0.3549 0.3533 0.4308 Ave 27.9 0.4984 0.5626 0.6144 0.6816 30.00.4775 Styrene 0.4838 0.4547 0.4739 0.5026 0.4994 Ave 11.6 0.5570 0.5679 0.5967 0.6341 30.00.5300 Nonane 0.5411 0.5367 0.4787 0.4749 0.4842 Ave 9.0 0.4846 0.4726 0.4453 0.3983 30.00.4796 o-Xylene 0.7933 0.7152 0.7611 0.7535 0.6981 Ave 5.5 0.7508 0.7913 0.8122 0.8224 30.00.7664 1,1,2,2-Tetrachloroethane 0.4823 0.4635 0.4856 0.4828 0.4596 Ave 7.5 0.5023 0.5417 0.5522 0.5559 30.00.5029 1,2,3-Trichloropropane 0.1701 0.1670 0.1662 0.1686 0.1568 Ave 5.6 0.1683 0.1770 0.1836 0.1883 30.00.1718 Isopropylbenzene 1.2326 1.0842 1.1242 1.0859 1.0079 Ave 6.0 1.0738 1.0968 1.1363 1.1921 30.01.1149 Propylbenzene 0.2758 0.2723 0.2890 0.2831 0.2661 Ave 9.2 0.2957 0.3225 0.3215 0.3466 30.00.2970 2-Chlorotoluene 0.2773 0.2761 0.2812 0.2687 0.2674 Ave 6.3 0.2839 0.3061 0.3013 0.3196 30.00.2868 4-Ethyltoluene 1.0167 0.9877 1.0185 1.0205 0.9369 Ave 7.9 1.0329 1.1175 1.1423 1.1986 30.01.0524 1,3,5-Trimethylbenzene 0.4375 0.4637 0.4701 0.4713 0.4372 Ave 10.4 0.4881 0.5310 0.5417 0.5872 30.00.4920 Alpha Methyl Styrene 0.3568 0.3295 0.3595 0.3667 0.3682 Ave 17.5 0.4189 0.4693 0.4944 0.5331 30.00.4107 Decane 0.6012 0.6176 0.5894 0.5667 0.5867 Ave 5.3 0.5948 0.6146 0.5680 0.5153 30.00.5838 tert-Butylbenzene 0.9434 0.9204 0.9462 0.9528 0.8852 Ave 10.0 1.0008 1.0324 1.1038 1.2001 30.00.9984 1,2,4-Trimethylbenzene 0.8573 0.8501 0.8848 0.8783 0.8172 Ave 8.8 0.9161 0.9444 0.9960 1.0739 30.00.9131 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 140 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 0.32(mm)RTX-5 ID: CURVE EVALUATION ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 1,3-Dichlorobenzene 0.6600 0.7453 0.6648 0.6577 0.6849 Ave 13.0 0.7459 0.7649 0.8573 0.9387 30.00.7466 sec-Butylbenzene 1.1859 1.2224 1.2505 1.2539 1.1711 Ave 9.8 1.3433 1.3600 1.4707 1.5387 30.01.3107 Benzyl chloride 0.7098 0.7639 0.7754 0.7932 0.7575 Ave 11.2 0.8659 0.9136 0.8903 1.0007 30.00.8300 1,4-Dichlorobenzene 0.6888 0.7564 0.6795 0.6592 0.6702 Ave 10.7 0.7315 0.7485 0.8122 0.9042 30.00.7389 4-Isopropyltoluene 1.0407 1.0633 1.0789 1.0886 1.0082 Ave 9.8 1.1378 1.2007 1.2610 1.3435 30.01.1358 1,2,3-Trimethylbenzene 0.6316 0.6389 0.6747 0.6650 0.6064 Ave 7.8 0.6658 0.7216 0.7456 0.7612 30.00.6790 Butylcyclohexane 0.8000 0.8740 0.7546 0.7551 0.7958 Ave 4.6 0.7925 0.7953 0.7850 0.7630 30.00.7906 1,2-Dichlorobenzene 0.6228 0.6806 0.6392 0.6184 0.6254 Ave 12.6 0.6928 0.7058 0.7936 0.8738 30.00.6947 Indane 0.7592 0.7952 0.8007 0.7944 0.7642 Ave 12.0 0.8705 0.8888 0.9739 1.0584 30.00.8561 Indene 0.5669 0.5859 0.5640 0.5682 0.5551 Ave 12.6 0.6213 0.6863 0.7065 0.7753 30.00.6255 Butylbenzene 1.0095 1.0462 1.0120 1.0319 0.9573 Ave 5.5 1.0552 1.1041 1.1114 1.1392 30.01.0519 Undecane 0.6494 0.6794 0.6228 0.6097 0.6316 Ave 5.9 0.6237 0.6564 0.6227 0.5466 30.00.6269 1,2-Dimethyl-4-Ethylbenzene 0.7435 0.8211 0.7564 0.7739 0.7552 Ave 10.1 0.8392 0.9129 0.9162 0.9719 30.00.8323 1,2-Dibromo-3-Chloropropane +++++0.2343 0.2314 0.2096 0.2400 Ave 19.9 0.2858 0.3191 0.3271 0.3606 30.00.2760 1,2,4,5-Tetramethylbenzene 0.8881 1.0116 0.9247 0.8913 0.9061 Ave 11.8 1.0306 1.1035 1.1545 1.2049 30.01.0128 1,2,3,5-Tetramethylbenzene 0.5575 0.6324 0.5681 0.5450 0.5273 Ave 9.6 0.6091 0.6464 0.6727 0.6855 30.00.6049 1,2,3,4-Tetramethylbenzene 0.7687 0.9229 0.7703 0.7228 0.7149 Ave 10.7 0.8435 0.9067 0.9302 0.9148 30.00.8328 Dodecane 0.6486 0.6823 0.6341 0.5328 0.5873 Ave 14.7 0.5643 0.5802 0.5823 0.3868 30.00.5776 1,2,4-Trichlorobenzene 0.5078 0.7842 0.5267 0.4730 0.5274 Ave 17.5 0.6098 0.6410 0.7310 0.6435 30.00.6049 Naphthalene 1.0739 1.8066 1.1594 0.9994 1.0730 Ave 19.2 1.2747 1.3578 1.3739 1.2327 30.01.2613 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 141 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 0.32(mm)RTX-5 ID: CURVE EVALUATION ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 Benzo(b)thiophene ++++++++++0.6615 0.5858 0.6396 Ave 11.4 0.7413 0.7885 0.8003 0.6798 30.00.6995 Hexachlorobutadiene 0.5816 0.6333 0.5542 0.5089 0.5805 Ave 9.2 0.5568 0.5954 0.7024 0.5999 30.00.5903 1,2,3-Trichlorobenzene ++++++++++0.5581 0.4833 0.5390 Ave 13.6 0.5976 0.5787 0.6573 0.4310 30.00.5493 2-Methylnaphthalene ++++++++++0.2482 0.1885 0.2565 Ave 14.9 0.2993 0.2684 0.2821 +++++ 50.00.2572 1-Methylnaphthalene ++++++++++0.1965 0.1589 0.2225 Ave 14.1 0.2469 0.2085 0.2096 +++++ 50.00.2071 4-Bromofluorobenzene (Surr)0.7462 0.7456 0.7448 0.7532 0.7523 Ave 1.4 0.7318 0.7488 0.7235 0.7564 30.00.7447 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 142 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION Calibration Files: LEVEL:LAB SAMPLE ID:LAB FILE ID: Level 1 IC 140-9079/3 GC02IC01.D Level 2 IC 140-9079/20 GC02IC02R.D Level 3 IC 140-9079/5 GC02IC03.D Level 4 IC 140-9079/6 GC02IC04.D Level 5 IC 140-9079/7 GC02IC05.D Level 6 ICIS 140-9079/8 GC02IC06.D Level 7 IC 140-9079/9 GC02IC07.D Level 8 IC 140-9079/10 GC02IC08.D Level 9 IC 140-9079/11 GC02IC09.D ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (PPB V/V) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 Chlorodifluoromethane AveCBM +++++4117 6808 14940 36701 73615 149012 306956 593423 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Propene AveCBM +++++8474 16251 36163 90943 181398 363824 745153 1481915 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Dichlorodifluoromethane AveCBM 14956 30346 53178 135386 353716 698780 1443467 2986792 5705597 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Chloromethane AveCBM ++++++++++5382 10642 29383 57078 118748 225417 404153 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2-Dichloro-1,1,2,2-tetrafluoroeth ane AveCBM 9146 19214 32441 80988 219262 436894 859118 1743498 3524679 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Acetaldehyde AveCBM +++++++++++++++134527 208740 412654 818363 1401677 2490767 +++++++++++++++2.00 4.99 9.99 20.0 40.0 80.0 Vinyl chloride AveCBM 4472 9681 16924 42048 112960 225546 463110 878033 1567179 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,3-Butadiene AveCBM 3513 6941 11714 29149 81559 163453 334116 634250 1122777 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Butane AveCBM 7076 15104 25743 63224 170131 336204 696236 1317188 2265735 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Bromomethane AveCBM 4934 9906 16675 42057 112705 223993 458263 868899 1656810 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Chloroethane AveCBM 2593 5028 8789 22651 60191 117430 242874 464117 869966 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Ethanol AveCBM +++++19813 36579 89923 203965 438460 900932 1777636 3392647 +++++0.397 0.793 2.00 4.99 9.99 20.0 40.0 80.0 Vinyl bromide AveCBM 4625 9517 16729 39895 108833 208124 415451 820833 1604482 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Methylbutane AveCBM +++++11336 19697 50052 137869 262104 518587 990458 1813405 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 FORM VI TO 15 LL 03/21/2017Page 143 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (PPB V/V) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 Acrolein AveCBM ++++++++++3634 5738 14386 31009 67683 104747 297063 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 Trichlorofluoromethane AveCBM 15547 32586 54904 136800 373948 714498 1437541 2874535 5842137 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Acetonitrile AveCBM ++++++++++6938 18563 36659 77854 159557 309526 617927 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 Acetone AveCBM +++++++++++++++72746 121293 254325 500469 909490 1722579 +++++++++++++++1.20 3.00 5.99 12.0 24.0 48.0 Pentane AveCBM ++++++++++3142 7706 22070 40620 82609 162991 321694 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 Isopropyl alcohol AveCBM 16048 33653 65802 154370 335763 773681 1516171 2917385 5697995 0.118 0.238 0.476 1.20 3.00 5.99 12.0 24.0 48.0 Ethyl ether AveCBM 4991 9749 20652 44528 110481 232288 488155 895503 1831153 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,1-Dichloroethene AveCBM 4878 8850 15365 37664 105498 200269 405837 830595 1677086 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Acrylonitrile AveCBM +++++4181 7699 19112 48269 101460 218964 420450 846465 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 tert-Butyl alcohol AveCBM ++++++++++25264 58501 142251 314466 640651 1273967 2458156 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,1,2-Trichloro-1,2,2-trifluoroetha ne AveCBM 9263 18876 32187 80017 222408 431163 890153 1809809 3768634 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Methylene Chloride AveCBM ++++++++++22114 39408 92548 172766 351168 684793 1363735 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 3-Chloropropene AveCBM +++++8422 17649 37029 101547 209098 419643 807303 1507366 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Carbon disulfide AveCBM 11699 24622 42161 99197 274333 545212 1120712 2281669 4478149 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 trans-1,2-Dichloroethene AveCBM 4384 9484 15286 37871 102572 205008 433627 909558 1782185 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Methylpentane AveCBM 8186 18650 30478 76233 209472 418548 868758 1860362 3465926 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Methyl tert-butyl ether AveCBM 10997 22357 43383 104801 244925 532900 1150545 2358248 5069342 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,1-Dichloroethane AveCBM 8270 17433 29248 71609 188496 381249 798627 1614530 3399866 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Vinyl acetate AveCBM 8256 15155 31751 80081 184358 416770 922344 1832225 4239860 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Butanone (MEK)AveCBM 1811 3759 7612 18610 37188 82283 178044 356743 764742 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Hexane AveCBM +++++7735 12837 29431 78896 158031 325047 667134 1303527 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 FORM VI TO 15 LL 03/21/2017Page 144 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (PPB V/V) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 Isopropyl ether AveCBM 10870 21051 44422 111795 256058 554336 1200569 2473083 5292599 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 cis-1,2-Dichloroethene AveCBM 4801 9880 16338 39588 104471 210694 450081 928515 1891071 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Ethyl acetate AveCBM +++++12453 26531 66540 150266 337970 749629 1524276 3378757 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Chloroform AveCBM 11656 23035 40318 98505 254283 511221 1073295 2194591 4371168 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Tert-butyl ethyl ether AveCBM 9844 20425 40459 101064 238643 518203 1129672 2339030 4983675 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Tetrahydrofuran AveCBM +++++8146 16742 38873 81529 188075 394414 821113 1695370 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,1,1-Trichloroethane AveCBM 12350 24836 43667 106654 282846 572725 1200734 2452233 5004599 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2-Dichloroethane AveDFBZ 7484 14813 27616 67542 175618 353536 743733 1507864 3179877 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Benzene AveDFBZ 13817 27690 48318 117159 305578 629128 1362801 2593773 5155161 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Cyclohexane AveDFBZ +++++5499 8701 20685 55034 110969 240083 451811 860520 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Carbon tetrachloride AveDFBZ 11663 23989 43951 95114 294089 614207 1304352 2621123 5537304 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1-Butanol AveDFBZ 1610 2718 5747 13386 31686 74293 162687 345495 676762 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2,3-Dimethylpentane AveDFBZ 3587 7119 11928 28526 74710 151135 317495 655602 1254475 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Thiophene AveDFBZ 7458 15596 28016 67355 177621 356253 758324 1556761 3127741 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Tert-amyl methyl ether AveDFBZ +++++16350 40454 108255 243858 554414 1188591 2461073 5035512 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2,2,4-Trimethylpentane AveDFBZ 21366 43551 77114 187987 487596 980383 2065349 4258623 8044250 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Heptane AveDFBZ 5142 10809 19116 45416 118391 238440 509798 1009968 1955729 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2-Dichloropropane AveDFBZ 4893 9757 18448 43467 110995 233060 493172 1006262 1909170 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Trichloroethene AveDFBZ 7333 16324 26791 66089 186014 361708 770017 1508689 3097983 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Dibromomethane AveDFBZ +++++13104 23258 54422 146524 293074 630013 1253711 2591765 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Bromodichloromethane AveDFBZ 9630 19956 38506 95415 258735 537969 1169408 2353711 4782156 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 FORM VI TO 15 LL 03/21/2017Page 145 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (PPB V/V) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 1,4-Dioxane AveDFBZ +++++3457 6467 16645 38926 85834 187768 370975 729179 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Methyl methacrylate AveDFBZ 4314 8746 16492 41751 96652 228935 509515 1074957 2304384 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Methylcyclohexane AveDFBZ 11334 22792 38650 95681 250534 510072 1092146 2120127 4223787 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 4-Methyl-2-pentanone (MIBK)AveDFBZ ++++++++++30859 76682 150862 374418 802345 1721840 3436700 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 cis-1,3-Dichloropropene AveDFBZ 8305 16607 30253 75926 199844 411086 874614 1789747 3537072 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 trans-1,3-Dichloropropene AveCBZd 5 7511 16151 29964 71985 190582 406181 860494 1762176 3639858 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Toluene Range AveDFBZ +++++++++++++++339092 853542 1798669 3880684 7812063 16100078 +++++++++++++++0.400 0.999 2.00 4.00 8.00 16.0 Toluene AveCBZd 5 15348 30391 58057 133914 339763 728639 1584870 3140955 6495080 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,1,2-Trichloroethane AveCBZd 5 4669 9194 17236 41787 103808 224974 487400 958533 1966781 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Methylthiophene AveCBZd 5 12517 26831 48275 119176 307996 649696 1403012 2777537 5668799 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 3-Methylthiophene AveCBZd 5 12381 26092 49080 118682 304111 638468 1383056 2774725 5585386 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Hexanone AveCBZd 5 ++++++++++14771 35230 75024 186539 399503 859377 1721121 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 Octane AveCBZd 5 5590 11680 20968 50555 132681 269612 581291 1101196 2237695 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 C8 Range AveDFBZ +++++++++++++++760418 1992357 3321390 5856098 11734517 18652465 +++++++++++++++0.400 0.999 2.00 4.00 8.00 16.0 Dibromochloromethane AveCBZd 5 7282 17043 33862 84996 246365 540498 1197096 2424106 5402658 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2-Dibromoethane (EDB)AveCBZd 5 8350 17865 32620 81398 217002 462418 1009922 1979331 4206014 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Tetrachloroethene AveCBZd 5 6499 13873 24115 58871 154481 320386 677805 1376890 3082194 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Chlorobenzene AveCBZd 5 12695 27763 48589 117838 310288 640391 1396401 2748594 5819873 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2,3-Dimethylheptane AveCBZd 5 14526 27702 51653 125279 323718 653073 1432853 2703240 4902679 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Ethylbenzene AveCBZd 5 18619 39230 73987 184802 444543 961131 2123060 4204604 8872329 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Ethylthiophene AveCBZd 5 15473 30884 59106 148208 364072 782539 1723412 3385428 7168291 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 FORM VI TO 15 LL 03/21/2017Page 146 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (PPB V/V) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 m-Xylene & p-Xylene AveCBZd 5 29718 58678 117078 291621 701860 1513863 3318439 6505497 14143266 0.0784 0.159 0.317 0.800 2.00 3.99 8.00 16.0 32.0 Bromoform AveCBZd 5 +++++13758 28324 69748 217947 509620 1199597 2529774 5899101 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Styrene AveCBZd 5 9629 19295 37823 99226 252653 569507 1210797 2456959 5488449 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Nonane AveCBZd 5 10771 22773 38208 93758 244961 495537 1007618 1833592 3447492 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 o-Xylene AveCBZd 5 15791 30347 60752 148753 353133 767665 1687122 3344040 7117819 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,1,2,2-Tetrachloroethane AveCBZd 5 9601 19669 38761 95320 232481 513576 1155005 2273528 4811457 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,3-Trichloropropane AveCBZd 5 3385 7086 13265 33294 79343 172113 377370 755995 1629852 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Isopropylbenzene AveCBZd 5 24534 46007 89734 214385 509862 1097926 2338552 4678588 10317786 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Propylbenzene AveCBZd 5 5490 11555 23064 55901 134620 302377 687647 1323708 2999820 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Chlorotoluene AveCBZd 5 5519 11716 22442 53040 135297 290310 652552 1240764 2766057 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 4-Ethyltoluene AveCBZd 5 20237 41911 81294 201470 473972 1056133 2382649 4703566 10374169 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,3,5-Trimethylbenzene AveCBZd 5 8708 19678 37525 93050 221193 499066 1132222 2230504 5082507 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Alpha Methyl Styrene AveCBZd 5 7102 13981 28693 72396 186268 428360 1000574 2035483 4614322 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Decane AveCBZd 5 11966 26206 47043 111892 296801 608205 1310271 2338575 4459815 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 tert-Butylbenzene AveCBZd 5 18779 39057 75521 188113 447831 1023334 2201186 4544874 10386644 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,4-Trimethylbenzene AveCBZd 5 17065 36071 70625 173408 413399 936657 2013472 4100916 9294406 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,3-Dichlorobenzene AveCBZd 5 13137 31625 53064 129852 346492 762687 1630912 3530077 8124131 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 sec-Butylbenzene AveCBZd 5 23605 51871 99807 247548 592460 1373491 2899550 6055449 13317673 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Benzyl chloride AveCBZd 5 14129 32413 61888 156606 383181 885361 1947940 3665923 8661607 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,4-Dichlorobenzene AveCBZd 5 13711 32098 54236 130139 339022 747931 1595871 3344089 7825807 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 4-Isopropyltoluene AveCBZd 5 20714 45117 86111 214918 510030 1163365 2559983 5192056 11628572 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 FORM VI TO 15 LL 03/21/2017Page 147 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (PPB V/V) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 1,2,3-Trimethylbenzene AveCBZd 5 12572 27110 53855 131293 306762 680764 1538574 3069806 6588120 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Butylcyclohexane AveCBZd 5 15924 37084 60233 149071 402561 810366 1695670 3232242 6603806 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2-Dichlorobenzene AveCBZd 5 12396 28881 51022 122080 316358 708335 1504756 3267696 7562744 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Indane AveCBZd 5 15111 33742 63910 156836 386578 890055 1895000 4009906 9160313 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Indene AveCBZd 5 11285 24860 45014 112170 280824 635278 1463201 2908946 6710686 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Butylbenzene AveCBZd 5 20094 44394 80776 203720 484303 1078971 2354005 4576198 9859788 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Undecane AveCBZd 5 12926 28830 49706 120374 319511 637737 1399535 2564058 4731040 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2-Dimethyl-4-Ethylbenzene AveCBZd 5 14800 34842 60370 152789 382029 858063 1946396 3772393 8411661 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2-Dibromo-3-Chloropropane AveCBZd 5 +++++9943 18473 41383 121417 292233 680296 1346687 3121002 +++++0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,4,5-Tetramethylbenzene AveCBZd 5 17677 42923 73810 175959 458404 1053727 2352685 4753691 10428510 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,3,5-Tetramethylbenzene AveCBZd 5 11096 26835 45344 107601 266757 622820 1378186 2770005 5932758 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,3,4-Tetramethylbenzene AveCBZd 5 15300 39160 61486 142698 361637 862421 1933165 3830160 7918123 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Dodecane AveCBZd 5 12911 28951 50609 105194 297125 576970 1237066 2397668 3347426 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,4-Trichlorobenzene AveCBZd 5 10108 33274 42037 93377 266823 623511 1366584 3009702 5569204 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Naphthalene AveCBZd 5 21376 76660 92541 197303 542795 1303379 2895014 5657107 10668835 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Benzo(b)thiophene AveCBZd 5 ++++++++++52800 115646 323541 758002 1681098 3295063 5884116 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 Hexachlorobutadiene AveCBZd 5 11577 26871 44234 100465 293683 569346 1269541 2891958 5192024 0.0392 0.0793 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,3-Trichlorobenzene AveCBZd 5 ++++++++++44545 95414 272663 611029 1233859 2706266 3730627 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Methylnaphthalene AveCBZd 5 ++++++++++61911 116309 405427 956277 1788441 3629803 +++++ ++++++++++0.496 1.25 3.12 6.24 12.5 25.0 +++++ 1-Methylnaphthalene AveCBZd 5 ++++++++++48997 98052 351664 788833 1389272 2696789 +++++ ++++++++++0.496 1.25 3.12 6.24 12.5 25.0 +++++ 4-Bromofluorobenzene (Surr)AveCBZd 5 1515557 1595251 1498709 1486983 1524315 1498532 1596553 1489493 1636640 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 FORM VI TO 15 LL 03/21/2017Page 148 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MG Analy Batch No.:9079 934Calibration Start Date:Calibration End Date:03/02/2017 13:34 N 03/02/2017 20:31 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION Curve Type Legend: Ave = Average ISTD FORM VI TO 15 LL 03/21/2017Page 149 of 377 Report Date: 03-Mar-2017 15:07:57 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC01.D Lims ID:IC L1 Client ID: Sample Type:IC Calib Level:1 Inject. Date:02-Mar-2017 13:34:30 ALS Bottle#:1 Worklist Smp#:3 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004202-003 Misc. Info.:073145 Operator ID:7126 Instrument ID:MG Sublist:chrom-MG_TO15*sub5 Method:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:03-Mar-2017 15:07:56 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK031 First Level Reviewer: barlozhetskayaa Date:02-Mar-2017 14:23:30 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.012 8.012 0.000 84 387158 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.174 10.179 -0.005 95 2005953 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.044 15.046 -0.002 87 2031101 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.715 16.717 -0.002 93 1515557 4.00 4.01 6 Chlorodifluoromethane 67 3.472 3.463 0.009 96 1783 0.0392 0.0471 7 Propene 41 3.477 3.471 0.006 89 5219 0.0392 0.0578 8 Dichlorodifluoromethane 85 3.520 3.514 0.006 99 14956 0.0392 0.0435 9 Chloromethane 52 3.666 3.665 0.001 66 1681 0.0392 0.0606 10 1,2-Dichloro-1,1,2,2-tetra 135 3.682 3.675 0.007 91 9146 0.0392 0.0436 11 Acetaldehyde 44 3.795 3.793 0.002 88 50592 0.1960 1.22 12 Vinyl chloride 62 3.812 3.809 0.003 31 4472 0.0392 0.0421 13 Butadiene 54 3.887 3.883 0.004 70 3513 0.0392 0.0458 14 Butane 43 3.887 3.885 0.002 85 7076 0.0392 0.0440 15 Bromomethane 94 4.157 4.149 0.008 95 4934 0.0392 0.0458 16 Chloroethane 64 4.270 4.267 0.003 96 2593 0.0392 0.0456 17 Ethanol 31 4.388 4.372 0.016 97 11095 0.1960 0.2607 18 Vinyl bromide 106 4.529 4.522 0.007 96 4625 0.0392 0.0451 19 2-Methylbutane 43 4.572 4.569 0.003 88 6280 0.0392 0.0513 21 Trichlorofluoromethane 101 4.755 4.753 0.002 99 15547 0.0392 0.0442 22 Acetonitrile 40 4.825 4.808 0.017 52 2214 0.0392 0.0569 23 Acetone 58 4.868 4.849 0.019 99 9828 0.1176 0.2376 24 Pentane 72 4.955 4.949 0.006 96 751 0.0392 0.0384 25 Isopropyl alcohol 45 4.982 4.963 0.019 95 16048 0.1176 0.1308 26 Ethyl ether 31 5.111 5.090 0.021 86 4991 0.0392 0.0439 27 1,1-Dichloroethene 96 5.375 5.367 0.008 97 4878 0.0392 0.0486 28 Acrylonitrile 53 5.456 5.450 0.006 90 1975 0.0392 0.0407 29 2-Methyl-2-propanol 59 5.532 5.494 0.038 59 5577 0.0392 0.0378 30 1,1,2-Trichloro-1,2,2-trif 101 5.548 5.536 0.012 94 9263 0.0392 0.0436 31 Methylene Chloride 84 5.672 5.669 0.003 93 11118 0.0392 0.1192 32 3-Chloro-1-propene 39 5.688 5.684 0.004 95 8084 0.0392 0.0832 03/21/2017Page 150 of 377 Report Date: 03-Mar-2017 15:07:57 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC01.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 33 Carbon disulfide 76 5.817 5.810 0.007 98 11699 0.0392 0.0438 34 trans-1,2-Dichloroethene 96 6.405 6.406 -0.001 96 4384 0.0392 0.0430 35 2-Methylpentane 43 6.443 6.439 0.004 93 8186 0.0392 0.0404 36 Methyl tert-butyl ether 73 6.572 6.533 0.039 95 10997 0.0392 0.0413 37 1,1-Dichloroethane 63 6.783 6.787 -0.004 98 8270 0.0392 0.0436 38 Vinyl acetate 43 6.907 6.898 0.009 99 8256 0.0392 0.0406 39 2-Butanone (MEK) 72 7.333 7.305 0.028 89 1811 0.0392 0.0422 40 Hexane 56 7.349 7.350 -0.001 92 4408 0.0392 0.0566 41 Isopropyl ether 45 7.527 7.502 0.025 94 10870 0.0392 0.0398 42 cis-1,2-Dichloroethene 96 7.705 7.707 -0.002 94 4801 0.0392 0.0450 43 Ethyl acetate 43 7.926 7.901 0.025 97 6611 0.0392 0.0399 44 Chloroform 83 8.034 8.035 -0.001 88 11656 0.0392 0.0455 45 Tert-butyl ethyl ether 59 8.169 8.144 0.025 96 9844 0.0392 0.0387 46 Tetrahydrofuran 42 8.449 8.410 0.039 83 5698 0.0392 0.0609 47 1,1,1-Trichloroethane 97 9.015 9.013 0.002 96 12350 0.0392 0.0438 48 1,2-Dichloroethane 62 9.107 9.106 0.001 98 7484 0.0392 0.0421 49 Benzene 78 9.598 9.599 -0.001 96 13817 0.0392 0.0440 50 Cyclohexane 69 9.603 9.604 -0.001 80 2831 0.0392 0.0512 52 Carbon tetrachloride 117 9.624 9.629 -0.005 97 11663 0.0392 0.0398 51 n-Butanol 31 9.705 9.647 0.058 68 1610 0.0392 0.0438 53 2,3-Dimethylpentane 71 9.754 9.754 0.000 89 3587 0.0392 0.0462 54 Thiophene 84 9.873 9.873 0.000 96 7458 0.0392 0.0414 56 Isooctane 57 10.433 10.430 0.003 97 21366 0.0392 0.0431 57 n-Heptane 71 10.827 10.831 -0.004 91 5142 0.0392 0.0427 58 1,2-Dichloropropane 63 10.859 10.862 -0.003 83 4893 0.0392 0.0423 59 Trichloroethene 130 10.908 10.913 -0.005 96 7333 0.0392 0.0407 60 Dibromomethane 93 10.978 10.978 0.000 92 7071 0.0392 0.0480 61 Dichlorobromomethane 83 11.140 11.143 -0.003 97 9630 0.0392 0.0373 62 1,4-Dioxane 88 11.204 11.173 0.031 84 1238 0.0392 0.0295 63 Methyl methacrylate 41 11.285 11.278 0.007 90 4314 0.0392 0.0383 64 Methylcyclohexane 83 11.722 11.718 0.004 94 11334 0.0392 0.0443 65 4-Methyl-2-pentanone (MIBK 43 12.175 12.153 0.022 95 6654 0.0392 0.0352 66 cis-1,3-Dichloropropene 75 12.191 12.190 0.001 97 8305 0.0392 0.0411 67 trans-1,3-Dichloropropene 75 12.908 12.911 -0.003 97 7511 0.0392 0.0378 68 Toluene 91 13.032 13.035 -0.003 92 15348 0.0392 0.0416 69 1,1,2-Trichloroethane 83 13.103 13.106 -0.003 96 4669 0.0392 0.0415 70 2-Methylthiophene 97 13.183 13.186 -0.003 96 12517 0.0392 0.0389 71 3-Methylthiophene 97 13.388 13.394 -0.006 97 12381 0.0392 0.0389 72 2-Hexanone 58 13.556 13.535 0.021 94 3114 0.0392 0.0333 73 n-Octane 85 13.793 13.792 0.001 92 5590 0.0392 0.0413 74 Chlorodibromomethane 129 13.814 13.816 -0.002 95 7282 0.0392 0.0293 75 Ethylene Dibromide 107 14.100 14.106 -0.006 99 8350 0.0392 0.0372 76 Tetrachloroethene 129 14.208 14.207 0.001 93 6499 0.0392 0.0400 77 Chlorobenzene 112 15.092 15.095 -0.003 92 12695 0.0392 0.0393 78 2,3-Dimethylheptane 43 15.162 15.165 -0.003 92 14526 0.0392 0.0441 79 Ethylbenzene 91 15.400 15.402 -0.002 98 18619 0.0392 0.0384 80 2-Ethylthiophene 97 15.502 15.502 0.000 98 15473 0.0392 0.0395 81 m-Xylene & p-Xylene 91 15.572 15.572 0.000 99 29718 0.0784 0.0783 82 Bromoform 173 15.993 15.991 0.002 91 2701 0.0392 0.0111 84 Styrene 104 16.036 16.037 -0.001 97 9629 0.0392 0.0358 83 n-Nonane 57 16.036 16.038 -0.002 87 10771 0.0392 0.0442 85 o-Xylene 91 16.095 16.099 -0.004 99 15791 0.0392 0.0406 03/21/2017Page 151 of 377 Report Date: 03-Mar-2017 15:07:57 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC01.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 86 1,1,2,2-Tetrachloroethane 83 16.419 16.422 -0.003 97 9601 0.0392 0.0376 87 1,2,3-Trichloropropane 110 16.575 16.577 -0.002 96 3385 0.0392 0.0388 88 Isopropylbenzene 105 16.705 16.703 0.002 93 24534 0.0392 0.0433 89 N-Propylbenzene 120 17.255 17.257 -0.002 98 5490 0.0392 0.0364 90 2-Chlorotoluene 126 17.292 17.288 0.004 97 5519 0.0392 0.0379 91 4-Ethyltoluene 105 17.416 17.418 -0.002 98 20237 0.0392 0.0379 92 1,3,5-Trimethylbenzene 120 17.497 17.502 -0.005 91 8708 0.0392 0.0349 93 Alpha Methyl Styrene 118 17.740 17.744 -0.004 87 7102 0.0392 0.0341 94 n-Decane 57 17.842 17.846 -0.004 93 11966 0.0392 0.0404 95 tert-Butylbenzene 119 17.945 17.949 -0.004 92 18779 0.0392 0.0370 96 1,2,4-Trimethylbenzene 105 17.961 17.963 -0.002 96 17065 0.0392 0.0368 97 1,3-Dichlorobenzene 146 18.231 18.232 -0.001 73 13137 0.0392 0.0347 98 sec-Butylbenzene 105 18.231 18.235 -0.004 97 23605 0.0392 0.0355 99 Benzyl chloride 91 18.312 18.311 0.001 98 14129 0.0392 0.0335 100 1,4-Dichlorobenzene 146 18.322 18.324 -0.002 93 13711 0.0392 0.0365 101 4-Isopropyltoluene 119 18.409 18.410 -0.001 97 20714 0.0392 0.0359 102 1,2,3-Trimethylbenzene 105 18.452 18.454 -0.002 97 12572 0.0392 0.0365 103 Butylcyclohexane 83 18.527 18.527 0.000 95 15924 0.0392 0.0397 104 1,2-Dichlorobenzene 146 18.694 18.698 -0.004 91 12396 0.0392 0.0351 105 2,3-Dihydroindene 117 18.700 18.702 -0.002 93 15111 0.0392 0.0348 106 Indene 116 18.829 18.833 -0.004 92 11285 0.0392 0.0355 107 n-Butylbenzene 91 18.862 18.862 0.000 97 20094 0.0392 0.0376 108 Undecane 57 19.218 19.217 0.001 94 12926 0.0392 0.0406 109 1,2-Dimethyl-4-Ethylbenzen 119 19.244 19.247 -0.003 96 14800 0.0392 0.0350 110 1,2-Dibromo-3-Chloropropan 157 19.315 19.317 -0.002 83 1891 0.0392 0.0135 111 1,2,4,5-Tetramethylbenzene 119 19.644 19.642 0.002 95 17677 0.0392 0.0344 112 1,2,3,5-Tetramethylbenzene 119 19.697 19.696 0.001 93 11096 0.0392 0.0361 113 1,2,3,4-Tetramethylbenzene 119 20.091 20.092 -0.001 96 15300 0.0392 0.0362 114 Dodecane 57 20.285 20.286 -0.001 93 12911 0.0392 0.0440 115 1,2,4-Trichlorobenzene 180 20.425 20.427 -0.002 93 10108 0.0392 0.0329 116 Naphthalene 128 20.555 20.555 0.000 99 21376 0.0392 0.0334 117 Benzo(b)thiophene 134 20.652 20.653 -0.001 98 12572 0.0392 0.0354 118 Hexachlorobutadiene 225 20.781 20.783 -0.002 92 11577 0.0392 0.0386 119 1,2,3-Trichlorobenzene 180 20.830 20.831 -0.001 95 10864 0.0392 0.0390 120 2-Methylnaphthalene 142 21.628 21.628 0.000 99 13785 0.1225 0.1056 121 1-Methylnaphthalene 142 21.806 21.808 -0.002 98 13113 0.1225 0.1247 A 124 Toluene Range 1 13.027 (12.992-13.062) 0 34105 0.0392 0.0381 A 125 C8 Range 1 13.798 (13.783-13.813) 0 75709 0.0392 0.0481 S 126 Xylenes, Total 100 0 0.1176 0.1189 S 127 1,2-Dichloroethene, Total 1 0 0.0784 0.0880 Reagents: 40L12DNP_00009 Amount Added: 100.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 152 of 377 Report Date: 03-Mar-2017 15:07:57 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC01.D Injection Date:02-Mar-2017 13:34:30 Instrument ID:MG Operator ID:7126 Lims ID:IC L1 Worklist Smp#:3 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:1 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 Y ( X10 0 0 0 0 ) GC02IC01[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 0 0 7 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 7 4 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 4 4 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 7 1 5 ) 03/21/2017Page 153 of 377 Report Date: 03-Mar-2017 15:07:57 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC01.D Injection Date:02-Mar-2017 13:34:30 Instrument ID:MG Lims ID:IC L1 Client ID: Operator ID:7126 ALS Bottle#:1 Worklist Smp#:3 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 124 Toluene Range, CAS: STL02011 12.9 Min 4 6 8 10 12 14 16 18 20 22 24 Y ( X10 0 0 ) GC02IC01[MS SCAN Chro]:Total 03/21/2017Page 154 of 377 Report Date: 03-Mar-2017 15:07:57 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC01.D Injection Date:02-Mar-2017 13:34:30 Instrument ID:MG Lims ID:IC L1 Client ID: Operator ID:7126 ALS Bottle#:1 Worklist Smp#:3 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 125 C8 Range, CAS: STL00834 13.7 Min 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 Y ( X10 0 0 ) GC02IC01[MS SCAN Chro]:Total 03/21/2017Page 155 of 377 Report Date: 03-Mar-2017 15:11:12 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC03.D Lims ID:IC L3 Client ID: Sample Type:IC Calib Level:3 Inject. Date:02-Mar-2017 14:57:30 ALS Bottle#:2 Worklist Smp#:5 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004202-005 Misc. Info.:073146 Operator ID:7126 Instrument ID:MG Sublist:chrom-MG_TO15*sub5 Method:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:03-Mar-2017 15:11:10 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK031 First Level Reviewer: tajh Date:02-Mar-2017 15:32:47 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.007 8.012 -0.005 85 379983 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.175 10.179 -0.004 95 1958683 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.044 15.046 -0.002 87 2012188 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.716 16.717 -0.001 93 1498709 4.00 4.00 6 Chlorodifluoromethane 67 3.461 3.463 -0.002 97 6808 0.1587 0.1832 7 Propene 41 3.472 3.471 0.001 96 16251 0.1587 0.1835 8 Dichlorodifluoromethane 85 3.515 3.514 0.001 100 53178 0.1587 0.1577 9 Chloromethane 52 3.666 3.665 0.001 63 5382 0.1587 0.1978 10 1,2-Dichloro-1,1,2,2-tetra 135 3.677 3.675 0.002 91 32441 0.1587 0.1576 11 Acetaldehyde 44 3.795 3.793 0.002 88 80566 0.7933 1.99 12 Vinyl chloride 62 3.812 3.809 0.003 99 16924 0.1587 0.1625 13 Butadiene 54 3.887 3.883 0.004 66 11714 0.1587 0.1557 14 Butane 43 3.887 3.885 0.002 85 25743 0.1587 0.1632 15 Bromomethane 94 4.151 4.149 0.002 97 16675 0.1587 0.1577 16 Chloroethane 64 4.270 4.267 0.003 91 8789 0.1587 0.1577 17 Ethanol 31 4.367 4.372 -0.005 96 36579 0.7933 0.8758 18 Vinyl bromide 106 4.523 4.522 0.001 97 16729 0.1587 0.1663 19 2-Methylbutane 43 4.572 4.569 0.003 91 19697 0.1587 0.1638 20 Acrolein 56 4.755 4.732 0.023 29 3634 0.1587 0.2333 21 Trichlorofluoromethane 101 4.755 4.753 0.002 100 54904 0.1587 0.1589 22 Acetonitrile 40 4.809 4.808 0.001 98 6938 0.1587 0.1817 23 Acetone 58 4.852 4.849 0.003 99 34826 0.4760 0.8577 24 Pentane 72 4.955 4.949 0.006 78 3142 0.1587 0.1637 25 Isopropyl alcohol 45 4.949 4.963 -0.014 80 65802 0.4760 0.5464 26 Ethyl ether 31 5.095 5.090 0.005 90 20652 0.1587 0.1853 27 1,1-Dichloroethene 96 5.365 5.367 -0.002 96 15365 0.1587 0.1561 28 Acrylonitrile 53 5.445 5.450 -0.005 98 7699 0.1587 0.1618 29 2-Methyl-2-propanol 59 5.483 5.494 -0.011 94 25264 0.1587 0.1743 30 1,1,2-Trichloro-1,2,2-trif 101 5.537 5.536 0.001 96 32187 0.1587 0.1545 31 Methylene Chloride 84 5.661 5.669 -0.008 93 22114 0.1587 0.2416 03/21/2017Page 156 of 377 Report Date: 03-Mar-2017 15:11:12 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC03.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.683 5.684 -0.001 96 17649 0.1587 0.1850 33 Carbon disulfide 76 5.812 5.810 0.002 99 42161 0.1587 0.1608 34 trans-1,2-Dichloroethene 96 6.405 6.406 -0.001 97 15286 0.1587 0.1528 35 2-Methylpentane 43 6.438 6.439 -0.001 93 30478 0.1587 0.1531 36 Methyl tert-butyl ether 73 6.535 6.533 0.002 96 43383 0.1587 0.1661 37 1,1-Dichloroethane 63 6.783 6.787 -0.004 100 29248 0.1587 0.1571 38 Vinyl acetate 43 6.896 6.898 -0.002 99 31751 0.1587 0.1591 39 2-Butanone (MEK) 72 7.300 7.305 -0.005 99 7612 0.1587 0.1809 40 Hexane 56 7.354 7.350 0.004 81 12837 0.1587 0.1679 41 Isopropyl ether 45 7.505 7.502 0.003 94 44422 0.1587 0.1656 42 cis-1,2-Dichloroethene 96 7.705 7.707 -0.002 96 16338 0.1587 0.1560 43 Ethyl acetate 43 7.899 7.901 -0.002 98 26531 0.1587 0.1630 44 Chloroform 83 8.028 8.035 -0.007 94 40318 0.1587 0.1602 45 Tert-butyl ethyl ether 59 8.147 8.144 0.003 95 40459 0.1587 0.1620 46 Tetrahydrofuran 42 8.411 8.410 0.001 94 16742 0.1587 0.1822 47 1,1,1-Trichloroethane 97 9.010 9.013 -0.003 95 43667 0.1587 0.1576 48 1,2-Dichloroethane 62 9.096 9.106 -0.010 99 27616 0.1587 0.1590 49 Benzene 78 9.592 9.599 -0.007 96 48318 0.1587 0.1575 50 Cyclohexane 69 9.598 9.604 -0.006 89 8701 0.1587 0.1611 52 Carbon tetrachloride 117 9.625 9.629 -0.004 97 43951 0.1587 0.1536 51 n-Butanol 31 9.646 9.647 -0.001 63 5747 0.1587 0.1603 53 2,3-Dimethylpentane 71 9.749 9.754 -0.005 90 11928 0.1587 0.1574 54 Thiophene 84 9.867 9.873 -0.006 95 28016 0.1587 0.1593 55 Tert-amyl methyl ether 73 10.121 10.121 0.000 99 40454 0.1587 0.1573 56 Isooctane 57 10.423 10.430 -0.007 97 77114 0.1587 0.1595 57 n-Heptane 71 10.827 10.831 -0.004 91 19116 0.1587 0.1624 58 1,2-Dichloropropane 63 10.854 10.862 -0.008 85 18448 0.1587 0.1635 59 Trichloroethene 130 10.908 10.913 -0.005 96 26791 0.1587 0.1522 60 Dibromomethane 93 10.973 10.978 -0.005 94 23258 0.1587 0.1616 61 Dichlorobromomethane 83 11.140 11.143 -0.003 97 38506 0.1587 0.1527 62 1,4-Dioxane 88 11.172 11.173 -0.001 93 6467 0.1587 0.1577 63 Methyl methacrylate 41 11.275 11.278 -0.003 94 16492 0.1587 0.1499 64 Methylcyclohexane 83 11.717 11.718 -0.001 95 38650 0.1587 0.1547 65 4-Methyl-2-pentanone (MIBK 43 12.154 12.153 0.001 96 30859 0.1587 0.1674 66 cis-1,3-Dichloropropene 75 12.186 12.190 -0.004 97 30253 0.1587 0.1533 67 trans-1,3-Dichloropropene 75 12.909 12.911 -0.002 98 29964 0.1587 0.1521 68 Toluene 91 13.033 13.035 -0.002 93 58057 0.1587 0.1590 69 1,1,2-Trichloroethane 83 13.103 13.106 -0.003 97 17236 0.1587 0.1547 70 2-Methylthiophene 97 13.184 13.186 -0.002 96 48275 0.1587 0.1515 71 3-Methylthiophene 97 13.388 13.394 -0.006 98 49080 0.1587 0.1555 72 2-Hexanone 58 13.529 13.535 -0.006 94 14771 0.1587 0.1594 73 n-Octane 85 13.787 13.792 -0.005 91 20968 0.1587 0.1563 74 Chlorodibromomethane 129 13.809 13.816 -0.007 97 33862 0.1587 0.1373 75 Ethylene Dibromide 107 14.100 14.106 -0.006 98 32620 0.1587 0.1465 76 Tetrachloroethene 129 14.203 14.207 -0.004 94 24115 0.1587 0.1498 77 Chlorobenzene 112 15.092 15.095 -0.003 93 48589 0.1587 0.1517 78 2,3-Dimethylheptane 43 15.163 15.165 -0.002 94 51653 0.1587 0.1583 79 Ethylbenzene 91 15.400 15.402 -0.002 99 73987 0.1587 0.1542 80 2-Ethylthiophene 97 15.497 15.502 -0.005 98 59106 0.1587 0.1524 81 m-Xylene & p-Xylene 91 15.567 15.572 -0.005 99 117078 0.3173 0.3113 82 Bromoform 173 15.988 15.991 -0.003 95 28324 0.1587 0.1179 84 Styrene 104 16.036 16.037 -0.001 98 37823 0.1587 0.1419 03/21/2017Page 157 of 377 Report Date: 03-Mar-2017 15:11:12 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC03.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 83 n-Nonane 57 16.036 16.038 -0.002 90 38208 0.1587 0.1584 85 o-Xylene 91 16.095 16.099 -0.004 97 60752 0.1587 0.1576 86 1,1,2,2-Tetrachloroethane 83 16.419 16.422 -0.003 99 38761 0.1587 0.1532 87 1,2,3-Trichloropropane 110 16.570 16.577 -0.007 97 13265 0.1587 0.1535 88 Isopropylbenzene 105 16.699 16.703 -0.004 97 89734 0.1587 0.1600 89 N-Propylbenzene 120 17.255 17.257 -0.002 99 23064 0.1587 0.1544 90 2-Chlorotoluene 126 17.282 17.288 -0.006 96 22442 0.1587 0.1555 91 4-Ethyltoluene 105 17.411 17.418 -0.007 98 81294 0.1587 0.1536 92 1,3,5-Trimethylbenzene 120 17.497 17.502 -0.005 93 37525 0.1587 0.1516 93 Alpha Methyl Styrene 118 17.740 17.744 -0.004 87 28693 0.1587 0.1389 94 n-Decane 57 17.843 17.846 -0.003 93 47043 0.1587 0.1602 95 tert-Butylbenzene 119 17.945 17.949 -0.004 91 75521 0.1587 0.1504 96 1,2,4-Trimethylbenzene 105 17.956 17.963 -0.007 96 70625 0.1587 0.1538 97 1,3-Dichlorobenzene 146 18.225 18.232 -0.007 97 53064 0.1587 0.1413 98 sec-Butylbenzene 105 18.231 18.235 -0.004 98 99807 0.1587 0.1514 99 Benzyl chloride 91 18.306 18.311 -0.005 98 61888 0.1587 0.1482 100 1,4-Dichlorobenzene 146 18.317 18.324 -0.007 93 54236 0.1587 0.1459 101 4-Isopropyltoluene 119 18.409 18.410 -0.001 97 86111 0.1587 0.1507 102 1,2,3-Trimethylbenzene 105 18.447 18.454 -0.008 98 53855 0.1587 0.1577 103 Butylcyclohexane 83 18.522 18.527 -0.005 93 60233 0.1587 0.1515 104 1,2-Dichlorobenzene 146 18.695 18.698 -0.003 93 51022 0.1587 0.1460 105 2,3-Dihydroindene 117 18.700 18.702 -0.002 93 63910 0.1587 0.1484 106 Indene 116 18.829 18.833 -0.004 93 45014 0.1587 0.1431 107 n-Butylbenzene 91 18.862 18.862 0.000 98 80776 0.1587 0.1527 108 Undecane 57 19.218 19.217 0.001 94 49706 0.1587 0.1576 109 1,2-Dimethyl-4-Ethylbenzen 119 19.245 19.247 -0.002 97 60370 0.1587 0.1442 110 1,2-Dibromo-3-Chloropropan 157 19.315 19.317 -0.002 87 18473 0.1587 0.1331 111 1,2,4,5-Tetramethylbenzene 119 19.638 19.642 -0.004 96 73810 0.1587 0.1449 112 1,2,3,5-Tetramethylbenzene 119 19.692 19.696 -0.004 96 45344 0.1587 0.1490 113 1,2,3,4-Tetramethylbenzene 119 20.091 20.092 -0.001 96 61486 0.1587 0.1468 114 Dodecane 57 20.285 20.286 -0.001 95 50609 0.1587 0.1742 115 1,2,4-Trichlorobenzene 180 20.426 20.427 -0.001 93 42037 0.1587 0.1381 116 Naphthalene 128 20.555 20.555 0.000 99 92541 0.1587 0.1459 117 Benzo(b)thiophene 134 20.652 20.653 -0.001 99 52800 0.1587 0.1500 118 Hexachlorobutadiene 225 20.781 20.783 -0.002 94 44234 0.1587 0.1490 119 1,2,3-Trichlorobenzene 180 20.830 20.831 -0.001 95 44545 0.1587 0.1612 120 2-Methylnaphthalene 142 21.628 21.628 0.000 100 61911 0.4958 0.4785 121 1-Methylnaphthalene 142 21.806 21.808 -0.002 100 48997 0.4958 0.4702 A 124 Toluene Range 1 13.028 (12.993-13.063) 0 143509 0.1587 0.1640 A 125 C8 Range 1 13.792 (13.777-13.807) 0 312006 0.1587 0.2030 S 126 Xylenes, Total 100 0 0.4760 0.4689 S 127 1,2-Dichloroethene, Total 1 0 0.3173 0.3088 Reagents: 40L3DNP_00010 Amount Added: 200.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 158 of 377 Report Date: 03-Mar-2017 15:11:12 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC03.D Injection Date:02-Mar-2017 14:57:30 Instrument ID:MG Operator ID:7126 Lims ID:IC L3 Worklist Smp#:5 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:2 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 Y ( X10 0 0 0 0 ) GC02IC03[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 0 0 7 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 7 5 )* C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 4 4 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 7 1 0 ) 03/21/2017Page 159 of 377 Report Date: 03-Mar-2017 15:11:12 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC03.D Injection Date:02-Mar-2017 14:57:30 Instrument ID:MG Lims ID:IC L3 Client ID: Operator ID:7126 ALS Bottle#:2 Worklist Smp#:5 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 124 Toluene Range, CAS: STL02011 12.9 Min 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 Y ( X10 0 0 ) GC02IC03[MS SCAN Chro]:Total 03/21/2017Page 160 of 377 Report Date: 03-Mar-2017 15:11:12 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC03.D Injection Date:02-Mar-2017 14:57:30 Instrument ID:MG Lims ID:IC L3 Client ID: Operator ID:7126 ALS Bottle#:2 Worklist Smp#:5 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 125 C8 Range, CAS: STL00834 13.7 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 Y ( X10 0 0 0 ) GC02IC03[MS SCAN Chro]:Total 03/21/2017Page 161 of 377 Report Date: 03-Mar-2017 15:12:06 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC04.D Lims ID:IC L4 Client ID: Sample Type:IC Calib Level:4 Inject. Date:02-Mar-2017 15:39:30 ALS Bottle#:3 Worklist Smp#:6 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004202-006 Misc. Info.:073144 Operator ID:7126 Instrument ID:MG Sublist:chrom-MG_TO15*sub5 Method:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:03-Mar-2017 15:12:05 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK031 First Level Reviewer: tajh Date:02-Mar-2017 16:19:02 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.002 8.012 -0.010 85 374224 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.169 10.179 -0.010 95 1955072 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.039 15.046 -0.007 87 1974284 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.710 16.717 -0.007 94 1486983 4.00 4.05 6 Chlorodifluoromethane 67 3.456 3.463 -0.007 97 14940 0.4000 0.4083 7 Propene 41 3.467 3.471 -0.004 97 36163 0.4000 0.4146 8 Dichlorodifluoromethane 85 3.510 3.514 -0.004 100 135386 0.4000 0.4078 9 Chloromethane 52 3.661 3.665 -0.004 56 10642 0.4000 0.3972 10 1,2-Dichloro-1,1,2,2-tetra 135 3.666 3.675 -0.009 92 80988 0.4000 0.3995 11 Acetaldehyde 44 3.785 3.793 -0.008 89 134527 2.00 3.37 12 Vinyl chloride 62 3.801 3.809 -0.008 99 42048 0.4000 0.4099 13 Butadiene 54 3.876 3.883 -0.007 84 29149 0.4000 0.3935 14 Butane 43 3.876 3.885 -0.009 93 63224 0.4000 0.4069 15 Bromomethane 94 4.141 4.149 -0.008 98 42057 0.4000 0.4039 16 Chloroethane 64 4.259 4.267 -0.008 92 22651 0.4000 0.4126 17 Ethanol 31 4.345 4.372 -0.027 97 89923 2.00 2.19 18 Vinyl bromide 106 4.513 4.522 -0.009 97 39895 0.4000 0.4027 19 2-Methylbutane 43 4.561 4.569 -0.008 93 50052 0.4000 0.4227 20 Acrolein 56 4.739 4.732 0.007 29 5738 0.4000 0.3740 21 Trichlorofluoromethane 101 4.745 4.753 -0.009 100 136800 0.4000 0.4021 22 Acetonitrile 40 4.793 4.808 -0.015 94 18563 0.4000 0.4936 23 Acetone 58 4.836 4.849 -0.013 100 72746 1.20 1.82 24 Pentane 72 4.939 4.949 -0.010 95 7706 0.4000 0.4077 25 Isopropyl alcohol 45 4.922 4.963 -0.041 96 154370 1.20 1.30 26 Ethyl ether 31 5.079 5.090 -0.011 92 44528 0.4000 0.4056 27 1,1-Dichloroethene 96 5.359 5.367 -0.008 96 37664 0.4000 0.3886 28 Acrylonitrile 53 5.440 5.450 -0.010 94 19112 0.4000 0.4079 29 2-Methyl-2-propanol 59 5.451 5.494 -0.043 96 58501 0.4000 0.4099 30 1,1,2-Trichloro-1,2,2-trif 101 5.526 5.536 -0.010 96 80017 0.4000 0.3899 31 Methylene Chloride 84 5.656 5.669 -0.013 92 39408 0.4000 0.4371 03/21/2017Page 162 of 377 Report Date: 03-Mar-2017 15:12:06 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC04.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.672 5.684 -0.012 97 37029 0.4000 0.3941 33 Carbon disulfide 76 5.801 5.810 -0.009 100 99197 0.4000 0.3842 34 trans-1,2-Dichloroethene 96 6.400 6.406 -0.006 99 37871 0.4000 0.3844 35 2-Methylpentane 43 6.427 6.439 -0.012 93 76233 0.4000 0.3889 36 Methyl tert-butyl ether 73 6.519 6.533 -0.014 96 104801 0.4000 0.4075 37 1,1-Dichloroethane 63 6.777 6.787 -0.010 100 71609 0.4000 0.3906 38 Vinyl acetate 43 6.885 6.898 -0.013 99 80081 0.4000 0.4075 39 2-Butanone (MEK) 72 7.290 7.305 -0.015 99 18610 0.4000 0.4491 40 Hexane 56 7.338 7.350 -0.012 86 29431 0.4000 0.3908 41 Isopropyl ether 45 7.489 7.502 -0.013 95 111795 0.4000 0.4233 42 cis-1,2-Dichloroethene 96 7.694 7.707 -0.013 95 39588 0.4000 0.3839 43 Ethyl acetate 43 7.883 7.901 -0.018 98 66540 0.4000 0.4152 44 Chloroform 83 8.023 8.035 -0.012 95 98505 0.4000 0.3974 45 Tert-butyl ethyl ether 59 8.131 8.144 -0.013 95 101064 0.4000 0.4110 46 Tetrahydrofuran 42 8.401 8.410 -0.009 91 38873 0.4000 0.4295 47 1,1,1-Trichloroethane 97 9.004 9.013 -0.009 94 106654 0.4000 0.3910 48 1,2-Dichloroethane 62 9.091 9.106 -0.015 99 67542 0.4000 0.3895 49 Benzene 78 9.592 9.599 -0.007 96 117159 0.4000 0.3826 50 Cyclohexane 69 9.603 9.604 -0.001 92 20685 0.4000 0.3836 52 Carbon tetrachloride 117 9.619 9.629 -0.010 97 95114 0.4000 0.3331 51 n-Butanol 31 9.603 9.647 -0.044 67 13386 0.4000 0.3740 53 2,3-Dimethylpentane 71 9.743 9.754 -0.011 90 28526 0.4000 0.3772 54 Thiophene 84 9.862 9.873 -0.011 96 67355 0.4000 0.3836 55 Tert-amyl methyl ether 73 10.110 10.121 -0.011 98 108255 0.4000 0.4217 56 Isooctane 57 10.423 10.430 -0.007 96 187987 0.4000 0.3895 57 n-Heptane 71 10.822 10.831 -0.009 91 45416 0.4000 0.3865 58 1,2-Dichloropropane 63 10.854 10.862 -0.008 89 43467 0.4000 0.3859 59 Trichloroethene 130 10.908 10.913 -0.005 96 66089 0.4000 0.3762 60 Dibromomethane 93 10.967 10.978 -0.011 95 54422 0.4000 0.3789 61 Dichlorobromomethane 83 11.134 11.143 -0.009 98 95415 0.4000 0.3791 62 1,4-Dioxane 88 11.156 11.173 -0.017 92 16645 0.4000 0.4067 63 Methyl methacrylate 41 11.264 11.278 -0.014 94 41751 0.4000 0.3801 64 Methylcyclohexane 83 11.711 11.718 -0.007 95 95681 0.4000 0.3837 65 4-Methyl-2-pentanone (MIBK 43 12.137 12.153 -0.016 96 76682 0.4000 0.4166 66 cis-1,3-Dichloropropene 75 12.181 12.190 -0.009 94 75926 0.4000 0.3854 67 trans-1,3-Dichloropropene 75 12.903 12.911 -0.008 97 71985 0.4000 0.3725 68 Toluene 91 13.027 13.035 -0.008 93 133914 0.4000 0.3737 69 1,1,2-Trichloroethane 83 13.097 13.106 -0.009 98 41787 0.4000 0.3824 70 2-Methylthiophene 97 13.178 13.186 -0.008 97 119176 0.4000 0.3811 71 3-Methylthiophene 97 13.388 13.394 -0.006 99 118682 0.4000 0.3833 72 2-Hexanone 58 13.523 13.535 -0.012 95 35230 0.4000 0.3876 73 n-Octane 85 13.788 13.792 -0.004 91 50555 0.4000 0.3842 74 Chlorodibromomethane 129 13.809 13.816 -0.007 97 84996 0.4000 0.3513 75 Ethylene Dibromide 107 14.100 14.106 -0.006 98 81398 0.4000 0.3726 76 Tetrachloroethene 129 14.203 14.207 -0.004 94 58871 0.4000 0.3726 77 Chlorobenzene 112 15.087 15.095 -0.008 93 117838 0.4000 0.3748 78 2,3-Dimethylheptane 43 15.163 15.165 -0.002 92 125279 0.4000 0.3913 79 Ethylbenzene 91 15.394 15.402 -0.008 99 184802 0.4000 0.3926 80 2-Ethylthiophene 97 15.497 15.502 -0.005 98 148208 0.4000 0.3894 81 m-Xylene & p-Xylene 91 15.567 15.572 -0.005 99 291621 0.8000 0.7902 82 Bromoform 173 15.982 15.991 -0.009 95 69748 0.4000 0.2959 84 Styrene 104 16.031 16.037 -0.006 98 99226 0.4000 0.3793 03/21/2017Page 163 of 377 Report Date: 03-Mar-2017 15:12:06 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC04.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 83 n-Nonane 57 16.036 16.038 -0.002 89 93758 0.4000 0.3961 85 o-Xylene 91 16.095 16.099 -0.004 98 148753 0.4000 0.3932 86 1,1,2,2-Tetrachloroethane 83 16.414 16.422 -0.008 99 95320 0.4000 0.3840 87 1,2,3-Trichloropropane 110 16.570 16.577 -0.007 97 33294 0.4000 0.3927 88 Isopropylbenzene 105 16.699 16.703 -0.004 97 214385 0.4000 0.3896 89 N-Propylbenzene 120 17.249 17.257 -0.008 99 55901 0.4000 0.3814 90 2-Chlorotoluene 126 17.282 17.288 -0.006 97 53040 0.4000 0.3746 91 4-Ethyltoluene 105 17.411 17.418 -0.007 98 201470 0.4000 0.3879 92 1,3,5-Trimethylbenzene 120 17.492 17.502 -0.010 92 93050 0.4000 0.3832 93 Alpha Methyl Styrene 118 17.740 17.744 -0.004 86 72396 0.4000 0.3571 94 n-Decane 57 17.843 17.846 -0.003 93 111892 0.4000 0.3883 95 tert-Butylbenzene 119 17.945 17.949 -0.004 90 188113 0.4000 0.3818 96 1,2,4-Trimethylbenzene 105 17.956 17.963 -0.007 96 173408 0.4000 0.3848 97 1,3-Dichlorobenzene 146 18.225 18.232 -0.007 97 129852 0.4000 0.3524 98 sec-Butylbenzene 105 18.231 18.235 -0.004 98 247548 0.4000 0.3827 99 Benzyl chloride 91 18.306 18.311 -0.005 97 156606 0.4000 0.3823 100 1,4-Dichlorobenzene 146 18.317 18.324 -0.007 95 130139 0.4000 0.3568 101 4-Isopropyltoluene 119 18.403 18.410 -0.007 97 214918 0.4000 0.3834 102 1,2,3-Trimethylbenzene 105 18.447 18.454 -0.007 98 131293 0.4000 0.3918 103 Butylcyclohexane 83 18.522 18.527 -0.005 95 149071 0.4000 0.3820 104 1,2-Dichlorobenzene 146 18.695 18.698 -0.003 93 122080 0.4000 0.3560 105 2,3-Dihydroindene 117 18.700 18.702 -0.002 94 156836 0.4000 0.3712 106 Indene 116 18.829 18.833 -0.004 91 112170 0.4000 0.3633 107 n-Butylbenzene 91 18.856 18.862 -0.006 98 203720 0.4000 0.3924 108 Undecane 57 19.212 19.217 -0.005 94 120374 0.4000 0.3890 109 1,2-Dimethyl-4-Ethylbenzen 119 19.245 19.247 -0.002 97 152789 0.4000 0.3720 110 1,2-Dibromo-3-Chloropropan 157 19.315 19.317 -0.002 93 41383 0.4000 0.3038 111 1,2,4,5-Tetramethylbenzene 119 19.638 19.642 -0.004 96 175959 0.4000 0.3520 112 1,2,3,5-Tetramethylbenzene 119 19.692 19.696 -0.004 94 107601 0.4000 0.3604 113 1,2,3,4-Tetramethylbenzene 119 20.091 20.092 -0.001 96 142698 0.4000 0.3472 114 Dodecane 57 20.285 20.286 -0.001 94 105194 0.4000 0.3690 115 1,2,4-Trichlorobenzene 180 20.426 20.427 -0.001 94 93377 0.4000 0.3127 116 Naphthalene 128 20.555 20.555 0.000 99 197303 0.4000 0.3169 117 Benzo(b)thiophene 134 20.652 20.653 -0.001 99 115646 0.4000 0.3349 118 Hexachlorobutadiene 225 20.781 20.783 -0.002 88 100465 0.4000 0.3448 119 1,2,3-Trichlorobenzene 180 20.830 20.831 -0.001 95 95414 0.4000 0.3519 120 2-Methylnaphthalene 142 21.628 21.628 0.000 99 116309 1.25 0.9163 121 1-Methylnaphthalene 142 21.806 21.808 -0.002 100 98052 1.25 0.9590 A 124 Toluene Range 1 13.022 (12.987-13.057) 0 339092 0.4000 0.3882 A 125 C8 Range 1 13.793 (13.778-13.808) 0 760418 0.4000 0.4956 S 126 Xylenes, Total 100 0 1.20 1.18 S 127 1,2-Dichloroethene, Total 1 0 0.8000 0.7683 Reagents: 40L4DNP_00009 Amount Added: 200.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 164 of 377 Report Date: 03-Mar-2017 15:12:07 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC04.D Injection Date:02-Mar-2017 15:39:30 Instrument ID:MG Operator ID:7126 Lims ID:IC L4 Worklist Smp#:6 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:3 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 Y ( X10 0 0 0 0 ) GC02IC04[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 0 0 2 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 6 9 )* C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 3 9 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 7 1 0 ) 03/21/2017Page 165 of 377 Report Date: 03-Mar-2017 15:12:07 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC04.D Injection Date:02-Mar-2017 15:39:30 Instrument ID:MG Lims ID:IC L4 Client ID: Operator ID:7126 ALS Bottle#:3 Worklist Smp#:6 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 124 Toluene Range, CAS: STL02011 12.9 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Y ( X10 0 0 0 ) GC02IC04[MS SCAN Chro]:Total 03/21/2017Page 166 of 377 Report Date: 03-Mar-2017 15:12:07 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC04.D Injection Date:02-Mar-2017 15:39:30 Instrument ID:MG Lims ID:IC L4 Client ID: Operator ID:7126 ALS Bottle#:3 Worklist Smp#:6 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 125 C8 Range, CAS: STL00834 13.7 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 Y ( X10 0 0 0 ) GC02IC04[MS SCAN Chro]:Total 03/21/2017Page 167 of 377 Report Date: 03-Mar-2017 15:13:21 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC05.D Lims ID:IC L5 Client ID: Sample Type:IC Calib Level:5 Inject. Date:02-Mar-2017 16:20:30 ALS Bottle#:4 Worklist Smp#:7 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004202-007 Misc. Info.:073142 Operator ID:7126 Instrument ID:MG Sublist:chrom-MG_TO15*sub5 Method:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:03-Mar-2017 15:13:19 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK031 First Level Reviewer: barlozhetskayaa Date:03-Mar-2017 12:01:41 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.007 8.012 -0.005 85 382085 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.174 10.179 -0.005 95 1984249 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.044 15.046 -0.002 87 2026230 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.715 16.717 -0.002 93 1524315 4.00 4.04 6 Chlorodifluoromethane 67 3.461 3.463 -0.002 97 36701 1.00 0.9823 7 Propene 41 3.466 3.471 -0.005 98 90943 1.00 1.02 8 Dichlorodifluoromethane 85 3.515 3.514 0.001 100 353716 1.00 1.04 9 Chloromethane 52 3.660 3.665 -0.005 97 29383 1.00 1.07 10 1,2-Dichloro-1,1,2,2-tetra 135 3.671 3.675 -0.004 92 219262 1.00 1.06 11 Acetaldehyde 44 3.790 3.793 -0.003 89 208740 4.99 5.12 12 Vinyl chloride 62 3.806 3.809 -0.003 99 112960 1.00 1.08 13 Butadiene 54 3.882 3.883 -0.001 87 81559 1.00 1.08 14 Butane 43 3.882 3.885 -0.003 95 170131 1.00 1.07 15 Bromomethane 94 4.146 4.149 -0.003 98 112705 1.00 1.06 16 Chloroethane 64 4.264 4.267 -0.003 91 60191 1.00 1.07 17 Ethanol 31 4.356 4.372 -0.016 97 203965 4.99 4.86 18 Vinyl bromide 106 4.518 4.522 -0.004 97 108833 1.00 1.08 19 2-Methylbutane 43 4.566 4.569 -0.003 92 137869 1.00 1.14 20 Acrolein 56 4.744 4.732 0.012 28 14386 1.00 0.9184 21 Trichlorofluoromethane 101 4.750 4.753 -0.003 100 373948 1.00 1.08 22 Acetonitrile 40 4.798 4.808 -0.010 98 36659 1.00 0.9548 23 Acetone 58 4.841 4.849 -0.008 99 121293 3.00 2.97 24 Pentane 72 4.944 4.949 -0.005 97 22070 1.00 1.14 25 Isopropyl alcohol 45 4.938 4.963 -0.025 94 335763 3.00 2.77 26 Ethyl ether 31 5.084 5.090 -0.006 90 110481 1.00 0.9857 27 1,1-Dichloroethene 96 5.364 5.367 -0.003 96 105498 1.00 1.07 28 Acrylonitrile 53 5.440 5.450 -0.010 95 48269 1.00 1.01 29 2-Methyl-2-propanol 59 5.462 5.494 -0.032 96 142251 1.00 0.9762 30 1,1,2-Trichloro-1,2,2-trif 101 5.532 5.536 -0.004 96 222408 1.00 1.06 31 Methylene Chloride 84 5.666 5.669 -0.003 94 92548 1.00 1.01 03/21/2017Page 168 of 377 Report Date: 03-Mar-2017 15:13:21 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC05.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.677 5.684 -0.007 96 101547 1.00 1.06 33 Carbon disulfide 76 5.807 5.810 -0.003 100 274333 1.00 1.04 34 trans-1,2-Dichloroethene 96 6.400 6.406 -0.006 97 102572 1.00 1.02 35 2-Methylpentane 43 6.438 6.439 -0.001 93 209472 1.00 1.05 36 Methyl tert-butyl ether 73 6.524 6.533 -0.009 96 244925 1.00 0.9329 37 1,1-Dichloroethane 63 6.783 6.787 -0.004 100 188496 1.00 1.01 38 Vinyl acetate 43 6.890 6.898 -0.008 99 184358 1.00 0.9189 39 2-Butanone (MEK) 72 7.290 7.305 -0.015 99 37188 1.00 0.8789 40 Hexane 56 7.343 7.350 -0.007 85 78896 1.00 1.03 41 Isopropyl ether 45 7.489 7.502 -0.013 95 256058 1.00 0.9495 42 cis-1,2-Dichloroethene 96 7.699 7.707 -0.008 96 104471 1.00 0.99 43 Ethyl acetate 43 7.888 7.901 -0.013 98 150266 1.00 0.9184 44 Chloroform 83 8.028 8.035 -0.007 96 254283 1.00 1.00 45 Tert-butyl ethyl ether 59 8.131 8.144 -0.013 95 238643 1.00 0.9505 46 Tetrahydrofuran 42 8.400 8.410 -0.010 91 81529 1.00 0.8823 47 1,1,1-Trichloroethane 97 9.010 9.013 -0.003 95 282846 1.00 1.02 48 1,2-Dichloroethane 62 9.101 9.106 -0.005 99 175618 1.00 1.00 49 Benzene 78 9.592 9.599 -0.007 96 305578 1.00 0.9833 50 Cyclohexane 69 9.597 9.604 -0.007 94 55034 1.00 1.01 52 Carbon tetrachloride 117 9.624 9.629 -0.005 98 294089 1.00 1.01 51 n-Butanol 31 9.635 9.647 -0.012 69 31686 1.00 0.8722 53 2,3-Dimethylpentane 71 9.748 9.754 -0.006 89 74710 1.00 0.9733 54 Thiophene 84 9.867 9.873 -0.006 95 177621 1.00 1.00 55 Tert-amyl methyl ether 73 10.110 10.121 -0.011 98 243858 1.00 0.9361 56 Isooctane 57 10.422 10.430 -0.008 97 487596 1.00 1.00 57 n-Heptane 71 10.827 10.831 -0.004 90 118391 1.00 0.99 58 1,2-Dichloropropane 63 10.859 10.862 -0.003 85 110995 1.00 0.9710 59 Trichloroethene 130 10.908 10.913 -0.005 96 186014 1.00 1.04 60 Dibromomethane 93 10.973 10.978 -0.006 95 146524 1.00 1.01 61 Dichlorobromomethane 83 11.134 11.143 -0.009 98 258735 1.00 1.01 62 1,4-Dioxane 88 11.161 11.173 -0.012 92 38926 1.00 0.9370 63 Methyl methacrylate 41 11.269 11.278 -0.009 93 96652 1.00 0.8671 64 Methylcyclohexane 83 11.711 11.718 -0.007 95 250534 1.00 0.9899 65 4-Methyl-2-pentanone (MIBK 43 12.143 12.153 -0.010 97 150862 1.00 0.8076 66 cis-1,3-Dichloropropene 75 12.186 12.190 -0.004 95 199844 1.00 1.00 67 trans-1,3-Dichloropropene 75 12.903 12.911 -0.008 97 190582 1.00 0.9608 68 Toluene 91 13.032 13.035 -0.003 94 339763 1.00 0.9239 69 1,1,2-Trichloroethane 83 13.103 13.106 -0.004 99 103808 1.00 0.9256 70 2-Methylthiophene 97 13.183 13.186 -0.003 97 307996 1.00 0.9598 71 3-Methylthiophene 97 13.388 13.394 -0.006 99 304111 1.00 0.9569 72 2-Hexanone 58 13.523 13.535 -0.012 93 75024 1.00 0.8042 73 n-Octane 85 13.787 13.792 -0.005 91 132681 1.00 0.9824 74 Chlorodibromomethane 129 13.809 13.816 -0.007 97 246365 1.00 0.99 75 Ethylene Dibromide 107 14.100 14.106 -0.006 98 217002 1.00 0.9680 76 Tetrachloroethene 129 14.203 14.207 -0.004 94 154481 1.00 0.9527 77 Chlorobenzene 112 15.092 15.095 -0.003 93 310288 1.00 0.9617 78 2,3-Dimethylheptane 43 15.162 15.165 -0.003 92 323718 1.00 0.9852 79 Ethylbenzene 91 15.400 15.402 -0.002 99 444543 1.00 0.9201 80 2-Ethylthiophene 97 15.497 15.502 -0.005 98 364072 1.00 0.9320 81 m-Xylene & p-Xylene 91 15.567 15.572 -0.005 99 701860 2.00 1.85 82 Bromoform 173 15.987 15.991 -0.004 96 217947 1.00 0.9010 84 Styrene 104 16.031 16.037 -0.006 97 252653 1.00 0.9410 03/21/2017Page 169 of 377 Report Date: 03-Mar-2017 15:13:21 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC05.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 83 n-Nonane 57 16.036 16.038 -0.002 88 244961 1.00 1.01 85 o-Xylene 91 16.095 16.099 -0.004 98 353133 1.00 0.9096 86 1,1,2,2-Tetrachloroethane 83 16.419 16.422 -0.003 99 232481 1.00 0.9126 87 1,2,3-Trichloropropane 110 16.570 16.577 -0.007 97 79343 1.00 0.9118 88 Isopropylbenzene 105 16.699 16.703 -0.004 98 509862 1.00 0.9028 89 N-Propylbenzene 120 17.255 17.257 -0.002 99 134620 1.00 0.8949 90 2-Chlorotoluene 126 17.282 17.288 -0.006 97 135297 1.00 0.9311 91 4-Ethyltoluene 105 17.416 17.418 -0.002 98 473972 1.00 0.8891 92 1,3,5-Trimethylbenzene 120 17.497 17.502 -0.005 92 221193 1.00 0.8875 93 Alpha Methyl Styrene 118 17.740 17.744 -0.004 88 186268 1.00 0.8953 94 n-Decane 57 17.842 17.846 -0.004 93 296801 1.00 1.00 95 tert-Butylbenzene 119 17.945 17.949 -0.004 91 447831 1.00 0.8855 96 1,2,4-Trimethylbenzene 105 17.961 17.963 -0.002 95 413399 1.00 0.8937 97 1,3-Dichlorobenzene 146 18.231 18.232 -0.001 97 346492 1.00 0.9161 98 sec-Butylbenzene 105 18.231 18.235 -0.004 98 592460 1.00 0.8923 99 Benzyl chloride 91 18.306 18.311 -0.005 98 383181 1.00 0.9113 100 1,4-Dichlorobenzene 146 18.322 18.324 -0.002 96 339022 1.00 0.9057 101 4-Isopropyltoluene 119 18.409 18.410 -0.001 97 510030 1.00 0.8864 102 1,2,3-Trimethylbenzene 105 18.452 18.454 -0.002 98 306762 1.00 0.8919 103 Butylcyclohexane 83 18.527 18.527 0.000 96 402561 1.00 1.01 104 1,2-Dichlorobenzene 146 18.694 18.698 -0.004 93 316358 1.00 0.8990 105 2,3-Dihydroindene 117 18.700 18.702 -0.002 93 386578 1.00 0.8914 106 Indene 116 18.829 18.833 -0.004 92 280824 1.00 0.8863 107 n-Butylbenzene 91 18.856 18.862 -0.006 98 484303 1.00 0.9089 108 Undecane 57 19.217 19.217 0.000 94 319511 1.00 1.01 109 1,2-Dimethyl-4-Ethylbenzen 119 19.244 19.247 -0.003 97 382029 1.00 0.9062 110 1,2-Dibromo-3-Chloropropan 157 19.315 19.317 -0.003 96 121417 1.00 0.8685 111 1,2,4,5-Tetramethylbenzene 119 19.638 19.642 -0.004 96 458404 1.00 0.8935 112 1,2,3,5-Tetramethylbenzene 119 19.692 19.696 -0.004 94 266757 1.00 0.8706 113 1,2,3,4-Tetramethylbenzene 119 20.091 20.092 -0.001 97 361637 1.00 0.8573 114 Dodecane 57 20.285 20.286 -0.001 94 297125 1.00 1.02 115 1,2,4-Trichlorobenzene 180 20.425 20.427 -0.002 94 266823 1.00 0.8708 116 Naphthalene 128 20.555 20.555 0.000 99 542795 1.00 0.8496 117 Benzo(b)thiophene 134 20.652 20.653 -0.001 99 323541 1.00 0.9130 118 Hexachlorobutadiene 225 20.781 20.783 -0.002 95 293683 1.00 0.9821 119 1,2,3-Trichlorobenzene 180 20.830 20.831 -0.001 94 272663 1.00 0.9799 120 2-Methylnaphthalene 142 21.628 21.628 0.000 99 405427 3.12 3.11 121 1-Methylnaphthalene 142 21.806 21.808 -0.002 100 351664 3.12 3.35 A 124 Toluene Range 1 13.027 (12.992-13.062) 0 853542 1.00 0.9629 A 125 C8 Range 1 13.792 (13.777-13.807) 0 1992357 1.00 1.28 S 126 Xylenes, Total 100 0 3.00 2.76 S 127 1,2-Dichloroethene, Total 1 0 2.00 2.01 Reagents: 40L6DNP_00010 Amount Added: 100.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 170 of 377 Report Date: 03-Mar-2017 15:13:21 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC05.D Injection Date:02-Mar-2017 16:20:30 Instrument ID:MG Operator ID:7126 Lims ID:IC L5 Worklist Smp#:7 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:4 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 Y ( X10 0 0 0 0 ) GC02IC05[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 0 0 7 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 7 4 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 4 4 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 7 1 0 ) 03/21/2017Page 171 of 377 Report Date: 03-Mar-2017 15:13:21 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC05.D Injection Date:02-Mar-2017 16:20:30 Instrument ID:MG Lims ID:IC L5 Client ID: Operator ID:7126 ALS Bottle#:4 Worklist Smp#:7 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 124 Toluene Range, CAS: STL02011 12.9 Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 42 45 Y ( X10 0 0 0 ) GC02IC05[MS SCAN Chro]:Total 03/21/2017Page 172 of 377 Report Date: 03-Mar-2017 15:13:21 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC05.D Injection Date:02-Mar-2017 16:20:30 Instrument ID:MG Lims ID:IC L5 Client ID: Operator ID:7126 ALS Bottle#:4 Worklist Smp#:7 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 125 C8 Range, CAS: STL00834 13.7 Min 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 Y ( X10 0 0 0 ) GC02IC05[MS SCAN Chro]:Total 03/21/2017Page 173 of 377 Report Date: 03-Mar-2017 15:14:02 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC06.D Lims ID:ICIS L6 Client ID: Sample Type:ICIS Calib Level:6 Inject. Date:02-Mar-2017 17:02:30 ALS Bottle#:5 Worklist Smp#:8 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004202-008 Misc. Info.:073142 Operator ID:7126 Instrument ID:MG Sublist:chrom-MG_TO15*sub5 Method:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:03-Mar-2017 15:14:02 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK031 First Level Reviewer: barlozhetskayaa Date:03-Mar-2017 10:05:01 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.012 8.012 0.000 85 397020 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.180 10.179 0.001 95 1995357 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.044 15.046 -0.002 87 2047691 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.715 16.717 -0.002 96 1498532 4.00 3.93 6 Chlorodifluoromethane 67 3.466 3.463 0.003 97 73615 2.00 1.90 7 Propene 41 3.472 3.471 0.001 98 181398 2.00 1.96 8 Dichlorodifluoromethane 85 3.515 3.514 0.001 100 698780 2.00 1.98 9 Chloromethane 52 3.666 3.665 0.001 97 57078 2.00 2.01 10 1,2-Dichloro-1,1,2,2-tetra 135 3.677 3.675 0.002 92 436894 2.00 2.03 11 Acetaldehyde 44 3.795 3.793 0.002 89 412654 9.99 9.74 12 Vinyl chloride 62 3.811 3.809 0.002 99 225546 2.00 2.07 13 Butadiene 54 3.887 3.883 0.004 66 163453 2.00 2.08 14 Butane 43 3.887 3.885 0.002 86 336204 2.00 2.04 15 Bromomethane 94 4.151 4.149 0.002 98 223993 2.00 2.03 16 Chloroethane 64 4.264 4.267 -0.003 91 117430 2.00 2.02 17 Ethanol 31 4.367 4.372 -0.005 96 438460 9.99 10.0 18 Vinyl bromide 106 4.523 4.522 0.001 97 208124 2.00 1.98 19 2-Methylbutane 43 4.572 4.569 0.003 92 262104 2.00 2.09 20 Acrolein 56 4.750 4.732 0.018 29 31009 2.00 1.91 21 Trichlorofluoromethane 101 4.755 4.753 0.002 100 714498 2.00 1.98 22 Acetonitrile 40 4.804 4.808 -0.004 98 77854 2.00 1.95 23 Acetone 58 4.841 4.849 -0.008 99 254325 5.99 5.99 24 Pentane 72 4.949 4.949 0.000 97 40620 2.00 2.03 25 Isopropyl alcohol 45 4.955 4.963 -0.008 93 773681 5.99 6.15 26 Ethyl ether 31 5.084 5.090 -0.006 90 232288 2.00 1.99 27 1,1-Dichloroethene 96 5.364 5.367 -0.003 96 200269 2.00 1.95 28 Acrylonitrile 53 5.445 5.450 -0.005 95 101460 2.00 2.04 29 2-Methyl-2-propanol 59 5.478 5.494 -0.016 93 314466 2.00 2.08 30 1,1,2-Trichloro-1,2,2-trif 101 5.537 5.536 0.001 96 431163 2.00 1.98 31 Methylene Chloride 84 5.672 5.669 0.003 94 172766 2.00 1.81 03/21/2017Page 174 of 377 Report Date: 03-Mar-2017 15:14:02 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC06.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.688 5.684 0.004 97 209098 2.00 2.10 33 Carbon disulfide 76 5.812 5.810 0.002 100 545212 2.00 1.99 34 trans-1,2-Dichloroethene 96 6.405 6.406 -0.001 98 205008 2.00 1.96 35 2-Methylpentane 43 6.438 6.439 -0.001 93 418548 2.00 2.01 36 Methyl tert-butyl ether 73 6.524 6.533 -0.009 95 532900 2.00 1.95 37 1,1-Dichloroethane 63 6.788 6.787 0.001 100 381249 2.00 1.96 38 Vinyl acetate 43 6.896 6.898 -0.002 100 416770 2.00 2.00 39 2-Butanone (MEK) 72 7.295 7.305 -0.010 99 82283 2.00 1.87 40 Hexane 56 7.349 7.350 -0.001 86 158031 2.00 1.98 41 Isopropyl ether 45 7.494 7.502 -0.008 95 554336 2.00 1.98 42 cis-1,2-Dichloroethene 96 7.710 7.707 0.003 95 210694 2.00 1.93 43 Ethyl acetate 43 7.893 7.901 -0.008 98 337970 2.00 1.99 44 Chloroform 83 8.034 8.035 -0.001 96 511221 2.00 1.94 45 Tert-butyl ethyl ether 59 8.136 8.144 -0.008 95 518203 2.00 1.99 46 Tetrahydrofuran 42 8.395 8.410 -0.015 91 188075 2.00 1.96 47 1,1,1-Trichloroethane 97 9.015 9.013 0.002 94 572725 2.00 1.98 48 1,2-Dichloroethane 62 9.107 9.106 0.001 99 353536 2.00 2.00 49 Benzene 78 9.603 9.599 0.004 96 629128 2.00 2.01 50 Cyclohexane 69 9.603 9.604 -0.001 92 110969 2.00 2.02 52 Carbon tetrachloride 117 9.630 9.629 0.001 97 614207 2.00 2.11 51 n-Butanol 31 9.619 9.647 -0.028 69 74293 2.00 2.03 53 2,3-Dimethylpentane 71 9.754 9.754 0.000 90 151135 2.00 1.96 54 Thiophene 84 9.872 9.873 -0.001 95 356253 2.00 1.99 55 Tert-amyl methyl ether 73 10.115 10.121 -0.006 98 554414 2.00 2.12 56 Isooctane 57 10.428 10.430 -0.002 97 980383 2.00 1.99 57 n-Heptane 71 10.832 10.831 0.001 90 238440 2.00 1.99 58 1,2-Dichloropropane 63 10.865 10.862 0.003 86 233060 2.00 2.03 59 Trichloroethene 130 10.913 10.913 0.000 96 361708 2.00 2.02 60 Dibromomethane 93 10.978 10.978 0.000 94 293074 2.00 2.00 61 Dichlorobromomethane 83 11.145 11.143 0.002 98 537969 2.00 2.09 62 1,4-Dioxane 88 11.156 11.173 -0.017 92 85834 2.00 2.05 63 Methyl methacrylate 41 11.274 11.278 -0.004 94 228935 2.00 2.04 64 Methylcyclohexane 83 11.717 11.718 -0.001 96 510072 2.00 2.00 65 4-Methyl-2-pentanone (MIBK 43 12.143 12.153 -0.010 97 374418 2.00 1.99 66 cis-1,3-Dichloropropene 75 12.191 12.190 0.001 95 411086 2.00 2.04 67 trans-1,3-Dichloropropene 75 12.908 12.911 -0.003 97 406181 2.00 2.03 68 Toluene 91 13.038 13.035 0.003 94 728639 2.00 1.96 69 1,1,2-Trichloroethane 83 13.103 13.106 -0.004 99 224974 2.00 1.98 70 2-Methylthiophene 97 13.183 13.186 -0.003 97 649696 2.00 2.00 71 3-Methylthiophene 97 13.394 13.394 0.000 99 638468 2.00 1.99 72 2-Hexanone 58 13.529 13.535 -0.007 93 186539 2.00 1.98 73 n-Octane 85 13.793 13.792 0.001 91 269612 2.00 1.98 74 Chlorodibromomethane 129 13.814 13.816 -0.002 97 540498 2.00 2.15 75 Ethylene Dibromide 107 14.105 14.106 -0.001 97 462418 2.00 2.04 76 Tetrachloroethene 129 14.208 14.207 0.001 95 320386 2.00 1.96 77 Chlorobenzene 112 15.092 15.095 -0.003 93 640391 2.00 1.96 78 2,3-Dimethylheptane 43 15.162 15.165 -0.003 92 653073 2.00 1.97 79 Ethylbenzene 91 15.400 15.402 -0.002 99 961131 2.00 1.97 80 2-Ethylthiophene 97 15.502 15.502 0.000 98 782539 2.00 1.98 81 m-Xylene & p-Xylene 91 15.572 15.572 0.000 99 1513863 3.99 3.96 82 Bromoform 173 15.987 15.991 -0.004 96 509620 2.00 2.08 84 Styrene 104 16.036 16.037 -0.001 97 569507 2.00 2.10 03/21/2017Page 175 of 377 Report Date: 03-Mar-2017 15:14:02 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC06.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 83 n-Nonane 57 16.036 16.038 -0.002 88 495537 2.00 2.02 85 o-Xylene 91 16.095 16.099 -0.004 98 767665 2.00 1.96 86 1,1,2,2-Tetrachloroethane 83 16.419 16.422 -0.003 99 513576 2.00 1.99 87 1,2,3-Trichloropropane 110 16.575 16.577 -0.002 97 172113 2.00 1.96 88 Isopropylbenzene 105 16.699 16.703 -0.004 98 1097926 2.00 1.92 89 N-Propylbenzene 120 17.255 17.257 -0.002 99 302377 2.00 1.99 90 2-Chlorotoluene 126 17.287 17.288 -0.001 97 290310 2.00 1.98 91 4-Ethyltoluene 105 17.416 17.418 -0.002 98 1056133 2.00 1.96 92 1,3,5-Trimethylbenzene 120 17.503 17.502 0.001 93 499066 2.00 1.98 93 Alpha Methyl Styrene 118 17.745 17.744 0.001 88 428360 2.00 2.04 94 n-Decane 57 17.842 17.846 -0.004 93 608205 2.00 2.04 95 tert-Butylbenzene 119 17.950 17.949 0.001 93 1023334 2.00 2.00 96 1,2,4-Trimethylbenzene 105 17.961 17.963 -0.002 96 936657 2.00 2.00 97 1,3-Dichlorobenzene 146 18.231 18.232 -0.001 98 762687 2.00 2.00 98 sec-Butylbenzene 105 18.236 18.235 0.001 98 1373491 2.00 2.05 99 Benzyl chloride 91 18.312 18.311 0.001 98 885361 2.00 2.08 100 1,4-Dichlorobenzene 146 18.322 18.324 -0.002 95 747931 2.00 1.98 101 4-Isopropyltoluene 119 18.409 18.410 -0.001 97 1163365 2.00 2.00 102 1,2,3-Trimethylbenzene 105 18.452 18.454 -0.002 97 680764 2.00 1.96 103 Butylcyclohexane 83 18.527 18.527 0.000 95 810366 2.00 2.00 104 1,2-Dichlorobenzene 146 18.694 18.698 -0.004 94 708335 2.00 1.99 105 2,3-Dihydroindene 117 18.700 18.702 -0.002 94 890055 2.00 2.03 106 Indene 116 18.835 18.833 0.002 92 635278 2.00 1.98 107 n-Butylbenzene 91 18.862 18.862 0.000 98 1078971 2.00 2.00 108 Undecane 57 19.217 19.217 0.000 93 637737 2.00 1.99 109 1,2-Dimethyl-4-Ethylbenzen 119 19.244 19.247 -0.003 97 858063 2.00 2.01 110 1,2-Dibromo-3-Chloropropan 157 19.315 19.317 -0.002 98 292233 2.00 2.07 111 1,2,4,5-Tetramethylbenzene 119 19.643 19.642 0.001 96 1053727 2.00 2.03 112 1,2,3,5-Tetramethylbenzene 119 19.697 19.696 0.001 95 622820 2.00 2.01 113 1,2,3,4-Tetramethylbenzene 119 20.091 20.092 -0.001 97 862421 2.00 2.02 114 Dodecane 57 20.285 20.286 -0.001 94 576970 2.00 1.95 115 1,2,4-Trichlorobenzene 180 20.425 20.427 -0.002 94 623511 2.00 2.01 116 Naphthalene 128 20.555 20.555 0.000 99 1303379 2.00 2.02 117 Benzo(b)thiophene 134 20.652 20.653 -0.001 99 758002 2.00 2.12 118 Hexachlorobutadiene 225 20.781 20.783 -0.002 95 569346 2.00 1.88 119 1,2,3-Trichlorobenzene 180 20.830 20.831 -0.001 95 611029 2.00 2.17 120 2-Methylnaphthalene 142 21.628 21.628 0.000 100 956277 6.24 7.26 121 1-Methylnaphthalene 142 21.806 21.808 -0.002 100 788833 6.24 7.44 A 124 Toluene Range 1 13.033 (12.998-13.068) 0 1798669 2.00 2.02 A 125 C8 Range 1 13.798 (13.783-13.813) 0 3321390 2.00 2.12 M S 126 Xylenes, Total 100 0 5.99 5.91 S 127 1,2-Dichloroethene, Total 1 0 3.99 3.89 QC Flag Legend Review Flags M - Manually Integrated Reagents: 40L6DNP_00010 Amount Added: 200.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 176 of 377 Report Date: 03-Mar-2017 15:14:03 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC06.D Injection Date:02-Mar-2017 17:02:30 Instrument ID:MG Operator ID:7126 Lims ID:ICIS L6 Worklist Smp#:8 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:5 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 Y ( X10 0 0 0 0 ) GC02IC06[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 0 1 2 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 8 0 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 4 4 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 7 1 5 ) 03/21/2017Page 177 of 377 Report Date: 03-Mar-2017 15:14:03 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC06.D Injection Date:02-Mar-2017 17:02:30 Instrument ID:MG Lims ID:ICIS L6 Client ID: Operator ID:7126 ALS Bottle#:5 Worklist Smp#:8 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 124 Toluene Range, CAS: STL02011 12.9 Min 0 6 12 18 24 30 36 42 48 54 60 66 72 78 84 90 Y ( X10 0 0 0 ) GC02IC06[MS SCAN Chro]:Total 03/21/2017Page 178 of 377 Report Date: 03-Mar-2017 15:14:03 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC06.D Injection Date:02-Mar-2017 17:02:30 Instrument ID:MG Lims ID:ICIS L6 Client ID: Operator ID:7126 ALS Bottle#:5 Worklist Smp#:8 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 125 C8 Range, CAS: STL00834 13.7 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Y ( X10 0 0 0 0 ) GC02IC06[MS SCAN Chro]:Total 03/21/2017Page 179 of 377 Report Date: 03-Mar-2017 15:14:03 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Manual Integration/User Assign Peak Report TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC06.D Injection Date:02-Mar-2017 17:02:30 Instrument ID:MG Lims ID:ICIS L6 Client ID: Operator ID:7126 ALS Bottle#:5 Worklist Smp#:8 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 125 C8 Range, RT: 13.798, CAS: STL00834 Signal: 1 Processing Integration Results RT: 13.80 Response: 4159754 Amount: 2.378888 13.7 Min 0 2 4 6 8 10 12 14 16 Y ( X10 0 0 0 0 ) GC02IC06[MS SCAN Chro]:Total Manual Integration Results RT: 13.80 Response: 3321390 Amount: 2.120993 13.7 Min 0 2 4 6 8 10 12 14 16 Y ( X10 0 0 0 0 ) GC02IC06[MS SCAN Chro]:Total Reviewer: tajh, 03-Mar-2017 15:13:23 Audit Action: Manually Integrated Audit Reason: Split Peak 03/21/2017Page 180 of 377 Report Date: 03-Mar-2017 15:14:42 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC07.D Lims ID:IC L7 Client ID: Sample Type:IC Calib Level:7 Inject. Date:02-Mar-2017 17:44:30 ALS Bottle#:6 Worklist Smp#:9 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004202-009 Misc. Info.:073141 Operator ID:7126 Instrument ID:MG Sublist:chrom-MG_TO15*sub5 Method:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:03-Mar-2017 15:14:40 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK031 First Level Reviewer: tajh Date:03-Mar-2017 13:03:30 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.018 8.012 0.006 88 432870 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.185 10.179 0.006 94 2161798 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.049 15.046 0.003 88 2132071 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.721 16.717 0.004 93 1596553 4.00 4.02 6 Chlorodifluoromethane 67 3.466 3.463 0.003 97 149012 4.00 3.52 7 Propene 41 3.472 3.471 0.001 98 363824 4.00 3.61 8 Dichlorodifluoromethane 85 3.515 3.514 0.001 100 1443467 4.00 3.76 9 Chloromethane 52 3.666 3.665 0.001 98 118748 4.00 3.83 10 1,2-Dichloro-1,1,2,2-tetra 135 3.677 3.675 0.002 93 859118 4.00 3.66 11 Acetaldehyde 44 3.795 3.793 0.002 89 818363 20.0 17.7 12 Vinyl chloride 62 3.812 3.809 0.003 99 463110 4.00 3.90 13 Butadiene 54 3.887 3.883 0.004 66 334116 4.00 3.90 14 Butane 43 3.887 3.885 0.002 86 696236 4.00 3.87 15 Bromomethane 94 4.151 4.149 0.002 98 458263 4.00 3.80 16 Chloroethane 64 4.270 4.267 0.003 91 242874 4.00 3.82 17 Ethanol 31 4.378 4.372 0.006 97 900932 20.0 18.9 18 Vinyl bromide 106 4.523 4.522 0.001 97 415451 4.00 3.63 19 2-Methylbutane 43 4.572 4.569 0.003 91 518587 4.00 3.79 20 Acrolein 56 4.750 4.732 0.018 29 67683 4.00 3.81 21 Trichlorofluoromethane 101 4.755 4.753 0.002 99 1437541 4.00 3.65 22 Acetonitrile 40 4.804 4.808 -0.004 99 159557 4.00 3.67 23 Acetone 58 4.847 4.849 -0.002 99 500469 12.0 10.8 24 Pentane 72 4.949 4.949 0.000 96 82609 4.00 3.78 25 Isopropyl alcohol 45 4.971 4.963 0.008 94 1516171 12.0 11.1 26 Ethyl ether 31 5.084 5.090 -0.006 90 488155 4.00 3.84 27 1,1-Dichloroethene 96 5.370 5.367 0.003 97 405837 4.00 3.62 28 Acrylonitrile 53 5.451 5.450 0.001 96 218964 4.00 4.04 29 2-Methyl-2-propanol 59 5.494 5.494 0.000 96 640651 4.00 3.88 30 1,1,2-Trichloro-1,2,2-trif 101 5.537 5.536 0.001 96 890153 4.00 3.75 31 Methylene Chloride 84 5.672 5.669 0.003 93 351168 4.00 3.37 03/21/2017Page 181 of 377 Report Date: 03-Mar-2017 15:14:42 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC07.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.688 5.684 0.004 97 419643 4.00 3.86 33 Carbon disulfide 76 5.812 5.810 0.002 100 1120712 4.00 3.75 34 trans-1,2-Dichloroethene 96 6.411 6.406 0.005 98 433627 4.00 3.80 35 2-Methylpentane 43 6.443 6.439 0.004 93 868758 4.00 3.83 36 Methyl tert-butyl ether 73 6.524 6.533 -0.009 96 1150545 4.00 3.87 37 1,1-Dichloroethane 63 6.788 6.787 0.001 100 798627 4.00 3.77 38 Vinyl acetate 43 6.901 6.898 0.003 100 922344 4.00 4.06 39 2-Butanone (MEK) 72 7.300 7.305 -0.005 99 178044 4.00 3.71 40 Hexane 56 7.354 7.350 0.004 85 325047 4.00 3.73 41 Isopropyl ether 45 7.500 7.502 -0.002 94 1200569 4.00 3.93 42 cis-1,2-Dichloroethene 96 7.710 7.707 0.003 95 450081 4.00 3.77 43 Ethyl acetate 43 7.899 7.901 -0.002 98 749629 4.00 4.04 44 Chloroform 83 8.045 8.035 0.010 96 1073295 4.00 3.74 45 Tert-butyl ethyl ether 59 8.136 8.144 -0.008 95 1129672 4.00 3.97 46 Tetrahydrofuran 42 8.400 8.410 -0.010 91 394414 4.00 3.77 47 1,1,1-Trichloroethane 97 9.015 9.013 0.002 95 1200734 4.00 3.81 48 1,2-Dichloroethane 62 9.112 9.106 0.006 99 743733 4.00 3.88 49 Benzene 78 9.603 9.599 0.004 96 1362801 4.00 4.02 50 Cyclohexane 69 9.603 9.604 -0.001 92 240083 4.00 4.03 52 Carbon tetrachloride 117 9.635 9.629 0.006 98 1304352 4.00 4.13 51 n-Butanol 31 9.630 9.647 -0.017 75 162687 4.00 4.11 53 2,3-Dimethylpentane 71 9.759 9.754 0.005 90 317495 4.00 3.80 54 Thiophene 84 9.878 9.873 0.005 95 758324 4.00 3.91 55 Tert-amyl methyl ether 73 10.115 10.121 -0.006 98 1188591 4.00 4.19 56 Isooctane 57 10.433 10.430 0.003 97 2065349 4.00 3.87 57 n-Heptane 71 10.832 10.831 0.001 91 509798 4.00 3.92 58 1,2-Dichloropropane 63 10.865 10.862 0.003 85 493172 4.00 3.96 59 Trichloroethene 130 10.919 10.913 0.006 96 770017 4.00 3.96 60 Dibromomethane 93 10.983 10.978 0.005 94 630013 4.00 3.97 61 Dichlorobromomethane 83 11.145 11.143 0.002 98 1169408 4.00 4.20 62 1,4-Dioxane 88 11.167 11.173 -0.006 91 187768 4.00 4.15 63 Methyl methacrylate 41 11.280 11.278 0.002 94 509515 4.00 4.20 64 Methylcyclohexane 83 11.717 11.718 -0.001 95 1092146 4.00 3.96 65 4-Methyl-2-pentanone (MIBK 43 12.148 12.153 -0.005 97 802345 4.00 3.94 66 cis-1,3-Dichloropropene 75 12.191 12.190 0.001 95 874614 4.00 4.02 67 trans-1,3-Dichloropropene 75 12.914 12.911 0.003 98 860494 4.00 4.12 68 Toluene 91 13.038 13.035 0.003 94 1584870 4.00 4.10 69 1,1,2-Trichloroethane 83 13.108 13.106 0.002 99 487400 4.00 4.13 70 2-Methylthiophene 97 13.189 13.186 0.003 97 1403012 4.00 4.16 71 3-Methylthiophene 97 13.394 13.394 0.000 99 1383056 4.00 4.14 72 2-Hexanone 58 13.529 13.535 -0.006 94 399503 4.00 4.07 73 n-Octane 85 13.793 13.792 0.001 92 581291 4.00 4.09 74 Chlorodibromomethane 129 13.820 13.816 0.004 97 1197096 4.00 4.58 75 Ethylene Dibromide 107 14.111 14.106 0.005 98 1009922 4.00 4.28 76 Tetrachloroethene 129 14.208 14.207 0.001 95 677805 4.00 3.97 77 Chlorobenzene 112 15.098 15.095 0.003 93 1396401 4.00 4.11 78 2,3-Dimethylheptane 43 15.168 15.165 0.003 93 1432853 4.00 4.14 79 Ethylbenzene 91 15.405 15.402 0.003 98 2123060 4.00 4.18 80 2-Ethylthiophene 97 15.508 15.502 0.006 98 1723412 4.00 4.19 81 m-Xylene & p-Xylene 91 15.572 15.572 0.000 99 3318439 8.00 8.33 82 Bromoform 173 15.993 15.991 0.002 96 1199597 4.00 4.71 84 Styrene 104 16.041 16.037 0.004 98 1210797 4.00 4.29 03/21/2017Page 182 of 377 Report Date: 03-Mar-2017 15:14:42 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC07.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 83 n-Nonane 57 16.041 16.038 0.003 88 1007618 4.00 3.94 85 o-Xylene 91 16.101 16.099 0.002 98 1687122 4.00 4.13 86 1,1,2,2-Tetrachloroethane 83 16.424 16.422 0.002 99 1155005 4.00 4.31 87 1,2,3-Trichloropropane 110 16.581 16.577 0.004 97 377370 4.00 4.12 88 Isopropylbenzene 105 16.705 16.703 0.002 97 2338552 4.00 3.94 89 N-Propylbenzene 120 17.260 17.257 0.003 99 687647 4.00 4.34 90 2-Chlorotoluene 126 17.292 17.288 0.004 97 652552 4.00 4.27 91 4-Ethyltoluene 105 17.422 17.418 0.004 98 2382649 4.00 4.25 92 1,3,5-Trimethylbenzene 120 17.503 17.502 0.001 93 1132222 4.00 4.32 93 Alpha Methyl Styrene 118 17.745 17.744 0.001 88 1000574 4.00 4.57 94 n-Decane 57 17.848 17.846 0.002 93 1310271 4.00 4.21 95 tert-Butylbenzene 119 17.950 17.949 0.001 92 2201186 4.00 4.14 96 1,2,4-Trimethylbenzene 105 17.966 17.963 0.003 95 2013472 4.00 4.14 97 1,3-Dichlorobenzene 146 18.236 18.232 0.004 98 1630912 4.00 4.10 98 sec-Butylbenzene 105 18.236 18.235 0.001 97 2899550 4.00 4.15 99 Benzyl chloride 91 18.312 18.311 0.001 98 1947940 4.00 4.40 100 1,4-Dichlorobenzene 146 18.328 18.324 0.004 95 1595871 4.00 4.05 101 4-Isopropyltoluene 119 18.414 18.410 0.004 97 2559983 4.00 4.23 102 1,2,3-Trimethylbenzene 105 18.457 18.454 0.003 97 1538574 4.00 4.25 103 Butylcyclohexane 83 18.527 18.527 0.000 94 1695670 4.00 4.02 104 1,2-Dichlorobenzene 146 18.700 18.698 0.002 94 1504756 4.00 4.06 105 2,3-Dihydroindene 117 18.705 18.702 0.003 94 1895000 4.00 4.15 106 Indene 116 18.835 18.833 0.002 92 1463201 4.00 4.39 107 n-Butylbenzene 91 18.862 18.862 0.000 98 2354005 4.00 4.20 108 Undecane 57 19.218 19.217 0.001 94 1399535 4.00 4.19 109 1,2-Dimethyl-4-Ethylbenzen 119 19.250 19.247 0.003 97 1946396 4.00 4.39 110 1,2-Dibromo-3-Chloropropan 157 19.320 19.317 0.003 99 680296 4.00 4.62 111 1,2,4,5-Tetramethylbenzene 119 19.644 19.642 0.002 97 2352685 4.00 4.36 112 1,2,3,5-Tetramethylbenzene 119 19.697 19.696 0.001 95 1378186 4.00 4.27 113 1,2,3,4-Tetramethylbenzene 119 20.091 20.092 -0.001 97 1933165 4.00 4.36 114 Dodecane 57 20.285 20.286 -0.001 94 1237066 4.00 4.02 115 1,2,4-Trichlorobenzene 180 20.425 20.427 -0.002 94 1366584 4.00 4.24 116 Naphthalene 128 20.555 20.555 0.000 99 2895014 4.00 4.31 117 Benzo(b)thiophene 134 20.652 20.653 -0.001 99 1681098 4.00 4.51 118 Hexachlorobutadiene 225 20.781 20.783 -0.002 96 1269541 4.00 4.03 119 1,2,3-Trichlorobenzene 180 20.830 20.831 -0.001 95 1233859 4.00 4.21 120 2-Methylnaphthalene 142 21.628 21.628 0.000 100 1788441 12.5 13.0 121 1-Methylnaphthalene 142 21.811 21.808 0.003 100 1389272 12.5 12.6 A 124 Toluene Range 1 13.033 (12.998-13.068) 0 3880684 4.00 4.02 A 125 C8 Range 1 13.798 (13.783-13.813) 0 5856098 4.00 3.45 M S 126 Xylenes, Total 100 0 12.0 12.5 S 127 1,2-Dichloroethene, Total 1 0 8.00 7.58 QC Flag Legend Review Flags M - Manually Integrated Reagents: 40L7DNP_00009 Amount Added: 200.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 183 of 377 Report Date: 03-Mar-2017 15:14:42 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC07.D Injection Date:02-Mar-2017 17:44:30 Instrument ID:MG Operator ID:7126 Lims ID:IC L7 Worklist Smp#:9 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:6 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 42 45 48 51 54 57 60 63 66 69 72 75 78 81 84 Y ( X10 0 0 0 0 ) GC02IC07[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 0 2 3 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 8 5 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 4 9 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 7 1 5 ) 03/21/2017Page 184 of 377 Report Date: 03-Mar-2017 15:14:42 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC07.D Injection Date:02-Mar-2017 17:44:30 Instrument ID:MG Lims ID:IC L7 Client ID: Operator ID:7126 ALS Bottle#:6 Worklist Smp#:9 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 124 Toluene Range, CAS: STL02011 12.9 Min 0 2 4 6 8 10 12 14 16 18 20 Y ( X10 0 0 0 0 ) GC02IC07[MS SCAN Chro]:Total 03/21/2017Page 185 of 377 Report Date: 03-Mar-2017 15:14:42 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC07.D Injection Date:02-Mar-2017 17:44:30 Instrument ID:MG Lims ID:IC L7 Client ID: Operator ID:7126 ALS Bottle#:6 Worklist Smp#:9 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 125 C8 Range, CAS: STL00834 13.7 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 Y ( X10 0 0 0 0 ) GC02IC07[MS SCAN Chro]:Total 03/21/2017Page 186 of 377 Report Date: 03-Mar-2017 15:14:42 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Manual Integration/User Assign Peak Report TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC07.D Injection Date:02-Mar-2017 17:44:30 Instrument ID:MG Lims ID:IC L7 Client ID: Operator ID:7126 ALS Bottle#:6 Worklist Smp#:9 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 125 C8 Range, RT: 13.798, CAS: STL00834 Signal: 1 Processing Integration Results RT: 13.80 Response: 9090782 Amount: 4.479872 13.7 Min 0 3 6 9 12 15 18 21 24 27 30 Y ( X10 0 0 0 0 ) GC02IC07[MS SCAN Chro]:Total Manual Integration Results RT: 13.80 Response: 5856098 Amount: 3.451702 13.7 Min 0 3 6 9 12 15 18 21 24 27 30 Y ( X10 0 0 0 0 ) GC02IC07[MS SCAN Chro]:Total Reviewer: tajh, 03-Mar-2017 15:14:06 Audit Action: Manually Integrated Audit Reason: Split Peak 03/21/2017Page 187 of 377 Report Date: 03-Mar-2017 15:15:38 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC08.D Lims ID:IC L8 Client ID: Sample Type:IC Calib Level:8 Inject. Date:02-Mar-2017 18:26:30 ALS Bottle#:7 Worklist Smp#:10 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004202-010 Misc. Info.:073140 Operator ID:7126 Instrument ID:MG Sublist:chrom-MG_TO15*sub5 Method:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:03-Mar-2017 15:15:35 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK031 First Level Reviewer: barlozhetskayaa Date:03-Mar-2017 10:10:18 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.018 8.012 0.006 89 421342 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.185 10.179 0.006 94 2107145 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.049 15.046 0.003 88 2058729 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.721 16.717 0.004 96 1489493 4.00 3.89 6 Chlorodifluoromethane 67 3.456 3.463 -0.007 97 306956 8.00 7.45 7 Propene 41 3.466 3.471 -0.005 98 745153 8.00 7.59 8 Dichlorodifluoromethane 85 3.510 3.514 -0.004 100 2986792 8.00 7.99 9 Chloromethane 52 3.661 3.665 -0.004 98 225417 8.00 7.47 10 1,2-Dichloro-1,1,2,2-tetra 135 3.671 3.675 -0.004 91 1743498 8.00 7.64 11 Acetaldehyde 44 3.790 3.793 -0.003 92 1401677 40.0 31.2 12 Vinyl chloride 62 3.806 3.809 -0.003 99 878033 8.00 7.60 13 Butadiene 54 3.876 3.883 -0.007 69 634250 8.00 7.60 14 Butane 43 3.882 3.885 -0.003 86 1317188 8.00 7.53 15 Bromomethane 94 4.146 4.149 -0.003 98 868899 8.00 7.41 16 Chloroethane 64 4.265 4.267 -0.002 91 464117 8.00 7.51 17 Ethanol 31 4.378 4.372 0.006 96 1777636 40.0 38.4 18 Vinyl bromide 106 4.518 4.522 -0.004 97 820833 8.00 7.36 19 2-Methylbutane 43 4.567 4.569 -0.002 91 990458 8.00 7.43 20 Acrolein 56 4.744 4.732 0.012 97 104747 8.00 6.06 21 Trichlorofluoromethane 101 4.750 4.753 -0.003 99 2874535 8.00 7.50 22 Acetonitrile 40 4.804 4.808 -0.004 98 309526 8.00 7.31 23 Acetone 58 4.842 4.849 -0.007 99 909490 24.0 20.2 24 Pentane 72 4.944 4.949 -0.005 98 162991 8.00 7.66 25 Isopropyl alcohol 45 4.971 4.963 0.008 96 2917385 24.0 21.8 26 Ethyl ether 31 5.079 5.090 -0.011 91 895503 8.00 7.25 27 1,1-Dichloroethene 96 5.365 5.367 -0.002 97 830595 8.00 7.61 28 Acrylonitrile 53 5.451 5.450 0.001 96 420450 8.00 7.97 29 2-Methyl-2-propanol 59 5.494 5.494 0.000 96 1273967 8.00 7.93 30 1,1,2-Trichloro-1,2,2-trif 101 5.532 5.536 -0.004 95 1809809 8.00 7.83 31 Methylene Chloride 84 5.672 5.669 0.003 91 684793 8.00 6.75 03/21/2017Page 188 of 377 Report Date: 03-Mar-2017 15:15:38 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC08.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.683 5.684 -0.001 96 807303 8.00 7.63 33 Carbon disulfide 76 5.807 5.810 -0.003 100 2281669 8.00 7.85 34 trans-1,2-Dichloroethene 96 6.405 6.406 -0.001 98 909558 8.00 8.20 35 2-Methylpentane 43 6.438 6.439 -0.001 94 1860362 8.00 8.43 36 Methyl tert-butyl ether 73 6.519 6.533 -0.014 96 2358248 8.00 8.15 37 1,1-Dichloroethane 63 6.788 6.787 0.001 100 1614530 8.00 7.82 38 Vinyl acetate 43 6.896 6.898 -0.002 99 1832225 8.00 8.28 39 2-Butanone (MEK) 72 7.300 7.305 -0.005 99 356743 8.00 7.65 40 Hexane 56 7.349 7.350 -0.001 86 667134 8.00 7.87 41 Isopropyl ether 45 7.495 7.502 -0.007 94 2473083 8.00 8.32 42 cis-1,2-Dichloroethene 96 7.710 7.707 0.003 94 928515 8.00 8.00 43 Ethyl acetate 43 7.894 7.901 -0.007 98 1524276 8.00 8.45 44 Chloroform 83 8.039 8.035 0.004 96 2194591 8.00 7.86 45 Tert-butyl ethyl ether 59 8.136 8.144 -0.008 95 2339030 8.00 8.45 46 Tetrahydrofuran 42 8.395 8.410 -0.015 90 821113 8.00 8.06 47 1,1,1-Trichloroethane 97 9.015 9.013 0.002 95 2452233 8.00 7.98 48 1,2-Dichloroethane 62 9.112 9.106 0.006 99 1507864 8.00 8.07 49 Benzene 78 9.603 9.599 0.004 96 2593773 8.00 7.86 50 Cyclohexane 69 9.608 9.604 0.004 92 451811 8.00 7.77 52 Carbon tetrachloride 117 9.630 9.629 0.001 99 2621123 8.00 8.52 51 n-Butanol 31 9.630 9.647 -0.017 69 345495 8.00 8.96 53 2,3-Dimethylpentane 71 9.754 9.754 0.000 91 655602 8.00 8.04 54 Thiophene 84 9.878 9.873 0.005 94 1556761 8.00 8.23 55 Tert-amyl methyl ether 73 10.115 10.121 -0.006 98 2461073 8.00 8.90 56 Isooctane 57 10.433 10.430 0.003 97 4258623 8.00 8.19 57 n-Heptane 71 10.832 10.831 0.001 91 1009968 8.00 7.97 58 1,2-Dichloropropane 63 10.870 10.862 0.008 85 1006262 8.00 8.29 59 Trichloroethene 130 10.919 10.913 0.006 96 1508689 8.00 7.97 60 Dibromomethane 93 10.983 10.978 0.005 93 1253711 8.00 8.10 61 Dichlorobromomethane 83 11.151 11.143 0.008 98 2353711 8.00 8.68 62 1,4-Dioxane 88 11.167 11.173 -0.006 92 370975 8.00 8.41 63 Methyl methacrylate 41 11.280 11.278 0.002 93 1074957 8.00 9.08 64 Methylcyclohexane 83 11.722 11.718 0.004 96 2120127 8.00 7.89 65 4-Methyl-2-pentanone (MIBK 43 12.148 12.153 -0.005 97 1721840 8.00 8.68 66 cis-1,3-Dichloropropene 75 12.197 12.190 0.007 96 1789747 8.00 8.43 67 trans-1,3-Dichloropropene 75 12.919 12.911 0.008 98 1762176 8.00 8.74 68 Toluene 91 13.038 13.035 0.003 94 3140955 8.00 8.41 69 1,1,2-Trichloroethane 83 13.113 13.106 0.007 99 958533 8.00 8.41 70 2-Methylthiophene 97 13.194 13.186 0.008 97 2777537 8.00 8.52 71 3-Methylthiophene 97 13.399 13.394 0.005 99 2774725 8.00 8.59 72 2-Hexanone 58 13.534 13.535 -0.001 93 859377 8.00 9.07 73 n-Octane 85 13.793 13.792 0.001 90 1101196 8.00 8.03 74 Chlorodibromomethane 129 13.820 13.816 0.004 97 2424106 8.00 9.61 75 Ethylene Dibromide 107 14.111 14.106 0.005 98 1979331 8.00 8.69 76 Tetrachloroethene 129 14.213 14.207 0.006 95 1376890 8.00 8.36 77 Chlorobenzene 112 15.098 15.095 0.003 93 2748594 8.00 8.38 78 2,3-Dimethylheptane 43 15.168 15.165 0.003 92 2703240 8.00 8.10 79 Ethylbenzene 91 15.405 15.402 0.003 99 4204604 8.00 8.57 80 2-Ethylthiophene 97 15.508 15.502 0.006 98 3385428 8.00 8.53 81 m-Xylene & p-Xylene 91 15.578 15.572 0.006 99 6505497 16.0 16.9 82 Bromoform 173 15.998 15.991 0.007 97 2529774 8.00 10.3 84 Styrene 104 16.041 16.037 0.004 97 2456959 8.00 9.01 03/21/2017Page 189 of 377 Report Date: 03-Mar-2017 15:15:38 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC08.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 83 n-Nonane 57 16.041 16.038 0.003 88 1833592 8.00 7.43 85 o-Xylene 91 16.106 16.099 0.007 98 3344040 8.00 8.48 86 1,1,2,2-Tetrachloroethane 83 16.430 16.422 0.008 99 2273528 8.00 8.78 87 1,2,3-Trichloropropane 110 16.586 16.577 0.009 97 755995 8.00 8.55 88 Isopropylbenzene 105 16.705 16.703 0.002 96 4678588 8.00 8.15 89 N-Propylbenzene 120 17.260 17.257 0.003 99 1323708 8.00 8.66 90 2-Chlorotoluene 126 17.293 17.288 0.004 97 1240764 8.00 8.40 91 4-Ethyltoluene 105 17.422 17.418 0.004 98 4703566 8.00 8.68 92 1,3,5-Trimethylbenzene 120 17.508 17.502 0.006 93 2230504 8.00 8.81 93 Alpha Methyl Styrene 118 17.751 17.744 0.007 88 2035483 8.00 9.63 94 n-Decane 57 17.853 17.846 0.007 93 2338575 8.00 7.78 95 tert-Butylbenzene 119 17.956 17.949 0.007 93 4544874 8.00 8.84 96 1,2,4-Trimethylbenzene 105 17.972 17.963 0.009 95 4100916 8.00 8.73 97 1,3-Dichlorobenzene 146 18.236 18.232 0.004 97 3530077 8.00 9.19 98 sec-Butylbenzene 105 18.242 18.235 0.007 98 6055449 8.00 8.98 99 Benzyl chloride 91 18.317 18.311 0.006 98 3665923 8.00 8.58 100 1,4-Dichlorobenzene 146 18.328 18.324 0.004 96 3344089 8.00 8.79 101 4-Isopropyltoluene 119 18.414 18.410 0.004 97 5192056 8.00 8.88 102 1,2,3-Trimethylbenzene 105 18.457 18.454 0.003 98 3069806 8.00 8.78 103 Butylcyclohexane 83 18.533 18.527 0.006 96 3232242 8.00 7.94 104 1,2-Dichlorobenzene 146 18.705 18.698 0.007 96 3267696 8.00 9.14 105 2,3-Dihydroindene 117 18.705 18.702 0.003 94 4009906 8.00 9.10 106 Indene 116 18.840 18.833 0.007 92 2908946 8.00 9.04 107 n-Butylbenzene 91 18.867 18.862 0.005 97 4576198 8.00 8.45 108 Undecane 57 19.218 19.217 0.001 92 2564058 8.00 7.95 109 1,2-Dimethyl-4-Ethylbenzen 119 19.250 19.247 0.003 97 3772393 8.00 8.81 110 1,2-Dibromo-3-Chloropropan 157 19.320 19.317 0.003 99 1346687 8.00 9.48 111 1,2,4,5-Tetramethylbenzene 119 19.644 19.642 0.002 97 4753691 8.00 9.12 112 1,2,3,5-Tetramethylbenzene 119 19.698 19.696 0.002 95 2770005 8.00 8.90 113 1,2,3,4-Tetramethylbenzene 119 20.091 20.092 -0.001 97 3830160 8.00 8.94 114 Dodecane 57 20.291 20.286 0.005 93 2397668 8.00 8.06 115 1,2,4-Trichlorobenzene 180 20.431 20.427 0.004 94 3009702 8.00 9.67 116 Naphthalene 128 20.555 20.555 0.000 99 5657107 8.00 8.71 117 Benzo(b)thiophene 134 20.657 20.653 0.004 99 3295063 8.00 9.15 118 Hexachlorobutadiene 225 20.787 20.783 0.004 96 2891958 8.00 9.52 119 1,2,3-Trichlorobenzene 180 20.835 20.831 0.004 96 2706266 8.00 9.57 120 2-Methylnaphthalene 142 21.628 21.628 0.000 100 3629803 25.0 27.4 121 1-Methylnaphthalene 142 21.811 21.808 0.003 100 2696789 25.0 25.3 A 124 Toluene Range 1 13.033 (12.998-13.068) 0 7812063 8.00 8.30 A 125 C8 Range 1 13.798 (13.783-13.813) 0 11734517 8.00 7.10 M S 126 Xylenes, Total 100 0 24.0 25.4 S 127 1,2-Dichloroethene, Total 1 0 16.0 16.2 QC Flag Legend Review Flags M - Manually Integrated Reagents: 40L8DNP_00009 Amount Added: 200.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 190 of 377 Report Date: 03-Mar-2017 15:15:38 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC08.D Injection Date:02-Mar-2017 18:26:30 Instrument ID:MG Operator ID:7126 Lims ID:IC L8 Worklist Smp#:10 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:7 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Y ( X10 0 0 0 0 0 ) GC02IC08[MS SCAN Chro]:Total * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 8 5 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 4 9) 03/21/2017Page 191 of 377 Report Date: 03-Mar-2017 15:15:38 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC08.D Injection Date:02-Mar-2017 18:26:30 Instrument ID:MG Lims ID:IC L8 Client ID: Operator ID:7126 ALS Bottle#:7 Worklist Smp#:10 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 124 Toluene Range, CAS: STL02011 12.9 Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 Y ( X10 0 0 0 0 ) GC02IC08[MS SCAN Chro]:Total 03/21/2017Page 192 of 377 Report Date: 03-Mar-2017 15:15:38 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC08.D Injection Date:02-Mar-2017 18:26:30 Instrument ID:MG Lims ID:IC L8 Client ID: Operator ID:7126 ALS Bottle#:7 Worklist Smp#:10 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 125 C8 Range, CAS: STL00834 13.7 Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 42 45 48 51 54 Y ( X10 0 0 0 0 ) GC02IC08[MS SCAN Chro]:Total 03/21/2017Page 193 of 377 Report Date: 03-Mar-2017 15:15:38 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Manual Integration/User Assign Peak Report TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC08.D Injection Date:02-Mar-2017 18:26:30 Instrument ID:MG Lims ID:IC L8 Client ID: Operator ID:7126 ALS Bottle#:7 Worklist Smp#:10 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 125 C8 Range, RT: 13.798, CAS: STL00834 Signal: 1 Processing Integration Results RT: 13.80 Response: 17447001 Amount: 9.842043 13.7 Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 Y ( X10 0 0 0 0 ) GC02IC08[MS SCAN Chro]:Total Manual Integration Results RT: 13.80 Response: 11734517 Amount: 7.095955 13.7 Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 Y ( X10 0 0 0 0 ) GC02IC08[MS SCAN Chro]:Total Reviewer: tajh, 03-Mar-2017 15:14:44 Audit Action: Manually Integrated Audit Reason: Split Peak 03/21/2017Page 194 of 377 Report Date: 03-Mar-2017 15:04:24 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC09.D Lims ID:IC L9 Client ID: Sample Type:IC Calib Level:9 Inject. Date:02-Mar-2017 19:08:30 ALS Bottle#:8 Worklist Smp#:11 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004202-011 Misc. Info.:073138 Operator ID:7126 Instrument ID:MG Sublist:chrom-MG_TO15*sub5 Method:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:03-Mar-2017 15:04:23 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK031 First Level Reviewer: tajh Date:03-Mar-2017 13:09:35 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.023 8.012 0.011 93 448428 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.196 10.179 0.017 95 2223552 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.060 15.046 0.014 88 2163779 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.726 16.717 0.009 96 1636640 4.00 4.06 6 Chlorodifluoromethane 67 3.461 3.463 -0.002 97 593423 16.0 13.5 7 Propene 41 3.467 3.471 -0.004 98 1481915 16.0 14.2 8 Dichlorodifluoromethane 85 3.510 3.514 -0.004 100 5705597 16.0 14.3 9 Chloromethane 52 3.661 3.665 -0.004 97 404153 16.0 12.6 10 1,2-Dichloro-1,1,2,2-tetra 135 3.671 3.675 -0.004 90 3524679 16.0 14.5 11 Acetaldehyde 44 3.790 3.793 -0.003 90 2490767 80.0 52.0 12 Vinyl chloride 62 3.806 3.809 -0.003 99 1567179 16.0 12.7 13 Butadiene 54 3.882 3.883 -0.001 68 1122777 16.0 12.6 14 Butane 43 3.882 3.885 -0.003 85 2265735 16.0 12.2 15 Bromomethane 94 4.146 4.149 -0.003 98 1656810 16.0 13.3 16 Chloroethane 64 4.270 4.267 0.003 91 869966 16.0 13.2 17 Ethanol 31 4.394 4.372 0.022 96 3392647 80.0 68.8 18 Vinyl bromide 106 4.523 4.522 0.001 97 1604482 16.0 13.5 19 2-Methylbutane 43 4.567 4.569 -0.002 90 1813405 16.0 12.8 20 Acrolein 56 4.750 4.732 0.018 98 297063 16.0 16.2 21 Trichlorofluoromethane 101 4.755 4.753 0.002 99 5842137 16.0 14.3 22 Acetonitrile 40 4.815 4.808 0.007 98 617927 16.0 13.7 23 Acetone 58 4.847 4.849 -0.002 99 1722579 48.0 35.9 24 Pentane 72 4.949 4.949 0.000 98 321694 16.0 14.2 25 Isopropyl alcohol 45 5.009 4.963 0.046 97 5697995 48.0 40.1 26 Ethyl ether 31 5.079 5.090 -0.011 93 1831153 16.0 13.9 27 1,1-Dichloroethene 96 5.370 5.367 0.003 98 1677086 16.0 14.4 28 Acrylonitrile 53 5.462 5.450 0.012 96 846465 16.0 15.1 29 2-Methyl-2-propanol 59 5.537 5.494 0.043 56 2458156 16.0 14.4 30 1,1,2-Trichloro-1,2,2-trif 101 5.537 5.536 0.001 92 3768634 16.0 15.3 31 Methylene Chloride 84 5.677 5.669 0.008 89 1363735 16.0 12.6 03/21/2017Page 195 of 377 Report Date: 03-Mar-2017 15:04:24 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC09.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.694 5.684 0.010 98 1507366 16.0 13.4 33 Carbon disulfide 76 5.812 5.810 0.002 100 4478149 16.0 14.5 34 trans-1,2-Dichloroethene 96 6.416 6.406 0.010 98 1782185 16.0 15.1 35 2-Methylpentane 43 6.443 6.439 0.004 95 3465926 16.0 14.8 36 Methyl tert-butyl ether 73 6.524 6.533 -0.009 96 5069342 16.0 16.5 37 1,1-Dichloroethane 63 6.799 6.787 0.012 100 3399866 16.0 15.5 38 Vinyl acetate 43 6.907 6.898 0.009 100 4239860 16.0 18.0 39 2-Butanone (MEK) 72 7.311 7.305 0.006 99 764742 16.0 15.4 40 Hexane 56 7.354 7.350 0.004 90 1303527 16.0 14.4 41 Isopropyl ether 45 7.505 7.502 0.003 95 5292599 16.0 16.7 42 cis-1,2-Dichloroethene 96 7.721 7.707 0.014 96 1891071 16.0 15.3 43 Ethyl acetate 43 7.910 7.901 0.009 98 3378757 16.0 17.6 44 Chloroform 83 8.055 8.035 0.020 97 4371168 16.0 14.7 45 Tert-butyl ethyl ether 59 8.147 8.144 0.003 95 4983675 16.0 16.9 46 Tetrahydrofuran 42 8.406 8.410 -0.004 90 1695370 16.0 15.6 47 1,1,1-Trichloroethane 97 9.026 9.013 0.013 92 5004599 16.0 15.3 48 1,2-Dichloroethane 62 9.123 9.106 0.017 99 3179877 16.0 16.1 49 Benzene 78 9.614 9.599 0.015 95 5155161 16.0 14.8 50 Cyclohexane 69 9.614 9.604 0.010 73 860520 16.0 14.0 52 Carbon tetrachloride 117 9.641 9.629 0.012 98 5537304 16.0 17.0 51 n-Butanol 31 9.662 9.647 0.015 81 676762 16.0 16.6 53 2,3-Dimethylpentane 71 9.765 9.754 0.011 90 1254475 16.0 14.6 54 Thiophene 84 9.889 9.873 0.016 95 3127741 16.0 15.7 55 Tert-amyl methyl ether 73 10.126 10.121 0.005 98 5035512 16.0 17.2 56 Isooctane 57 10.439 10.430 0.009 97 8044250 16.0 14.7 57 n-Heptane 71 10.843 10.831 0.012 89 1955729 16.0 14.6 58 1,2-Dichloropropane 63 10.876 10.862 0.014 85 1909170 16.0 14.9 59 Trichloroethene 130 10.930 10.913 0.017 98 3097983 16.0 15.5 60 Dibromomethane 93 10.994 10.978 0.016 90 2591765 16.0 15.9 61 Dichlorobromomethane 83 11.161 11.143 0.018 98 4782156 16.0 16.7 62 1,4-Dioxane 88 11.183 11.173 0.010 92 729179 16.0 15.7 63 Methyl methacrylate 41 11.291 11.278 0.013 92 2304384 16.0 18.4 64 Methylcyclohexane 83 11.728 11.718 0.010 94 4223787 16.0 14.9 65 4-Methyl-2-pentanone (MIBK 43 12.164 12.153 0.011 97 3436700 16.0 16.4 66 cis-1,3-Dichloropropene 75 12.202 12.190 0.012 94 3537072 16.0 15.8 67 trans-1,3-Dichloropropene 75 12.925 12.911 0.014 98 3639858 16.0 17.2 68 Toluene 91 13.049 13.035 0.014 94 6495080 16.0 16.5 69 1,1,2-Trichloroethane 83 13.124 13.106 0.018 99 1966781 16.0 16.4 70 2-Methylthiophene 97 13.200 13.186 0.014 97 5668799 16.0 16.5 71 3-Methylthiophene 97 13.410 13.394 0.016 99 5585386 16.0 16.5 72 2-Hexanone 58 13.545 13.535 0.010 93 1721121 16.0 17.3 73 n-Octane 85 13.798 13.792 0.006 87 2237695 16.0 15.5 74 Chlorodibromomethane 129 13.831 13.816 0.015 97 5402658 16.0 20.4 75 Ethylene Dibromide 107 14.122 14.106 0.016 98 4206014 16.0 17.6 76 Tetrachloroethene 129 14.219 14.207 0.012 96 3082194 16.0 17.8 77 Chlorobenzene 112 15.109 15.095 0.014 95 5819873 16.0 16.9 78 2,3-Dimethylheptane 43 15.173 15.165 0.008 87 4902679 16.0 14.0 79 Ethylbenzene 91 15.416 15.402 0.014 98 8872329 16.0 17.2 80 2-Ethylthiophene 97 15.513 15.502 0.011 97 7168291 16.0 17.2 81 m-Xylene & p-Xylene 91 15.583 15.572 0.011 98 14143266 32.0 35.0 82 Bromoform 173 16.004 15.991 0.013 98 5899101 16.0 22.8 84 Styrene 104 16.052 16.037 0.015 96 5488449 16.0 19.1 03/21/2017Page 196 of 377 Report Date: 03-Mar-2017 15:04:24 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC09.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 83 n-Nonane 57 16.047 16.038 0.009 85 3447492 16.0 13.3 85 o-Xylene 91 16.112 16.099 0.013 98 7117819 16.0 17.2 86 1,1,2,2-Tetrachloroethane 83 16.435 16.422 0.013 99 4811457 16.0 17.7 87 1,2,3-Trichloropropane 110 16.592 16.577 0.015 96 1629852 16.0 17.5 88 Isopropylbenzene 105 16.716 16.703 0.013 96 10317786 16.0 17.1 89 N-Propylbenzene 120 17.266 17.257 0.009 99 2999820 16.0 18.7 90 2-Chlorotoluene 126 17.298 17.288 0.010 97 2766057 16.0 17.8 91 4-Ethyltoluene 105 17.433 17.418 0.015 98 10374169 16.0 18.2 92 1,3,5-Trimethylbenzene 120 17.519 17.502 0.017 93 5082507 16.0 19.1 93 Alpha Methyl Styrene 118 17.756 17.744 0.012 90 4614322 16.0 20.8 94 n-Decane 57 17.859 17.846 0.013 94 4459815 16.0 14.1 95 tert-Butylbenzene 119 17.961 17.949 0.012 94 10386644 16.0 19.2 96 1,2,4-Trimethylbenzene 105 17.977 17.963 0.014 95 9294406 16.0 18.8 97 1,3-Dichlorobenzene 146 18.242 18.232 0.010 98 8124131 16.0 20.1 98 sec-Butylbenzene 105 18.247 18.235 0.012 97 13317673 16.0 18.8 99 Benzyl chloride 91 18.323 18.311 0.012 99 8661607 16.0 19.3 100 1,4-Dichlorobenzene 146 18.339 18.324 0.015 96 7825807 16.0 19.6 101 4-Isopropyltoluene 119 18.420 18.410 0.010 97 11628572 16.0 18.9 102 1,2,3-Trimethylbenzene 105 18.468 18.454 0.014 98 6588120 16.0 17.9 103 Butylcyclohexane 83 18.538 18.527 0.011 96 6603806 16.0 15.4 104 1,2-Dichlorobenzene 146 18.711 18.698 0.013 96 7562744 16.0 20.1 105 2,3-Dihydroindene 117 18.711 18.702 0.009 94 9160313 16.0 19.8 106 Indene 116 18.846 18.833 0.013 93 6710686 16.0 19.8 107 n-Butylbenzene 91 18.873 18.862 0.011 97 9859788 16.0 17.3 108 Undecane 57 19.223 19.217 0.006 89 4731040 16.0 14.0 109 1,2-Dimethyl-4-Ethylbenzen 119 19.255 19.247 0.008 97 8411661 16.0 18.7 110 1,2-Dibromo-3-Chloropropan 157 19.326 19.317 0.009 95 3121002 16.0 20.9 111 1,2,4,5-Tetramethylbenzene 119 19.649 19.642 0.007 97 10428510 16.0 19.0 112 1,2,3,5-Tetramethylbenzene 119 19.703 19.696 0.007 95 5932758 16.0 18.1 113 1,2,3,4-Tetramethylbenzene 119 20.097 20.092 0.005 97 7918123 16.0 17.6 114 Dodecane 57 20.291 20.286 0.005 93 3347426 16.0 10.7 115 1,2,4-Trichlorobenzene 180 20.431 20.427 0.004 94 5569204 16.0 17.0 116 Naphthalene 128 20.560 20.555 0.005 99 10668835 16.0 15.6 117 Benzo(b)thiophene 134 20.657 20.653 0.004 99 5884116 16.0 15.5 118 Hexachlorobutadiene 225 20.787 20.783 0.004 94 5192024 16.0 16.3 119 1,2,3-Trichlorobenzene 180 20.835 20.831 0.004 96 3730627 16.0 12.6 120 2-Methylnaphthalene 142 21.628 21.628 0.000 100 884406 50.0 6.36 121 1-Methylnaphthalene 142 21.811 21.808 0.003 100 490550 50.0 4.38 A 124 Toluene Range 1 13.044 (13.009-13.079) 0 16100078 16.0 16.2 A 125 C8 Range 1 13.796 (13.788-13.818) 0 18652465 16.0 10.7 S 126 Xylenes, Total 100 0 48.0 52.1 S 127 1,2-Dichloroethene, Total 1 0 32.0 30.4 Reagents: 40L9DNP_00012 Amount Added: 200.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 197 of 377 Report Date: 03-Mar-2017 15:04:24 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC09.D Injection Date:02-Mar-2017 19:08:30 Instrument ID:MG Operator ID:7126 Lims ID:IC L9 Worklist Smp#:11 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:8 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 Y ( X10 0 0 0 0 0 ) GC02IC09[MS SCAN Chro]:Total * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 9 6 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 6 0 ) 03/21/2017Page 198 of 377 Report Date: 03-Mar-2017 15:04:24 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC09.D Injection Date:02-Mar-2017 19:08:30 Instrument ID:MG Lims ID:IC L9 Client ID: Operator ID:7126 ALS Bottle#:8 Worklist Smp#:11 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 124 Toluene Range, CAS: STL02011 13.0 Min 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 Y ( X10 0 0 0 0 ) GC02IC09[MS SCAN Chro]:Total 03/21/2017Page 199 of 377 Report Date: 03-Mar-2017 15:04:24 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC09.D Injection Date:02-Mar-2017 19:08:30 Instrument ID:MG Lims ID:IC L9 Client ID: Operator ID:7126 ALS Bottle#:8 Worklist Smp#:11 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 125 C8 Range, CAS: STL00834 13.7 Min 0 6 12 18 24 30 36 42 48 54 60 66 72 78 84 90 96 Y ( X10 0 0 0 0 ) GC02IC09[MS SCAN Chro]:Total 03/21/2017Page 200 of 377 Report Date: 03-Mar-2017 15:10:21 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Lims ID:IC L2 Client ID: Sample Type:IC Calib Level:2 Inject. Date:02-Mar-2017 20:31:30 ALS Bottle#:2 Worklist Smp#:20 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004202-004 Misc. Info.:073145 Operator ID:7126 Instrument ID:MG Sublist:chrom-MG_TO15*sub5 Method:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:03-Mar-2017 15:10:20 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK031 First Level Reviewer: barlozhetskayaa Date:03-Mar-2017 14:52:03 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.007 8.012 -0.005 83 429826 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.174 10.179 -0.005 94 2178997 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.044 15.046 -0.002 86 2139458 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.710 16.717 -0.007 94 1595251 4.00 4.00 6 Chlorodifluoromethane 67 3.472 3.463 0.009 97 4117 0.0793 0.0979 7 Propene 41 3.477 3.471 0.006 97 8474 0.0793 0.0846 8 Dichlorodifluoromethane 85 3.520 3.514 0.006 100 30346 0.0793 0.0796 9 Chloromethane 52 3.677 3.665 0.012 52 3546 0.0793 0.1152 10 1,2-Dichloro-1,1,2,2-tetra 135 3.682 3.675 0.007 91 19214 0.0793 0.0825 11 Acetaldehyde 44 3.801 3.793 0.008 88 60200 0.3967 1.31 12 Vinyl chloride 62 3.811 3.809 0.002 98 9681 0.0793 0.0822 13 Butadiene 54 3.887 3.883 0.004 67 6941 0.0793 0.0816 14 Butane 43 3.892 3.885 0.007 88 15104 0.0793 0.0846 15 Bromomethane 94 4.151 4.149 0.002 98 9906 0.0793 0.0828 16 Chloroethane 64 4.275 4.267 0.008 90 5028 0.0793 0.0797 17 Ethanol 31 4.378 4.372 0.006 96 19813 0.3967 0.4194 18 Vinyl bromide 106 4.523 4.522 0.001 95 9517 0.0793 0.0836 19 2-Methylbutane 43 4.577 4.569 0.008 92 11336 0.0793 0.0833 21 Trichlorofluoromethane 101 4.755 4.753 0.002 99 32586 0.0793 0.0834 22 Acetonitrile 40 4.820 4.808 0.012 95 3813 0.0793 0.0883 23 Acetone 58 4.868 4.849 0.019 98 19302 0.2380 0.4203 24 Pentane 72 4.955 4.949 0.006 95 2030 0.0793 0.0935 25 Isopropyl alcohol 45 4.971 4.963 0.008 93 33653 0.2380 0.2470 26 Ethyl ether 31 5.111 5.090 0.021 91 9749 0.0793 0.0773 27 1,1-Dichloroethene 96 5.370 5.367 0.003 98 8850 0.0793 0.0795 28 Acrylonitrile 53 5.462 5.450 0.012 91 4181 0.0793 0.0777 29 2-Methyl-2-propanol 59 5.515 5.494 0.021 97 9859 0.0793 0.0601 30 1,1,2-Trichloro-1,2,2-trif 101 5.542 5.536 0.006 95 18876 0.0793 0.0801 31 Methylene Chloride 84 5.672 5.669 0.003 92 15333 0.0793 0.1481 32 3-Chloro-1-propene 39 5.688 5.684 0.004 87 8422 0.0793 0.0780 03/21/2017Page 201 of 377 Report Date: 03-Mar-2017 15:10:21 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 33 Carbon disulfide 76 5.812 5.810 0.002 99 24622 0.0793 0.0830 34 trans-1,2-Dichloroethene 96 6.411 6.406 0.005 98 9484 0.0793 0.0838 35 2-Methylpentane 43 6.448 6.439 0.009 93 18650 0.0793 0.0828 36 Methyl tert-butyl ether 73 6.556 6.533 0.023 95 22357 0.0793 0.0757 37 1,1-Dichloroethane 63 6.793 6.787 0.006 99 17433 0.0793 0.0828 38 Vinyl acetate 43 6.907 6.898 0.009 99 15155 0.0793 0.0671 39 2-Butanone (MEK) 72 7.322 7.305 0.017 92 3759 0.0793 0.0790 40 Hexane 56 7.360 7.350 0.010 87 7735 0.0793 0.0894 41 Isopropyl ether 45 7.516 7.502 0.014 94 21051 0.0793 0.0694 42 cis-1,2-Dichloroethene 96 7.710 7.707 0.003 93 9880 0.0793 0.0834 43 Ethyl acetate 43 7.920 7.901 0.019 98 12453 0.0793 0.0677 44 Chloroform 83 8.028 8.035 -0.007 94 23035 0.0793 0.0809 45 Tert-butyl ethyl ether 59 8.163 8.144 0.019 95 20425 0.0793 0.0723 46 Tetrahydrofuran 42 8.433 8.410 0.023 88 8146 0.0793 0.0784 47 1,1,1-Trichloroethane 97 9.010 9.013 -0.003 95 24836 0.0793 0.0793 48 1,2-Dichloroethane 62 9.101 9.106 -0.005 99 14813 0.0793 0.0766 49 Benzene 78 9.598 9.599 -0.001 96 27690 0.0793 0.0811 50 Cyclohexane 69 9.603 9.604 -0.001 83 5499 0.0793 0.0915 52 Carbon tetrachloride 117 9.630 9.629 0.001 97 23989 0.0793 0.0754 51 n-Butanol 31 9.695 9.647 0.048 43 2718 0.0793 0.0681 53 2,3-Dimethylpentane 71 9.759 9.754 0.005 90 7119 0.0793 0.0845 54 Thiophene 84 9.873 9.873 -0.001 96 15596 0.0793 0.0797 55 Tert-amyl methyl ether 73 10.153 10.121 0.032 97 16350 0.0793 0.0572 M 56 Isooctane 57 10.433 10.430 0.003 97 43551 0.0793 0.0810 57 n-Heptane 71 10.832 10.831 0.001 91 10809 0.0793 0.0825 58 1,2-Dichloropropane 63 10.859 10.862 -0.003 86 9757 0.0793 0.0777 59 Trichloroethene 130 10.908 10.913 -0.005 96 16324 0.0793 0.0834 60 Dibromomethane 93 10.973 10.978 -0.005 95 13104 0.0793 0.0818 61 Dichlorobromomethane 83 11.140 11.143 -0.003 96 19956 0.0793 0.0711 62 1,4-Dioxane 88 11.188 11.173 0.015 89 3457 0.0793 0.0758 63 Methyl methacrylate 41 11.280 11.278 0.002 94 8746 0.0793 0.0714 64 Methylcyclohexane 83 11.717 11.718 -0.001 96 22792 0.0793 0.0820 65 4-Methyl-2-pentanone (MIBK 43 12.164 12.153 0.011 96 12134 0.0793 0.0592 66 cis-1,3-Dichloropropene 75 12.186 12.190 -0.004 97 16607 0.0793 0.0756 67 trans-1,3-Dichloropropene 75 12.908 12.911 -0.003 97 16151 0.0793 0.0771 68 Toluene 91 13.032 13.035 -0.003 94 30391 0.0793 0.0783 69 1,1,2-Trichloroethane 83 13.103 13.106 -0.003 97 9194 0.0793 0.0776 70 2-Methylthiophene 97 13.183 13.186 -0.003 97 26831 0.0793 0.0792 71 3-Methylthiophene 97 13.394 13.394 0.000 98 26092 0.0793 0.0778 72 2-Hexanone 58 13.545 13.535 0.010 94 6053 0.0793 0.0614 73 n-Octane 85 13.793 13.792 0.001 90 11680 0.0793 0.0819 74 Chlorodibromomethane 129 13.814 13.816 -0.002 97 17043 0.0793 0.0650 75 Ethylene Dibromide 107 14.100 14.106 -0.006 96 17865 0.0793 0.0755 76 Tetrachloroethene 129 14.203 14.207 -0.004 94 13873 0.0793 0.0810 77 Chlorobenzene 112 15.092 15.095 -0.003 97 27763 0.0793 0.0815 78 2,3-Dimethylheptane 43 15.162 15.165 -0.003 91 27702 0.0793 0.0798 79 Ethylbenzene 91 15.400 15.402 -0.002 99 39230 0.0793 0.0769 80 2-Ethylthiophene 97 15.497 15.502 -0.005 98 30884 0.0793 0.0749 81 m-Xylene & p-Xylene 91 15.567 15.572 -0.005 99 58678 0.1587 0.1467 82 Bromoform 173 15.987 15.991 -0.004 95 13758 0.0793 0.0539 84 Styrene 104 16.031 16.037 -0.006 95 19295 0.0793 0.0681 83 n-Nonane 57 16.036 16.038 -0.002 88 22773 0.0793 0.0888 03/21/2017Page 202 of 377 Report Date: 03-Mar-2017 15:10:21 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 85 o-Xylene 91 16.095 16.099 -0.004 98 30347 0.0793 0.0740 86 1,1,2,2-Tetrachloroethane 83 16.419 16.422 -0.003 98 19669 0.0793 0.0731 87 1,2,3-Trichloropropane 110 16.575 16.577 -0.002 97 7086 0.0793 0.0771 88 Isopropylbenzene 105 16.699 16.703 -0.004 97 46007 0.0793 0.0772 89 N-Propylbenzene 120 17.255 17.257 -0.002 99 11555 0.0793 0.0727 90 2-Chlorotoluene 126 17.282 17.288 -0.006 94 11716 0.0793 0.0764 91 4-Ethyltoluene 105 17.411 17.418 -0.007 98 41911 0.0793 0.0745 92 1,3,5-Trimethylbenzene 120 17.497 17.502 -0.005 92 19678 0.0793 0.0748 93 Alpha Methyl Styrene 118 17.740 17.744 -0.004 86 13981 0.0793 0.0636 94 n-Decane 57 17.842 17.846 -0.004 93 26206 0.0793 0.0839 95 tert-Butylbenzene 119 17.945 17.949 -0.004 93 39057 0.0793 0.0731 96 1,2,4-Trimethylbenzene 105 17.956 17.963 -0.007 95 36071 0.0793 0.0739 97 1,3-Dichlorobenzene 146 18.231 18.232 -0.001 96 31625 0.0793 0.0792 98 sec-Butylbenzene 105 18.231 18.235 -0.004 97 51871 0.0793 0.0740 99 Benzyl chloride 91 18.306 18.311 -0.005 98 32413 0.0793 0.0730 100 1,4-Dichlorobenzene 146 18.322 18.324 -0.002 94 32098 0.0793 0.0812 101 4-Isopropyltoluene 119 18.403 18.410 -0.007 97 45117 0.0793 0.0743 102 1,2,3-Trimethylbenzene 105 18.452 18.454 -0.002 98 27110 0.0793 0.0746 103 Butylcyclohexane 83 18.522 18.527 -0.005 94 37084 0.0793 0.0877 104 1,2-Dichlorobenzene 146 18.694 18.698 -0.004 91 28881 0.0793 0.0777 105 2,3-Dihydroindene 117 18.700 18.702 -0.002 92 33742 0.0793 0.0737 106 Indene 116 18.829 18.833 -0.004 93 24860 0.0793 0.0743 107 n-Butylbenzene 91 18.862 18.862 0.000 98 44394 0.0793 0.0789 108 Undecane 57 19.212 19.217 -0.005 94 28830 0.0793 0.0860 109 1,2-Dimethyl-4-Ethylbenzen 119 19.244 19.247 -0.003 97 34842 0.0793 0.0783 110 1,2-Dibromo-3-Chloropropan 157 19.315 19.317 -0.002 91 9943 0.0793 0.0674 111 1,2,4,5-Tetramethylbenzene 119 19.638 19.642 -0.004 97 42923 0.0793 0.0792 112 1,2,3,5-Tetramethylbenzene 119 19.692 19.696 -0.004 95 26835 0.0793 0.0829 113 1,2,3,4-Tetramethylbenzene 119 20.091 20.092 -0.001 97 39160 0.0793 0.0879 114 Dodecane 57 20.285 20.286 -0.001 95 28951 0.0793 0.0937 115 1,2,4-Trichlorobenzene 180 20.425 20.427 -0.002 94 33274 0.0793 0.1028 116 Naphthalene 128 20.555 20.555 0.000 99 76660 0.0793 0.1136 117 Benzo(b)thiophene 134 20.652 20.653 -0.001 99 48504 0.0793 0.1296 118 Hexachlorobutadiene 225 20.781 20.783 -0.002 94 26871 0.0793 0.0851 119 1,2,3-Trichlorobenzene 180 20.830 20.831 -0.001 94 43065 0.0793 0.1466 120 2-Methylnaphthalene 142 21.628 21.628 0.000 100 85009 0.2479 0.6180 121 1-Methylnaphthalene 142 21.806 21.808 -0.002 100 80091 0.2479 0.7229 A 124 Toluene Range 1 13.027 (12.992-13.062) 0 72089 0.0793 0.0741 A 125 C8 Range 1 13.798 (13.783-13.813) 0 165967 0.0793 0.0971 S 126 Xylenes, Total 100 0 0.2380 0.2208 S 127 1,2-Dichloroethene, Total 1 0 0.1587 0.1672 QC Flag Legend Review Flags M - Manually Integrated Reagents: 40L3DNP_00010 Amount Added: 100.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 203 of 377 Report Date: 03-Mar-2017 15:10:21 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Injection Date:02-Mar-2017 20:31:30 Instrument ID:MG Operator ID:7126 Lims ID:IC L2 Worklist Smp#:20 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:2 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 Y ( X10 0 0 0 0 ) GC02IC02R[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 0 0 7 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 7 4 )+ * C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 4 4 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 7 1 5 ) 03/21/2017Page 204 of 377 Report Date: 03-Mar-2017 15:10:21 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Injection Date:02-Mar-2017 20:31:30 Instrument ID:MG Lims ID:IC L2 Client ID: Operator ID:7126 ALS Bottle#:2 Worklist Smp#:20 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 124 Toluene Range, CAS: STL02011 12.9 Min 4 7 10 13 16 19 22 25 28 31 34 37 40 43 Y ( X10 0 0 ) GC02IC02R[MS SCAN Chro]:Total 03/21/2017Page 205 of 377 Report Date: 03-Mar-2017 15:10:21 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Injection Date:02-Mar-2017 20:31:30 Instrument ID:MG Lims ID:IC L2 Client ID: Operator ID:7126 ALS Bottle#:2 Worklist Smp#:20 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 125 C8 Range, CAS: STL00834 13.7 Min 4 8 12 16 20 24 28 32 36 40 44 48 52 56 60 64 68 Y ( X10 0 0 ) GC02IC02R[MS SCAN Chro]:Total 03/21/2017Page 206 of 377 Report Date: 03-Mar-2017 15:10:21 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Manual Integration/User Assign Peak Report TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Injection Date:02-Mar-2017 20:31:30 Instrument ID:MG Lims ID:IC L2 Client ID: Operator ID:7126 ALS Bottle#:2 Worklist Smp#:20 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN 55 Tert-amyl methyl ether, CAS: 994-05-8 Signal: 1 Processing Integration Results RT: 10.17 Area: 46494 Amount: 0.122635 Amount Units: ppb v/v 9.8 10.0 10.2 10.4 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Y ( X10 0 0 ) m/z 73.0 1 0 . 1 7 4 Manual Integration Results RT: 10.15 Area: 16350 Amount: 0.057151 Amount Units: ppb v/v 9.8 10.0 10.2 10.4 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Y ( X10 0 0 ) m/z 73.0 1 0 . 1 5 3 Reviewer: barlozhetskayaa, 03-Mar-2017 15:08:00 Audit Action: Split an Integrated Peak Audit Reason: Split Peak 03/21/2017Page 207 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 0.32(mm)RTX-5 ID: CURVE EVALUATION Calibration Files: LEVEL:LAB SAMPLE ID:LAB FILE ID: 1Level IC 140-8740/3 RB23IC01.D 2Level IC 140-8740/4 RB23IC02.D 3Level IC 140-8740/5 RB23IC03.D 4Level IC 140-8740/6 RB23IC04.D 5Level IC 140-8740/7 RB23IC05.D 6Level ICIS 140-8740/8 RB23IC06.D 7Level IC 140-8740/9 RB23IC07.D 8Level IC 140-8740/10 RB23IC08.D 9Level IC 140-8740/11 RB23IC09.D ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 Chlorodifluoromethane +++++0.4091 0.4038 0.3740 0.3822 Ave 8.1 0.3731 0.3493 0.3392 0.3252 30.00.3695 Propene +++++1.6505 1.6486 1.5907 1.6280 Ave 17.7 1.4939 1.3071 1.1638 0.9824 30.01.4331 Dichlorodifluoromethane 3.3153 2.5695 2.5866 2.6872 3.3047 Ave 14.2 2.5992 2.5447 2.3376 2.2279 30.02.6859 Chloromethane +++++0.5841 0.6056 0.5001 0.5215 Ave 22.7 0.4562 0.4094 0.3794 0.2916 30.00.4685 1,2-Dichlorotetrafluoroethane 2.7709 2.6468 2.6263 2.7330 2.8020 Ave 14.6 2.5520 2.3328 2.1374 1.7039 30.02.4783 Acetaldehyde +++++++++++++++0.7078 0.4726 Ave 40.1 0.4021 0.3107 0.2687 +++++ *30.00.4324 Vinyl chloride 1.3668 1.3820 1.3775 1.3056 1.2312 Ave 25.3 1.0785 0.8848 0.8111 0.6239 30.01.1179 1,3-Butadiene +++++0.9021 0.9670 0.9524 0.8770 Ave 23.2 0.7631 0.6328 0.5940 0.4984 30.00.7734 Butane ++++++++++1.9631 1.9363 1.7034 Ave 28.3 1.4504 1.1789 1.1039 0.9239 30.01.4657 Bromomethane +++++1.1425 0.9606 1.0053 0.9491 Ave 20.8 0.8480 0.7185 0.6806 0.6224 30.00.8659 Chloroethane +++++0.5582 0.5338 0.4775 0.4198 Ave 24.9 0.3882 0.3295 0.3136 0.2839 30.00.4131 Ethanol ++++++++++0.3994 0.3653 0.3152 Ave 25.7 0.2824 0.2364 0.2237 0.2031 30.00.2894 Vinyl bromide +++++0.9464 0.8840 0.8169 0.7703 Ave 19.4 0.7125 0.6138 0.5944 0.5515 30.00.7362 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 208 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 0.32(mm)RTX-5 ID: CURVE EVALUATION ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 2-Methylbutane ++++++++++1.1227 0.9620 0.8035 Ave 27.3 0.7229 0.6328 0.5891 0.5495 30.00.7689 Acrolein ++++++++++0.3972 0.2995 0.2535 Ave 27.3 0.2337 0.2024 ++++++++++ 30.00.2773 Trichlorofluoromethane 3.7727 3.5870 3.4577 3.4301 3.4661 Ave 11.7 3.3109 2.9703 2.7814 2.6431 30.03.2688 Acetonitrile ++++++++++0.5548 0.5670 0.5563 Ave 11.7 0.5601 0.4595 0.4566 0.4318 30.00.5123 Acetone +++++++++++++++0.9304 0.6987 Ave 24.1 0.6891 0.6100 0.5479 0.4731 30.00.6582 Isopropyl alcohol 2.0365 2.0902 1.8661 2.0186 2.1810 Ave 10.9 2.1774 1.9787 1.8292 1.4913 30.01.9632 Pentane +++++0.2477 0.2220 0.2222 0.2489 Ave 9.8 0.2466 0.2301 0.2224 0.1809 30.00.2276 Ethyl ether 1.6986 1.7047 1.5476 1.6629 1.7996 Ave 11.4 1.6959 1.5009 1.4067 1.2258 30.01.5825 1,1-Dichloroethene 1.4051 1.1956 1.2127 1.2152 1.2559 Ave 6.0 1.2300 1.2026 1.2091 1.1369 30.01.2292 Acrylonitrile 0.9742 0.9216 0.9746 0.9745 1.0785 Ave 5.7 1.0713 1.0539 1.0145 0.9434 30.01.0007 t-Butyl alcohol 2.1405 2.1175 2.2687 2.2453 2.4745 Ave 7.4 2.5828 2.5381 2.5154 2.3793 30.02.3624 1,1,2-Trichlorotrifluoroethane 2.8376 2.9466 2.8116 2.8228 2.8118 Ave 6.2 2.8263 2.7276 2.6690 2.3461 30.02.7555 Methylene Chloride ++++++++++1.7271 1.3318 1.2402 Ave 18.9 1.1952 1.1350 1.1024 1.0021 30.01.2477 3-Chloropropene +++++1.5749 1.0781 1.1901 1.2746 Ave 12.7 1.3189 1.2376 1.2079 1.0799 30.01.2452 Carbon disulfide 3.6082 3.6924 3.4319 3.5064 3.5295 Ave 3.5 3.6305 3.5624 3.6504 3.2914 30.03.5448 trans-1,2-Dichloroethene 1.2864 1.2843 1.2582 1.2616 1.2745 Ave 2.8 1.2837 1.2506 1.2680 1.1723 30.01.2600 2-Methylpentane 3.1533 2.9791 2.8260 3.0247 3.2328 Ave 8.7 3.3038 3.1230 2.8727 2.4396 30.02.9950 Methyl tert-butyl ether 2.9110 2.9543 2.9249 3.0697 3.2717 Ave 7.7 3.4617 3.4884 3.4882 3.3070 30.03.2085 1,1-Dichloroethane 2.5277 2.4435 2.4124 2.3753 2.5012 Ave 3.8 2.6346 2.5592 2.5425 2.3524 30.02.4832 Vinyl acetate 3.1388 3.0315 3.0241 3.4033 3.8989 Ave 12.1 4.1432 3.9944 3.8132 3.5830 30.03.5589 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 209 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 0.32(mm)RTX-5 ID: CURVE EVALUATION ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 2-Butanone +++++0.5037 0.6060 0.6358 0.5936 Ave 7.1 0.6313 0.6247 0.6235 0.5916 30.00.6013 Hexane 1.2896 1.1399 1.0987 1.0910 1.1223 Ave 7.8 1.1683 1.1294 1.0857 0.9551 30.01.1200 C6 Range +++++++++++++++2.1313 2.0464 Ave 8.8 2.0878 1.9611 1.8682 1.6629 30.01.9596 Isopropyl ether 4.5315 4.7751 4.6868 4.8896 5.2884 Ave 8.3 5.4158 5.1267 4.7769 4.1039 30.04.8439 cis-1,2-Dichloroethene 1.3415 1.2774 1.3418 1.2750 1.3413 Ave 2.6 1.3298 1.3177 1.3213 1.2489 30.01.3105 Ethyl acetate 2.6219 2.7766 2.7499 3.0384 3.3703 Ave 10.5 3.5342 3.3771 3.2686 2.9813 30.03.0798 Chloroform 2.7715 2.7246 2.6092 2.5716 2.6519 Ave 2.9 2.7684 2.7497 2.7447 2.6040 30.02.6884 Tert-butyl ethyl ether 3.2647 3.3053 3.4728 3.6325 4.0277 Ave 10.0 4.2125 4.1861 4.1247 3.7770 30.03.7782 Tetrahydrofuran 1.5920 1.7103 1.6474 1.6372 1.7291 Ave 5.1 1.7503 1.6627 1.6069 1.4737 30.01.6455 1,1,1-Trichloroethane 2.4293 2.4732 2.2640 2.3283 2.5221 Ave 7.6 2.6928 2.7127 2.8175 2.7180 30.02.5509 1,2-Dichloroethane 0.3558 0.3650 0.3378 0.3419 0.3638 Ave 6.5 0.3932 0.3944 0.3982 0.3961 30.00.3718 1-Butanol +++++0.1086 0.0913 0.0955 0.1130 Ave 10.7 0.1252 0.1178 0.1187 0.1052 30.00.1094 Benzene 0.8259 0.7754 0.7230 0.7352 0.7253 Ave 9.6 0.7479 0.7306 0.6847 0.5718 30.00.7244 Cyclohexane 0.1253 0.1107 0.1069 0.1219 0.1207 Ave 11.0 0.1286 0.1243 0.1124 0.0876 30.00.1154 Carbon tetrachloride 0.5423 0.5313 0.5048 0.4669 0.5529 Ave 8.0 0.5884 0.5941 0.6016 0.5646 30.00.5497 2,3-Dimethylpentane 0.1485 0.1726 0.1653 0.1676 0.1772 Ave 6.9 0.1869 0.1828 0.1776 0.1609 30.00.1710 Thiophene 0.4231 0.4291 0.4202 0.4348 0.4364 Ave 2.8 0.4504 0.4501 0.4455 0.4213 30.00.4346 Tert-amyl methyl ether +++++0.4378 0.6877 0.6536 0.7204 Ave 15.3 0.7605 0.7463 0.7357 0.6874 30.00.6787 2,2,4-Trimethylpentane 1.3172 1.2566 1.2953 1.3473 1.3998 Ave 7.7 1.4654 1.4282 1.3338 1.1219 30.01.3295 1,2-Dichloropropane 0.3473 0.3326 0.3005 0.3169 0.3284 Ave 11.8 0.3318 0.3229 0.2904 0.2248 30.00.3106 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 210 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 0.32(mm)RTX-5 ID: CURVE EVALUATION ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 Heptane 0.2353 0.2275 0.2590 0.2641 0.2816 Ave 11.3 0.2908 0.2815 0.2612 0.2024 30.00.2559 Trichloroethene 0.3763 0.3817 0.3529 0.3658 0.3578 Ave 6.0 0.3567 0.3432 0.3456 0.3092 30.00.3544 Dibromomethane 0.3368 0.3340 0.3070 0.3038 0.3106 Ave 4.5 0.3240 0.3255 0.3261 0.2958 30.00.3182 Bromodichloromethane 0.4663 0.4798 0.4513 0.4868 0.5299 Ave 9.9 0.5746 0.5800 0.5835 0.5396 30.00.5213 1,4-Dioxane 0.0955 0.0973 0.1080 0.1081 0.1180 Ave 9.4 0.1208 0.1162 0.1119 0.0937 30.00.1077 Methyl methacrylate 0.2948 0.2926 0.3019 0.3382 0.3887 Ave 13.8 0.4155 0.4018 0.3943 0.3639 30.00.3546 Methylcyclohexane 0.5249 0.4823 0.5045 0.5416 0.5664 Ave 7.2 0.5800 0.5724 0.5475 0.4768 30.00.5329 4-Methyl-2-pentanone (MIBK)0.5451 0.5831 0.5890 0.6733 0.7057 Ave 11.4 0.7612 0.7193 0.6786 0.5958 30.00.6501 cis-1,3-Dichloropropene 0.3325 0.3580 0.3691 0.3881 0.4163 Ave 11.4 0.4545 0.4588 0.4524 0.4296 30.00.4066 trans-1,3-Dichloropropene 0.3439 0.3713 0.3700 0.3990 0.4502 Ave 16.6 0.4969 0.5120 0.5423 0.5042 30.00.4433 Toluene 0.9897 1.1262 1.0484 1.0868 1.1353 Ave 6.2 1.1563 1.1350 1.1215 0.9730 30.01.0858 1,1,2-Trichloroethane 0.3385 0.3467 0.3263 0.3332 0.3327 Ave 5.6 0.3438 0.3365 0.3306 0.2836 30.00.3302 2-Methylthiophene 0.7648 0.8124 0.8091 0.8550 0.8939 Ave 6.6 0.9175 0.9073 0.9013 0.7986 30.00.8511 3-Methylthiophene 0.7410 0.7956 0.7731 0.8464 0.8746 Ave 7.5 0.9150 0.8949 0.8873 0.7837 30.00.8346 2-Hexanone ++++++++++0.2939 0.3464 0.4025 Ave 13.7 0.4413 0.4193 0.4095 0.3479 30.00.3801 Dibromochloromethane 0.4539 0.4589 0.5439 0.5767 0.6651 Ave 16.8 0.7002 0.7087 0.6920 0.5676 30.00.5963 Octane 0.3050 0.2812 0.3062 0.3226 0.3580 Ave 13.0 0.3634 0.3499 0.3175 0.2334 30.00.3153 1,2-Dibromoethane 0.5025 0.5348 0.5271 0.5526 0.5718 Ave 6.8 0.6052 0.6004 0.6043 0.5347 30.00.5593 Tetrachloroethene 0.4127 0.4281 0.4170 0.3858 0.4085 Ave 7.6 0.4118 0.3977 0.3891 0.3259 30.00.3974 Chlorobenzene 1.0317 0.9878 0.9702 0.9165 0.9332 Ave 8.5 0.9145 0.8942 0.8663 0.7600 30.00.9194 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 211 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 0.32(mm)RTX-5 ID: CURVE EVALUATION ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 2,3-Dimethylheptane 1.0501 1.0390 1.0703 1.1262 1.1983 Ave 13.2 1.1998 1.0884 0.9834 0.7362 30.01.0546 Ethylbenzene 1.3063 1.4337 1.3764 1.3796 1.4565 Ave 6.5 1.4538 1.4187 1.3421 1.1735 30.01.3712 2-Ethylthiophene 0.8479 0.9131 0.9199 0.9869 1.0353 Ave 7.8 1.0639 1.0422 0.9980 0.8991 30.00.9674 m-Xylene & p-Xylene 1.0164 1.0833 1.0855 1.0961 1.1333 Ave 10.1 1.1258 1.0712 0.9735 0.7951 30.01.0422 Bromoform +++++0.2970 0.6137 0.6358 0.7832 Ave 25.9 0.8185 0.8349 0.8051 0.7265 30.00.6894 Styrene 0.5197 0.5721 0.6375 0.7086 0.7932 Ave 14.6 0.8003 0.7785 0.7450 0.6553 30.00.6900 Nonane 0.6514 0.6809 0.7464 0.8049 0.8308 Ave 16.3 0.8033 0.7192 0.6330 0.4629 30.00.7036 o-Xylene 1.1138 1.1521 1.1730 1.1231 1.1726 Ave 7.5 1.1413 1.0964 1.0251 0.9159 30.01.1015 1,1,2,2-Tetrachloroethane 0.7878 0.8367 0.8501 0.8438 0.8988 Ave 9.4 0.8665 0.8111 0.7454 0.6464 30.00.8096 1,2,3-Trichloropropane 0.2101 0.2380 0.2280 0.2501 0.2629 Ave 7.6 0.2375 0.2278 0.2197 0.2101 30.00.2316 Isopropylbenzene 1.7492 1.6875 1.6330 1.6163 1.6399 Ave 12.9 1.5241 1.4170 1.3116 1.1480 30.01.5252 Propylbenzene 0.3854 0.4069 0.4415 0.4673 0.4679 Ave 13.0 0.4272 0.3895 0.3553 0.3080 30.00.4054 2-Chlorotoluene 0.4071 0.4381 0.4586 0.4318 0.4377 Ave 13.8 0.3909 0.3650 0.3350 0.2943 30.00.3954 4-Ethyltoluene 1.3243 1.4805 1.5694 1.6643 1.7621 Ave 11.5 1.6298 1.5104 1.3764 1.2214 30.01.5043 1,3,5-Trimethylbenzene 0.6749 0.7066 0.7458 0.7784 0.7913 Ave 12.4 0.7298 0.6700 0.6055 0.5234 30.00.6917 Alpha Methyl Styrene ++++++++++0.4980 0.5540 0.6499 Ave 10.0 0.6295 0.5986 0.5681 0.5108 30.00.5727 Decane 0.6968 0.8474 0.9402 1.0437 1.1355 Ave 19.2 1.1564 1.0233 0.8697 0.6547 30.00.9298 tert-Butylbenzene 1.2446 1.4333 1.4639 1.5038 1.5594 Ave 13.5 1.5225 1.3789 1.2312 0.9844 30.01.3691 1,2,4-Trimethylbenzene 1.1996 1.3154 1.4107 1.4603 1.5433 Ave 16.2 1.4308 1.2656 1.0769 0.8842 30.01.2874 1,3-Dichlorobenzene 1.1048 1.1311 1.1523 1.1608 1.2098 Ave 17.0 1.1072 0.9704 0.8363 0.6809 30.01.0393 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 212 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 0.32(mm)RTX-5 ID: CURVE EVALUATION ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 sec-Butylbenzene 1.8928 1.9981 1.9998 2.1158 2.2549 Ave 16.1 2.1829 1.9160 1.6284 1.2558 30.01.9161 Benzyl chloride +++++0.9601 0.9968 1.1384 1.3053 Ave 14.5 1.3549 1.2520 1.0577 0.9364 30.01.1252 1,4-Dichlorobenzene 1.0766 1.1599 1.2010 1.1747 1.2284 Ave 15.8 1.1344 0.9981 0.8772 0.7272 30.01.0642 4-Isopropyltoluene 1.4213 1.5183 1.6092 1.7329 1.8549 Ave 14.0 1.8407 1.6610 1.4559 1.1632 30.01.5842 1,2,3-Trimethylbenzene 0.9732 1.0118 1.0688 1.1322 1.2012 Ave 10.8 1.1275 1.0054 0.9363 0.8419 30.01.0331 Butylcyclohexane 0.9768 1.0934 1.0648 1.1463 1.2414 Ave 13.8 1.2131 1.0887 0.9689 0.7608 30.01.0616 1,2-Dichlorobenzene 1.0234 1.1221 1.1167 1.1528 1.2005 Ave 17.8 1.1072 0.9562 0.8161 0.6482 30.01.0159 Indane 1.2597 1.2475 1.2966 1.3573 1.4129 Ave 18.1 1.2576 1.0987 0.9372 0.7525 30.01.1800 Indene 0.7109 0.7763 0.8300 0.9159 1.0499 Ave 13.2 1.0002 0.9097 0.8432 0.7456 30.00.8646 Butylbenzene 1.5501 1.6901 1.7162 1.7850 1.9632 Ave 14.2 1.9872 1.8259 1.5829 1.1976 30.01.6998 Undecane 0.8599 0.9699 1.0813 1.1463 1.3802 Ave 22.1 1.3923 1.1925 0.9635 0.6664 30.01.0725 1,2-Dimethyl-4-Ethylbenzene +++++1.1654 1.2700 1.3013 1.4397 Ave 10.3 1.4479 1.3042 1.0860 +++++ 30.01.2878 1,2-Dibromo-3-Chloropropane +++++0.1595 0.4032 0.4088 0.5302 Ave 29.4 0.5566 0.5399 0.5054 0.4185 30.00.4403 1,2,4,5-Tetramethylbenzene 1.1956 1.3327 1.4080 1.4358 1.6947 Ave 13.7 1.7148 1.6373 1.5448 1.1937 30.01.4619 1,2,3,5-Tetramethylbenzene 0.8256 0.8320 0.8607 0.9064 1.0442 Ave 10.3 1.0520 1.0055 0.9909 0.8315 30.00.9276 1,2,3,4-Tetramethylbenzene 1.0921 1.0723 1.2008 1.1955 1.4212 Ave 11.9 1.4380 1.3827 1.3367 1.0885 30.01.2475 Dodecane +++++0.7856 1.0259 0.9522 1.3481 Ave 23.0 1.4735 1.3165 1.1351 0.8207 30.01.1072 1,2,4-Trichlorobenzene 0.8581 0.9338 1.0791 0.9985 1.2415 Ave 14.6 1.3099 1.2394 1.1805 0.9729 30.01.0904 Naphthalene 1.4479 1.6362 1.9175 1.7509 2.1982 Ave 15.9 2.3089 2.2091 2.0993 1.6619 30.01.9144 Benzo(b)thiophene +++++0.8478 1.0151 0.9632 1.2274 Ave 15.7 1.3129 1.3020 1.3124 1.1588 30.01.1425 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 213 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:GC Column:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 0.32(mm)RTX-5 ID: CURVE EVALUATION ANALYTE RRF LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CURVE TYPE COEFFICIENT B M1 M2 #%RSD #MAX %RSD R^2 OR COD #MIN R^2 OR COD MIN RRF LVL 6 LVL 7 LVL 8 LVL 9 Hexachlorobutadiene 0.9831 1.0290 1.0951 1.0316 1.2395 Ave 9.0 1.2409 1.1724 1.1316 1.0023 30.01.1028 1,2,3-Trichlorobenzene 0.9323 0.9595 1.0971 0.9545 1.2242 Ave 11.9 1.2522 1.1927 1.1249 0.9587 30.01.0773 2-Methylnaphthalene +++++++++++++++0.0469 0.1287 Ave 40.6 0.1873 0.2045 0.2124 0.2253 50.00.1675 1-Methylnaphthalene ++++++++++0.0449 0.0432 0.1073 Ave 47.9 0.1549 0.1697 0.1697 0.1782 50.00.1240 4-Bromofluorobenzene (Surr)0.7152 0.7077 0.7161 0.7225 0.7386 Ave 6.3 0.7166 0.7098 0.6627 0.5943 30.00.6982 FORM VI TO 15 LL Note: The M1 coefficient is the same as Ave RRF for an Ave curve type. 03/21/2017Page 214 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION Calibration Files: LEVEL:LAB SAMPLE ID:LAB FILE ID: Level 1 IC 140-8740/3 RB23IC01.D Level 2 IC 140-8740/4 RB23IC02.D Level 3 IC 140-8740/5 RB23IC03.D Level 4 IC 140-8740/6 RB23IC04.D Level 5 IC 140-8740/7 RB23IC05.D Level 6 ICIS 140-8740/8 RB23IC06.D Level 7 IC 140-8740/9 RB23IC07.D Level 8 IC 140-8740/10 RB23IC08.D Level 9 IC 140-8740/11 RB23IC09.D ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (PPB V/V) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 Chlorodifluoromethane AveCBM +++++2717 5714 13525 36029 77337 164616 341742 701702 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Propene AveCBM +++++10961 23326 57519 153453 309645 616102 1172387 2119514 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Dichlorodifluoromethane AveCBM 10481 17064 36597 97168 311496 538735 1199423 2354948 4806853 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Chloromethane AveCBM +++++3879 8569 18083 49158 94563 192950 382249 629051 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2-Dichlorotetrafluoroethane AveCBM 8760 17577 37159 98824 264107 528953 1099525 2153188 3676373 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Acetaldehyde AveCBM +++++++++++++++127965 222712 416688 732315 1353530 +++++ +++++++++++++++2.00 4.99 9.99 20.0 40.0 +++++ Vinyl chloride AveCBM 4321 9178 19490 47210 116046 223530 417030 817062 1346176 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,3-Butadiene AveCBM +++++5991 13682 34439 82666 158175 298274 598358 1075330 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Butane AveCBM ++++++++++27776 70015 160556 300625 555644 1112031 1993462 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 Bromomethane AveCBM +++++7587 13592 36351 89463 175754 338670 685673 1342819 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Chloroethane AveCBM +++++3707 7552 17265 39574 80451 155307 315958 612586 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Ethanol AveCBM ++++++++++28254 66047 148558 292636 557068 1126938 2190820 ++++++++++0.793 2.00 4.99 9.99 20.0 40.0 80.0 Vinyl bromide AveCBM +++++6285 12508 29539 72610 147675 289326 598787 1189919 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Methylbutane AveCBM ++++++++++15885 34784 75735 149838 298288 593509 1185662 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 FORM VI TO 15 LL 03/21/2017Page 215 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (PPB V/V) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 Acrolein AveCBM ++++++++++5620 10830 23899 48441 95411 ++++++++++ ++++++++++0.159 0.400 0.999 2.00 4.00 ++++++++++ Trichlorofluoromethane AveCBM 11927 23821 48923 124033 326703 686235 1400003 2801983 5702636 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Acetonitrile AveCBM ++++++++++7850 20501 52436 116089 216580 460029 931637 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 Acetone AveCBM +++++++++++++++100931 197602 428503 862681 1656093 3062269 +++++++++++++++1.20 3.00 5.99 12.0 24.0 48.0 Isopropyl alcohol AveCBM 19316 41645 79216 218989 616764 1354035 2798169 5528721 9653805 0.118 0.235 0.476 1.20 3.00 5.99 12.0 24.0 48.0 Pentane AveCBM +++++1645 3141 8034 23465 51117 108438 224005 390407 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Ethyl ether AveCBM 5370 11321 21897 60129 169629 351514 707415 1417102 2644820 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,1-Dichloroethene AveCBM 4442 7940 17158 43941 118379 254943 566831 1218064 2452857 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Acrylonitrile AveCBM 3080 6120 13790 35238 101655 222055 496743 1022056 2035476 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 t-Butyl alcohol AveCBM 6767 14062 32099 81188 233237 535332 1196301 2533997 5133511 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,1,2-Trichlorotrifluoroethane AveCBM 8971 19568 39781 102072 265033 585806 1285623 2688728 5061965 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Methylene Chloride AveCBM ++++++++++24437 48158 116898 247716 534995 1110586 2162136 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 3-Chloropropene AveCBM +++++10459 15254 43032 120145 273367 583311 1216806 2329963 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Carbon disulfide AveCBM 11407 24521 48557 126789 332680 752486 1679091 3677457 7101466 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 trans-1,2-Dichloroethene AveCBM 4067 8529 17802 45618 120134 266070 589438 1277383 2529264 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Methylpentane AveCBM 9969 19784 39985 109374 304717 684768 1472011 2893931 5263706 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Methyl tert-butyl ether AveCBM 9203 19619 41384 110998 308385 717493 1644239 3514051 7135130 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,1-Dichloroethane AveCBM 7991 16227 34133 85892 235756 546060 1206246 2561351 5075426 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Vinyl acetate AveCBM 9923 20132 42788 123061 367502 858751 1882713 3841494 7730530 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Butanone AveCBM +++++3345 8574 22992 55955 130850 294463 628092 1276403 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Hexane AveCBM 4077 7570 15546 39451 105783 242145 532333 1093784 2060711 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 FORM VI TO 15 LL 03/21/2017Page 216 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (PPB V/V) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 C6 Range AveDFBZ +++++++++++++++369743 946720 2114371 4501964 9178276 17203049 +++++++++++++++0.400 0.999 2.00 4.00 8.00 16.0 Isopropyl ether AveCBM 14326 31711 66313 176808 498469 1122507 2416434 4812302 8854520 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 cis-1,2-Dichloroethene AveCBM 4241 8483 18985 46105 126425 275633 621102 1331136 2694692 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Ethyl acetate AveCBM 8289 18439 38908 109869 317674 732523 1591786 3292786 6432390 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Chloroform AveCBM 8762 18094 36917 92987 249964 573807 1296029 2765081 5618386 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Tert-butyl ethyl ether AveCBM 10321 21950 49137 131350 379641 873119 1973104 4155244 8149213 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Tetrahydrofuran AveCBM 5033 11358 23309 59200 162980 362782 783690 1618818 3179689 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,1,1-Trichloroethane AveCBM 7680 16424 32033 84191 237728 558131 1278599 2838322 5864283 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2-Dichloroethane AveDFBZ 5395 11614 22850 59318 168285 398175 905386 1956139 4097974 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1-Butanol AveDFBZ +++++3455 6173 16572 52295 126841 270509 583174 1087852 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Benzene AveDFBZ 12524 24674 48907 127540 335562 757353 1677250 3363998 5915532 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Cyclohexane AveDFBZ 1900 3521 7234 21140 55861 130260 285427 552190 906562 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Carbon tetrachloride AveDFBZ 8224 16905 34144 81002 255790 595862 1363863 2955600 5840819 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2,3-Dimethylpentane AveDFBZ 2252 5491 11183 29068 81981 189272 419595 872362 1664608 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Thiophene AveDFBZ 6417 13654 28426 75422 201904 456153 1033269 2188596 4358587 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Tert-amyl methyl ether AveDFBZ +++++13931 46518 113391 333304 770144 1713213 3614164 7110699 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2,2,4-Trimethylpentane AveDFBZ 19975 39986 87619 233738 647577 1483986 3278689 6552928 11606245 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2-Dichloropropane AveDFBZ 5267 10585 20327 54978 151945 335988 741321 1426473 2325405 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Heptane AveDFBZ 3569 7240 17517 45810 130261 294527 646231 1283209 2094048 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Trichloroethene AveDFBZ 5706 12147 23873 63467 165540 361242 787921 1697706 3199084 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Dibromomethane AveDFBZ 5107 10628 20765 52696 143675 328140 747292 1602016 3060446 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 FORM VI TO 15 LL 03/21/2017Page 217 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (PPB V/V) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 Bromodichloromethane AveDFBZ 7071 15268 30527 84444 245143 581937 1331396 2866521 5582595 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,4-Dioxane AveDFBZ 1448 3097 7308 18752 54586 122338 266658 549623 969543 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Methyl methacrylate AveDFBZ 4470 9311 20422 58677 179826 420770 922438 1936917 3764789 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Methylcyclohexane AveDFBZ 7960 15346 34127 93957 262049 587324 1314112 2689602 4932261 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 4-Methyl-2-pentanone (MIBK)AveDFBZ 8267 18554 39845 116812 326469 770834 1651361 3334023 6163255 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 cis-1,3-Dichloropropene AveDFBZ 5043 11393 24970 67326 192581 460289 1053282 2222764 4444447 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 trans-1,3-Dichloropropene AveCBZd 5 4190 9323 20070 55793 168680 407884 961977 2116906 4314889 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Toluene AveCBZd 5 12057 28273 56866 151950 425356 949069 2132262 4377764 8326940 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,1,2-Trichloroethane AveCBZd 5 4124 8704 17701 46587 124669 282164 632212 1290344 2427275 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Methylthiophene AveCBZd 5 9317 20397 43887 119545 334934 753080 1704543 3518170 6834736 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 3-Methylthiophene AveCBZd 5 9027 19973 41936 118345 327679 751011 1681316 3463489 6707253 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Hexanone AveCBZd 5 ++++++++++15939 48432 150804 362209 787724 1598395 2977612 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 Dibromochloromethane AveCBZd 5 5530 11521 29500 80628 249214 574706 1331407 2701236 4857610 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Octane AveCBZd 5 3716 7061 16610 45104 134151 298259 657401 1239163 1997649 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2-Dibromoethane AveCBZd 5 6121 13427 28588 77258 214254 496771 1127971 2358773 4575751 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Tetrachloroethene AveCBZd 5 5027 10747 22616 53937 153057 338008 747185 1518756 2789077 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Chlorobenzene AveCBZd 5 12568 24800 52626 128145 349650 750598 1679949 3381719 6504560 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2,3-Dimethylheptane AveCBZd 5 12792 26084 58055 157463 448957 984747 2044712 3838726 6300729 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Ethylbenzene AveCBZd 5 15913 35993 74659 192894 545725 1193234 2665373 5238775 10042970 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Ethylthiophene AveCBZd 5 10329 22924 49896 137984 387899 873189 1958038 3895698 7694998 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 m-Xylene & p-Xylene AveCBZd 5 24763 54395 117759 306509 849245 1848010 4024786 7600175 13609680 0.0784 0.157 0.317 0.800 2.00 3.99 8.00 16.0 32.0 FORM VI TO 15 LL 03/21/2017Page 218 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (PPB V/V) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 Bromoform AveCBZd 5 +++++7456 33288 88903 293454 671801 1568536 3142805 6217969 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Styrene AveCBZd 5 6331 14364 34579 99070 297206 656912 1462535 2907897 5608457 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Nonane AveCBZd 5 7935 17094 40483 112542 311279 659323 1351079 2470879 3961418 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 o-Xylene AveCBZd 5 13569 28924 63625 157032 439347 936796 2059774 4001349 7838829 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,1,2,2-Tetrachloroethane AveCBZd 5 9597 21006 46111 117978 336748 711168 1523825 2909802 5531960 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,3-Trichloropropane AveCBZd 5 2560 5974 12366 34975 98499 194922 428051 857552 1797695 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Isopropylbenzene AveCBZd 5 21309 42366 88577 225985 614427 1250923 2662166 5119668 9824520 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Propylbenzene AveCBZd 5 4695 10216 23946 65333 175311 350675 731805 1386895 2635592 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Chlorotoluene AveCBZd 5 4959 10999 24877 60368 164005 320862 685774 1307704 2518415 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 4-Ethyltoluene AveCBZd 5 16133 37169 85126 232695 660235 1337683 2837542 5372799 10452735 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,3,5-Trimethylbenzene AveCBZd 5 8222 17741 40452 108841 296486 598983 1258645 2363652 4479062 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Alpha Methyl Styrene AveCBZd 5 ++++++++++27013 77461 243487 516658 1124551 2217522 4371974 ++++++++++0.159 0.400 0.999 2.00 4.00 8.00 16.0 Decane AveCBZd 5 8489 21274 50999 145932 425460 949126 1922503 3394674 5603231 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 tert-Butylbenzene AveCBZd 5 15162 35984 79403 210262 584282 1249656 2590545 4805951 8424853 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,4-Trimethylbenzene AveCBZd 5 14614 33025 76518 204178 578234 1174348 2377769 4203802 7566924 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,3-Dichlorobenzene AveCBZd 5 13459 28396 62501 162298 453278 908799 1823090 3264552 5827565 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 sec-Butylbenzene AveCBZd 5 23058 50165 108474 295827 844875 1791681 3599528 6356290 10747733 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Benzyl chloride AveCBZd 5 +++++24103 54066 159172 489081 1112104 2352128 4128671 8014177 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,4-Dichlorobenzene AveCBZd 5 13115 29121 65142 164245 460249 931133 1875178 3424013 6223742 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 4-Isopropyltoluene AveCBZd 5 17315 38119 87284 242297 694973 1510793 3120571 5683045 9955102 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,3-Trimethylbenzene AveCBZd 5 11856 25401 57972 158300 450050 925394 1888807 3654635 7205534 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 FORM VI TO 15 LL 03/21/2017Page 219 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION ANALYTE CURVE TYPE IS REF RESPONSE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 CONCENTRATION (PPB V/V) LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 6 LVL 7 LVL 8 LVL 9 Butylcyclohexane AveCBZd 5 11900 27451 57754 160274 465131 995717 2045438 3782240 6510976 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2-Dichlorobenzene AveCBZd 5 12467 28172 60572 161183 449782 908758 1796455 3185630 5547661 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Indane AveCBZd 5 15346 31320 70331 189774 529393 1032175 2064201 3658240 6439833 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Indene AveCBZd 5 8660 19489 45019 128054 393389 820907 1709131 3291239 6380743 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Butylbenzene AveCBZd 5 18884 42432 93087 249573 735562 1631072 3430316 6178847 10249297 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Undecane AveCBZd 5 10476 24349 58652 160272 517142 1142764 2240401 3760994 5703184 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2-Dimethyl-4-Ethylbenzene AveCBZd 5 +++++29259 68884 181950 539412 1188411 2450287 4239183 +++++ +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 +++++ 1,2-Dibromo-3-Chloropropane AveCBZd 5 +++++4005 21869 57159 198649 456821 1014303 1973001 3581933 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,4,5-Tetramethylbenzene AveCBZd 5 14565 33459 76370 200754 634976 1407460 3075927 6030209 10215880 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,3,5-Tetramethylbenzene AveCBZd 5 10058 20887 46686 126732 391237 863457 1889050 3867833 7116459 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,3,4-Tetramethylbenzene AveCBZd 5 13304 26921 65134 167151 532497 1180268 2597679 5217806 9315480 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Dodecane AveCBZd 5 +++++19723 55647 133130 505118 1209447 2473317 4430925 7023895 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,4-Trichlorobenzene AveCBZd 5 10453 23444 58530 139606 465148 1075136 2328403 4608196 8326267 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Naphthalene AveCBZd 5 17639 41077 104007 244813 823611 1895111 4150285 8194497 14223211 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Benzo(b)thiophene AveCBZd 5 +++++21284 55059 134679 459875 1077615 2446149 5123070 9916966 +++++0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 Hexachlorobutadiene AveCBZd 5 11976 25833 59398 144240 464424 1018485 2202550 4417255 8577746 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 1,2,3-Trichlorobenzene AveCBZd 5 11357 24088 59506 133457 458690 1027789 2240673 4390985 8204831 0.0392 0.0784 0.159 0.400 0.999 2.00 4.00 8.00 16.0 2-Methylnaphthalene AveCBZd 5 +++++++++++++++20471 150695 480479 1200547 2590764 6023991 +++++++++++++++1.25 3.12 6.24 12.5 25.0 50.0 1-Methylnaphthalene AveCBZd 5 ++++++++++7607 18889 125607 397397 996171 2070086 4765773 ++++++++++0.496 1.25 3.12 6.24 12.5 25.0 50.0 4-Bromofluorobenzene (Surr)AveCBZd 5 889007 906481 979197 1010124 1108358 1177919 1333550 1293417 1271651 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 FORM VI TO 15 LL 03/21/2017Page 220 of 377 FORM VI Lab Name:Job No.: Calibration ID: SDG No.: Instrument ID:Heated Purge: (Y/N) AIR - GC/MS VOA BY INTERNAL STANDARD - INITIAL CALIBRATION DATA TestAmerica Knoxville 140-7345-1 MR Analy Batch No.:8740 919Calibration Start Date:Calibration End Date:02/23/2017 22:59 N 02/24/2017 05:21 GC Column:RTX-5 ID:0.32(mm) RESPONSE AND CONCENTRATION Curve Type Legend: Ave = Average ISTD FORM VI TO 15 LL 03/21/2017Page 221 of 377 Report Date: 24-Feb-2017 16:53:45 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC01.D Lims ID:IC L1 Client ID: Sample Type:IC Calib Level:1 Inject. Date:23-Feb-2017 22:59:30 ALS Bottle#:2 Worklist Smp#:3 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004095-003 Misc. Info.:073145 Operator ID:Instrument ID:MR Sublist:chrom-MR_TO15*sub7 Method:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:24-Feb-2017 16:53:45 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK010 First Level Reviewer: barlozhetskayaa Date:24-Feb-2017 14:37:39 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.215 8.227 -0.012 96 322594 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.383 10.390 -0.007 94 1547434 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.279 15.280 -0.001 88 1243073 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.967 16.970 -0.003 95 889007 4.00 4.10 6 Chlorodifluoromethane 67 3.734 3.720 0.014 95 1171 0.0392 0.0393 7 Propene 41 3.728 3.722 0.006 80 6231 0.0392 0.0539 8 Dichlorodifluoromethane 85 3.782 3.772 0.010 98 10481 0.0392 0.0484 9 Chloromethane 52 3.933 3.920 0.013 98 1686 0.0392 0.0446 10 1,2-Dichloro-1,1,2,2-tetra 135 3.949 3.945 0.004 91 8760 0.0392 0.0438 11 Acetaldehyde 44 4.068 4.063 0.005 87 20138 0.1960 0.5775 12 Vinyl chloride 62 4.079 4.069 0.010 40 4321 0.0392 0.0479 13 Butadiene 54 4.154 4.150 0.004 65 3287 0.0392 0.0527 14 Butane 43 4.154 4.152 0.002 89 7141 0.0392 0.0604 15 Bromomethane 94 4.413 4.409 0.004 95 4316 0.0392 0.0618 16 Chloroethane 64 4.543 4.534 0.009 70 1641 0.0392 0.0493 17 Ethanol 31 4.645 4.648 -0.003 97 8349 0.1960 0.3578 18 Vinyl bromide 106 4.791 4.790 0.001 79 3108 0.0392 0.0523 19 2-Methylbutane 43 4.850 4.848 0.002 73 4737 0.0392 0.0764 20 Acrolein 56 5.028 5.025 0.003 37 2482 0.0392 0.1110 21 Trichlorofluoromethane 101 5.033 5.030 0.003 98 11927 0.0392 0.0452 23 Acetone 58 5.130 5.124 0.006 98 9162 0.1176 0.1726 24 Isopropyl alcohol 45 5.227 5.227 0.000 80 19316 0.1176 0.1220 25 Pentane 72 5.227 5.229 -0.002 77 685 0.0392 0.0373 26 Ethyl ether 31 5.378 5.367 0.011 92 5370 0.0392 0.0421 27 1,1-Dichloroethene 96 5.627 5.629 -0.003 98 4442 0.0392 0.0448 28 Acrylonitrile 53 5.707 5.705 0.002 76 3080 0.0392 0.0382 29 2-Methyl-2-propanol 59 5.751 5.739 0.012 92 6767 0.0392 0.0355 30 1,1,2-Trichloro-1,2,2-trif 101 5.810 5.809 0.001 93 8971 0.0392 0.0404 31 Methylene Chloride 84 5.918 5.920 -0.002 98 10968 0.0392 0.1090 32 3-Chloro-1-propene 39 5.939 5.942 -0.003 79 6632 0.0392 0.0660 03/21/2017Page 222 of 377 Report Date: 24-Feb-2017 16:53:45 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC01.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 33 Carbon disulfide 76 6.063 6.062 0.001 97 11407 0.0392 0.0399 34 trans-1,2-Dichloroethene 96 6.651 6.657 -0.006 98 4067 0.0392 0.0400 35 2-Methylpentane 43 6.700 6.705 -0.005 93 9969 0.0392 0.0413 36 Methyl tert-butyl ether 73 6.802 6.785 0.017 96 9203 0.0392 0.0356 37 1,1-Dichloroethane 63 7.012 7.023 -0.011 98 7991 0.0392 0.0399 38 Vinyl acetate 43 7.142 7.135 0.007 99 9923 0.0392 0.0346 39 2-Butanone (MEK) 72 7.535 7.522 0.013 97 1365 0.0392 0.0281 40 Hexane 56 7.600 7.610 -0.010 86 4077 0.0392 0.0451 41 Isopropyl ether 45 7.756 7.748 0.008 96 14326 0.0392 0.0367 42 cis-1,2-Dichloroethene 96 7.929 7.930 -0.001 92 4241 0.0392 0.0401 43 Ethyl acetate 43 8.129 8.118 0.011 97 8289 0.0392 0.0334 44 Chloroform 83 8.242 8.258 -0.016 27 8762 0.0392 0.0404 45 Tert-butyl ethyl ether 59 8.387 8.381 0.006 97 10321 0.0392 0.0339 46 Tetrahydrofuran 42 8.635 8.621 0.014 94 5033 0.0392 0.0379 47 1,1,1-Trichloroethane 97 9.229 9.239 -0.010 95 7680 0.0392 0.0373 48 1,2-Dichloroethane 62 9.304 9.311 -0.007 95 5395 0.0392 0.0375 49 n-Butanol 31 9.843 9.810 0.033 66 1333 0.0392 0.0315 50 Benzene 78 9.811 9.821 -0.010 89 12524 0.0392 0.0447 51 Cyclohexane 69 9.849 9.849 0.000 88 1900 0.0392 0.0426 52 Carbon tetrachloride 117 9.860 9.860 0.000 84 8224 0.0392 0.0387 53 2,3-Dimethylpentane 71 10.000 10.009 -0.009 92 2252 0.0392 0.0340 54 Thiophene 84 10.081 10.088 -0.007 92 6417 0.0392 0.0382 56 Isooctane 57 10.668 10.676 -0.008 98 19975 0.0392 0.0388 57 1,2-Dichloropropane 63 11.062 11.062 0.000 70 5267 0.0392 0.0438 58 n-Heptane 71 11.057 11.070 -0.013 82 3569 0.0392 0.0360 59 Trichloroethene 130 11.116 11.125 -0.009 89 5706 0.0392 0.0416 60 Dibromomethane 93 11.159 11.169 -0.010 88 5107 0.0392 0.0415 61 Dichlorobromomethane 83 11.326 11.338 -0.012 98 7071 0.0392 0.0351 62 1,4-Dioxane 88 11.364 11.347 0.017 48 1448 0.0392 0.0347 63 Methyl methacrylate 41 11.483 11.473 0.010 93 4470 0.0392 0.0326 64 Methylcyclohexane 83 11.946 11.948 -0.002 94 7960 0.0392 0.0386 65 4-Methyl-2-pentanone (MIBK 43 12.351 12.341 0.010 96 8267 0.0392 0.0329 66 cis-1,3-Dichloropropene 75 12.383 12.389 -0.006 91 5043 0.0392 0.0321 67 trans-1,3-Dichloropropene 75 13.106 13.112 -0.006 94 4190 0.0392 0.0304 68 Toluene 91 13.251 13.254 -0.003 94 12057 0.0392 0.0357 69 1,1,2-Trichloroethane 83 13.311 13.308 0.003 91 4124 0.0392 0.0402 70 2-Methylthiophene 97 13.397 13.402 -0.005 97 9317 0.0392 0.0352 71 3-Methylthiophene 97 13.618 13.612 0.006 98 9027 0.0392 0.0348 72 2-Hexanone 58 13.742 13.736 0.006 91 2995 0.0392 0.0254 73 Chlorodibromomethane 129 14.017 14.025 -0.008 92 5530 0.0392 0.0298 74 n-Octane 85 14.039 14.045 -0.006 91 3716 0.0392 0.0379 75 Ethylene Dibromide 107 14.319 14.320 -0.001 98 6121 0.0392 0.0352 76 Tetrachloroethene 129 14.438 14.441 -0.003 92 5027 0.0392 0.0407 77 Chlorobenzene 112 15.327 15.330 -0.003 92 12568 0.0392 0.0440 78 2,3-Dimethylheptane 43 15.430 15.432 -0.002 95 12792 0.0392 0.0390 79 Ethylbenzene 91 15.646 15.647 -0.001 98 15913 0.0392 0.0373 80 2-Ethylthiophene 97 15.743 15.744 -0.001 98 10329 0.0392 0.0344 81 m-Xylene & p-Xylene 91 15.813 15.819 -0.006 98 24763 0.0784 0.0765 82 Bromoform 173 16.223 16.221 0.001 95 3731 0.0392 0.0174 83 Styrene 104 16.282 16.282 0.000 95 6331 0.0392 0.0295 84 n-Nonane 57 16.309 16.312 -0.003 88 7935 0.0392 0.0363 85 o-Xylene 91 16.341 16.347 -0.006 97 13569 0.0392 0.0396 03/21/2017Page 223 of 377 Report Date: 24-Feb-2017 16:53:45 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC01.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 86 1,1,2,2-Tetrachloroethane 83 16.654 16.658 -0.004 96 9597 0.0392 0.0381 87 1,2,3-Trichloropropane 110 16.821 16.819 0.002 93 2560 0.0392 0.0356 88 Isopropylbenzene 105 16.961 16.963 -0.002 47 21309 0.0392 0.0450 89 N-Propylbenzene 120 17.538 17.540 -0.002 99 4695 0.0392 0.0373 90 2-Chlorotoluene 126 17.560 17.565 -0.005 91 4959 0.0392 0.0404 91 4-Ethyltoluene 105 17.705 17.706 -0.001 98 16133 0.0392 0.0345 92 1,3,5-Trimethylbenzene 120 17.792 17.790 0.002 93 8222 0.0392 0.0382 93 Alpha Methyl Styrene 118 18.034 18.031 0.003 85 4899 0.0392 0.0275 94 n-Decane 57 18.153 18.157 -0.004 87 8489 0.0392 0.0294 95 tert-Butylbenzene 119 18.239 18.240 -0.001 91 15162 0.0392 0.0356 96 1,2,4-Trimethylbenzene 105 18.255 18.256 -0.001 95 14614 0.0392 0.0365 97 1,3-Dichlorobenzene 146 18.520 18.520 0.000 93 13459 0.0392 0.0417 98 sec-Butylbenzene 105 18.530 18.532 -0.002 99 23058 0.0392 0.0387 99 Benzyl chloride 91 18.595 18.596 -0.001 96 10340 0.0392 0.0296 100 1,4-Dichlorobenzene 146 18.617 18.614 0.003 95 13115 0.0392 0.0397 101 4-Isopropyltoluene 119 18.708 18.710 -0.002 95 17315 0.0392 0.0352 102 1,2,3-Trimethylbenzene 105 18.752 18.751 0.001 96 11856 0.0392 0.0369 103 Butylcyclohexane 83 18.838 18.840 -0.002 88 11900 0.0392 0.0361 104 1,2-Dichlorobenzene 146 18.989 18.990 -0.001 95 12467 0.0392 0.0395 105 2,3-Dihydroindene 117 19.000 19.001 -0.001 91 15346 0.0392 0.0418 106 Indene 116 19.134 19.134 0.000 89 8660 0.0392 0.0322 107 n-Butylbenzene 91 19.172 19.173 -0.001 97 18884 0.0392 0.0357 108 Undecane 57 19.555 19.552 0.003 91 10476 0.0392 0.0314 109 1,2-Dimethyl-4-Ethylbenzen 119 19.566 19.566 0.000 98 12811 0.0392 0.0320 110 1,2-Dibromo-3-Chloropropan 157 19.620 19.620 0.000 87 1980 0.0392 0.0145 111 1,2,4,5-Tetramethylbenzene 119 19.970 19.970 0.000 99 14565 0.0392 0.0321 112 1,2,3,5-Tetramethylbenzene 119 20.024 20.024 0.000 95 10058 0.0392 0.0349 113 1,2,3,4-Tetramethylbenzene 119 20.429 20.429 0.000 96 13304 0.0392 0.0343 114 Dodecane 57 20.655 20.656 -0.001 90 7675 0.0392 0.0223 115 1,2,4-Trichlorobenzene 180 20.774 20.779 -0.005 90 10453 0.0392 0.0308 116 Naphthalene 128 20.914 20.913 0.001 99 17639 0.0392 0.0296 117 Benzo(b)thiophene 134 21.011 21.015 -0.004 98 9215 0.0392 0.0260 118 Hexachlorobutadiene 225 21.167 21.166 0.001 91 11976 0.0392 0.0349 119 1,2,3-Trichlorobenzene 180 21.205 21.207 -0.002 93 11357 0.0392 0.0339 A 122 C6 Range 1 7.591 (7.562-7.619) 0 35507 0.0392 0.0468 S 124 Xylenes, Total 100 0 0.1176 0.1161 S 125 1,2-Dichloroethene, Total 1 0 0.0784 0.0802 Reagents: 40L12DNP_00009 Amount Added: 100.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 224 of 377 Report Date: 24-Feb-2017 16:53:45 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC01.D Injection Date:23-Feb-2017 22:59:30 Instrument ID:MR Operator ID: Lims ID:IC L1 Worklist Smp#:3 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:2 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 Y ( X10 0 0 0 0 ) RB23IC01[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 1 5 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 8 3 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 7 9 ) $ 4 - B r o m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 7 )+ 03/21/2017Page 225 of 377 Report Date: 24-Feb-2017 16:53:46 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC01.D Injection Date:23-Feb-2017 22:59:30 Instrument ID:MR Lims ID:IC L1 Client ID: Operator ID:ALS Bottle#:2 Worklist Smp#:3 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 122 C6 Range, CAS: STL01725 7.5 Min 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 Y ( X10 0 0 ) RB23IC01[MS SCAN Chro]:Total 03/21/2017Page 226 of 377 Report Date: 24-Feb-2017 16:53:49 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC02.D Lims ID:IC L2 Client ID: Sample Type:IC Calib Level:2 Inject. Date:23-Feb-2017 23:47:30 ALS Bottle#:3 Worklist Smp#:4 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004095-004 Misc. Info.:073145 Operator ID:Instrument ID:MR Sublist:chrom-MR_TO15*sub7 Method:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:24-Feb-2017 16:53:48 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK010 First Level Reviewer: barlozhetskayaa Date:24-Feb-2017 15:34:04 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.215 8.227 -0.012 96 338821 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.383 10.390 -0.007 94 1623488 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.279 15.280 -0.001 88 1280909 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.967 16.970 -0.003 95 906481 4.00 4.05 6 Chlorodifluoromethane 67 3.728 3.720 0.008 96 2717 0.0784 0.0868 7 Propene 41 3.728 3.722 0.006 65 10961 0.0784 0.0903 8 Dichlorodifluoromethane 85 3.777 3.772 0.005 99 17064 0.0784 0.0750 9 Chloromethane 52 3.928 3.920 0.008 100 3879 0.0784 0.0977 10 1,2-Dichloro-1,1,2,2-tetra 135 3.944 3.945 -0.001 91 17577 0.0784 0.0837 11 Acetaldehyde 44 4.063 4.063 0.000 91 41613 0.3920 1.14 12 Vinyl chloride 62 4.074 4.069 0.005 93 9178 0.0784 0.0969 13 Butadiene 54 4.149 4.150 -0.001 73 5991 0.0784 0.0915 14 Butane 43 4.154 4.152 0.002 82 13345 0.0784 0.1075 15 Bromomethane 94 4.408 4.409 -0.001 96 7587 0.0784 0.1034 16 Chloroethane 64 4.526 4.534 -0.008 89 3707 0.0784 0.1059 17 Ethanol 31 4.640 4.648 -0.008 99 17404 0.3920 0.7101 18 Vinyl bromide 106 4.785 4.790 -0.005 96 6285 0.0784 0.1008 19 2-Methylbutane 43 4.850 4.848 0.002 86 7289 0.0784 0.1119 20 Acrolein 56 5.028 5.025 0.003 33 3778 0.0784 0.1609 21 Trichlorofluoromethane 101 5.023 5.030 -0.007 98 23821 0.0784 0.0860 22 Acetonitrile 40 5.077 5.075 0.001 63 304 0.0784 0.007005 23 Acetone 58 5.130 5.124 0.006 100 16793 0.2352 0.3012 24 Isopropyl alcohol 45 5.222 5.227 -0.005 82 41645 0.2352 0.2504 25 Pentane 72 5.217 5.229 -0.012 75 1645 0.0784 0.0853 26 Ethyl ether 31 5.373 5.367 0.006 91 11321 0.0784 0.0845 27 1,1-Dichloroethene 96 5.627 5.629 -0.002 97 7940 0.0784 0.0763 28 Acrylonitrile 53 5.702 5.705 -0.003 93 6120 0.0784 0.0722 29 2-Methyl-2-propanol 59 5.740 5.739 0.001 97 14062 0.0784 0.0703 30 1,1,2-Trichloro-1,2,2-trif 101 5.804 5.809 -0.005 96 19568 0.0784 0.0838 31 Methylene Chloride 84 5.907 5.920 -0.013 98 15000 0.0784 0.1419 03/21/2017Page 227 of 377 Report Date: 24-Feb-2017 16:53:49 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC02.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.934 5.942 -0.008 93 10459 0.0784 0.0992 33 Carbon disulfide 76 6.058 6.062 -0.004 98 24521 0.0784 0.0817 34 trans-1,2-Dichloroethene 96 6.646 6.657 -0.011 97 8529 0.0784 0.0799 35 2-Methylpentane 43 6.700 6.705 -0.005 95 19784 0.0784 0.0780 36 Methyl tert-butyl ether 73 6.797 6.785 0.012 96 19619 0.0784 0.0722 37 1,1-Dichloroethane 63 7.007 7.023 -0.016 98 16227 0.0784 0.0771 38 Vinyl acetate 43 7.131 7.135 -0.004 99 20132 0.0784 0.0668 39 2-Butanone (MEK) 72 7.525 7.522 0.003 96 3345 0.0784 0.0657 40 Hexane 56 7.611 7.610 0.001 89 7570 0.0784 0.0798 41 Isopropyl ether 45 7.751 7.748 0.003 98 31711 0.0784 0.0773 42 cis-1,2-Dichloroethene 96 7.924 7.930 -0.006 94 8483 0.0784 0.0764 43 Ethyl acetate 43 8.123 8.118 0.005 98 18439 0.0784 0.0707 44 Chloroform 83 8.247 8.258 -0.011 91 18094 0.0784 0.0795 45 Tert-butyl ethyl ether 59 8.382 8.381 0.001 96 21950 0.0784 0.0686 46 Tetrahydrofuran 42 8.630 8.621 0.009 91 11358 0.0784 0.0815 47 1,1,1-Trichloroethane 97 9.234 9.239 -0.005 97 16424 0.0784 0.0760 48 1,2-Dichloroethane 62 9.299 9.311 -0.012 98 11614 0.0784 0.0770 49 n-Butanol 31 9.827 9.810 0.017 69 3455 0.0784 0.0778 50 Benzene 78 9.816 9.821 -0.005 97 24674 0.0784 0.0839 51 Cyclohexane 69 9.849 9.849 0.000 89 3521 0.0784 0.0752 52 Carbon tetrachloride 117 9.860 9.860 0.000 91 16905 0.0784 0.0758 53 2,3-Dimethylpentane 71 10.005 10.009 -0.004 92 5491 0.0784 0.0791 54 Thiophene 84 10.075 10.088 -0.013 95 13654 0.0784 0.0774 55 Tert-amyl methyl ether 73 10.350 10.344 0.006 62 13931 0.0784 0.0506 56 Isooctane 57 10.668 10.676 -0.008 97 39986 0.0784 0.0741 57 1,2-Dichloropropane 63 11.051 11.062 -0.011 69 10585 0.0784 0.0840 58 n-Heptane 71 11.062 11.070 -0.008 82 7240 0.0784 0.0697 59 Trichloroethene 130 11.121 11.125 -0.004 94 12147 0.0784 0.0845 60 Dibromomethane 93 11.164 11.169 -0.005 89 10628 0.0784 0.0823 61 Dichlorobromomethane 83 11.332 11.338 -0.006 96 15268 0.0784 0.0722 62 1,4-Dioxane 88 11.348 11.347 0.001 39 3097 0.0784 0.0708 63 Methyl methacrylate 41 11.477 11.473 0.004 96 9311 0.0784 0.0647 64 Methylcyclohexane 83 11.946 11.948 -0.002 93 15346 0.0784 0.0709 65 4-Methyl-2-pentanone (MIBK 43 12.345 12.341 0.004 97 18554 0.0784 0.0703 66 cis-1,3-Dichloropropene 75 12.389 12.389 0.000 98 11393 0.0784 0.0690 67 trans-1,3-Dichloropropene 75 13.111 13.112 -0.001 96 9323 0.0784 0.0657 68 Toluene 91 13.251 13.254 -0.003 94 28273 0.0784 0.0813 69 1,1,2-Trichloroethane 83 13.300 13.308 -0.008 94 8704 0.0784 0.0823 70 2-Methylthiophene 97 13.397 13.402 -0.005 96 20397 0.0784 0.0748 71 3-Methylthiophene 97 13.607 13.612 -0.005 98 19973 0.0784 0.0747 72 2-Hexanone 58 13.737 13.736 0.001 92 6657 0.0784 0.0547 73 Chlorodibromomethane 129 14.017 14.025 -0.008 97 11521 0.0784 0.0603 74 n-Octane 85 14.044 14.045 -0.001 96 7061 0.0784 0.0699 75 Ethylene Dibromide 107 14.314 14.320 -0.006 96 13427 0.0784 0.0750 76 Tetrachloroethene 129 14.438 14.441 -0.003 92 10747 0.0784 0.0845 77 Chlorobenzene 112 15.333 15.330 0.003 96 24800 0.0784 0.0842 78 2,3-Dimethylheptane 43 15.430 15.432 -0.002 96 26084 0.0784 0.0772 79 Ethylbenzene 91 15.646 15.647 -0.001 98 35993 0.0784 0.0820 80 2-Ethylthiophene 97 15.743 15.744 -0.001 97 22924 0.0784 0.0740 81 m-Xylene & p-Xylene 91 15.824 15.819 0.005 99 54395 0.1568 0.1630 82 Bromoform 173 16.217 16.221 -0.004 95 7456 0.0784 0.0338 83 Styrene 104 16.276 16.282 -0.006 95 14364 0.0784 0.0650 03/21/2017Page 228 of 377 Report Date: 24-Feb-2017 16:53:49 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC02.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 84 n-Nonane 57 16.309 16.312 -0.003 93 17094 0.0784 0.0759 85 o-Xylene 91 16.347 16.347 0.000 99 28924 0.0784 0.0820 86 1,1,2,2-Tetrachloroethane 83 16.659 16.658 0.001 98 21006 0.0784 0.0810 87 1,2,3-Trichloropropane 110 16.821 16.819 0.002 92 5974 0.0784 0.0806 88 Isopropylbenzene 105 16.961 16.963 -0.002 94 42366 0.0784 0.0867 89 N-Propylbenzene 120 17.544 17.540 0.004 99 10216 0.0784 0.0787 90 2-Chlorotoluene 126 17.560 17.565 -0.005 93 10999 0.0784 0.0869 91 4-Ethyltoluene 105 17.705 17.706 -0.001 99 37169 0.0784 0.0772 92 1,3,5-Trimethylbenzene 120 17.792 17.790 0.002 94 17741 0.0784 0.0801 93 Alpha Methyl Styrene 118 18.034 18.031 0.003 85 10687 0.0784 0.0583 94 n-Decane 57 18.158 18.157 0.001 91 21274 0.0784 0.0715 95 tert-Butylbenzene 119 18.239 18.240 -0.001 94 35984 0.0784 0.0821 96 1,2,4-Trimethylbenzene 105 18.255 18.256 -0.001 95 33025 0.0784 0.0801 97 1,3-Dichlorobenzene 146 18.520 18.520 0.000 97 28396 0.0784 0.0853 98 sec-Butylbenzene 105 18.530 18.532 -0.002 98 50165 0.0784 0.0818 99 Benzyl chloride 91 18.595 18.596 -0.001 98 24103 0.0784 0.0669 100 1,4-Dichlorobenzene 146 18.611 18.614 -0.003 97 29121 0.0784 0.0855 101 4-Isopropyltoluene 119 18.708 18.710 -0.002 95 38119 0.0784 0.0751 102 1,2,3-Trimethylbenzene 105 18.746 18.751 -0.005 96 25401 0.0784 0.0768 103 Butylcyclohexane 83 18.838 18.840 -0.002 92 27451 0.0784 0.0807 104 1,2-Dichlorobenzene 146 18.989 18.990 -0.001 97 28172 0.0784 0.0866 105 2,3-Dihydroindene 117 19.000 19.001 -0.001 91 31320 0.0784 0.0829 106 Indene 116 19.134 19.134 0.000 88 19489 0.0784 0.0704 107 n-Butylbenzene 91 19.172 19.173 -0.001 96 42432 0.0784 0.0780 108 Undecane 57 19.550 19.552 -0.002 94 24349 0.0784 0.0709 109 1,2-Dimethyl-4-Ethylbenzen 119 19.566 19.566 0.000 99 29259 0.0784 0.0710 110 1,2-Dibromo-3-Chloropropan 157 19.614 19.620 -0.006 89 4005 0.0784 0.0284 111 1,2,4,5-Tetramethylbenzene 119 19.970 19.970 0.000 99 33459 0.0784 0.0715 112 1,2,3,5-Tetramethylbenzene 119 20.019 20.024 -0.005 98 20887 0.0784 0.0703 113 1,2,3,4-Tetramethylbenzene 119 20.429 20.429 0.000 97 26921 0.0784 0.0674 114 Dodecane 57 20.655 20.656 -0.001 95 19723 0.0784 0.0556 115 1,2,4-Trichlorobenzene 180 20.779 20.779 0.000 92 23444 0.0784 0.0671 116 Naphthalene 128 20.909 20.913 -0.005 99 41077 0.0784 0.0670 117 Benzo(b)thiophene 134 21.016 21.015 0.001 99 21284 0.0784 0.0582 118 Hexachlorobutadiene 225 21.167 21.166 0.001 76 25833 0.0784 0.0731 119 1,2,3-Trichlorobenzene 180 21.205 21.207 -0.002 95 24088 0.0784 0.0698 121 1-Methylnaphthalene 142 22.057 22.052 0.005 13 483 0.2450 0.0122 A 122 C6 Range 1 7.601 (7.557-7.624) 0 66015 0.0784 0.0830 S 124 Xylenes, Total 100 0 0.2352 0.2450 S 125 1,2-Dichloroethene, Total 1 0 0.1568 0.1563 Reagents: 40L12DNP_00009 Amount Added: 200.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 229 of 377 Report Date: 24-Feb-2017 16:53:49 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC02.D Injection Date:23-Feb-2017 23:47:30 Instrument ID:MR Operator ID: Lims ID:IC L2 Worklist Smp#:4 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:3 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 Y ( X10 0 0 0 0 ) RB23IC02[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 1 5 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 8 3 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 7 9 ) $ 4 - B r o m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 7 )+ 03/21/2017Page 230 of 377 Report Date: 24-Feb-2017 16:53:49 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC02.D Injection Date:23-Feb-2017 23:47:30 Instrument ID:MR Lims ID:IC L2 Client ID: Operator ID:ALS Bottle#:3 Worklist Smp#:4 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 122 C6 Range, CAS: STL01725 7.5 Min 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 Y ( X10 0 0 ) RB23IC02[MS SCAN Chro]:Total 03/21/2017Page 231 of 377 Report Date: 24-Feb-2017 16:53:52 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC03.D Lims ID:IC L3 Client ID: Sample Type:IC Calib Level:3 Inject. Date:24-Feb-2017 00:35:30 ALS Bottle#:4 Worklist Smp#:5 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004095-005 Misc. Info.:073146 Operator ID:Instrument ID:MR Sublist:chrom-MR_TO15*sub7 Method:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:24-Feb-2017 16:53:51 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK010 First Level Reviewer: barlozhetskayaa Date:24-Feb-2017 16:22:09 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.220 8.227 -0.007 95 356695 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.383 10.390 -0.007 94 1705319 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.279 15.280 -0.001 88 1367427 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.967 16.970 -0.003 95 979197 4.00 4.10 6 Chlorodifluoromethane 67 3.729 3.720 0.009 97 5714 0.1587 0.1734 7 Propene 41 3.729 3.722 0.007 69 23326 0.1587 0.1825 8 Dichlorodifluoromethane 85 3.777 3.772 0.005 99 36597 0.1587 0.1528 9 Chloromethane 52 3.917 3.920 -0.003 100 8569 0.1587 0.2051 10 1,2-Dichloro-1,1,2,2-tetra 135 3.950 3.945 0.005 92 37159 0.1587 0.1681 11 Acetaldehyde 44 4.063 4.063 0.000 92 64604 0.7933 1.68 12 Vinyl chloride 62 4.074 4.069 0.005 51 19490 0.1587 0.1955 13 Butadiene 54 4.155 4.150 0.005 64 13682 0.1587 0.1984 14 Butane 43 4.155 4.152 0.003 85 27776 0.1587 0.2125 15 Bromomethane 94 4.413 4.409 0.004 97 13592 0.1587 0.1760 16 Chloroethane 64 4.532 4.534 -0.002 86 7552 0.1587 0.2050 17 Ethanol 31 4.640 4.648 -0.008 100 28254 0.7933 1.10 18 Vinyl bromide 106 4.785 4.790 -0.005 95 12508 0.1587 0.1905 19 2-Methylbutane 43 4.850 4.848 0.002 87 15885 0.1587 0.2317 20 Acrolein 56 5.028 5.025 0.003 32 5620 0.1587 0.2273 21 Trichlorofluoromethane 101 5.028 5.030 -0.002 98 48923 0.1587 0.1678 22 Acetonitrile 40 5.071 5.075 -0.004 97 7850 0.1587 0.1718 23 Acetone 58 5.125 5.124 0.001 98 42286 0.4760 0.7204 24 Isopropyl alcohol 45 5.217 5.227 -0.010 92 79216 0.4760 0.4525 25 Pentane 72 5.233 5.229 0.004 97 3141 0.1587 0.1548 26 Ethyl ether 31 5.373 5.367 0.006 92 21897 0.1587 0.1552 27 1,1-Dichloroethene 96 5.621 5.629 -0.008 97 17158 0.1587 0.1565 28 Acrylonitrile 53 5.708 5.705 0.003 95 13790 0.1587 0.1545 29 2-Methyl-2-propanol 59 5.740 5.739 0.001 96 32099 0.1587 0.1524 30 1,1,2-Trichloro-1,2,2-trif 101 5.810 5.809 0.001 96 39781 0.1587 0.1619 31 Methylene Chloride 84 5.918 5.920 -0.002 98 24437 0.1587 0.2196 03/21/2017Page 232 of 377 Report Date: 24-Feb-2017 16:53:52 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC03.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.939 5.942 -0.003 95 15254 0.1587 0.1374 33 Carbon disulfide 76 6.058 6.062 -0.004 99 48557 0.1587 0.1536 34 trans-1,2-Dichloroethene 96 6.657 6.657 0.000 96 17802 0.1587 0.1584 35 2-Methylpentane 43 6.705 6.705 0.000 95 39985 0.1587 0.1497 36 Methyl tert-butyl ether 73 6.786 6.785 0.001 95 41384 0.1587 0.1446 37 1,1-Dichloroethane 63 7.018 7.023 -0.005 99 34133 0.1587 0.1541 38 Vinyl acetate 43 7.131 7.135 -0.004 100 42788 0.1587 0.1348 39 2-Butanone (MEK) 72 7.525 7.522 0.003 98 8574 0.1587 0.1599 40 Hexane 56 7.611 7.610 0.001 90 15546 0.1587 0.1557 41 Isopropyl ether 45 7.751 7.748 0.003 97 66313 0.1587 0.1535 42 cis-1,2-Dichloroethene 96 7.913 7.930 -0.017 95 18985 0.1587 0.1625 43 Ethyl acetate 43 8.118 8.118 0.000 98 38908 0.1587 0.1417 44 Chloroform 83 8.247 8.258 -0.011 94 36917 0.1587 0.1540 45 Tert-butyl ethyl ether 59 8.382 8.381 0.001 97 49137 0.1587 0.1458 46 Tetrahydrofuran 42 8.625 8.621 0.004 96 23309 0.1587 0.1588 47 1,1,1-Trichloroethane 97 9.234 9.239 -0.005 97 32033 0.1587 0.1408 48 1,2-Dichloroethane 62 9.310 9.311 -0.001 96 22850 0.1587 0.1442 49 n-Butanol 31 9.817 9.810 0.007 66 6173 0.1587 0.1323 50 Benzene 78 9.817 9.821 -0.004 97 48907 0.1587 0.1584 51 Cyclohexane 69 9.849 9.849 0.000 94 7234 0.1587 0.1471 52 Carbon tetrachloride 117 9.854 9.860 -0.006 97 34144 0.1587 0.1457 53 2,3-Dimethylpentane 71 10.011 10.009 0.002 91 11183 0.1587 0.1534 54 Thiophene 84 10.086 10.088 -0.002 95 28426 0.1587 0.1534 55 Tert-amyl methyl ether 73 10.350 10.344 0.006 96 46518 0.1587 0.1608 56 Isooctane 57 10.679 10.676 0.003 98 87619 0.1587 0.1546 57 1,2-Dichloropropane 63 11.062 11.062 0.000 67 20327 0.1587 0.1535 58 n-Heptane 71 11.068 11.070 -0.002 90 17517 0.1587 0.1605 59 Trichloroethene 130 11.122 11.125 -0.003 93 23873 0.1587 0.1580 60 Dibromomethane 93 11.165 11.169 -0.004 87 20765 0.1587 0.1531 61 Dichlorobromomethane 83 11.332 11.338 -0.006 98 30527 0.1587 0.1374 62 1,4-Dioxane 88 11.353 11.347 0.006 95 7308 0.1587 0.1591 63 Methyl methacrylate 41 11.472 11.473 -0.001 95 20422 0.1587 0.1351 64 Methylcyclohexane 83 11.941 11.948 -0.007 90 34127 0.1587 0.1502 65 4-Methyl-2-pentanone (MIBK 43 12.340 12.341 -0.001 97 39845 0.1587 0.1438 66 cis-1,3-Dichloropropene 75 12.389 12.389 0.000 98 24970 0.1587 0.1440 67 trans-1,3-Dichloropropene 75 13.111 13.112 -0.001 96 20070 0.1587 0.1324 68 Toluene 91 13.252 13.254 -0.002 94 56866 0.1587 0.1532 69 1,1,2-Trichloroethane 83 13.305 13.308 -0.003 96 17701 0.1587 0.1568 70 2-Methylthiophene 97 13.397 13.402 -0.005 97 43887 0.1587 0.1508 71 3-Methylthiophene 97 13.607 13.612 -0.005 100 41936 0.1587 0.1470 72 2-Hexanone 58 13.742 13.736 0.006 92 15939 0.1587 0.1227 73 Chlorodibromomethane 129 14.023 14.025 -0.002 96 29500 0.1587 0.1447 74 n-Octane 85 14.044 14.045 -0.001 95 16610 0.1587 0.1541 75 Ethylene Dibromide 107 14.319 14.320 -0.001 97 28588 0.1587 0.1495 76 Tetrachloroethene 129 14.438 14.441 -0.003 92 22616 0.1587 0.1665 77 Chlorobenzene 112 15.333 15.330 0.003 98 52626 0.1587 0.1674 78 2,3-Dimethylheptane 43 15.430 15.432 -0.002 96 58055 0.1587 0.1610 79 Ethylbenzene 91 15.646 15.647 -0.001 98 74659 0.1587 0.1593 80 2-Ethylthiophene 97 15.743 15.744 -0.001 97 49896 0.1587 0.1509 81 m-Xylene & p-Xylene 91 15.818 15.819 -0.001 100 117759 0.3173 0.3305 82 Bromoform 173 16.217 16.221 -0.004 97 33288 0.1587 0.1413 83 Styrene 104 16.282 16.282 0.000 96 34579 0.1587 0.1466 03/21/2017Page 233 of 377 Report Date: 24-Feb-2017 16:53:52 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC03.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 84 n-Nonane 57 16.314 16.312 0.002 96 40483 0.1587 0.1683 85 o-Xylene 91 16.347 16.347 0.000 97 63625 0.1587 0.1690 86 1,1,2,2-Tetrachloroethane 83 16.654 16.658 -0.004 99 46111 0.1587 0.1666 87 1,2,3-Trichloropropane 110 16.816 16.819 -0.003 95 12366 0.1587 0.1562 88 Isopropylbenzene 105 16.961 16.963 -0.002 95 88577 0.1587 0.1699 89 N-Propylbenzene 120 17.538 17.540 -0.002 99 23946 0.1587 0.1728 90 2-Chlorotoluene 126 17.565 17.565 0.000 94 24877 0.1587 0.1840 91 4-Ethyltoluene 105 17.706 17.706 0.000 98 85126 0.1587 0.1655 92 1,3,5-Trimethylbenzene 120 17.786 17.790 -0.004 93 40452 0.1587 0.1711 93 Alpha Methyl Styrene 118 18.029 18.031 -0.002 90 27013 0.1587 0.1380 94 n-Decane 57 18.153 18.157 -0.004 89 50999 0.1587 0.1605 95 tert-Butylbenzene 119 18.239 18.240 -0.001 93 79403 0.1587 0.1696 96 1,2,4-Trimethylbenzene 105 18.256 18.256 0.000 96 76518 0.1587 0.1739 97 1,3-Dichlorobenzene 146 18.520 18.520 0.000 95 62501 0.1587 0.1759 98 sec-Butylbenzene 105 18.531 18.532 -0.001 99 108474 0.1587 0.1656 99 Benzyl chloride 91 18.595 18.596 -0.001 98 54066 0.1587 0.1406 100 1,4-Dichlorobenzene 146 18.612 18.614 -0.002 97 65142 0.1587 0.1791 101 4-Isopropyltoluene 119 18.709 18.710 -0.001 95 87284 0.1587 0.1612 102 1,2,3-Trimethylbenzene 105 18.752 18.751 0.001 97 57972 0.1587 0.1641 103 Butylcyclohexane 83 18.838 18.840 -0.002 91 57754 0.1587 0.1591 104 1,2-Dichlorobenzene 146 18.989 18.990 -0.001 97 60572 0.1587 0.1744 105 2,3-Dihydroindene 117 19.000 19.001 -0.001 94 70331 0.1587 0.1743 106 Indene 116 19.135 19.134 0.001 90 45019 0.1587 0.1523 107 n-Butylbenzene 91 19.172 19.173 -0.001 98 93087 0.1587 0.1602 108 Undecane 57 19.550 19.552 -0.002 96 58652 0.1587 0.1600 109 1,2-Dimethyl-4-Ethylbenzen 119 19.566 19.566 0.000 99 68884 0.1587 0.1565 110 1,2-Dibromo-3-Chloropropan 157 19.620 19.620 0.000 90 21869 0.1587 0.1453 111 1,2,4,5-Tetramethylbenzene 119 19.970 19.970 0.000 99 76370 0.1587 0.1528 112 1,2,3,5-Tetramethylbenzene 119 20.024 20.024 0.000 96 46686 0.1587 0.1472 113 1,2,3,4-Tetramethylbenzene 119 20.429 20.429 0.000 99 65134 0.1587 0.1527 114 Dodecane 57 20.655 20.656 -0.001 93 55647 0.1587 0.1470 115 1,2,4-Trichlorobenzene 180 20.779 20.779 0.000 92 58530 0.1587 0.1570 116 Naphthalene 128 20.909 20.913 -0.004 99 104007 0.1587 0.1589 117 Benzo(b)thiophene 134 21.017 21.015 0.002 100 55059 0.1587 0.1410 118 Hexachlorobutadiene 225 21.162 21.166 -0.004 93 59398 0.1587 0.1576 119 1,2,3-Trichlorobenzene 180 21.211 21.207 0.004 95 59506 0.1587 0.1616 120 2-Methylnaphthalene 142 21.928 21.929 -0.001 96 7717 0.4958 0.1348 121 1-Methylnaphthalene 142 22.052 22.052 0.000 94 7607 0.4958 0.1795 A 122 C6 Range 1 7.606 (7.568-7.635) 0 146672 0.1587 0.1756 S 124 Xylenes, Total 100 0 0.4760 0.4995 S 125 1,2-Dichloroethene, Total 1 0 0.3173 0.3209 Reagents: 40L3DNP_00010 Amount Added: 200.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 234 of 377 Report Date: 24-Feb-2017 16:53:52 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC03.D Injection Date:24-Feb-2017 00:35:30 Instrument ID:MR Operator ID: Lims ID:IC L3 Worklist Smp#:5 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:4 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 Y ( X10 0 0 0 0 ) RB23IC03[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 2 0 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 8 3 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 7 9 ) $ 4 - B r o m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 7 )+ 03/21/2017Page 235 of 377 Report Date: 24-Feb-2017 16:53:52 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC03.D Injection Date:24-Feb-2017 00:35:30 Instrument ID:MR Lims ID:IC L3 Client ID: Operator ID:ALS Bottle#:4 Worklist Smp#:5 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 122 C6 Range, CAS: STL01725 7.5 Min 8 12 16 20 24 28 32 36 40 44 48 52 56 60 64 68 Y ( X10 0 0 ) RB23IC03[MS SCAN Chro]:Total 03/21/2017Page 236 of 377 Report Date: 24-Feb-2017 16:53:56 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC04.D Lims ID:IC L4 Client ID: Sample Type:IC Calib Level:4 Inject. Date:24-Feb-2017 01:23:30 ALS Bottle#:5 Worklist Smp#:6 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004095-006 Misc. Info.:073144 Operator ID:Instrument ID:MR Sublist:chrom-MR_TO15*sub7 Method:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:24-Feb-2017 16:53:55 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK010 First Level Reviewer: tajh Date:24-Feb-2017 09:23:41 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.220 8.227 -0.007 96 361598 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.388 10.390 -0.002 95 1734799 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.279 15.280 -0.001 88 1398187 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.967 16.970 -0.003 95 1010124 4.00 4.14 6 Chlorodifluoromethane 67 3.723 3.720 0.003 97 13525 0.4000 0.4049 7 Propene 41 3.723 3.722 0.001 96 57519 0.4000 0.4440 8 Dichlorodifluoromethane 85 3.772 3.772 0.000 99 97168 0.4000 0.4002 9 Chloromethane 52 3.917 3.920 -0.003 99 18083 0.4000 0.4270 10 1,2-Dichloro-1,1,2,2-tetra 135 3.944 3.945 -0.001 91 98824 0.4000 0.4411 11 Acetaldehyde 44 4.058 4.063 -0.005 97 127965 2.00 3.27 12 Vinyl chloride 62 4.068 4.069 -0.001 99 47210 0.4000 0.4672 13 Butadiene 54 4.149 4.150 -0.001 89 34439 0.4000 0.4926 14 Butane 43 4.149 4.152 -0.003 91 70015 0.4000 0.5284 15 Bromomethane 94 4.403 4.409 -0.006 97 36351 0.4000 0.4644 16 Chloroethane 64 4.532 4.534 -0.002 94 17265 0.4000 0.4624 17 Ethanol 31 4.635 4.648 -0.013 98 66047 2.00 2.52 18 Vinyl bromide 106 4.786 4.790 -0.004 96 29539 0.4000 0.4438 19 2-Methylbutane 43 4.845 4.848 -0.003 86 34784 0.4000 0.5004 20 Acrolein 56 5.023 5.025 -0.002 30 10830 0.4000 0.4321 21 Trichlorofluoromethane 101 5.023 5.030 -0.007 99 124033 0.4000 0.4197 22 Acetonitrile 40 5.066 5.075 -0.009 99 20501 0.4000 0.4427 23 Acetone 58 5.120 5.124 -0.004 98 100931 1.20 1.70 24 Isopropyl alcohol 45 5.217 5.227 -0.010 92 218989 1.20 1.23 25 Pentane 72 5.228 5.229 -0.001 94 8034 0.4000 0.3905 26 Ethyl ether 31 5.363 5.367 -0.004 92 60129 0.4000 0.4203 27 1,1-Dichloroethene 96 5.621 5.629 -0.008 98 43941 0.4000 0.3954 28 Acrylonitrile 53 5.702 5.705 -0.003 97 35238 0.4000 0.3895 29 2-Methyl-2-propanol 59 5.729 5.739 -0.010 97 81188 0.4000 0.3802 30 1,1,2-Trichloro-1,2,2-trif 101 5.799 5.809 -0.010 96 102072 0.4000 0.4098 31 Methylene Chloride 84 5.907 5.920 -0.013 98 48158 0.4000 0.4270 03/21/2017Page 237 of 377 Report Date: 24-Feb-2017 16:53:56 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC04.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.934 5.942 -0.008 94 43032 0.4000 0.3823 33 Carbon disulfide 76 6.053 6.062 -0.009 99 126789 0.4000 0.3957 34 trans-1,2-Dichloroethene 96 6.651 6.657 -0.006 98 45618 0.4000 0.4005 35 2-Methylpentane 43 6.705 6.705 0.000 96 109374 0.4000 0.4040 36 Methyl tert-butyl ether 73 6.781 6.785 -0.004 97 110998 0.4000 0.3827 37 1,1-Dichloroethane 63 7.013 7.023 -0.010 100 85892 0.4000 0.3826 38 Vinyl acetate 43 7.131 7.135 -0.004 100 123061 0.4000 0.3825 39 2-Butanone (MEK) 72 7.519 7.522 -0.003 98 22992 0.4000 0.4230 40 Hexane 56 7.606 7.610 -0.004 90 39451 0.4000 0.3896 41 Isopropyl ether 45 7.741 7.748 -0.007 98 176808 0.4000 0.4038 42 cis-1,2-Dichloroethene 96 7.924 7.930 -0.006 95 46105 0.4000 0.3892 43 Ethyl acetate 43 8.113 8.118 -0.005 98 109869 0.4000 0.3946 44 Chloroform 83 8.253 8.258 -0.005 96 92987 0.4000 0.3826 45 Tert-butyl ethyl ether 59 8.377 8.381 -0.004 97 131350 0.4000 0.3846 46 Tetrahydrofuran 42 8.620 8.621 -0.001 96 59200 0.4000 0.3980 47 1,1,1-Trichloroethane 97 9.234 9.239 -0.005 97 84191 0.4000 0.3651 48 1,2-Dichloroethane 62 9.304 9.311 -0.007 96 59318 0.4000 0.3679 49 n-Butanol 31 9.806 9.810 -0.004 63 16572 0.4000 0.3492 50 Benzene 78 9.817 9.821 -0.004 97 127540 0.4000 0.4059 51 Cyclohexane 69 9.838 9.849 -0.011 96 21140 0.4000 0.4224 52 Carbon tetrachloride 117 9.854 9.860 -0.006 96 81002 0.4000 0.3398 53 2,3-Dimethylpentane 71 10.005 10.009 -0.004 91 29068 0.4000 0.3919 54 Thiophene 84 10.086 10.088 -0.002 97 75422 0.4000 0.4002 55 Tert-amyl methyl ether 73 10.340 10.344 -0.004 94 113391 0.4000 0.3852 56 Isooctane 57 10.674 10.676 -0.002 98 233738 0.4000 0.4054 57 1,2-Dichloropropane 63 11.057 11.062 -0.005 67 54978 0.4000 0.4081 58 n-Heptane 71 11.068 11.070 -0.002 90 45810 0.4000 0.4127 59 Trichloroethene 130 11.122 11.125 -0.003 90 63467 0.4000 0.4130 60 Dibromomethane 93 11.165 11.169 -0.004 88 52696 0.4000 0.3819 61 Dichlorobromomethane 83 11.337 11.338 -0.001 98 84444 0.4000 0.3735 62 1,4-Dioxane 88 11.348 11.347 0.001 48 18752 0.4000 0.4014 63 Methyl methacrylate 41 11.467 11.473 -0.006 94 58677 0.4000 0.3815 64 Methylcyclohexane 83 11.947 11.948 -0.001 93 93957 0.4000 0.4065 65 4-Methyl-2-pentanone (MIBK 43 12.340 12.341 -0.001 98 116812 0.4000 0.4143 66 cis-1,3-Dichloropropene 75 12.383 12.389 -0.006 97 67326 0.4000 0.3818 67 trans-1,3-Dichloropropene 75 13.111 13.112 -0.001 98 55793 0.4000 0.3600 68 Toluene 91 13.252 13.254 -0.002 94 151950 0.4000 0.4004 69 1,1,2-Trichloroethane 83 13.305 13.308 -0.003 97 46587 0.4000 0.4036 70 2-Methylthiophene 97 13.403 13.402 0.001 98 119545 0.4000 0.4018 71 3-Methylthiophene 97 13.607 13.612 -0.005 100 118345 0.4000 0.4057 72 2-Hexanone 58 13.737 13.736 0.001 91 48432 0.4000 0.3645 73 Chlorodibromomethane 129 14.023 14.025 -0.002 97 80628 0.4000 0.3868 74 n-Octane 85 14.044 14.045 -0.001 95 45104 0.4000 0.4093 75 Ethylene Dibromide 107 14.319 14.320 -0.001 99 77258 0.4000 0.3952 76 Tetrachloroethene 129 14.438 14.441 -0.003 92 53937 0.4000 0.3883 77 Chlorobenzene 112 15.328 15.330 -0.002 96 128145 0.4000 0.3987 78 2,3-Dimethylheptane 43 15.430 15.432 -0.002 96 157463 0.4000 0.4271 79 Ethylbenzene 91 15.646 15.647 -0.001 99 192894 0.4000 0.4025 80 2-Ethylthiophene 97 15.743 15.744 -0.001 97 137984 0.4000 0.4081 81 m-Xylene & p-Xylene 91 15.818 15.819 -0.001 99 306509 0.8000 0.8413 82 Bromoform 173 16.223 16.221 0.002 97 88903 0.4000 0.3690 83 Styrene 104 16.282 16.282 0.000 97 99070 0.4000 0.4107 03/21/2017Page 238 of 377 Report Date: 24-Feb-2017 16:53:56 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC04.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 84 n-Nonane 57 16.309 16.312 -0.003 95 112542 0.4000 0.4576 85 o-Xylene 91 16.347 16.347 0.000 98 157032 0.4000 0.4079 86 1,1,2,2-Tetrachloroethane 83 16.660 16.658 0.002 99 117978 0.4000 0.4169 87 1,2,3-Trichloropropane 110 16.816 16.819 -0.003 96 34975 0.4000 0.4321 88 Isopropylbenzene 105 16.962 16.963 -0.001 95 225985 0.4000 0.4239 89 N-Propylbenzene 120 17.539 17.540 -0.002 99 65333 0.4000 0.4610 90 2-Chlorotoluene 126 17.565 17.565 0.000 97 60368 0.4000 0.4368 91 4-Ethyltoluene 105 17.706 17.706 0.000 99 232695 0.4000 0.4425 92 1,3,5-Trimethylbenzene 120 17.787 17.790 -0.003 93 108841 0.4000 0.4501 93 Alpha Methyl Styrene 118 18.029 18.031 -0.002 91 77461 0.4000 0.3869 94 n-Decane 57 18.159 18.157 0.002 89 145932 0.4000 0.4490 95 tert-Butylbenzene 119 18.240 18.240 0.000 94 210262 0.4000 0.4394 96 1,2,4-Trimethylbenzene 105 18.256 18.256 0.000 96 204178 0.4000 0.4537 97 1,3-Dichlorobenzene 146 18.520 18.520 0.000 96 162298 0.4000 0.4468 98 sec-Butylbenzene 105 18.531 18.532 -0.001 98 295827 0.4000 0.4417 99 Benzyl chloride 91 18.595 18.596 -0.001 99 159172 0.4000 0.4047 100 1,4-Dichlorobenzene 146 18.612 18.614 -0.002 97 164245 0.4000 0.4415 101 4-Isopropyltoluene 119 18.709 18.710 -0.001 96 242297 0.4000 0.4376 102 1,2,3-Trimethylbenzene 105 18.752 18.751 0.001 97 158300 0.4000 0.4384 103 Butylcyclohexane 83 18.838 18.840 -0.002 94 160274 0.4000 0.4319 104 1,2-Dichlorobenzene 146 18.989 18.990 -0.001 96 161183 0.4000 0.4539 105 2,3-Dihydroindene 117 19.000 19.001 -0.001 94 189774 0.4000 0.4601 106 Indene 116 19.135 19.134 0.001 91 128054 0.4000 0.4237 107 n-Butylbenzene 91 19.172 19.173 -0.001 98 249573 0.4000 0.4200 108 Undecane 57 19.550 19.552 -0.002 94 160272 0.4000 0.4275 109 1,2-Dimethyl-4-Ethylbenzen 119 19.566 19.566 0.000 99 181950 0.4000 0.4042 110 1,2-Dibromo-3-Chloropropan 157 19.620 19.620 0.000 92 57159 0.4000 0.3714 111 1,2,4,5-Tetramethylbenzene 119 19.970 19.970 0.000 99 200754 0.4000 0.3929 112 1,2,3,5-Tetramethylbenzene 119 20.024 20.024 0.000 96 126732 0.4000 0.3908 113 1,2,3,4-Tetramethylbenzene 119 20.429 20.429 0.000 98 167151 0.4000 0.3833 114 Dodecane 57 20.655 20.656 -0.001 94 133130 0.4000 0.3440 115 1,2,4-Trichlorobenzene 180 20.779 20.779 0.000 93 139606 0.4000 0.3663 116 Naphthalene 128 20.914 20.913 0.001 99 244813 0.4000 0.3658 117 Benzo(b)thiophene 134 21.017 21.015 0.002 99 134679 0.4000 0.3373 118 Hexachlorobutadiene 225 21.168 21.166 0.002 94 144240 0.4000 0.3742 119 1,2,3-Trichlorobenzene 180 21.205 21.207 -0.002 95 133457 0.4000 0.3544 120 2-Methylnaphthalene 142 21.928 21.929 -0.001 95 20471 1.25 0.3496 121 1-Methylnaphthalene 142 22.052 22.052 0.000 96 18889 1.25 0.4358 A 122 C6 Range 1 7.601 (7.557-7.635) 0 369743 0.4000 0.4350 S 124 Xylenes, Total 100 0 1.20 1.25 S 125 1,2-Dichloroethene, Total 1 0 0.8000 0.7897 Reagents: 40L4DNP_00009 Amount Added: 200.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 239 of 377 Report Date: 24-Feb-2017 16:53:56 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC04.D Injection Date:24-Feb-2017 01:23:30 Instrument ID:MR Operator ID: Lims ID:IC L4 Worklist Smp#:6 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:5 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 Y ( X10 0 0 0 0 ) RB23IC04[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 2 0 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 8 3 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 7 9 ) $ 4 - B r o m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 7 )+ 03/21/2017Page 240 of 377 Report Date: 24-Feb-2017 16:53:56 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC04.D Injection Date:24-Feb-2017 01:23:30 Instrument ID:MR Lims ID:IC L4 Client ID: Operator ID:ALS Bottle#:5 Worklist Smp#:6 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 122 C6 Range, CAS: STL01725 7.5 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 Y ( X10 0 0 0 ) RB23IC04[MS SCAN Chro]:Total 03/21/2017Page 241 of 377 Report Date: 24-Feb-2017 16:54:00 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC05.D Lims ID:IC L5 Client ID: Sample Type:IC Calib Level:5 Inject. Date:24-Feb-2017 02:09:30 ALS Bottle#:6 Worklist Smp#:7 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004095-007 Misc. Info.:073142 Operator ID:Instrument ID:MR Sublist:chrom-MR_TO15*sub7 Method:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:24-Feb-2017 16:53:59 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK010 First Level Reviewer: tajh Date:24-Feb-2017 09:22:26 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.226 8.227 -0.001 97 377535 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.388 10.390 -0.002 95 1853019 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.279 15.280 -0.001 89 1500706 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.972 16.970 0.002 95 1108358 4.00 4.23 6 Chlorodifluoromethane 67 3.718 3.720 -0.002 97 36029 1.00 1.03 7 Propene 41 3.723 3.722 0.001 99 153453 1.00 1.13 8 Dichlorodifluoromethane 85 3.771 3.772 -0.001 100 311496 1.00 1.23 9 Chloromethane 52 3.917 3.920 -0.003 100 49158 1.00 1.11 10 1,2-Dichloro-1,1,2,2-tetra 135 3.944 3.945 -0.001 91 264107 1.00 1.13 11 Acetaldehyde 44 4.057 4.063 -0.006 96 222712 4.99 5.46 12 Vinyl chloride 62 4.068 4.069 -0.001 99 116046 1.00 1.10 13 Butadiene 54 4.144 4.150 -0.006 88 82666 1.00 1.13 14 Butane 43 4.149 4.152 -0.003 91 160556 1.00 1.16 15 Bromomethane 94 4.402 4.409 -0.007 96 89463 1.00 1.09 16 Chloroethane 64 4.532 4.534 -0.002 91 39574 1.00 1.02 17 Ethanol 31 4.645 4.648 -0.003 98 148558 4.99 5.44 18 Vinyl bromide 106 4.785 4.790 -0.005 96 72610 1.00 1.04 19 2-Methylbutane 43 4.845 4.848 -0.003 85 75735 1.00 1.04 20 Acrolein 56 5.017 5.025 -0.008 30 23899 1.00 0.9132 21 Trichlorofluoromethane 101 5.028 5.030 -0.002 99 326703 1.00 1.06 22 Acetonitrile 40 5.071 5.075 -0.004 94 52436 1.00 1.08 23 Acetone 58 5.114 5.124 -0.010 98 197602 3.00 3.18 24 Isopropyl alcohol 45 5.222 5.227 -0.005 92 616764 3.00 3.33 25 Pentane 72 5.227 5.229 -0.002 94 23465 1.00 1.09 26 Ethyl ether 31 5.357 5.367 -0.010 91 169629 1.00 1.14 27 1,1-Dichloroethene 96 5.621 5.629 -0.008 96 118379 1.00 1.02 28 Acrylonitrile 53 5.697 5.705 -0.008 92 101655 1.00 1.08 29 2-Methyl-2-propanol 59 5.729 5.739 -0.010 97 233237 1.00 1.05 30 1,1,2-Trichloro-1,2,2-trif 101 5.804 5.809 -0.005 95 265033 1.00 1.02 31 Methylene Chloride 84 5.918 5.920 -0.002 98 116898 1.00 0.99 03/21/2017Page 242 of 377 Report Date: 24-Feb-2017 16:54:00 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC05.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.939 5.942 -0.003 94 120145 1.00 1.02 33 Carbon disulfide 76 6.058 6.062 -0.004 100 332680 1.00 0.99 34 trans-1,2-Dichloroethene 96 6.651 6.657 -0.006 97 120134 1.00 1.01 35 2-Methylpentane 43 6.700 6.705 -0.005 97 304717 1.00 1.08 36 Methyl tert-butyl ether 73 6.780 6.785 -0.005 97 308385 1.00 1.02 37 1,1-Dichloroethane 63 7.023 7.023 0.000 100 235756 1.00 1.01 38 Vinyl acetate 43 7.131 7.135 -0.004 100 367502 1.00 1.09 39 2-Butanone (MEK) 72 7.514 7.522 -0.008 98 55955 1.00 0.9860 40 Hexane 56 7.611 7.610 0.001 92 105783 1.00 1.00 41 Isopropyl ether 45 7.740 7.748 -0.008 98 498469 1.00 1.09 42 cis-1,2-Dichloroethene 96 7.924 7.930 -0.006 96 126425 1.00 1.02 43 Ethyl acetate 43 8.112 8.118 -0.006 98 317674 1.00 1.09 44 Chloroform 83 8.258 8.258 0.000 96 249964 1.00 0.9851 45 Tert-butyl ethyl ether 59 8.377 8.381 -0.004 97 379641 1.00 1.06 46 Tetrahydrofuran 42 8.614 8.621 -0.007 95 162980 1.00 1.05 47 1,1,1-Trichloroethane 97 9.239 9.239 0.000 96 237728 1.00 0.9874 48 1,2-Dichloroethane 62 9.309 9.311 -0.002 96 168285 1.00 0.9771 49 n-Butanol 31 9.800 9.810 -0.010 87 52295 1.00 1.03 50 Benzene 78 9.822 9.821 0.001 98 335562 1.00 1.00 51 Cyclohexane 69 9.843 9.849 -0.006 95 55861 1.00 1.05 52 Carbon tetrachloride 117 9.854 9.860 -0.006 97 255790 1.00 1.00 53 2,3-Dimethylpentane 71 10.005 10.009 -0.004 92 81981 1.00 1.03 54 Thiophene 84 10.086 10.088 -0.002 97 201904 1.00 1.00 55 Tert-amyl methyl ether 73 10.345 10.344 0.001 96 333304 1.00 1.06 56 Isooctane 57 10.674 10.676 -0.002 98 647577 1.00 1.05 57 1,2-Dichloropropane 63 11.062 11.062 0.000 88 151945 1.00 1.06 58 n-Heptane 71 11.067 11.070 -0.003 94 130261 1.00 1.10 59 Trichloroethene 130 11.121 11.125 -0.004 95 165540 1.00 1.01 60 Dibromomethane 93 11.170 11.169 0.001 89 143675 1.00 0.9748 61 Dichlorobromomethane 83 11.337 11.338 -0.001 98 245143 1.00 1.02 62 1,4-Dioxane 88 11.342 11.347 -0.005 95 54586 1.00 1.09 63 Methyl methacrylate 41 11.472 11.473 -0.001 95 179826 1.00 1.09 64 Methylcyclohexane 83 11.946 11.948 -0.002 93 262049 1.00 1.06 65 4-Methyl-2-pentanone (MIBK 43 12.335 12.341 -0.006 96 326469 1.00 1.08 66 cis-1,3-Dichloropropene 75 12.389 12.389 -0.001 97 192581 1.00 1.02 67 trans-1,3-Dichloropropene 75 13.111 13.112 -0.001 97 168680 1.00 1.01 68 Toluene 91 13.251 13.254 -0.003 93 425356 1.00 1.04 69 1,1,2-Trichloroethane 83 13.305 13.308 -0.003 98 124669 1.00 1.01 70 2-Methylthiophene 97 13.402 13.402 0.000 98 334934 1.00 1.05 71 3-Methylthiophene 97 13.613 13.612 0.001 99 327679 1.00 1.05 72 2-Hexanone 58 13.731 13.736 -0.005 91 150804 1.00 1.06 73 Chlorodibromomethane 129 14.028 14.025 0.003 98 249214 1.00 1.11 74 n-Octane 85 14.044 14.045 -0.001 96 134151 1.00 1.13 75 Ethylene Dibromide 107 14.319 14.320 -0.001 98 214254 1.00 1.02 76 Tetrachloroethene 129 14.443 14.441 0.002 92 153057 1.00 1.03 77 Chlorobenzene 112 15.327 15.330 -0.003 96 349650 1.00 1.01 78 2,3-Dimethylheptane 43 15.430 15.432 -0.002 95 448957 1.00 1.13 79 Ethylbenzene 91 15.645 15.647 -0.002 99 545725 1.00 1.06 80 2-Ethylthiophene 97 15.743 15.744 -0.001 98 387899 1.00 1.07 81 m-Xylene & p-Xylene 91 15.818 15.819 -0.001 100 849245 2.00 2.17 82 Bromoform 173 16.222 16.221 0.001 97 293454 1.00 1.13 83 Styrene 104 16.282 16.282 0.000 97 297206 1.00 1.15 03/21/2017Page 243 of 377 Report Date: 24-Feb-2017 16:54:00 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC05.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 84 n-Nonane 57 16.309 16.312 -0.003 96 311279 1.00 1.18 85 o-Xylene 91 16.347 16.347 -0.001 98 439347 1.00 1.06 86 1,1,2,2-Tetrachloroethane 83 16.659 16.658 0.001 99 336748 1.00 1.11 87 1,2,3-Trichloropropane 110 16.821 16.819 0.002 95 98499 1.00 1.13 88 Isopropylbenzene 105 16.961 16.963 -0.002 96 614427 1.00 1.07 89 N-Propylbenzene 120 17.538 17.540 -0.002 99 175311 1.00 1.15 90 2-Chlorotoluene 126 17.565 17.565 0.000 97 164005 1.00 1.11 91 4-Ethyltoluene 105 17.705 17.706 -0.001 99 660235 1.00 1.17 92 1,3,5-Trimethylbenzene 120 17.786 17.790 -0.004 92 296486 1.00 1.14 93 Alpha Methyl Styrene 118 18.029 18.031 -0.002 89 243487 1.00 1.13 94 n-Decane 57 18.153 18.157 -0.004 88 425460 1.00 1.22 95 tert-Butylbenzene 119 18.239 18.240 -0.001 92 584282 1.00 1.14 96 1,2,4-Trimethylbenzene 105 18.255 18.256 -0.001 96 578234 1.00 1.20 97 1,3-Dichlorobenzene 146 18.520 18.520 0.000 97 453278 1.00 1.16 98 sec-Butylbenzene 105 18.530 18.532 -0.002 99 844875 1.00 1.18 99 Benzyl chloride 91 18.595 18.596 -0.001 98 489081 1.00 1.16 100 1,4-Dichlorobenzene 146 18.611 18.614 -0.003 96 460249 1.00 1.15 101 4-Isopropyltoluene 119 18.708 18.710 -0.002 96 694973 1.00 1.17 102 1,2,3-Trimethylbenzene 105 18.752 18.751 0.001 98 450050 1.00 1.16 103 Butylcyclohexane 83 18.838 18.840 -0.002 92 465131 1.00 1.17 104 1,2-Dichlorobenzene 146 18.989 18.990 -0.001 97 449782 1.00 1.18 105 2,3-Dihydroindene 117 19.000 19.001 -0.001 94 529393 1.00 1.20 106 Indene 116 19.134 19.134 0.000 90 393389 1.00 1.21 107 n-Butylbenzene 91 19.172 19.173 -0.001 98 735562 1.00 1.15 108 Undecane 57 19.550 19.552 -0.002 95 517142 1.00 1.29 109 1,2-Dimethyl-4-Ethylbenzen 119 19.566 19.566 0.000 98 539412 1.00 1.12 110 1,2-Dibromo-3-Chloropropan 157 19.620 19.620 0.000 94 198649 1.00 1.20 111 1,2,4,5-Tetramethylbenzene 119 19.965 19.970 -0.005 99 634976 1.00 1.16 112 1,2,3,5-Tetramethylbenzene 119 20.024 20.024 0.000 96 391237 1.00 1.12 113 1,2,3,4-Tetramethylbenzene 119 20.429 20.429 0.000 98 532497 1.00 1.14 114 Dodecane 57 20.655 20.656 -0.001 93 505118 1.00 1.22 115 1,2,4-Trichlorobenzene 180 20.779 20.779 0.000 93 465148 1.00 1.14 116 Naphthalene 128 20.914 20.913 0.001 99 823611 1.00 1.15 117 Benzo(b)thiophene 134 21.016 21.015 0.001 100 459875 1.00 1.07 118 Hexachlorobutadiene 225 21.162 21.166 -0.004 93 464424 1.00 1.12 119 1,2,3-Trichlorobenzene 180 21.205 21.207 -0.002 95 458690 1.00 1.13 120 2-Methylnaphthalene 142 21.928 21.929 -0.001 97 150695 3.12 2.40 121 1-Methylnaphthalene 142 22.052 22.052 0.000 97 125607 3.12 2.70 A 122 C6 Range 1 7.614 (7.552-7.651) 0 946720 1.00 1.04 S 124 Xylenes, Total 100 0 3.00 3.23 S 125 1,2-Dichloroethene, Total 1 0 2.00 2.03 Reagents: 40L6DNP_00010 Amount Added: 100.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 244 of 377 Report Date: 24-Feb-2017 16:54:00 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC05.D Injection Date:24-Feb-2017 02:09:30 Instrument ID:MR Operator ID: Lims ID:IC L5 Worklist Smp#:7 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:6 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 Y ( X10 0 0 0 0 ) RB23IC05[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 2 6 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 8 8 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 7 9 ) $ 4 - B r o m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 7 )+ 03/21/2017Page 245 of 377 Report Date: 24-Feb-2017 16:54:00 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC05.D Injection Date:24-Feb-2017 02:09:30 Instrument ID:MR Lims ID:IC L5 Client ID: Operator ID:ALS Bottle#:6 Worklist Smp#:7 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 122 C6 Range, CAS: STL01725 7.5 Min 1 4 7 10 13 16 19 22 25 28 31 34 37 40 Y ( X10 0 0 0 ) RB23IC05[MS SCAN Chro]:Total 03/21/2017Page 246 of 377 Report Date: 24-Feb-2017 16:54:06 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC06.D Lims ID:ICIS L6 Client ID: Sample Type:ICIS Calib Level:6 Inject. Date:24-Feb-2017 02:57:30 ALS Bottle#:7 Worklist Smp#:8 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004095-008 Misc. Info.:073142 Operator ID:Instrument ID:MR Sublist:chrom-MR_TO15*sub7 Method:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:24-Feb-2017 16:54:06 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK010 First Level Reviewer: tajh Date:24-Feb-2017 09:21:35 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.231 8.227 0.004 98 415087 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.394 10.390 0.004 95 2028116 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.279 15.280 -0.001 89 1643754 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.972 16.970 0.002 95 1177919 4.00 4.11 6 Chlorodifluoromethane 67 3.718 3.720 -0.002 97 77337 2.00 2.02 7 Propene 41 3.723 3.722 0.001 98 309645 2.00 2.08 8 Dichlorodifluoromethane 85 3.772 3.772 0.000 100 538735 2.00 1.93 9 Chloromethane 52 3.917 3.920 -0.003 100 94563 2.00 1.95 10 1,2-Dichloro-1,1,2,2-tetra 135 3.944 3.945 -0.001 96 528953 2.00 2.06 11 Acetaldehyde 44 4.063 4.063 0.000 95 416688 9.99 9.29 12 Vinyl chloride 62 4.068 4.069 -0.001 64 223530 2.00 1.93 13 Butadiene 54 4.149 4.150 -0.001 92 158175 2.00 1.97 14 Butane 43 4.155 4.152 0.003 93 300625 2.00 1.98 15 Bromomethane 94 4.408 4.409 -0.001 97 175754 2.00 1.96 16 Chloroethane 64 4.532 4.534 -0.002 88 80451 2.00 1.88 17 Ethanol 31 4.651 4.648 0.003 99 292636 9.99 9.75 18 Vinyl bromide 106 4.791 4.790 0.001 97 147675 2.00 1.93 19 2-Methylbutane 43 4.850 4.848 0.002 85 149838 2.00 1.88 20 Acrolein 56 5.023 5.025 -0.002 30 48441 2.00 1.68 21 Trichlorofluoromethane 101 5.028 5.030 -0.002 99 686235 2.00 2.02 22 Acetonitrile 40 5.071 5.075 -0.004 98 116089 2.00 2.18 23 Acetone 58 5.120 5.124 -0.004 98 428503 5.99 6.27 24 Isopropyl alcohol 45 5.222 5.227 -0.005 94 1354035 5.99 6.65 25 Pentane 72 5.233 5.229 0.004 96 51117 2.00 2.16 26 Ethyl ether 31 5.362 5.367 -0.005 94 351514 2.00 2.14 27 1,1-Dichloroethene 96 5.632 5.629 0.003 95 254943 2.00 2.00 28 Acrylonitrile 53 5.702 5.705 -0.003 95 222055 2.00 2.14 29 2-Methyl-2-propanol 59 5.735 5.739 -0.004 96 535332 2.00 2.18 30 1,1,2-Trichloro-1,2,2-trif 101 5.810 5.809 0.001 97 585806 2.00 2.05 31 Methylene Chloride 84 5.923 5.920 0.003 98 247716 2.00 1.91 03/21/2017Page 247 of 377 Report Date: 24-Feb-2017 16:54:06 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC06.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.945 5.942 0.003 93 273367 2.00 2.12 33 Carbon disulfide 76 6.064 6.062 0.002 100 752486 2.00 2.05 34 trans-1,2-Dichloroethene 96 6.657 6.657 0.000 96 266070 2.00 2.03 35 2-Methylpentane 43 6.705 6.705 0.000 96 684768 2.00 2.20 36 Methyl tert-butyl ether 73 6.781 6.785 -0.004 98 717493 2.00 2.15 37 1,1-Dichloroethane 63 7.023 7.023 0.000 99 546060 2.00 2.12 38 Vinyl acetate 43 7.131 7.135 -0.004 100 858751 2.00 2.33 39 2-Butanone (MEK) 72 7.519 7.522 -0.003 98 130850 2.00 2.10 40 Hexane 56 7.611 7.610 0.001 90 242145 2.00 2.08 41 Isopropyl ether 45 7.746 7.748 -0.002 97 1122507 2.00 2.23 42 cis-1,2-Dichloroethene 96 7.935 7.930 0.005 97 275633 2.00 2.03 43 Ethyl acetate 43 8.113 8.118 -0.005 98 732523 2.00 2.29 44 Chloroform 83 8.264 8.258 0.006 95 573807 2.00 2.06 45 Tert-butyl ethyl ether 59 8.377 8.381 -0.004 97 873119 2.00 2.23 46 Tetrahydrofuran 42 8.614 8.621 -0.007 94 362782 2.00 2.12 47 1,1,1-Trichloroethane 97 9.240 9.239 0.001 97 558131 2.00 2.11 48 1,2-Dichloroethane 62 9.315 9.311 0.004 96 398175 2.00 2.11 49 n-Butanol 31 9.800 9.810 -0.010 90 126841 2.00 2.29 50 Benzene 78 9.822 9.821 0.001 98 757353 2.00 2.06 51 Cyclohexane 69 9.849 9.849 0.000 96 130260 2.00 2.23 52 Carbon tetrachloride 117 9.860 9.860 0.000 97 595862 2.00 2.14 53 2,3-Dimethylpentane 71 10.011 10.009 0.002 91 189272 2.00 2.18 54 Thiophene 84 10.092 10.088 0.004 96 456153 2.00 2.07 55 Tert-amyl methyl ether 73 10.340 10.344 -0.004 96 770144 2.00 2.24 56 Isooctane 57 10.674 10.676 -0.002 99 1483986 2.00 2.20 57 1,2-Dichloropropane 63 11.062 11.062 0.000 88 335988 2.00 2.13 58 n-Heptane 71 11.073 11.070 0.003 94 294527 2.00 2.27 59 Trichloroethene 130 11.127 11.125 0.002 92 361242 2.00 2.01 60 Dibromomethane 93 11.170 11.169 0.001 90 328140 2.00 2.03 61 Dichlorobromomethane 83 11.343 11.338 0.005 98 581937 2.00 2.20 62 1,4-Dioxane 88 11.343 11.347 -0.004 41 122338 2.00 2.24 63 Methyl methacrylate 41 11.472 11.473 -0.001 95 420770 2.00 2.34 64 Methylcyclohexane 83 11.952 11.948 0.004 93 587324 2.00 2.17 65 4-Methyl-2-pentanone (MIBK 43 12.335 12.341 -0.006 98 770834 2.00 2.34 66 cis-1,3-Dichloropropene 75 12.389 12.389 0.000 96 460289 2.00 2.23 67 trans-1,3-Dichloropropene 75 13.111 13.112 -0.001 98 407884 2.00 2.24 68 Toluene 91 13.252 13.254 -0.002 93 949069 2.00 2.13 69 1,1,2-Trichloroethane 83 13.311 13.308 0.003 98 282164 2.00 2.08 70 2-Methylthiophene 97 13.403 13.402 0.001 98 753080 2.00 2.15 71 3-Methylthiophene 97 13.613 13.612 0.001 100 751011 2.00 2.19 72 2-Hexanone 58 13.731 13.736 -0.005 92 362209 2.00 2.32 73 Chlorodibromomethane 129 14.028 14.025 0.003 98 574706 2.00 2.35 74 n-Octane 85 14.044 14.045 -0.001 96 298259 2.00 2.30 75 Ethylene Dibromide 107 14.319 14.320 -0.001 97 496771 2.00 2.16 76 Tetrachloroethene 129 14.443 14.441 0.002 94 338008 2.00 2.07 77 Chlorobenzene 112 15.328 15.330 -0.002 95 750598 2.00 1.99 78 2,3-Dimethylheptane 43 15.430 15.432 -0.002 96 984747 2.00 2.27 79 Ethylbenzene 91 15.646 15.647 -0.001 99 1193234 2.00 2.12 80 2-Ethylthiophene 97 15.743 15.744 -0.001 98 873189 2.00 2.20 81 m-Xylene & p-Xylene 91 15.818 15.819 -0.001 99 1848010 3.99 4.31 82 Bromoform 173 16.223 16.221 0.002 97 671801 2.00 2.37 83 Styrene 104 16.282 16.282 0.000 98 656912 2.00 2.32 03/21/2017Page 248 of 377 Report Date: 24-Feb-2017 16:54:06 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC06.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 84 n-Nonane 57 16.314 16.312 0.002 94 659323 2.00 2.28 85 o-Xylene 91 16.347 16.347 0.000 98 936796 2.00 2.07 86 1,1,2,2-Tetrachloroethane 83 16.660 16.658 0.002 100 711168 2.00 2.14 87 1,2,3-Trichloropropane 110 16.821 16.819 0.002 96 194922 2.00 2.05 88 Isopropylbenzene 105 16.961 16.963 -0.002 97 1250923 2.00 2.00 89 N-Propylbenzene 120 17.538 17.540 -0.002 99 350675 2.00 2.10 90 2-Chlorotoluene 126 17.565 17.565 0.000 98 320862 2.00 1.97 91 4-Ethyltoluene 105 17.706 17.706 0.000 99 1337683 2.00 2.16 92 1,3,5-Trimethylbenzene 120 17.787 17.790 -0.003 92 598983 2.00 2.11 93 Alpha Methyl Styrene 118 18.029 18.031 -0.002 87 516658 2.00 2.20 94 n-Decane 57 18.159 18.157 0.002 89 949126 2.00 2.48 95 tert-Butylbenzene 119 18.239 18.240 -0.001 91 1249656 2.00 2.22 96 1,2,4-Trimethylbenzene 105 18.256 18.256 0.000 96 1174348 2.00 2.22 97 1,3-Dichlorobenzene 146 18.520 18.520 0.000 97 908799 2.00 2.13 98 sec-Butylbenzene 105 18.531 18.532 -0.001 99 1791681 2.00 2.28 99 Benzyl chloride 91 18.595 18.596 -0.001 98 1112104 2.00 2.41 100 1,4-Dichlorobenzene 146 18.612 18.614 -0.002 96 931133 2.00 2.13 101 4-Isopropyltoluene 119 18.709 18.710 -0.001 96 1510793 2.00 2.32 102 1,2,3-Trimethylbenzene 105 18.752 18.751 0.001 97 925394 2.00 2.18 103 Butylcyclohexane 83 18.843 18.840 0.003 93 995717 2.00 2.28 104 1,2-Dichlorobenzene 146 18.989 18.990 -0.001 96 908758 2.00 2.18 105 2,3-Dihydroindene 117 19.000 19.001 -0.001 94 1032175 2.00 2.13 106 Indene 116 19.135 19.134 0.001 91 820907 2.00 2.31 107 n-Butylbenzene 91 19.172 19.173 -0.001 98 1631072 2.00 2.34 108 Undecane 57 19.555 19.552 0.003 97 1142764 2.00 2.59 109 1,2-Dimethyl-4-Ethylbenzen 119 19.566 19.566 0.000 99 1188411 2.00 2.25 110 1,2-Dibromo-3-Chloropropan 157 19.620 19.620 0.000 95 456821 2.00 2.52 111 1,2,4,5-Tetramethylbenzene 119 19.970 19.970 0.000 98 1407460 2.00 2.34 112 1,2,3,5-Tetramethylbenzene 119 20.024 20.024 0.000 96 863457 2.00 2.27 113 1,2,3,4-Tetramethylbenzene 119 20.429 20.429 0.000 98 1180268 2.00 2.30 114 Dodecane 57 20.655 20.656 -0.001 95 1209447 2.00 2.66 115 1,2,4-Trichlorobenzene 180 20.779 20.779 0.000 93 1075136 2.00 2.40 116 Naphthalene 128 20.914 20.913 0.001 99 1895111 2.00 2.41 117 Benzo(b)thiophene 134 21.011 21.015 -0.004 100 1077615 2.00 2.30 118 Hexachlorobutadiene 225 21.168 21.166 0.002 94 1018485 2.00 2.25 119 1,2,3-Trichlorobenzene 180 21.205 21.207 -0.002 95 1027789 2.00 2.32 120 2-Methylnaphthalene 142 21.928 21.929 -0.001 98 480479 6.24 6.98 121 1-Methylnaphthalene 142 22.052 22.052 0.000 97 397397 6.24 7.80 A 122 C6 Range 1 7.617 (7.557-7.657) 0 2114371 2.00 2.13 S 124 Xylenes, Total 100 0 5.99 6.38 S 125 1,2-Dichloroethene, Total 1 0 3.99 4.06 Reagents: 40L6DNP_00010 Amount Added: 200.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 249 of 377 Report Date: 24-Feb-2017 16:54:07 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC06.D Injection Date:24-Feb-2017 02:57:30 Instrument ID:MR Operator ID: Lims ID:ICIS L6 Worklist Smp#:8 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:7 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 Y ( X10 0 0 0 0 ) RB23IC06[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 3 1 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 9 4 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 7 9 ) $ 4 - B r o m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 7 )+ 03/21/2017Page 250 of 377 Report Date: 24-Feb-2017 16:54:07 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC06.D Injection Date:24-Feb-2017 02:57:30 Instrument ID:MR Lims ID:ICIS L6 Client ID: Operator ID:ALS Bottle#:7 Worklist Smp#:8 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 122 C6 Range, CAS: STL01725 7.5 Min 1 6 11 16 21 26 31 36 41 46 51 56 61 66 71 76 81 86 91 Y ( X10 0 0 0 ) RB23IC06[MS SCAN Chro]:Total 03/21/2017Page 251 of 377 Report Date: 24-Feb-2017 16:54:12 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC07.D Lims ID:IC L7 Client ID: Sample Type:IC Calib Level:7 Inject. Date:24-Feb-2017 03:45:30 ALS Bottle#:8 Worklist Smp#:9 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004095-009 Misc. Info.:073141 Operator ID:Instrument ID:MR Sublist:chrom-MR_TO15*sub7 Method:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:24-Feb-2017 16:54:11 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK010 First Level Reviewer: barlozhetskayaa Date:24-Feb-2017 14:38:25 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.231 8.227 0.004 98 471341 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.394 10.390 0.004 95 2295635 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.279 15.280 -0.001 89 1878709 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.972 16.970 0.002 95 1333550 4.00 4.07 6 Chlorodifluoromethane 67 3.712 3.720 -0.008 97 164616 4.00 3.78 7 Propene 41 3.718 3.722 -0.004 99 616102 4.00 3.65 8 Dichlorodifluoromethane 85 3.766 3.772 -0.006 100 1199423 4.00 3.79 9 Chloromethane 52 3.917 3.920 -0.003 100 192950 4.00 3.50 10 1,2-Dichloro-1,1,2,2-tetra 135 3.944 3.945 -0.001 90 1099525 4.00 3.77 11 Acetaldehyde 44 4.063 4.063 0.000 93 732315 20.0 14.4 12 Vinyl chloride 62 4.063 4.069 -0.006 62 417030 4.00 3.17 13 Butadiene 54 4.149 4.150 -0.001 90 298274 4.00 3.27 14 Butane 43 4.149 4.152 -0.003 91 555644 4.00 3.22 15 Bromomethane 94 4.408 4.409 -0.001 97 338670 4.00 3.32 16 Chloroethane 64 4.532 4.534 -0.002 95 155307 4.00 3.19 17 Ethanol 31 4.651 4.648 0.003 99 557068 20.0 16.3 18 Vinyl bromide 106 4.791 4.790 0.001 96 289326 4.00 3.33 19 2-Methylbutane 43 4.845 4.848 -0.003 85 298288 4.00 3.29 20 Acrolein 56 5.023 5.025 -0.002 30 95411 4.00 2.92 21 Trichlorofluoromethane 101 5.034 5.030 0.004 99 1400003 4.00 3.63 22 Acetonitrile 40 5.077 5.075 0.002 94 216580 4.00 3.59 23 Acetone 58 5.120 5.124 -0.004 98 862681 12.0 11.1 24 Isopropyl alcohol 45 5.228 5.227 0.001 83 2798169 12.0 12.1 25 Pentane 72 5.233 5.229 0.004 72 108438 4.00 4.04 26 Ethyl ether 31 5.363 5.367 -0.005 95 707415 4.00 3.79 27 1,1-Dichloroethene 96 5.632 5.629 0.003 95 566831 4.00 3.91 28 Acrylonitrile 53 5.702 5.705 -0.003 94 496743 4.00 4.21 29 2-Methyl-2-propanol 59 5.735 5.739 -0.004 95 1196301 4.00 4.30 30 1,1,2-Trichloro-1,2,2-trif 101 5.810 5.809 0.001 97 1285623 4.00 3.96 31 Methylene Chloride 84 5.923 5.920 0.003 98 534995 4.00 3.64 03/21/2017Page 252 of 377 Report Date: 24-Feb-2017 16:54:12 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC07.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.945 5.942 0.003 94 583311 4.00 3.98 33 Carbon disulfide 76 6.064 6.062 0.002 99 1679091 4.00 4.02 34 trans-1,2-Dichloroethene 96 6.657 6.657 0.000 96 589438 4.00 3.97 35 2-Methylpentane 43 6.705 6.705 0.000 96 1472011 4.00 4.17 36 Methyl tert-butyl ether 73 6.775 6.785 -0.010 97 1644239 4.00 4.35 37 1,1-Dichloroethane 63 7.029 7.023 0.006 100 1206246 4.00 4.12 38 Vinyl acetate 43 7.131 7.135 -0.004 100 1882713 4.00 4.49 39 2-Butanone (MEK) 72 7.514 7.522 -0.008 98 294463 4.00 4.16 40 Hexane 56 7.611 7.610 0.001 90 532333 4.00 4.03 41 Isopropyl ether 45 7.746 7.748 -0.002 98 2416434 4.00 4.23 42 cis-1,2-Dichloroethene 96 7.935 7.930 0.005 97 621102 4.00 4.02 43 Ethyl acetate 43 8.113 8.118 -0.005 99 1591786 4.00 4.39 44 Chloroform 83 8.264 8.258 0.006 96 1296029 4.00 4.09 45 Tert-butyl ethyl ether 59 8.377 8.381 -0.004 96 1973104 4.00 4.43 46 Tetrahydrofuran 42 8.609 8.621 -0.012 95 783690 4.00 4.04 47 1,1,1-Trichloroethane 97 9.240 9.239 0.001 96 1278599 4.00 4.25 48 1,2-Dichloroethane 62 9.315 9.311 0.004 97 905386 4.00 4.24 49 n-Butanol 31 9.795 9.810 -0.015 86 270509 4.00 4.31 50 Benzene 78 9.822 9.821 0.001 98 1677250 4.00 4.03 51 Cyclohexane 69 9.849 9.849 0.000 95 285427 4.00 4.31 52 Carbon tetrachloride 117 9.860 9.860 0.000 99 1363863 4.00 4.32 53 2,3-Dimethylpentane 71 10.011 10.009 0.002 91 419595 4.00 4.27 54 Thiophene 84 10.092 10.088 0.004 97 1033269 4.00 4.14 55 Tert-amyl methyl ether 73 10.340 10.344 -0.004 97 1713213 4.00 4.40 56 Isooctane 57 10.679 10.676 0.003 99 3278689 4.00 4.30 57 1,2-Dichloropropane 63 11.062 11.062 0.000 89 741321 4.00 4.16 58 n-Heptane 71 11.073 11.070 0.003 93 646231 4.00 4.40 59 Trichloroethene 130 11.127 11.125 0.002 94 787921 4.00 3.87 60 Dibromomethane 93 11.170 11.169 0.001 89 747292 4.00 4.09 61 Dichlorobromomethane 83 11.343 11.338 0.005 98 1331396 4.00 4.45 62 1,4-Dioxane 88 11.337 11.347 -0.010 92 266658 4.00 4.31 63 Methyl methacrylate 41 11.467 11.473 -0.006 94 922438 4.00 4.53 64 Methylcyclohexane 83 11.947 11.948 -0.001 93 1314112 4.00 4.30 65 4-Methyl-2-pentanone (MIBK 43 12.335 12.341 -0.006 98 1651361 4.00 4.43 66 cis-1,3-Dichloropropene 75 12.389 12.389 0.000 96 1053282 4.00 4.51 67 trans-1,3-Dichloropropene 75 13.111 13.112 -0.001 98 961977 4.00 4.62 68 Toluene 91 13.257 13.254 0.003 93 2132262 4.00 4.18 69 1,1,2-Trichloroethane 83 13.305 13.308 -0.003 99 632212 4.00 4.08 70 2-Methylthiophene 97 13.403 13.402 0.001 98 1704543 4.00 4.26 71 3-Methylthiophene 97 13.613 13.612 0.001 100 1681316 4.00 4.29 72 2-Hexanone 58 13.731 13.736 -0.005 93 787724 4.00 4.41 73 Chlorodibromomethane 129 14.028 14.025 0.003 98 1331407 4.00 4.75 74 n-Octane 85 14.044 14.045 -0.001 95 657401 4.00 4.44 75 Ethylene Dibromide 107 14.319 14.320 -0.001 98 1127971 4.00 4.29 76 Tetrachloroethene 129 14.443 14.441 0.002 93 747185 4.00 4.00 77 Chlorobenzene 112 15.328 15.330 -0.002 95 1679949 4.00 3.89 78 2,3-Dimethylheptane 43 15.430 15.432 -0.002 96 2044712 4.00 4.13 79 Ethylbenzene 91 15.646 15.647 -0.001 99 2665373 4.00 4.14 80 2-Ethylthiophene 97 15.743 15.744 -0.001 98 1958038 4.00 4.31 81 m-Xylene & p-Xylene 91 15.818 15.819 -0.001 99 4024786 8.00 8.22 82 Bromoform 173 16.223 16.221 0.002 98 1568536 4.00 4.84 83 Styrene 104 16.282 16.282 0.000 99 1462535 4.00 4.51 03/21/2017Page 253 of 377 Report Date: 24-Feb-2017 16:54:12 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC07.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 84 n-Nonane 57 16.314 16.312 0.002 93 1351079 4.00 4.09 85 o-Xylene 91 16.347 16.347 0.000 98 2059774 4.00 3.98 86 1,1,2,2-Tetrachloroethane 83 16.660 16.658 0.002 100 1523825 4.00 4.01 87 1,2,3-Trichloropropane 110 16.816 16.819 -0.003 97 428051 4.00 3.94 88 Isopropylbenzene 105 16.961 16.963 -0.002 96 2662166 4.00 3.72 89 N-Propylbenzene 120 17.538 17.540 -0.002 98 731805 4.00 3.84 90 2-Chlorotoluene 126 17.565 17.565 0.000 98 685774 4.00 3.69 91 4-Ethyltoluene 105 17.706 17.706 0.000 99 2837542 4.00 4.02 92 1,3,5-Trimethylbenzene 120 17.792 17.790 0.002 92 1258645 4.00 3.87 93 Alpha Methyl Styrene 118 18.029 18.031 -0.002 88 1124551 4.00 4.18 94 n-Decane 57 18.159 18.157 0.002 90 1922503 4.00 4.40 95 tert-Butylbenzene 119 18.239 18.240 -0.001 94 2590545 4.00 4.03 96 1,2,4-Trimethylbenzene 105 18.256 18.256 0.000 97 2377769 4.00 3.93 97 1,3-Dichlorobenzene 146 18.520 18.520 0.000 98 1823090 4.00 3.73 98 sec-Butylbenzene 105 18.531 18.532 -0.001 98 3599528 4.00 4.00 99 Benzyl chloride 91 18.595 18.596 -0.001 98 2352128 4.00 4.45 100 1,4-Dichlorobenzene 146 18.617 18.614 0.003 96 1875178 4.00 3.75 101 4-Isopropyltoluene 119 18.714 18.710 0.004 96 3120571 4.00 4.19 102 1,2,3-Trimethylbenzene 105 18.752 18.751 0.001 98 1888807 4.00 3.89 103 Butylcyclohexane 83 18.843 18.840 0.003 93 2045438 4.00 4.10 104 1,2-Dichlorobenzene 146 18.989 18.990 -0.001 96 1796455 4.00 3.76 105 2,3-Dihydroindene 117 19.000 19.001 -0.001 94 2064201 4.00 3.72 106 Indene 116 19.135 19.134 0.001 91 1709131 4.00 4.21 107 n-Butylbenzene 91 19.172 19.173 -0.001 98 3430316 4.00 4.30 108 Undecane 57 19.550 19.552 -0.002 97 2240401 4.00 4.45 109 1,2-Dimethyl-4-Ethylbenzen 119 19.566 19.566 0.000 98 2450287 4.00 4.05 110 1,2-Dibromo-3-Chloropropan 157 19.620 19.620 0.000 96 1014303 4.00 4.91 111 1,2,4,5-Tetramethylbenzene 119 19.970 19.970 0.000 98 3075927 4.00 4.48 112 1,2,3,5-Tetramethylbenzene 119 20.024 20.024 0.000 96 1889050 4.00 4.34 113 1,2,3,4-Tetramethylbenzene 119 20.429 20.429 0.000 98 2597679 4.00 4.43 114 Dodecane 57 20.655 20.656 -0.001 96 2473317 4.00 4.76 115 1,2,4-Trichlorobenzene 180 20.779 20.779 0.000 93 2328403 4.00 4.55 116 Naphthalene 128 20.914 20.913 0.001 99 4150285 4.00 4.62 117 Benzo(b)thiophene 134 21.017 21.015 0.002 100 2446149 4.00 4.56 118 Hexachlorobutadiene 225 21.162 21.166 -0.004 94 2202550 4.00 4.25 119 1,2,3-Trichlorobenzene 180 21.205 21.207 -0.002 95 2240673 4.00 4.43 120 2-Methylnaphthalene 142 21.928 21.929 -0.001 98 1200547 12.5 15.3 121 1-Methylnaphthalene 142 22.052 22.052 0.000 98 996171 12.5 17.1 A 122 C6 Range 1 7.622 (7.557-7.689) 0 4501964 4.00 4.00 S 124 Xylenes, Total 100 0 12.0 12.2 S 125 1,2-Dichloroethene, Total 1 0 8.00 7.99 Reagents: 40L7DNP_00009 Amount Added: 200.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 254 of 377 Report Date: 24-Feb-2017 16:54:12 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC07.D Injection Date:24-Feb-2017 03:45:30 Instrument ID:MR Operator ID: Lims ID:IC L7 Worklist Smp#:9 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:8 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 56 60 64 68 72 76 80 84 88 92 96 Y ( X10 0 0 0 0 ) RB23IC07[MS SCAN Chro]:Total * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 9 4 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 7 9 ) $ 4 - B r o m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 7 )+ 03/21/2017Page 255 of 377 Report Date: 24-Feb-2017 16:54:12 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC07.D Injection Date:24-Feb-2017 03:45:30 Instrument ID:MR Lims ID:IC L7 Client ID: Operator ID:ALS Bottle#:8 Worklist Smp#:9 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 122 C6 Range, CAS: STL01725 7.5 Min 0 2 4 6 8 10 12 14 16 18 20 Y ( X10 0 0 0 0 ) RB23IC07[MS SCAN Chro]:Total 03/21/2017Page 256 of 377 Report Date: 24-Feb-2017 16:54:16 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC08.D Lims ID:IC L8 Client ID: Sample Type:IC Calib Level:8 Inject. Date:24-Feb-2017 04:33:30 ALS Bottle#:9 Worklist Smp#:10 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004095-010 Misc. Info.:073140 Operator ID:Instrument ID:MR Sublist:chrom-MR_TO15*sub7 Method:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:24-Feb-2017 16:54:15 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK010 First Level Reviewer: barlozhetskayaa Date:24-Feb-2017 16:30:58 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.236 8.227 0.009 95 503704 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.399 10.390 0.009 95 2456426 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.284 15.280 0.004 88 1951731 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.972 16.970 0.002 96 1293417 4.00 3.80 6 Chlorodifluoromethane 67 3.701 3.720 -0.019 97 341742 8.00 7.34 7 Propene 41 3.707 3.722 -0.015 99 1172387 8.00 6.50 8 Dichlorodifluoromethane 85 3.755 3.772 -0.017 100 2354948 8.00 6.96 9 Chloromethane 52 3.906 3.920 -0.014 100 382249 8.00 6.48 10 1,2-Dichloro-1,1,2,2-tetra 135 3.933 3.945 -0.012 90 2153188 8.00 6.90 11 Acetaldehyde 44 4.063 4.063 0.000 95 1353530 40.0 24.9 12 Vinyl chloride 62 4.057 4.069 -0.012 99 817062 8.00 5.80 13 Butadiene 54 4.138 4.150 -0.012 76 598358 8.00 6.14 14 Butane 43 4.144 4.152 -0.008 81 1112031 8.00 6.03 15 Bromomethane 94 4.402 4.409 -0.007 97 685673 8.00 6.29 16 Chloroethane 64 4.532 4.534 -0.002 86 315958 8.00 6.07 17 Ethanol 31 4.656 4.648 0.008 98 1126938 40.0 30.9 18 Vinyl bromide 106 4.791 4.790 0.001 97 598787 8.00 6.46 19 2-Methylbutane 43 4.839 4.848 -0.009 85 593509 8.00 6.13 20 Acrolein 56 5.023 5.025 -0.002 29 141454 8.00 4.05 21 Trichlorofluoromethane 101 5.028 5.030 -0.002 99 2801983 8.00 6.81 22 Acetonitrile 40 5.077 5.075 0.002 98 460029 8.00 7.13 23 Acetone 58 5.120 5.124 -0.004 98 1656093 24.0 20.0 24 Isopropyl alcohol 45 5.238 5.227 0.011 95 5528721 24.0 22.4 25 Pentane 72 5.222 5.229 -0.007 98 224005 8.00 7.82 26 Ethyl ether 31 5.357 5.367 -0.010 96 1417102 8.00 7.11 27 1,1-Dichloroethene 96 5.632 5.629 0.003 95 1218064 8.00 7.87 28 Acrylonitrile 53 5.707 5.705 0.002 94 1022056 8.00 8.11 29 2-Methyl-2-propanol 59 5.740 5.739 0.001 95 2533997 8.00 8.52 30 1,1,2-Trichloro-1,2,2-trif 101 5.810 5.809 0.001 97 2688728 8.00 7.75 31 Methylene Chloride 84 5.929 5.920 0.009 99 1110586 8.00 7.07 03/21/2017Page 257 of 377 Report Date: 24-Feb-2017 16:54:16 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC08.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.945 5.942 0.003 95 1216806 8.00 7.76 33 Carbon disulfide 76 6.063 6.062 0.001 99 3677457 8.00 8.24 34 trans-1,2-Dichloroethene 96 6.662 6.657 0.005 96 1277383 8.00 8.05 35 2-Methylpentane 43 6.705 6.705 0.000 95 2893931 8.00 7.67 36 Methyl tert-butyl ether 73 6.775 6.785 -0.010 97 3514051 8.00 8.70 37 1,1-Dichloroethane 63 7.034 7.023 0.011 100 2561351 8.00 8.19 38 Vinyl acetate 43 7.136 7.135 0.001 100 3841494 8.00 8.57 39 2-Butanone (MEK) 72 7.519 7.522 -0.003 99 628092 8.00 8.30 40 Hexane 56 7.611 7.610 0.001 89 1093784 8.00 7.76 41 Isopropyl ether 45 7.746 7.748 -0.002 98 4812302 8.00 7.89 42 cis-1,2-Dichloroethene 96 7.940 7.930 0.010 97 1331136 8.00 8.07 43 Ethyl acetate 43 8.118 8.118 0.000 99 3292786 8.00 8.49 44 Chloroform 83 8.269 8.258 0.011 97 2765081 8.00 8.17 45 Tert-butyl ethyl ether 59 8.382 8.381 0.001 96 4155244 8.00 8.73 46 Tetrahydrofuran 42 8.614 8.621 -0.007 95 1618818 8.00 7.81 47 1,1,1-Trichloroethane 97 9.245 9.239 0.006 96 2838322 8.00 8.84 48 1,2-Dichloroethane 62 9.320 9.311 0.009 97 1956139 8.00 8.57 49 n-Butanol 31 9.800 9.810 -0.010 86 583174 8.00 8.68 50 Benzene 78 9.827 9.821 0.006 98 3363998 8.00 7.56 51 Cyclohexane 69 9.854 9.849 0.005 97 552190 8.00 7.79 52 Carbon tetrachloride 117 9.865 9.860 0.005 99 2955600 8.00 8.76 53 2,3-Dimethylpentane 71 10.011 10.009 0.002 90 872362 8.00 8.31 54 Thiophene 84 10.097 10.088 0.009 97 2188596 8.00 8.20 55 Tert-amyl methyl ether 73 10.339 10.344 -0.005 97 3614164 8.00 8.67 56 Isooctane 57 10.679 10.676 0.003 98 6552928 8.00 8.03 57 1,2-Dichloropropane 63 11.067 11.062 0.005 88 1426473 8.00 7.48 58 n-Heptane 71 11.073 11.070 0.003 90 1283209 8.00 8.16 59 Trichloroethene 130 11.132 11.125 0.007 93 1697706 8.00 7.80 60 Dibromomethane 93 11.175 11.169 0.006 90 1602016 8.00 8.20 61 Dichlorobromomethane 83 11.342 11.338 0.004 99 2866521 8.00 8.95 62 1,4-Dioxane 88 11.342 11.347 -0.005 90 549623 8.00 8.31 63 Methyl methacrylate 41 11.472 11.473 -0.001 92 1936917 8.00 8.89 64 Methylcyclohexane 83 11.952 11.948 0.004 94 2689602 8.00 8.22 65 4-Methyl-2-pentanone (MIBK 43 12.340 12.341 -0.001 98 3334023 8.00 8.35 66 cis-1,3-Dichloropropene 75 12.394 12.389 0.005 96 2222764 8.00 8.90 67 trans-1,3-Dichloropropene 75 13.117 13.112 0.005 99 2116906 8.00 9.79 68 Toluene 91 13.257 13.254 0.003 93 4377764 8.00 8.26 69 1,1,2-Trichloroethane 83 13.311 13.308 0.003 99 1290344 8.00 8.01 70 2-Methylthiophene 97 13.408 13.402 0.006 98 3518170 8.00 8.47 71 3-Methylthiophene 97 13.613 13.612 0.001 100 3463489 8.00 8.50 72 2-Hexanone 58 13.731 13.736 -0.005 93 1598395 8.00 8.62 73 Chlorodibromomethane 129 14.028 14.025 0.003 97 2701236 8.00 9.28 74 n-Octane 85 14.049 14.045 0.004 92 1239163 8.00 8.06 75 Ethylene Dibromide 107 14.324 14.320 0.004 97 2358773 8.00 8.64 76 Tetrachloroethene 129 14.443 14.441 0.002 93 1518756 8.00 7.83 77 Chlorobenzene 112 15.333 15.330 0.003 97 3381719 8.00 7.54 78 2,3-Dimethylheptane 43 15.435 15.432 0.003 95 3838726 8.00 7.46 79 Ethylbenzene 91 15.651 15.647 0.004 99 5238775 8.00 7.83 80 2-Ethylthiophene 97 15.748 15.744 0.004 98 3895698 8.00 8.25 81 m-Xylene & p-Xylene 91 15.818 15.819 -0.001 99 7600175 16.0 14.9 82 Bromoform 173 16.223 16.221 0.002 97 3142805 8.00 9.34 83 Styrene 104 16.282 16.282 0.000 99 2907897 8.00 8.64 03/21/2017Page 258 of 377 Report Date: 24-Feb-2017 16:54:16 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC08.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 84 n-Nonane 57 16.314 16.312 0.002 92 2470879 8.00 7.20 85 o-Xylene 91 16.347 16.347 0.000 98 4001349 8.00 7.45 86 1,1,2,2-Tetrachloroethane 83 16.659 16.658 0.001 100 2909802 8.00 7.37 87 1,2,3-Trichloropropane 110 16.821 16.819 0.002 96 857552 8.00 7.59 88 Isopropylbenzene 105 16.967 16.963 0.004 97 5119668 8.00 6.88 89 N-Propylbenzene 120 17.538 17.540 -0.002 98 1386895 8.00 7.01 90 2-Chlorotoluene 126 17.565 17.565 0.000 96 1307704 8.00 6.78 91 4-Ethyltoluene 105 17.705 17.706 -0.001 99 5372799 8.00 7.32 92 1,3,5-Trimethylbenzene 120 17.792 17.790 0.002 92 2363652 8.00 7.00 93 Alpha Methyl Styrene 118 18.029 18.031 -0.002 88 2217522 8.00 7.94 94 n-Decane 57 18.158 18.157 0.001 91 3394674 8.00 7.48 95 tert-Butylbenzene 119 18.239 18.240 -0.001 96 4805951 8.00 7.19 96 1,2,4-Trimethylbenzene 105 18.255 18.256 -0.001 97 4203802 8.00 6.69 97 1,3-Dichlorobenzene 146 18.520 18.520 0.000 98 3264552 8.00 6.44 98 sec-Butylbenzene 105 18.536 18.532 0.004 98 6356290 8.00 6.80 99 Benzyl chloride 91 18.601 18.596 0.005 98 4128671 8.00 7.52 100 1,4-Dichlorobenzene 146 18.617 18.614 0.003 96 3424013 8.00 6.59 101 4-Isopropyltoluene 119 18.714 18.710 0.004 96 5683045 8.00 7.35 102 1,2,3-Trimethylbenzene 105 18.752 18.751 0.001 98 3654635 8.00 7.25 103 Butylcyclohexane 83 18.843 18.840 0.003 91 3782240 8.00 7.30 104 1,2-Dichlorobenzene 146 18.994 18.990 0.004 95 3185630 8.00 6.43 105 2,3-Dihydroindene 117 19.005 19.001 0.004 93 3658240 8.00 6.35 106 Indene 116 19.134 19.134 0.000 90 3291239 8.00 7.80 107 n-Butylbenzene 91 19.172 19.173 -0.001 98 6178847 8.00 7.45 108 Undecane 57 19.550 19.552 -0.002 94 3760994 8.00 7.19 109 1,2-Dimethyl-4-Ethylbenzen 119 19.566 19.566 0.000 97 4239183 8.00 6.75 110 1,2-Dibromo-3-Chloropropan 157 19.620 19.620 0.000 97 1973001 8.00 9.18 111 1,2,4,5-Tetramethylbenzene 119 19.970 19.970 0.000 97 6030209 8.00 8.45 112 1,2,3,5-Tetramethylbenzene 119 20.024 20.024 0.000 96 3867833 8.00 8.55 113 1,2,3,4-Tetramethylbenzene 119 20.429 20.429 0.000 98 5217806 8.00 8.57 114 Dodecane 57 20.655 20.656 -0.001 95 4430925 8.00 8.20 115 1,2,4-Trichlorobenzene 180 20.779 20.779 0.000 93 4608196 8.00 8.66 116 Naphthalene 128 20.914 20.913 0.001 99 8194497 8.00 8.77 117 Benzo(b)thiophene 134 21.016 21.015 0.001 100 5123070 8.00 9.19 118 Hexachlorobutadiene 225 21.167 21.166 0.001 93 4417255 8.00 8.21 119 1,2,3-Trichlorobenzene 180 21.210 21.207 0.003 95 4390985 8.00 8.35 120 2-Methylnaphthalene 142 21.928 21.929 -0.001 99 2590764 25.0 31.7 121 1-Methylnaphthalene 142 22.052 22.052 0.000 98 2070086 25.0 34.2 A 122 C6 Range 1 7.614 (7.552-7.651) 0 9178276 8.00 7.63 S 124 Xylenes, Total 100 0 24.0 22.4 S 125 1,2-Dichloroethene, Total 1 0 16.0 16.1 Reagents: 40L8DNP_00009 Amount Added: 200.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 259 of 377 Report Date: 24-Feb-2017 16:54:16 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC08.D Injection Date:24-Feb-2017 04:33:30 Instrument ID:MR Operator ID: Lims ID:IC L8 Worklist Smp#:10 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:9 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 Y ( X10 0 0 0 0 0 ) RB23IC08[MS SCAN Chro]:Total * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 9 9 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 8 4 ) $ 4 - B r o m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 7 )+ 03/21/2017Page 260 of 377 Report Date: 24-Feb-2017 16:54:16 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC08.D Injection Date:24-Feb-2017 04:33:30 Instrument ID:MR Lims ID:IC L8 Client ID: Operator ID:ALS Bottle#:9 Worklist Smp#:10 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 122 C6 Range, CAS: STL01725 7.5 Min 0 3 6 9 12 15 18 21 24 27 30 33 36 39 Y ( X10 0 0 0 0 ) RB23IC08[MS SCAN Chro]:Total 03/21/2017Page 261 of 377 Report Date: 24-Feb-2017 16:54:21 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Lims ID:IC L9 Client ID: Sample Type:IC Calib Level:9 Inject. Date:24-Feb-2017 05:21:30 ALS Bottle#:10 Worklist Smp#:11 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004095-011 Misc. Info.:073138 Operator ID:Instrument ID:MR Sublist:chrom-MR_TO15*sub7 Method:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:24-Feb-2017 16:54:20 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK010 First Level Reviewer: barlozhetskayaa Date:24-Feb-2017 14:45:29 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.247 8.227 0.020 94 539396 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.404 10.390 0.014 94 2586236 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.284 15.280 0.004 88 2139571 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.977 16.970 0.007 95 1271651 4.00 3.41 6 Chlorodifluoromethane 67 3.718 3.720 -0.002 97 701702 16.0 14.1 7 Propene 41 3.723 3.722 0.001 99 2119514 16.0 11.0 8 Dichlorodifluoromethane 85 3.772 3.772 0.000 100 4806853 16.0 13.3 9 Chloromethane 52 3.923 3.920 0.003 100 629051 16.0 9.96 10 1,2-Dichloro-1,1,2,2-tetra 135 3.950 3.945 0.005 90 3676373 16.0 11.0 11 Acetaldehyde 44 4.074 4.063 0.011 92 2159780 80.0 37.0 12 Vinyl chloride 62 4.074 4.069 0.005 99 1346176 16.0 8.93 13 Butadiene 54 4.160 4.150 0.010 77 1075330 16.0 10.3 14 Butane 43 4.160 4.152 0.008 81 1993462 16.0 10.1 15 Bromomethane 94 4.424 4.409 0.015 97 1342819 16.0 11.5 16 Chloroethane 64 4.548 4.534 0.014 85 612586 16.0 11.0 17 Ethanol 31 4.672 4.648 0.024 98 2190820 80.0 56.1 18 Vinyl bromide 106 4.807 4.790 0.017 97 1189919 16.0 12.0 19 2-Methylbutane 43 4.855 4.848 0.007 85 1185662 16.0 11.4 20 Acrolein 56 5.033 5.025 0.008 93 392205 16.0 10.5 21 Trichlorofluoromethane 101 5.044 5.030 0.014 99 5702636 16.0 12.9 22 Acetonitrile 40 5.093 5.075 0.018 99 931637 16.0 13.5 23 Acetone 58 5.136 5.124 0.012 99 3062269 48.0 34.5 24 Isopropyl alcohol 45 5.249 5.227 0.022 97 9653805 48.0 36.5 25 Pentane 72 5.238 5.229 0.009 98 390407 16.0 12.7 26 Ethyl ether 31 5.373 5.367 0.006 96 2644820 16.0 12.4 27 1,1-Dichloroethene 96 5.648 5.629 0.019 95 2452857 16.0 14.8 28 Acrylonitrile 53 5.718 5.705 0.013 94 2035476 16.0 15.1 29 2-Methyl-2-propanol 59 5.756 5.739 0.017 95 5133511 16.0 16.1 30 1,1,2-Trichloro-1,2,2-trif 101 5.821 5.809 0.012 96 5061965 16.0 13.6 31 Methylene Chloride 84 5.939 5.920 0.019 98 2162136 16.0 12.9 03/21/2017Page 262 of 377 Report Date: 24-Feb-2017 16:54:21 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.961 5.942 0.019 97 2329963 16.0 13.9 33 Carbon disulfide 76 6.080 6.062 0.018 99 7101466 16.0 14.9 34 trans-1,2-Dichloroethene 96 6.678 6.657 0.021 97 2529264 16.0 14.9 35 2-Methylpentane 43 6.721 6.705 0.016 94 5263706 16.0 13.0 36 Methyl tert-butyl ether 73 6.786 6.785 0.001 96 7135130 16.0 16.5 37 1,1-Dichloroethane 63 7.045 7.023 0.022 100 5075426 16.0 15.2 38 Vinyl acetate 43 7.147 7.135 0.012 100 7730530 16.0 16.1 39 2-Butanone (MEK) 72 7.530 7.522 0.008 99 1276403 16.0 15.7 40 Hexane 56 7.622 7.610 0.012 88 2060711 16.0 13.6 41 Isopropyl ether 45 7.757 7.748 0.009 96 8854520 16.0 13.6 42 cis-1,2-Dichloroethene 96 7.951 7.930 0.021 97 2694692 16.0 15.2 43 Ethyl acetate 43 8.123 8.118 0.005 99 6432390 16.0 15.5 44 Chloroform 83 8.280 8.258 0.022 98 5618386 16.0 15.5 45 Tert-butyl ethyl ether 59 8.387 8.381 0.006 95 8149213 16.0 16.0 46 Tetrahydrofuran 42 8.625 8.621 0.004 94 3179689 16.0 14.3 47 1,1,1-Trichloroethane 97 9.256 9.239 0.017 95 5864283 16.0 17.0 48 1,2-Dichloroethane 62 9.326 9.311 0.015 98 4097974 16.0 17.0 49 n-Butanol 31 9.806 9.810 -0.004 85 1087852 16.0 15.4 50 Benzene 78 9.838 9.821 0.017 98 5915532 16.0 12.6 51 Cyclohexane 69 9.860 9.849 0.011 95 906562 16.0 12.2 52 Carbon tetrachloride 117 9.876 9.860 0.016 97 5840819 16.0 16.4 53 2,3-Dimethylpentane 71 10.021 10.009 0.012 89 1664608 16.0 15.1 54 Thiophene 84 10.102 10.088 0.014 97 4358587 16.0 15.5 55 Tert-amyl methyl ether 73 10.350 10.344 0.006 97 7110699 16.0 16.2 56 Isooctane 57 10.690 10.676 0.014 98 11606245 16.0 13.5 57 1,2-Dichloropropane 63 11.067 11.062 0.005 88 2325405 16.0 11.6 58 n-Heptane 71 11.089 11.070 0.019 85 2094048 16.0 12.7 59 Trichloroethene 130 11.138 11.125 0.013 93 3199084 16.0 14.0 60 Dibromomethane 93 11.181 11.169 0.012 89 3060446 16.0 14.9 61 Dichlorobromomethane 83 11.348 11.338 0.010 99 5582595 16.0 16.6 62 1,4-Dioxane 88 11.348 11.347 0.001 87 969543 16.0 13.9 63 Methyl methacrylate 41 11.477 11.473 0.004 91 3764789 16.0 16.4 64 Methylcyclohexane 83 11.957 11.948 0.009 93 4932261 16.0 14.3 65 4-Methyl-2-pentanone (MIBK 43 12.345 12.341 0.004 98 6163255 16.0 14.7 66 cis-1,3-Dichloropropene 75 12.399 12.389 0.010 96 4444447 16.0 16.9 67 trans-1,3-Dichloropropene 75 13.122 13.112 0.010 98 4314889 16.0 18.2 68 Toluene 91 13.262 13.254 0.008 94 8326940 16.0 14.3 69 1,1,2-Trichloroethane 83 13.316 13.308 0.008 98 2427275 16.0 13.7 70 2-Methylthiophene 97 13.413 13.402 0.011 98 6834736 16.0 15.0 71 3-Methylthiophene 97 13.618 13.612 0.006 100 6707253 16.0 15.0 72 2-Hexanone 58 13.737 13.736 0.001 93 2977612 16.0 14.6 73 Chlorodibromomethane 129 14.033 14.025 0.008 97 4857610 16.0 15.2 74 n-Octane 85 14.055 14.045 0.010 89 1997649 16.0 11.8 75 Ethylene Dibromide 107 14.330 14.320 0.010 97 4575751 16.0 15.3 76 Tetrachloroethene 129 14.448 14.441 0.007 92 2789077 16.0 13.1 77 Chlorobenzene 112 15.333 15.330 0.003 94 6504560 16.0 13.2 78 2,3-Dimethylheptane 43 15.441 15.432 0.009 92 6300729 16.0 11.2 79 Ethylbenzene 91 15.656 15.647 0.009 99 10042970 16.0 13.7 80 2-Ethylthiophene 97 15.748 15.744 0.004 98 7694998 16.0 14.9 81 m-Xylene & p-Xylene 91 15.824 15.819 0.005 98 13609680 32.0 24.4 82 Bromoform 173 16.223 16.221 0.002 97 6217969 16.0 16.9 83 Styrene 104 16.287 16.282 0.005 99 5608457 16.0 15.2 03/21/2017Page 263 of 377 Report Date: 24-Feb-2017 16:54:21 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 84 n-Nonane 57 16.320 16.312 0.008 88 3961418 16.0 10.5 85 o-Xylene 91 16.352 16.347 0.005 97 7838829 16.0 13.3 86 1,1,2,2-Tetrachloroethane 83 16.659 16.658 0.001 98 5531960 16.0 12.8 87 1,2,3-Trichloropropane 110 16.821 16.819 0.002 95 1797695 16.0 14.5 88 Isopropylbenzene 105 16.967 16.963 0.004 97 9824520 16.0 12.0 89 N-Propylbenzene 120 17.544 17.540 0.004 98 2635592 16.0 12.2 90 2-Chlorotoluene 126 17.571 17.565 0.006 97 2518415 16.0 11.9 91 4-Ethyltoluene 105 17.711 17.706 0.005 98 10452735 16.0 13.0 92 1,3,5-Trimethylbenzene 120 17.797 17.790 0.007 91 4479062 16.0 12.1 93 Alpha Methyl Styrene 118 18.034 18.031 0.003 87 4371974 16.0 14.3 94 n-Decane 57 18.164 18.157 0.007 93 5603231 16.0 11.3 95 tert-Butylbenzene 119 18.245 18.240 0.005 94 8424853 16.0 11.5 96 1,2,4-Trimethylbenzene 105 18.261 18.256 0.005 97 7566924 16.0 11.0 97 1,3-Dichlorobenzene 146 18.520 18.520 0.000 98 5827565 16.0 10.5 98 sec-Butylbenzene 105 18.541 18.532 0.009 98 10747733 16.0 10.5 99 Benzyl chloride 91 18.601 18.596 0.005 98 8014177 16.0 13.3 100 1,4-Dichlorobenzene 146 18.622 18.614 0.008 96 6223742 16.0 10.9 101 4-Isopropyltoluene 119 18.714 18.710 0.004 98 9955102 16.0 11.7 102 1,2,3-Trimethylbenzene 105 18.752 18.751 0.001 98 7205534 16.0 13.0 103 Butylcyclohexane 83 18.843 18.840 0.003 89 6510976 16.0 11.5 104 1,2-Dichlorobenzene 146 18.994 18.990 0.004 95 5547661 16.0 10.2 105 2,3-Dihydroindene 117 19.010 19.001 0.009 93 6439833 16.0 10.2 106 Indene 116 19.134 19.134 0.000 91 6380743 16.0 13.8 107 n-Butylbenzene 91 19.178 19.173 0.005 98 10249297 16.0 11.3 108 Undecane 57 19.555 19.552 0.003 92 5703184 16.0 9.94 109 1,2-Dimethyl-4-Ethylbenzen 119 19.571 19.566 0.005 97 6706801 16.0 9.74 110 1,2-Dibromo-3-Chloropropan 157 19.625 19.620 0.005 98 3581933 16.0 15.2 111 1,2,4,5-Tetramethylbenzene 119 19.970 19.970 0.000 97 10215880 16.0 13.1 112 1,2,3,5-Tetramethylbenzene 119 20.024 20.024 0.000 95 7116459 16.0 14.3 113 1,2,3,4-Tetramethylbenzene 119 20.429 20.429 0.000 97 9315480 16.0 14.0 114 Dodecane 57 20.660 20.656 0.004 92 7023895 16.0 11.9 115 1,2,4-Trichlorobenzene 180 20.785 20.779 0.005 93 8326267 16.0 14.3 116 Naphthalene 128 20.914 20.913 0.001 98 14223211 16.0 13.9 117 Benzo(b)thiophene 134 21.016 21.015 0.001 99 9916966 16.0 16.2 118 Hexachlorobutadiene 225 21.167 21.166 0.001 92 8577746 16.0 14.5 119 1,2,3-Trichlorobenzene 180 21.210 21.207 0.003 95 8204831 16.0 14.2 120 2-Methylnaphthalene 142 21.928 21.929 -0.001 99 6023991 50.0 67.2 121 1-Methylnaphthalene 142 22.052 22.052 0.000 99 4765773 50.0 71.9 A 122 C6 Range 1 7.632 (7.562-7.694) 0 17203049 16.0 13.6 S 124 Xylenes, Total 100 0 48.0 37.7 S 125 1,2-Dichloroethene, Total 1 0 32.0 30.1 Reagents: 40L9DNP_00012 Amount Added: 200.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 264 of 377 Report Date: 24-Feb-2017 16:54:21 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Injection Date:24-Feb-2017 05:21:30 Instrument ID:MR Operator ID: Lims ID:IC L9 Worklist Smp#:11 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:10 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 Y ( X10 0 0 0 0 0 ) RB23IC09[MS SCAN Chro]:Total * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 4 0 4 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 8 4 ) 03/21/2017Page 265 of 377 Report Date: 24-Feb-2017 16:54:21 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Injection Date:24-Feb-2017 05:21:30 Instrument ID:MR Lims ID:IC L9 Client ID: Operator ID:ALS Bottle#:10 Worklist Smp#:11 Purge Vol:500.000 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column:RTX-5 ( 0.32 mm)Detector MS SCAN A 122 C6 Range, CAS: STL01725 7.5 Min 0 4 8 12 16 20 24 28 32 36 40 44 48 52 56 60 64 68 Y ( X10 0 0 0 0 ) RB23IC09[MS SCAN Chro]:Total 03/21/2017Page 266 of 377 FORM VII Lab Name:Job No.: SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID: AIR - GC/MS VOA CONTINUING CALIBRATION DATA 0.32(mm) 140-7345-1 MG 03/02/2017 23:17 03/02/2017 13:34 03/02/2017 20:31 ICV 140-9079/15 RTX-5 TestAmerica Knoxville Lab File ID:GLCSC02.D Heated Purge: (Y/N)NConc. Units:ppb v/v ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF Chlorodifluoromethane 0.40850.3912 2.09 2.00 4.4 35.0Ave Propene 0.98440.9322 2.11 2.00 5.6 35.0Ave Dichlorodifluoromethane 3.9253.549 2.21 2.00 10.6 35.0Ave Chloromethane 0.30120.2864 2.10 2.00 5.2 35.0Ave 1,2-Dichloro-1,1,2,2-tetrafl uoroethane 2.4642.167 2.28 2.00 13.7 35.0Ave Acetaldehyde 0.36000.4269 8.44 10.0 -15.7 35.0Ave Vinyl chloride 1.2431.096 2.27 2.00 13.4 35.0Ave 1,3-Butadiene 0.86210.7918 2.18 2.00 8.9 35.0Ave Butane 1.8401.661 2.22 2.00 10.8 35.0Ave Bromomethane 1.2021.113 2.16 2.00 8.0 35.0Ave Chloroethane 0.63190.5869 2.15 2.00 7.7 35.0Ave Ethanol 0.41850.4396 9.52 10.0 -4.8 35.0Ave Vinyl bromide 1.2521.059 2.37 2.00 18.3 35.0Ave 2-Methylbutane 1.4671.266 2.32 2.00 15.9 35.0Ave Acrolein 0.19800.1640 2.42 2.00 20.8 35.0Ave Trichlorofluoromethane 3.9823.637 2.19 2.00 9.5 35.0Ave Acetonitrile 0.36960.4020 1.84 2.00 -8.0 35.0Ave Acetone 0.36490.4274 5.13 6.00 -14.6 35.0Ave Isopropyl alcohol 1.2981.268 6.15 6.00 2.4 35.0Ave Pentane 0.23910.2020 2.37 2.00 18.3 35.0Ave Ethyl ether 1.1901.173 2.03 2.00 1.4 35.0Ave 1,1-Dichloroethene 1.1631.036 2.25 2.00 12.3 35.0Ave Acrylonitrile 0.51660.5008 2.06 2.00 3.2 35.0Ave tert-Butyl alcohol 1.5131.526 1.99 2.00 -0.8 35.0Ave 1,1,2-Trichloro-1,2,2-triflu oroethane 2.3992.193 2.19 2.00 9.4 35.0Ave Methylene Chloride 0.94760.9637 1.97 2.00 -1.7 35.0Ave 3-Chloropropene 1.1171.004 2.23 2.00 11.2 35.0Ave Carbon disulfide 2.9002.760 2.10 2.00 5.1 35.0Ave trans-1,2-Dichloroethene 1.1201.053 2.13 2.00 6.4 35.0Ave 2-Methylpentane 2.3962.095 2.29 2.00 14.3 35.0Ave Methyl tert-butyl ether 2.6282.749 1.91 2.00 -4.4 35.0Ave 1,1-Dichloroethane 2.0321.959 2.08 2.00 3.7 35.0Ave Vinyl acetate 1.9502.100 1.86 2.00 -7.2 35.0Ave 2-Butanone (MEK)0.37150.4429 1.68 2.00 -16.1 35.0Ave Hexane 0.82790.8049 2.06 2.00 2.9 35.0Ave Isopropyl ether 2.5512.823 1.81 2.00 -9.6 35.0Ave cis-1,2-Dichloroethene 1.1581.102 2.10 2.00 5.1 35.0Ave Ethyl acetate 1.4841.713 1.73 2.00 -13.4 35.0Ave Chloroform 2.7422.650 2.07 2.00 3.5 35.0Ave Tert-butyl ethyl ether 2.6572.628 2.02 2.00 1.1 35.0Ave FORM VII TO 15 LL 03/21/2017Page 267 of 377 FORM VII Lab Name:Job No.: SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID: AIR - GC/MS VOA CONTINUING CALIBRATION DATA 0.32(mm) 140-7345-1 MG 03/02/2017 23:17 03/02/2017 13:34 03/02/2017 20:31 ICV 140-9079/15 RTX-5 TestAmerica Knoxville Lab File ID:GLCSC02.D Heated Purge: (Y/N)NConc. Units:ppb v/v ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF Tetrahydrofuran 0.89540.9674 1.85 2.00 -7.4 35.0Ave 1,1,1-Trichloroethane 3.0252.916 2.08 2.00 3.7 35.0Ave 1,2-Dichloroethane 0.37150.3548 2.10 2.00 4.7 35.0Ave Benzene 0.67440.6265 2.15 2.00 7.6 35.0Ave Cyclohexane 0.11840.1103 2.15 2.00 7.3 35.0Ave 1-Butanol 0.07290.0732 1.99 2.00 -0.5 35.0Ave Carbon tetrachloride 0.65070.5843 2.23 2.00 11.4 35.0Ave 2,3-Dimethylpentane 0.14740.1547 1.91 2.00 -4.8 35.0Ave Thiophene 0.39560.3593 2.20 2.00 10.1 35.0Ave Tert-amyl methyl ether 0.52270.5252 1.99 2.00 -0.5 35.0Ave 2,2,4-Trimethylpentane 1.0410.9875 2.11 2.00 5.4 35.0Ave Heptane 0.25290.2404 2.10 2.00 5.2 35.0Ave 1,2-Dichloropropane 0.24370.2304 2.12 2.00 5.8 35.0Ave Trichloroethene 0.41890.3594 2.33 2.00 16.6 35.0Ave Dibromomethane 0.31470.2939 2.14 2.00 7.1 35.0Ave Bromodichloromethane 0.56730.5150 2.20 2.00 10.2 35.0Ave 1,4-Dioxane 0.07380.0837 1.76 2.00 -11.9 35.0Ave Methyl methacrylate 0.19740.2247 1.76 2.00 -12.1 35.0Ave Methylcyclohexane 0.43170.5102 1.69 2.00 -15.4 35.0Ave 4-Methyl-2-pentanone (MIBK)0.29590.3765 1.57 2.00 -21.4 35.0Ave cis-1,3-Dichloropropene 0.43940.4030 2.18 2.00 9.0 35.0Ave trans-1,3-Dichloropropene 0.41650.3916 2.13 2.00 6.4 35.0Ave Toluene 0.74930.7260 2.07 2.00 3.2 35.0Ave 1,1,2-Trichloroethane 0.22230.2214 2.01 2.00 0.4 35.0Ave 2-Methylthiophene 0.69800.6335 2.20 2.00 10.2 35.0Ave 3-Methylthiophene 0.71040.6274 2.27 2.00 13.2 35.0Ave 2-Hexanone 0.14770.1842 1.61 2.00 -19.8 35.0Ave Octane 0.28400.2666 2.13 2.00 6.5 35.0Ave Dibromochloromethane 0.55590.4903 2.27 2.00 13.4 35.0Ave 1,2-Dibromoethane (EDB)0.47260.4426 2.14 2.00 6.8 35.0Ave Tetrachloroethene 0.33750.3201 2.11 2.00 5.4 35.0Ave Chlorobenzene 0.68000.6369 2.14 2.00 6.8 35.0Ave 2,3-Dimethylheptane 0.68430.6487 2.11 2.00 5.5 35.0Ave Ethylbenzene 0.92740.9537 1.95 2.00 -2.8 35.0Ave 2-Ethylthiophene 0.76140.7711 1.98 2.00 -1.3 35.0Ave m-Xylene & p-Xylene 0.73850.7477 3.95 4.00 -1.2 35.0Ave Bromoform 0.50880.4775 2.13 2.00 6.6 35.0Ave Nonane 0.50780.4796 2.12 2.00 5.9 35.0Ave Styrene 0.56000.5300 2.11 2.00 5.7 35.0Ave o-Xylene 0.72530.7664 1.89 2.00 -5.4 35.0Ave 1,1,2,2-Tetrachloroethane 0.47590.5029 1.89 2.00 -5.4 35.0Ave FORM VII TO 15 LL 03/21/2017Page 268 of 377 FORM VII Lab Name:Job No.: SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID: AIR - GC/MS VOA CONTINUING CALIBRATION DATA 0.32(mm) 140-7345-1 MG 03/02/2017 23:17 03/02/2017 13:34 03/02/2017 20:31 ICV 140-9079/15 RTX-5 TestAmerica Knoxville Lab File ID:GLCSC02.D Heated Purge: (Y/N)NConc. Units:ppb v/v ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF 1,2,3-Trichloropropane 0.16100.1718 1.88 2.00 -6.3 35.0Ave Isopropylbenzene 1.0751.115 1.93 2.00 -3.6 35.0Ave Propylbenzene 0.29210.2970 1.97 2.00 -1.6 35.0Ave 2-Chlorotoluene 0.29730.2868 2.07 2.00 3.6 35.0Ave 4-Ethyltoluene 0.93801.052 1.78 2.00 -10.9 35.0Ave 1,3,5-Trimethylbenzene 0.47600.4920 1.94 2.00 -3.3 35.0Ave Alpha Methyl Styrene 0.41680.4107 2.03 2.00 1.5 35.0Ave Decane 0.61910.5838 2.12 2.00 6.1 35.0Ave tert-Butylbenzene 0.96160.998 1.93 2.00 -3.7 35.0Ave 1,2,4-Trimethylbenzene 0.86980.9131 1.91 2.00 -4.7 35.0Ave 1,3-Dichlorobenzene 0.77600.7466 2.08 2.00 3.9 35.0Ave sec-Butylbenzene 1.3001.311 1.99 2.00 -0.8 35.0Ave Benzyl chloride 0.83140.8300 2.00 2.00 0.2 35.0Ave 1,4-Dichlorobenzene 0.73980.7389 2.00 2.00 0.1 35.0Ave 4-Isopropyltoluene 1.0731.136 1.89 2.00 -5.5 35.0Ave 1,2,3-Trimethylbenzene 0.68410.6790 2.02 2.00 0.8 35.0Ave Butylcyclohexane 0.81900.7906 2.07 2.00 3.6 35.0Ave 1,2-Dichlorobenzene 0.68610.6947 1.98 2.00 -1.2 35.0Ave Indane 0.77760.8561 1.82 2.00 -9.2 35.0Ave Indene 0.76450.6255 2.45 2.00 22.2 35.0Ave Butylbenzene 0.9971.052 1.90 2.00 -5.2 35.0Ave Undecane 0.62640.6269 2.00 2.00 -0.0 35.0Ave 1,2-Dimethyl-4-Ethylbenzene 0.97470.8323 2.34 2.00 17.1 35.0Ave 1,2-Dibromo-3-Chloropropane 0.22790.2760 1.65 2.00 -17.4 35.0Ave 1,2,4,5-Tetramethylbenzene 1.0161.013 2.01 2.00 0.3 35.0Ave 1,2,3,5-Tetramethylbenzene 0.62660.6049 2.07 2.00 3.6 35.0Ave 1,2,3,4-Tetramethylbenzene 0.81030.8328 1.95 2.00 -2.7 35.0Ave Dodecane 0.57280.5776 1.98 2.00 -0.8 35.0Ave 1,2,4-Trichlorobenzene 0.60540.6049 2.00 2.00 0.0 35.0Ave Naphthalene 1.1761.261 1.87 2.00 -6.8 35.0Ave Benzo(b)thiophene 0.73470.6995 2.10 2.00 5.0 35.0Ave Hexachlorobutadiene 0.59900.5903 2.03 2.00 1.5 35.0Ave 1,2,3-Trichlorobenzene 0.58210.5493 2.12 2.00 6.0 35.0Ave 2-Methylnaphthalene 0.29210.2572 7.10 6.25 13.6 50.0Ave 1-Methylnaphthalene 0.28590.2071 8.63 6.25 38.0 50.0Ave 4-Bromofluorobenzene (Surr)0.74800.7447 4.02 4.00 0.4 35.0Ave FORM VII TO 15 LL 03/21/2017Page 269 of 377 Report Date: 03-Mar-2017 15:17:51 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GLCSC02.D Lims ID:ICV Client ID: Sample Type:ICV Inject. Date:02-Mar-2017 23:17:30 ALS Bottle#:15 Worklist Smp#:15 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004202-015 Misc. Info.:073135 Operator ID:7126 Instrument ID:MG Sublist: Method:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:03-Mar-2017 15:17:50 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK031 First Level Reviewer: barlozhetskayaa Date:03-Mar-2017 15:17:50 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.007 8.012 -0.005 84 386596 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.175 10.179 -0.004 94 1963711 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.044 15.046 -0.002 86 2019239 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.715 16.714 -0.002 96 1510451 4.00 4.02 6 Chlorodifluoromethane 67 3.456 3.461 -0.007 96 79002 2.00 2.09 7 Propene 41 3.466 3.469 -0.005 97 190374 2.00 2.11 8 Dichlorodifluoromethane 85 3.510 3.512 -0.004 100 759167 2.00 2.21 9 Chloromethane 52 3.661 3.663 -0.004 98 58255 2.00 2.10 10 1,2-Dichloro-1,1,2,2-tetra 135 3.671 3.673 -0.004 92 476482 2.00 2.28 11 Acetaldehyde 44 3.785 3.791 -0.008 92 348128 10.0 8.44 12 Vinyl chloride 62 3.806 3.806 -0.003 99 240439 2.00 2.27 13 Butadiene 54 3.876 3.881 -0.007 93 166728 2.00 2.18 14 Butane 43 3.882 3.882 -0.003 95 355823 2.00 2.22 15 Bromomethane 94 4.140 4.146 -0.009 98 232476 2.00 2.16 16 Chloroethane 64 4.259 4.265 -0.008 92 122204 2.00 2.15 17 Ethanol 31 4.356 4.370 -0.016 97 404719 10.0 9.52 18 Vinyl bromide 106 4.513 4.519 -0.009 97 242194 2.00 2.37 19 2-Methylbutane 43 4.561 4.567 -0.008 91 283732 2.00 2.32 20 Acrolein 56 4.744 4.730 0.012 94 38302 2.00 2.42 21 Trichlorofluoromethane 101 4.750 4.750 -0.003 99 770152 2.00 2.19 22 Acetonitrile 40 4.793 4.805 -0.015 95 71486 2.00 1.84 23 Acetone 58 4.836 4.846 -0.013 99 211720 6.00 5.13 24 Pentane 72 4.944 4.946 -0.005 96 46241 2.00 2.37 25 Isopropyl alcohol 45 4.933 4.960 -0.030 93 753308 6.00 6.15 26 Ethyl ether 31 5.073 5.086 -0.017 90 230081 2.00 2.03 27 1,1-Dichloroethene 96 5.359 5.364 -0.008 97 224917 2.00 2.25 28 Acrylonitrile 53 5.440 5.447 -0.010 95 99914 2.00 2.06 29 2-Methyl-2-propanol 59 5.462 5.491 -0.032 95 292694 2.00 1.99 30 1,1,2-Trichloro-1,2,2-trif 101 5.526 5.533 -0.010 96 464020 2.00 2.19 31 Methylene Chloride 84 5.661 5.666 -0.008 93 183272 2.00 1.97 03/21/2017Page 270 of 377 Report Date: 03-Mar-2017 15:17:51 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GLCSC02.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.677 5.681 -0.007 97 216036 2.00 2.23 33 Carbon disulfide 76 5.801 5.807 -0.009 100 560811 2.00 2.10 34 trans-1,2-Dichloroethene 96 6.400 6.403 -0.006 98 216678 2.00 2.13 35 2-Methylpentane 43 6.432 6.436 -0.007 93 463389 2.00 2.29 36 Methyl tert-butyl ether 73 6.519 6.529 -0.015 95 508324 2.00 1.91 37 1,1-Dichloroethane 63 6.783 6.783 -0.004 100 393066 2.00 2.08 38 Vinyl acetate 43 6.885 6.894 -0.013 100 377143 2.00 1.86 39 2-Butanone (MEK) 72 7.284 7.300 -0.021 98 71843 2.00 1.68 40 Hexane 56 7.344 7.346 -0.006 87 160112 2.00 2.06 41 Isopropyl ether 45 7.489 7.498 -0.013 94 493370 2.00 1.81 42 cis-1,2-Dichloroethene 96 7.699 7.703 -0.008 95 223980 2.00 2.10 43 Ethyl acetate 43 7.888 7.897 -0.013 98 287015 2.00 1.73 44 Chloroform 83 8.028 8.030 -0.007 96 530340 2.00 2.07 45 Tert-butyl ethyl ether 59 8.131 8.139 -0.013 95 513860 2.00 2.02 46 Tetrahydrofuran 42 8.390 8.405 -0.020 91 173164 2.00 1.85 47 1,1,1-Trichloroethane 97 9.004 9.008 -0.009 94 585058 2.00 2.08 48 1,2-Dichloroethane 62 9.096 9.101 -0.010 99 364940 2.00 2.10 49 Benzene 78 9.592 9.595 -0.007 96 662489 2.00 2.15 50 Cyclohexane 69 9.598 9.599 -0.006 93 116303 2.00 2.15 52 Carbon tetrachloride 117 9.625 9.624 -0.005 99 639223 2.00 2.23 51 n-Butanol 31 9.603 9.643 -0.044 69 71586 2.00 1.99 53 2,3-Dimethylpentane 71 9.749 9.749 -0.005 90 144769 2.00 1.91 54 Thiophene 84 9.867 9.868 -0.006 95 388659 2.00 2.20 55 Tert-amyl methyl ether 73 10.104 10.116 -0.017 98 513507 2.00 1.99 56 Isooctane 57 10.423 10.425 -0.007 98 1022172 2.00 2.11 57 n-Heptane 71 10.827 10.825 -0.004 89 248413 2.00 2.10 58 1,2-Dichloropropane 63 10.859 10.857 -0.003 86 239419 2.00 2.12 59 Trichloroethene 130 10.908 10.908 -0.005 97 411549 2.00 2.33 60 Dibromomethane 93 10.973 10.973 -0.005 93 309127 2.00 2.14 61 Dichlorobromomethane 83 11.140 11.138 -0.003 98 557263 2.00 2.20 62 1,4-Dioxane 88 11.151 11.167 -0.022 90 72469 2.00 1.76 63 Methyl methacrylate 41 11.269 11.272 -0.009 95 193930 2.00 1.76 64 Methylcyclohexane 83 11.711 11.712 -0.007 95 424041 2.00 1.69 65 4-Methyl-2-pentanone (MIBK 43 12.137 12.147 -0.016 97 290640 2.00 1.57 66 cis-1,3-Dichloropropene 75 12.186 12.184 -0.004 95 431667 2.00 2.18 67 trans-1,3-Dichloropropene 75 12.903 12.909 -0.008 97 420676 2.00 2.13 68 Toluene 91 13.032 13.033 -0.003 94 756882 2.00 2.07 69 1,1,2-Trichloroethane 83 13.103 13.098 -0.003 98 224553 2.00 2.01 70 2-Methylthiophene 97 13.183 13.184 -0.003 97 705115 2.00 2.20 71 3-Methylthiophene 97 13.388 13.392 -0.006 98 717654 2.00 2.27 72 2-Hexanone 58 13.523 13.532 -0.012 94 149224 2.00 1.61 73 n-Octane 85 13.787 13.789 -0.005 90 286912 2.00 2.13 74 Chlorodibromomethane 129 13.809 13.813 -0.007 97 561526 2.00 2.27 75 Ethylene Dibromide 107 14.100 14.103 -0.006 98 477427 2.00 2.14 76 Tetrachloroethene 129 14.203 14.205 -0.004 95 340878 2.00 2.11 77 Chlorobenzene 112 15.092 15.092 -0.003 94 686908 2.00 2.14 78 2,3-Dimethylheptane 43 15.162 15.162 -0.003 91 691277 2.00 2.11 79 Ethylbenzene 91 15.400 15.400 -0.002 98 936784 2.00 1.95 80 2-Ethylthiophene 97 15.497 15.500 -0.005 98 769145 2.00 1.98 81 m-Xylene & p-Xylene 91 15.567 15.569 -0.005 99 1491976 4.00 3.95 82 Bromoform 173 15.988 15.989 -0.003 96 514011 2.00 2.13 84 Styrene 104 16.036 16.035 -0.001 97 565722 2.00 2.11 03/21/2017Page 271 of 377 Report Date: 03-Mar-2017 15:17:51 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GLCSC02.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 83 n-Nonane 57 16.036 16.036 -0.002 87 512951 2.00 2.12 85 o-Xylene 91 16.095 16.096 -0.004 98 732627 2.00 1.89 86 1,1,2,2-Tetrachloroethane 83 16.419 16.419 -0.003 99 480716 2.00 1.89 87 1,2,3-Trichloropropane 110 16.575 16.574 -0.002 97 162652 2.00 1.88 88 Isopropylbenzene 105 16.699 16.700 -0.004 98 1085858 2.00 1.93 89 N-Propylbenzene 120 17.255 17.254 -0.002 99 295039 2.00 1.97 90 2-Chlorotoluene 126 17.287 17.285 -0.001 96 300265 2.00 2.07 91 4-Ethyltoluene 105 17.416 17.415 -0.002 98 947503 2.00 1.78 92 1,3,5-Trimethylbenzene 120 17.497 17.499 -0.005 93 480802 2.00 1.94 93 Alpha Methyl Styrene 118 17.740 17.741 -0.004 89 420994 2.00 2.03 94 n-Decane 57 17.842 17.843 -0.004 93 625417 2.00 2.12 95 tert-Butylbenzene 119 17.945 17.946 -0.004 91 971341 2.00 1.93 96 1,2,4-Trimethylbenzene 105 17.961 17.960 -0.002 95 878608 2.00 1.91 97 1,3-Dichlorobenzene 146 18.231 18.229 -0.001 98 783835 2.00 2.08 98 sec-Butylbenzene 105 18.231 18.232 -0.004 98 1313447 2.00 1.99 99 Benzyl chloride 91 18.312 18.308 0.001 98 839876 2.00 2.00 100 1,4-Dichlorobenzene 146 18.322 18.321 -0.002 95 747277 2.00 2.00 101 4-Isopropyltoluene 119 18.409 18.407 -0.001 97 1084150 2.00 1.89 102 1,2,3-Trimethylbenzene 105 18.452 18.451 -0.002 97 691077 2.00 2.02 103 Butylcyclohexane 83 18.527 18.524 0.000 96 827296 2.00 2.07 104 1,2-Dichlorobenzene 146 18.694 18.695 -0.004 95 693112 2.00 1.98 105 2,3-Dihydroindene 117 18.700 18.699 -0.002 93 785463 2.00 1.82 106 Indene 116 18.835 18.830 0.002 92 772251 2.00 2.45 107 n-Butylbenzene 91 18.862 18.859 0.000 97 1006839 2.00 1.90 108 Undecane 57 19.218 19.214 0.001 93 632789 2.00 2.00 109 1,2-Dimethyl-4-Ethylbenzen 119 19.244 19.244 -0.003 97 984597 2.00 2.34 110 1,2-Dibromo-3-Chloropropan 157 19.315 19.314 -0.002 99 230202 2.00 1.65 111 1,2,4,5-Tetramethylbenzene 119 19.638 19.639 -0.004 96 1026501 2.00 2.01 112 1,2,3,5-Tetramethylbenzene 119 19.697 19.693 0.001 95 632967 2.00 2.07 113 1,2,3,4-Tetramethylbenzene 119 20.091 20.088 -0.001 97 818553 2.00 1.95 114 Dodecane 57 20.285 20.283 -0.001 94 578663 2.00 1.98 115 1,2,4-Trichlorobenzene 180 20.425 20.423 -0.002 94 611563 2.00 2.00 116 Naphthalene 128 20.555 20.552 0.000 99 1187650 2.00 1.87 117 Benzo(b)thiophene 134 20.652 20.650 -0.001 99 742169 2.00 2.10 118 Hexachlorobutadiene 225 20.781 20.779 -0.002 95 605032 2.00 2.03 119 1,2,3-Trichlorobenzene 180 20.830 20.828 -0.001 95 588012 2.00 2.12 120 2-Methylnaphthalene 142 21.628 21.624 0.000 100 922169 6.25 7.10 121 1-Methylnaphthalene 142 21.806 21.804 -0.002 100 902671 6.25 8.63 A 124 Toluene Range 1 13.033 (12.998-13.068) 0 1878205 2.00 2.14 A 125 C8 Range 1 13.798 (13.783-13.813) 0 4313868 2.00 2.80 S 126 Xylenes, Total 100 0 6.00 5.85 S 127 1,2-Dichloroethene, Total 1 0 4.00 4.23 Reagents: 40CV101S_00031 Amount Added: 100.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 272 of 377 Report Date: 03-Mar-2017 15:17:51 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GLCSC02.D Injection Date:02-Mar-2017 23:17:30 Instrument ID:MG Operator ID:7126 Lims ID:ICV Worklist Smp#:15 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:15 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 Y ( X10 0 0 0 0 ) GLCSC02[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 0 0 7 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 7 5 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 4 4 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 7 1 0 ) 03/21/2017Page 273 of 377 FORM VII Lab Name:Job No.: SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID: AIR - GC/MS VOA CONTINUING CALIBRATION DATA 0.32(mm) 140-7345-1 MG 03/10/2017 08:21 03/02/2017 13:34 03/02/2017 20:31 CCVIS 140-9158/2 RTX-5 TestAmerica Knoxville Lab File ID:GCCVC10.D Heated Purge: (Y/N)NConc. Units:ppb v/v ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF Chlorodifluoromethane 0.48340.3912 2.47 2.00 23.6 30.0Ave Propene 1.0700.9322 2.30 2.00 14.8 30.0Ave Dichlorodifluoromethane 4.6133.549 2.60 2.00 30.0 30.0Ave Chloromethane 0.34300.2864 2.40 2.00 19.8 30.0Ave 1,2-Dichloro-1,1,2,2-tetrafl uoroethane 2.5892.167 2.39 2.00 19.5 30.0Ave Acetaldehyde 0.37970.4269 8.90 10.0 -11.1 30.0Ave Vinyl chloride 1.3421.096 2.45 2.00 22.4 30.0Ave 1,3-Butadiene 0.90180.7918 2.28 2.00 13.9 30.0Ave Butane 1.9861.661 2.39 2.00 19.6 30.0Ave Bromomethane 1.1921.113 2.14 2.00 7.1 30.0Ave Chloroethane 0.62860.5869 2.14 2.00 7.1 30.0Ave Ethanol 0.46170.4396 10.5 10.0 5.0 30.0Ave Vinyl bromide 1.2071.059 2.28 2.00 14.0 30.0Ave 2-Methylbutane 1.3131.266 2.08 2.00 3.7 30.0Ave Acrolein 0.20800.1640 2.54 2.00 26.9 30.0Ave Trichlorofluoromethane 4.3343.637 2.38 2.00 19.2 30.0Ave Acetonitrile 0.38860.4020 1.93 2.00 -3.3 30.0Ave Acetone 0.38560.4274 5.42 6.00 -9.8 30.0Ave Isopropyl alcohol 1.2781.268 6.05 6.00 0.8 30.0Ave Pentane 0.23230.2020 2.30 2.00 15.0 30.0Ave Ethyl ether 1.1141.173 1.90 2.00 -5.0 30.0Ave 1,1-Dichloroethene 1.1651.036 2.25 2.00 12.5 30.0Ave Acrylonitrile 0.53230.5008 2.13 2.00 6.3 30.0Ave tert-Butyl alcohol 1.6121.526 2.11 2.00 5.6 30.0Ave 1,1,2-Trichloro-1,2,2-triflu oroethane 2.5692.193 2.34 2.00 17.1 30.0Ave Methylene Chloride 0.94660.9637 1.97 2.00 -1.8 30.0Ave 3-Chloropropene 1.1101.004 2.21 2.00 10.5 30.0Ave Carbon disulfide 2.8732.760 2.08 2.00 4.1 30.0Ave trans-1,2-Dichloroethene 1.1011.053 2.09 2.00 4.6 30.0Ave 2-Methylpentane 2.6602.095 2.54 2.00 26.9 30.0Ave Methyl tert-butyl ether 3.2752.749 2.38 2.00 19.2 30.0Ave 1,1-Dichloroethane 2.2431.959 2.29 2.00 14.5 30.0Ave Vinyl acetate 2.7422.100 2.61 2.00 30.6 *30.0Ave 2-Butanone (MEK)0.46970.4429 2.12 2.00 6.0 30.0Ave Hexane 0.90940.8049 2.26 2.00 13.0 30.0Ave Isopropyl ether 3.2542.823 2.31 2.00 15.3 30.0Ave cis-1,2-Dichloroethene 1.1881.102 2.16 2.00 7.8 30.0Ave Ethyl acetate 2.0921.713 2.44 2.00 22.1 30.0Ave Chloroform 2.9872.650 2.26 2.00 12.7 30.0Ave Tert-butyl ethyl ether 3.3972.628 2.59 2.00 29.2 30.0Ave FORM VII TO 15 LL 03/21/2017Page 274 of 377 FORM VII Lab Name:Job No.: SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID: AIR - GC/MS VOA CONTINUING CALIBRATION DATA 0.32(mm) 140-7345-1 MG 03/10/2017 08:21 03/02/2017 13:34 03/02/2017 20:31 CCVIS 140-9158/2 RTX-5 TestAmerica Knoxville Lab File ID:GCCVC10.D Heated Purge: (Y/N)NConc. Units:ppb v/v ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF Tetrahydrofuran 1.1740.9674 2.43 2.00 21.4 30.0Ave 1,1,1-Trichloroethane 3.3572.916 2.30 2.00 15.1 30.0Ave 1,2-Dichloroethane 0.42770.3548 2.41 2.00 20.5 30.0Ave Benzene 0.69380.6265 2.22 2.00 10.7 30.0Ave Cyclohexane 0.12060.1103 2.19 2.00 9.3 30.0Ave 1-Butanol 0.08860.0732 2.42 2.00 21.0 30.0Ave Carbon tetrachloride 0.71010.5843 2.43 2.00 21.5 30.0Ave 2,3-Dimethylpentane 0.15430.1547 2.00 2.00 -0.3 30.0Ave Thiophene 0.41460.3593 2.31 2.00 15.4 30.0Ave Tert-amyl methyl ether 0.64890.5252 2.47 2.00 23.6 30.0Ave 2,2,4-Trimethylpentane 1.1040.9875 2.24 2.00 11.8 30.0Ave Heptane 0.25800.2404 2.15 2.00 7.3 30.0Ave 1,2-Dichloropropane 0.25270.2304 2.19 2.00 9.7 30.0Ave Trichloroethene 0.36890.3594 2.05 2.00 2.7 30.0Ave Dibromomethane 0.32070.2939 2.18 2.00 9.1 30.0Ave Bromodichloromethane 0.60790.5150 2.36 2.00 18.0 30.0Ave 1,4-Dioxane 0.08650.0837 2.07 2.00 3.3 30.0Ave Methyl methacrylate 0.27700.2247 2.47 2.00 23.3 30.0Ave Methylcyclohexane 0.43880.5102 1.72 2.00 -14.0 30.0Ave 4-Methyl-2-pentanone (MIBK)0.39060.3765 2.08 2.00 3.7 30.0Ave cis-1,3-Dichloropropene 0.47090.4030 2.34 2.00 16.8 30.0Ave trans-1,3-Dichloropropene 0.46620.3916 2.38 2.00 19.0 30.0Ave Toluene 0.82140.7260 2.26 2.00 13.1 30.0Ave 1,1,2-Trichloroethane 0.23540.2214 2.13 2.00 6.3 30.0Ave 2-Methylthiophene 0.73290.6335 2.32 2.00 15.7 30.0Ave 3-Methylthiophene 0.75120.6274 2.40 2.00 19.7 30.0Ave 2-Hexanone 0.18760.1842 2.04 2.00 1.8 30.0Ave Octane 0.29480.2666 2.21 2.00 10.6 30.0Ave Dibromochloromethane 0.59280.4903 2.42 2.00 20.9 30.0Ave 1,2-Dibromoethane (EDB)0.49260.4426 2.23 2.00 11.3 30.0Ave Tetrachloroethene 0.35640.3201 2.23 2.00 11.3 30.0Ave Chlorobenzene 0.70600.6369 2.22 2.00 10.8 30.0Ave 2,3-Dimethylheptane 0.76900.6487 2.37 2.00 18.5 30.0Ave Ethylbenzene 1.1040.9537 2.32 2.00 15.8 30.0Ave 2-Ethylthiophene 0.88130.7711 2.29 2.00 14.3 30.0Ave m-Xylene & p-Xylene 0.89830.7477 4.81 4.00 20.1 30.0Ave Bromoform 0.56240.4775 2.36 2.00 17.8 30.0Ave Styrene 0.63560.5300 2.40 2.00 19.9 30.0Ave Nonane 0.54390.4796 2.27 2.00 13.4 30.0Ave o-Xylene 0.89720.7664 2.34 2.00 17.1 30.0Ave 1,1,2,2-Tetrachloroethane 0.60140.5029 2.39 2.00 19.6 30.0Ave FORM VII TO 15 LL 03/21/2017Page 275 of 377 FORM VII Lab Name:Job No.: SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID: AIR - GC/MS VOA CONTINUING CALIBRATION DATA 0.32(mm) 140-7345-1 MG 03/10/2017 08:21 03/02/2017 13:34 03/02/2017 20:31 CCVIS 140-9158/2 RTX-5 TestAmerica Knoxville Lab File ID:GCCVC10.D Heated Purge: (Y/N)NConc. Units:ppb v/v ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF 1,2,3-Trichloropropane 0.20580.1718 2.40 2.00 19.8 30.0Ave Isopropylbenzene 1.3151.115 2.36 2.00 18.0 30.0Ave Propylbenzene 0.35060.2970 2.36 2.00 18.1 30.0Ave 2-Chlorotoluene 0.33080.2868 2.31 2.00 15.3 30.0Ave 4-Ethyltoluene 1.1881.052 2.26 2.00 12.9 30.0Ave 1,3,5-Trimethylbenzene 0.59150.4920 2.41 2.00 20.2 30.0Ave Alpha Methyl Styrene 0.49130.4107 2.39 2.00 19.6 30.0Ave Decane 0.71530.5838 2.45 2.00 22.5 30.0Ave tert-Butylbenzene 1.2220.998 2.45 2.00 22.4 30.0Ave 1,2,4-Trimethylbenzene 1.1160.9131 2.45 2.00 22.3 30.0Ave 1,3-Dichlorobenzene 0.84290.7466 2.26 2.00 12.9 30.0Ave sec-Butylbenzene 1.6031.311 2.45 2.00 22.3 30.0Ave Benzyl chloride 1.0890.8300 2.63 2.00 31.2 *30.0Ave 1,4-Dichlorobenzene 0.81830.7389 2.22 2.00 10.7 30.0Ave 4-Isopropyltoluene 1.3871.136 2.44 2.00 22.1 30.0Ave 1,2,3-Trimethylbenzene 0.89920.6790 2.65 2.00 32.4 *30.0Ave Butylcyclohexane 0.90090.7906 2.28 2.00 13.9 30.0Ave 1,2-Dichlorobenzene 0.78910.6947 2.27 2.00 13.6 30.0Ave Indane 0.95740.8561 2.24 2.00 11.8 30.0Ave Indene 0.93420.6255 2.99 2.00 49.4 *30.0Ave Butylbenzene 1.3231.052 2.52 2.00 25.7 30.0Ave Undecane 0.79540.6269 2.54 2.00 26.9 30.0Ave 1,2-Dimethyl-4-Ethylbenzene 1.2820.8323 3.08 2.00 54.0 *30.0Ave 1,2-Dibromo-3-Chloropropane 0.28930.2760 2.10 2.00 4.8 30.0Ave 1,2,4,5-Tetramethylbenzene 1.3631.013 2.69 2.00 34.6 *30.0Ave 1,2,3,5-Tetramethylbenzene 0.83310.6049 2.76 2.00 37.7 *30.0Ave 1,2,3,4-Tetramethylbenzene 1.0740.8328 2.58 2.00 29.0 30.0Ave Dodecane 0.76860.5776 2.66 2.00 33.1 *30.0Ave 1,2,4-Trichlorobenzene 0.70040.6049 2.32 2.00 15.8 30.0Ave Naphthalene 1.4331.261 2.27 2.00 13.6 30.0Ave Benzo(b)thiophene 0.87430.6995 2.50 2.00 25.0 30.0Ave Hexachlorobutadiene 0.72890.5903 2.47 2.00 23.5 30.0Ave 1,2,3-Trichlorobenzene 0.67290.5493 2.45 2.00 22.5 30.0Ave 2-Methylnaphthalene 0.34250.2572 8.33 6.25 33.2 50.0Ave 1-Methylnaphthalene 0.32980.2071 9.96 6.25 59.2 *50.0Ave 4-Bromofluorobenzene (Surr)0.79550.7447 4.27 4.00 6.8 30.0Ave FORM VII TO 15 LL 03/21/2017Page 276 of 377 Report Date: 10-Mar-2017 11:36:24 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GCCVC10.D Lims ID:CCVIS Client ID: Sample Type:CCVIS Inject. Date:10-Mar-2017 08:21:30 ALS Bottle#:15 Worklist Smp#:2 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004228-002 Misc. Info.:S31 Operator ID:7126 Instrument ID:MG Sublist:chrom-MG_TO15*sub5 Method:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 11:36:23 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 11:36:23 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.001 8.001 0.000 86 284389 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.169 10.169 0.000 95 1474377 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.038 15.038 0.000 88 1473079 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.710 16.710 0.000 95 1171759 4.00 4.27 6 Chlorodifluoromethane 67 3.461 3.461 0.000 97 68770 2.00 2.47 7 Propene 41 3.472 3.472 0.000 97 152258 2.00 2.30 8 Dichlorodifluoromethane 85 3.515 3.515 0.000 100 656352 2.00 2.60 9 Chloromethane 52 3.666 3.666 0.000 98 48792 2.00 2.40 10 1,2-Dichloro-1,1,2,2-tetra 135 3.677 3.677 0.000 92 368344 2.00 2.39 11 Acetaldehyde 44 3.790 3.790 0.000 90 270105 10.0 8.90 12 Vinyl chloride 62 3.806 3.806 0.000 99 190922 2.00 2.45 13 Butadiene 54 3.882 3.882 0.000 84 128301 2.00 2.28 14 Butane 43 3.882 3.882 0.000 95 282548 2.00 2.39 15 Bromomethane 94 4.146 4.146 0.000 97 169544 2.00 2.14 16 Chloroethane 64 4.264 4.264 0.000 90 89437 2.00 2.14 17 Ethanol 31 4.361 4.361 0.000 97 328424 10.0 10.5 18 Vinyl bromide 106 4.518 4.518 0.000 95 171764 2.00 2.28 19 2-Methylbutane 43 4.566 4.566 0.000 90 186807 2.00 2.08 20 Acrolein 56 4.744 4.744 0.000 97 29598 2.00 2.54 21 Trichlorofluoromethane 101 4.750 4.750 0.000 99 616541 2.00 2.38 22 Acetonitrile 40 4.798 4.798 0.000 98 55283 2.00 1.93 23 Acetone 58 4.836 4.836 0.000 99 164609 6.00 5.42 25 Isopropyl alcohol 45 4.938 4.938 0.000 94 545409 6.00 6.05 24 Pentane 72 4.944 4.944 0.000 96 33044 2.00 2.30 26 Ethyl ether 31 5.079 5.079 0.000 92 158533 2.00 1.90 27 1,1-Dichloroethene 96 5.359 5.359 0.000 97 165768 2.00 2.25 28 Acrylonitrile 53 5.440 5.440 0.000 96 75734 2.00 2.13 29 2-Methyl-2-propanol 59 5.461 5.461 0.000 95 229289 2.00 2.11 30 1,1,2-Trichloro-1,2,2-trif 101 5.532 5.532 0.000 94 365502 2.00 2.34 31 Methylene Chloride 84 5.666 5.666 0.000 90 134673 2.00 1.97 03/21/2017Page 277 of 377 Report Date: 10-Mar-2017 11:36:24 Chrom Revision: 2.2 05-Mar-2017 11:38:00 Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GCCVC10.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.683 5.683 0.000 94 157875 2.00 2.21 33 Carbon disulfide 76 5.801 5.801 0.000 100 408738 2.00 2.08 34 trans-1,2-Dichloroethene 96 6.400 6.400 0.000 96 156647 2.00 2.09 35 2-Methylpentane 43 6.432 6.432 0.000 93 378422 2.00 2.54 36 Methyl tert-butyl ether 73 6.518 6.518 0.000 96 465949 2.00 2.38 37 1,1-Dichloroethane 63 6.783 6.783 0.000 100 319153 2.00 2.29 38 Vinyl acetate 43 6.885 6.885 0.000 100 390124 2.00 2.61 39 2-Butanone (MEK) 72 7.284 7.284 0.000 99 66822 2.00 2.12 40 Hexane 56 7.343 7.343 0.000 88 129385 2.00 2.26 41 Isopropyl ether 45 7.484 7.484 0.000 95 462987 2.00 2.31 42 cis-1,2-Dichloroethene 96 7.699 7.699 0.000 98 169047 2.00 2.16 43 Ethyl acetate 43 7.883 7.883 0.000 98 297666 2.00 2.44 44 Chloroform 83 8.028 8.028 0.000 96 424980 2.00 2.26 45 Tert-butyl ethyl ether 59 8.125 8.125 0.000 96 483346 2.00 2.59 46 Tetrahydrofuran 42 8.390 8.390 0.000 91 167033 2.00 2.43 47 1,1,1-Trichloroethane 97 9.004 9.004 0.000 95 477578 2.00 2.30 48 1,2-Dichloroethane 62 9.096 9.096 0.000 99 315424 2.00 2.41 49 Benzene 78 9.592 9.592 0.000 96 511711 2.00 2.22 50 Cyclohexane 69 9.597 9.597 0.000 87 88928 2.00 2.19 51 n-Butanol 31 9.608 9.608 0.000 70 65370 2.00 2.42 52 Carbon tetrachloride 117 9.619 9.619 0.000 97 523745 2.00 2.43 53 2,3-Dimethylpentane 71 9.748 9.748 0.000 90 113785 2.00 2.00 54 Thiophene 84 9.867 9.867 0.000 96 305806 2.00 2.31 55 Tert-amyl methyl ether 73 10.104 10.104 0.000 98 478660 2.00 2.47 56 Isooctane 57 10.422 10.422 0.000 97 814011 2.00 2.24 57 n-Heptane 71 10.821 10.821 0.000 91 190314 2.00 2.15 58 1,2-Dichloropropane 63 10.854 10.854 0.000 88 186373 2.00 2.19 59 Trichloroethene 130 10.908 10.908 0.000 95 272118 2.00 2.05 60 Dibromomethane 93 10.967 10.967 0.000 95 236523 2.00 2.18 61 Dichlorobromomethane 83 11.134 11.134 0.000 98 448339 2.00 2.36 62 1,4-Dioxane 88 11.150 11.150 0.000 95 63777 2.00 2.07 63 Methyl methacrylate 41 11.264 11.264 0.000 92 204332 2.00 2.47 64 Methylcyclohexane 83 11.711 11.711 0.000 95 323619 2.00 1.72 65 4-Methyl-2-pentanone (MIBK 43 12.137 12.137 0.000 96 288080 2.00 2.08 66 cis-1,3-Dichloropropene 75 12.180 12.180 0.000 96 347340 2.00 2.34 67 trans-1,3-Dichloropropene 75 12.903 12.903 0.000 97 343528 2.00 2.38 68 Toluene 91 13.027 13.027 0.000 93 605300 2.00 2.26 69 1,1,2-Trichloroethane 83 13.097 13.097 0.000 98 173494 2.00 2.13 70 2-Methylthiophene 97 13.178 13.178 0.000 98 540109 2.00 2.32 71 3-Methylthiophene 97 13.388 13.388 0.000 99 553596 2.00 2.40 72 2-Hexanone 58 13.518 13.518 0.000 93 138228 2.00 2.04 73 n-Octane 85 13.787 13.787 0.000 90 217215 2.00 2.21 74 Chlorodibromomethane 129 13.809 13.809 0.000 97 436836 2.00 2.42 75 Ethylene Dibromide 107 14.100 14.100 0.000 97 363011 2.00 2.23 76 Tetrachloroethene 129 14.203 14.203 0.000 94 262625 2.00 2.23 77 Chlorobenzene 112 15.087 15.087 0.000 92 520253 2.00 2.22 78 2,3-Dimethylheptane 43 15.157 15.157 0.000 93 566689 2.00 2.37 79 Ethylbenzene 91 15.394 15.394 0.000 99 813912 2.00 2.32 80 2-Ethylthiophene 97 15.497 15.497 0.000 98 649445 2.00 2.29 81 m-Xylene & p-Xylene 91 15.567 15.567 0.000 99 1324027 4.00 4.81 82 Bromoform 173 15.982 15.982 0.000 95 414448 2.00 2.36 84 Styrene 104 16.031 16.031 0.000 97 468394 2.00 2.40 03/21/2017Page 278 of 377 Report Date: 10-Mar-2017 11:36:24 Chrom Revision: 2.2 05-Mar-2017 11:38:00 Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GCCVC10.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 83 n-Nonane 57 16.036 16.036 0.000 87 400835 2.00 2.27 85 o-Xylene 91 16.090 16.090 0.000 98 661156 2.00 2.34 86 1,1,2,2-Tetrachloroethane 83 16.413 16.413 0.000 98 443220 2.00 2.39 87 1,2,3-Trichloropropane 110 16.570 16.570 0.000 97 151664 2.00 2.40 88 Isopropylbenzene 105 16.694 16.694 0.000 97 969348 2.00 2.36 89 N-Propylbenzene 120 17.249 17.249 0.000 99 258398 2.00 2.36 90 2-Chlorotoluene 126 17.282 17.282 0.000 97 243807 2.00 2.31 91 4-Ethyltoluene 105 17.411 17.411 0.000 98 875761 2.00 2.26 92 1,3,5-Trimethylbenzene 120 17.497 17.497 0.000 92 435900 2.00 2.41 93 Alpha Methyl Styrene 118 17.740 17.740 0.000 87 362059 2.00 2.39 94 n-Decane 57 17.842 17.842 0.000 93 527128 2.00 2.45 95 tert-Butylbenzene 119 17.945 17.945 0.000 92 900836 2.00 2.45 96 1,2,4-Trimethylbenzene 105 17.956 17.956 0.000 96 822756 2.00 2.45 97 1,3-Dichlorobenzene 146 18.225 18.225 0.000 98 621147 2.00 2.26 98 sec-Butylbenzene 105 18.231 18.231 0.000 98 1181468 2.00 2.45 99 Benzyl chloride 91 18.306 18.306 0.000 98 802616 2.00 2.63 100 1,4-Dichlorobenzene 146 18.317 18.317 0.000 95 603053 2.00 2.22 101 4-Isopropyltoluene 119 18.403 18.403 0.000 97 1021977 2.00 2.44 102 1,2,3-Trimethylbenzene 105 18.446 18.446 0.000 98 662638 2.00 2.65 103 Butylcyclohexane 83 18.522 18.522 0.000 94 663866 2.00 2.28 104 1,2-Dichlorobenzene 146 18.694 18.694 0.000 94 581531 2.00 2.27 105 2,3-Dihydroindene 117 18.700 18.700 0.000 93 705526 2.00 2.24 106 Indene 116 18.829 18.829 0.000 91 688445 2.00 2.99 107 n-Butylbenzene 91 18.856 18.856 0.000 98 974727 2.00 2.52 108 Undecane 57 19.212 19.212 0.000 93 586142 2.00 2.54 109 1,2-Dimethyl-4-Ethylbenzen 119 19.244 19.244 0.000 97 944707 2.00 3.08 110 1,2-Dibromo-3-Chloropropan 157 19.314 19.314 0.000 96 213219 2.00 2.10 111 1,2,4,5-Tetramethylbenzene 119 19.638 19.638 0.000 96 1004245 2.00 2.69 112 1,2,3,5-Tetramethylbenzene 119 19.692 19.692 0.000 94 613908 2.00 2.76 113 1,2,3,4-Tetramethylbenzene 119 20.086 20.086 0.000 96 791749 2.00 2.58 114 Dodecane 57 20.285 20.285 0.000 93 566404 2.00 2.66 115 1,2,4-Trichlorobenzene 180 20.420 20.420 0.000 94 516115 2.00 2.32 116 Naphthalene 128 20.549 20.549 0.000 99 1055986 2.00 2.27 117 Benzo(b)thiophene 134 20.646 20.646 0.000 99 644261 2.00 2.50 118 Hexachlorobutadiene 225 20.781 20.781 0.000 95 537171 2.00 2.47 119 1,2,3-Trichlorobenzene 180 20.830 20.830 0.000 95 495900 2.00 2.45 120 2-Methylnaphthalene 142 21.622 21.622 0.000 100 788822 6.25 8.33 121 1-Methylnaphthalene 142 21.806 21.806 0.000 100 759671 6.25 9.96 A 124 Toluene Range 1 13.022 (12.987-13.057) 0 1518574 2.00 2.31 A 125 C8 Range 1 13.792 (13.777-13.807) 0 3428644 2.00 2.96 S 126 Xylenes, Total 100 0 6.00 7.15 S 127 1,2-Dichloroethene, Total 1 0 4.00 4.25 Reagents: 40CV101S_00031 Amount Added: 100.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 279 of 377 Report Date: 10-Mar-2017 11:36:24 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GCCVC10.D Injection Date:10-Mar-2017 08:21:30 Instrument ID:MG Operator ID:7126 Lims ID:CCVIS Worklist Smp#:2 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:15 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 Y ( X10 0 0 0 0 ) GCCVC10[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 0 0 7 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 6 9)* C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 3 8 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 7 1 0 ) 03/21/2017Page 280 of 377 FORM VII Lab Name:Job No.: SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID: AIR - GC/MS VOA CONTINUING CALIBRATION DATA 0.32(mm) 140-7345-1 MR 02/24/2017 09:49 02/23/2017 22:59 02/24/2017 05:21 ICV 140-8740/17 RTX-5 TestAmerica Knoxville Lab File ID:RB23LCS.D Heated Purge: (Y/N)NConc. Units:ppb v/v ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF Chlorodifluoromethane 0.35550.3695 1.92 2.00 -3.8 35.0Ave Propene 1.4881.433 2.08 2.00 3.8 35.0Ave Dichlorodifluoromethane 3.0912.686 2.30 2.00 15.1 35.0Ave Chloromethane 0.44540.4685 1.90 2.00 -4.9 35.0Ave 1,2-Dichlorotetrafluoroethan e 2.5232.478 2.04 2.00 1.8 35.0Ave Acetaldehyde 0.36340.4324 8.41 10.0 -15.9 35.0Ave Vinyl chloride 1.0721.118 1.92 2.00 -4.1 35.0Ave 1,3-Butadiene 0.73410.7734 1.90 2.00 -5.1 35.0Ave Butane 1.4721.466 2.01 2.00 0.4 35.0Ave Bromomethane 0.80830.8659 1.87 2.00 -6.6 35.0Ave Chloroethane 0.38190.4131 1.85 2.00 -7.5 35.0Ave Ethanol 0.27550.2894 9.52 10.0 -4.8 35.0Ave Vinyl bromide 0.71300.7362 1.94 2.00 -3.2 35.0Ave 2-Methylbutane 0.73110.7689 1.90 2.00 -4.9 35.0Ave Acrolein 0.22350.2773 1.61 2.00 -19.4 35.0Ave Trichlorofluoromethane 2.9833.269 1.83 2.00 -8.7 35.0Ave Acetonitrile 0.57100.5123 2.23 2.00 11.5 35.0Ave Acetone 0.63470.6582 5.79 6.00 -3.6 35.0Ave Isopropyl alcohol 2.1641.963 6.61 6.00 10.2 35.0Ave Pentane 0.24770.2276 2.18 2.00 8.8 35.0Ave Ethyl ether 1.7161.583 2.17 2.00 8.4 35.0Ave 1,1-Dichloroethene 1.1831.229 1.92 2.00 -3.8 35.0Ave Acrylonitrile 1.0901.001 2.18 2.00 8.9 35.0Ave t-Butyl alcohol 2.4032.362 2.03 2.00 1.7 35.0Ave 1,1,2-Trichlorotrifluoroetha ne 2.6902.755 1.95 2.00 -2.4 35.0Ave Methylene Chloride 1.1451.248 1.84 2.00 -8.2 35.0Ave 3-Chloropropene 1.2361.245 1.99 2.00 -0.7 35.0Ave Carbon disulfide 3.4963.545 1.97 2.00 -1.4 35.0Ave trans-1,2-Dichloroethene 1.2311.260 1.95 2.00 -2.3 35.0Ave 2-Methylpentane 3.4962.995 2.33 2.00 16.7 35.0Ave Methyl tert-butyl ether 3.2813.209 2.04 2.00 2.2 35.0Ave 1,1-Dichloroethane 2.4982.483 2.01 2.00 0.6 35.0Ave Vinyl acetate 3.6703.559 2.06 2.00 3.1 35.0Ave 2-Butanone 0.60360.6013 2.01 2.00 0.4 35.0Ave Hexane 1.1491.120 2.05 2.00 2.6 35.0Ave Isopropyl ether 5.0724.844 2.09 2.00 4.7 35.0Ave cis-1,2-Dichloroethene 1.3361.311 2.04 2.00 1.9 35.0Ave Ethyl acetate 3.3013.080 2.14 2.00 7.2 35.0Ave Chloroform 2.6692.688 1.99 2.00 -0.7 35.0Ave Tert-butyl ethyl ether 4.3053.778 2.28 2.00 14.0 35.0Ave FORM VII TO 15 LL 03/21/2017Page 281 of 377 FORM VII Lab Name:Job No.: SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID: AIR - GC/MS VOA CONTINUING CALIBRATION DATA 0.32(mm) 140-7345-1 MR 02/24/2017 09:49 02/23/2017 22:59 02/24/2017 05:21 ICV 140-8740/17 RTX-5 TestAmerica Knoxville Lab File ID:RB23LCS.D Heated Purge: (Y/N)NConc. Units:ppb v/v ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF Tetrahydrofuran 1.7491.646 2.13 2.00 6.3 35.0Ave 1,1,1-Trichloroethane 2.5932.551 2.03 2.00 1.6 35.0Ave 1,2-Dichloroethane 0.35960.3718 1.93 2.00 -3.3 35.0Ave 1-Butanol 0.08690.1094 1.59 2.00 -20.6 35.0Ave Benzene 0.76330.7244 2.11 2.00 5.4 35.0Ave Cyclohexane 0.12740.1154 2.21 2.00 10.4 35.0Ave Carbon tetrachloride 0.56020.5497 2.04 2.00 1.9 35.0Ave 2,3-Dimethylpentane 0.17170.1710 2.01 2.00 0.4 35.0Ave Thiophene 0.46140.4346 2.12 2.00 6.2 35.0Ave Tert-amyl methyl ether 0.75800.6787 2.23 2.00 11.7 35.0Ave 2,2,4-Trimethylpentane 1.4741.330 2.22 2.00 10.9 35.0Ave 1,2-Dichloropropane 0.33540.3106 2.16 2.00 8.0 35.0Ave Heptane 0.28880.2559 2.26 2.00 12.8 35.0Ave Trichloroethene 0.37780.3544 2.13 2.00 6.6 35.0Ave Dibromomethane 0.32260.3182 2.03 2.00 1.4 35.0Ave 1,4-Dioxane 0.11150.1077 2.07 2.00 3.5 35.0Ave Bromodichloromethane 0.55180.5213 2.12 2.00 5.8 35.0Ave Methyl methacrylate 0.38410.3546 2.17 2.00 8.3 35.0Ave Methylcyclohexane 0.46820.5329 1.76 2.00 -12.2 35.0Ave 4-Methyl-2-pentanone (MIBK)0.71200.6501 2.19 2.00 9.5 35.0Ave cis-1,3-Dichloropropene 0.44920.4066 2.21 2.00 10.5 35.0Ave trans-1,3-Dichloropropene 0.48230.4433 2.18 2.00 8.8 35.0Ave Toluene 1.1961.086 2.20 2.00 10.1 35.0Ave 1,1,2-Trichloroethane 0.34220.3302 2.07 2.00 3.6 35.0Ave 2-Methylthiophene 0.96300.8511 2.26 2.00 13.1 35.0Ave 3-Methylthiophene 0.99020.8346 2.37 2.00 18.6 35.0Ave 2-Hexanone 0.40040.3801 2.11 2.00 5.3 35.0Ave Dibromochloromethane 0.67660.5963 2.27 2.00 13.5 35.0Ave Octane 0.36100.3153 2.29 2.00 14.5 35.0Ave 1,2-Dibromoethane 0.59760.5593 2.14 2.00 6.9 35.0Ave Tetrachloroethene 0.40910.3974 2.06 2.00 3.0 35.0Ave Chlorobenzene 0.94160.9194 2.05 2.00 2.4 35.0Ave 2,3-Dimethylheptane 1.2111.055 2.30 2.00 14.8 35.0Ave Ethylbenzene 1.4761.371 2.15 2.00 7.6 35.0Ave 2-Ethylthiophene 1.0530.9674 2.18 2.00 8.8 35.0Ave m-Xylene & p-Xylene 1.1581.042 4.44 4.00 11.1 35.0Ave Bromoform 0.80660.6894 2.34 2.00 17.0 35.0Ave Styrene 0.75780.6900 2.20 2.00 9.8 35.0Ave Nonane 0.82960.7036 2.36 2.00 17.9 35.0Ave o-Xylene 1.1461.101 2.08 2.00 4.0 35.0Ave 1,1,2,2-Tetrachloroethane 0.80710.8096 1.99 2.00 -0.3 35.0Ave FORM VII TO 15 LL 03/21/2017Page 282 of 377 FORM VII Lab Name:Job No.: SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID: AIR - GC/MS VOA CONTINUING CALIBRATION DATA 0.32(mm) 140-7345-1 MR 02/24/2017 09:49 02/23/2017 22:59 02/24/2017 05:21 ICV 140-8740/17 RTX-5 TestAmerica Knoxville Lab File ID:RB23LCS.D Heated Purge: (Y/N)NConc. Units:ppb v/v ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF 1,2,3-Trichloropropane 0.23720.2316 2.05 2.00 2.4 35.0Ave Isopropylbenzene 1.6011.525 2.10 2.00 5.0 35.0Ave Propylbenzene 0.45160.4054 2.23 2.00 11.4 35.0Ave 2-Chlorotoluene 0.42020.3954 2.13 2.00 6.3 35.0Ave 4-Ethyltoluene 1.6201.504 2.15 2.00 7.7 35.0Ave 1,3,5-Trimethylbenzene 0.75570.6917 2.18 2.00 9.2 35.0Ave Alpha Methyl Styrene 0.47340.5727 1.65 2.00 -17.3 35.0Ave Decane 1.1770.9298 2.53 2.00 26.6 35.0Ave tert-Butylbenzene 1.5311.369 2.24 2.00 11.8 35.0Ave 1,2,4-Trimethylbenzene 1.4621.287 2.27 2.00 13.6 35.0Ave 1,3-Dichlorobenzene 1.1151.039 2.15 2.00 7.3 35.0Ave sec-Butylbenzene 2.1921.916 2.29 2.00 14.4 35.0Ave Benzyl chloride 1.1421.125 2.03 2.00 1.5 35.0Ave 1,4-Dichlorobenzene 1.1341.064 2.13 2.00 6.5 35.0Ave 4-Isopropyltoluene 1.8051.584 2.28 2.00 13.9 35.0Ave 1,2,3-Trimethylbenzene 1.2491.033 2.42 2.00 20.9 35.0Ave Butylcyclohexane 1.1991.062 2.26 2.00 13.0 35.0Ave 1,2-Dichlorobenzene 1.1091.016 2.18 2.00 9.2 35.0Ave Indane 1.2391.180 2.10 2.00 5.0 35.0Ave Indene 1.0670.8646 2.47 2.00 23.4 35.0Ave Butylbenzene 1.9191.700 2.26 2.00 12.9 35.0Ave Undecane 1.2831.072 2.39 2.00 19.7 35.0Ave 1,2-Dimethyl-4-Ethylbenzene 1.6591.288 2.58 2.00 28.8 35.0Ave 1,2-Dibromo-3-Chloropropane 0.43870.4403 1.99 2.00 -0.3 35.0Ave 1,2,4,5-Tetramethylbenzene 1.7211.462 2.35 2.00 17.7 35.0Ave 1,2,3,5-Tetramethylbenzene 1.0710.9276 2.31 2.00 15.4 35.0Ave 1,2,3,4-Tetramethylbenzene 1.3811.248 2.21 2.00 10.7 35.0Ave Dodecane 1.0271.107 1.85 2.00 -7.3 35.0Ave 1,2,4-Trichlorobenzene 1.1301.090 2.07 2.00 3.6 35.0Ave Naphthalene 1.9121.914 2.00 2.00 -0.1 35.0Ave Benzo(b)thiophene 1.0921.142 1.91 2.00 -4.4 35.0Ave Hexachlorobutadiene 1.0931.103 1.98 2.00 -0.9 35.0Ave 1,2,3-Trichlorobenzene 1.0191.077 1.89 2.00 -5.4 35.0Ave 2-Methylnaphthalene 0.04450.1675 1.66 6.25 -73.5 *50.0Ave 1-Methylnaphthalene 0.04770.1240 2.40 6.25 -61.5 *50.0Ave 4-Bromofluorobenzene (Surr)0.73650.6982 4.22 4.00 5.5 35.0Ave FORM VII TO 15 LL 03/21/2017Page 283 of 377 Report Date: 24-Feb-2017 16:54:27 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23LCS.D Lims ID:ICV Client ID: Sample Type:ICV Inject. Date:24-Feb-2017 09:49:30 ALS Bottle#:10 Worklist Smp#:17 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004095-017 Misc. Info.:073137 Operator ID:Instrument ID:MR Sublist: Method:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:24-Feb-2017 16:54:25 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK010 First Level Reviewer: barlozhetskayaa Date:24-Feb-2017 10:43:47 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.226 8.227 -0.001 98 429501 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.388 10.390 -0.002 95 2158241 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.279 15.280 -0.001 88 1765346 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.972 16.970 0.002 95 1300118 4.00 4.22 6 Chlorodifluoromethane 67 3.718 3.720 -0.002 96 76351 2.00 1.92 7 Propene 41 3.723 3.722 0.001 97 319542 2.00 2.08 8 Dichlorodifluoromethane 85 3.772 3.772 0.000 100 663893 2.00 2.30 9 Chloromethane 52 3.917 3.920 -0.003 100 95647 2.00 1.90 10 1,2-Dichloro-1,1,2,2-tetra 135 3.944 3.945 -0.001 96 541906 2.00 2.04 11 Acetaldehyde 44 4.063 4.063 0.000 98 390219 10.0 8.41 12 Vinyl chloride 62 4.068 4.069 -0.001 98 230169 2.00 1.92 13 Butadiene 54 4.149 4.150 -0.001 92 157646 2.00 1.90 14 Butane 43 4.155 4.152 0.003 92 316027 2.00 2.01 15 Bromomethane 94 4.408 4.409 -0.001 98 173589 2.00 1.87 16 Chloroethane 64 4.537 4.534 0.003 95 82017 2.00 1.85 17 Ethanol 31 4.645 4.648 -0.003 99 295761 10.0 9.52 18 Vinyl bromide 106 4.791 4.790 0.001 97 153121 2.00 1.94 19 2-Methylbutane 43 4.850 4.848 0.002 87 157005 2.00 1.90 20 Acrolein 56 5.023 5.025 -0.002 30 48000 2.00 1.61 21 Trichlorofluoromethane 101 5.028 5.030 -0.002 99 640607 2.00 1.83 22 Acetonitrile 40 5.071 5.075 -0.004 99 122616 2.00 2.23 23 Acetone 58 5.120 5.124 -0.004 98 408958 6.00 5.79 24 Isopropyl alcohol 45 5.222 5.227 -0.005 97 1394105 6.00 6.61 25 Pentane 72 5.233 5.229 0.004 95 53189 2.00 2.18 26 Ethyl ether 31 5.362 5.367 -0.005 93 368480 2.00 2.17 27 1,1-Dichloroethene 96 5.627 5.629 -0.002 96 254068 2.00 1.92 28 Acrylonitrile 53 5.702 5.705 -0.003 95 233985 2.00 2.18 29 2-Methyl-2-propanol 59 5.735 5.739 -0.004 96 515980 2.00 2.03 30 1,1,2-Trichloro-1,2,2-trif 101 5.805 5.809 -0.004 96 577625 2.00 1.95 31 Methylene Chloride 84 5.918 5.920 -0.002 98 245979 2.00 1.84 03/21/2017Page 284 of 377 Report Date: 24-Feb-2017 16:54:27 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23LCS.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.939 5.942 -0.003 92 265462 2.00 1.99 33 Carbon disulfide 76 6.063 6.062 0.001 99 750660 2.00 1.97 34 trans-1,2-Dichloroethene 96 6.651 6.657 -0.006 97 264255 2.00 1.95 35 2-Methylpentane 43 6.705 6.705 0.000 97 750834 2.00 2.33 36 Methyl tert-butyl ether 73 6.781 6.785 -0.004 98 704499 2.00 2.04 37 1,1-Dichloroethane 63 7.023 7.023 0.000 99 536400 2.00 2.01 38 Vinyl acetate 43 7.131 7.135 -0.004 100 788230 2.00 2.06 39 2-Butanone (MEK) 72 7.514 7.522 -0.008 98 129629 2.00 2.01 40 Hexane 56 7.611 7.610 0.001 90 246808 2.00 2.05 41 Isopropyl ether 45 7.746 7.748 -0.002 98 1089236 2.00 2.09 42 cis-1,2-Dichloroethene 96 7.929 7.930 -0.001 96 286829 2.00 2.04 43 Ethyl acetate 43 8.113 8.118 -0.005 98 708790 2.00 2.14 44 Chloroform 83 8.264 8.258 0.006 96 573273 2.00 1.99 45 Tert-butyl ethyl ether 59 8.377 8.381 -0.004 96 924672 2.00 2.28 46 Tetrahydrofuran 42 8.614 8.621 -0.007 95 375525 2.00 2.13 47 1,1,1-Trichloroethane 97 9.240 9.239 0.001 96 556757 2.00 2.03 48 1,2-Dichloroethane 62 9.315 9.311 0.004 96 388011 2.00 1.93 49 n-Butanol 31 9.800 9.810 -0.010 87 93727 2.00 1.59 50 Benzene 78 9.822 9.821 0.001 97 823714 2.00 2.11 51 Cyclohexane 69 9.849 9.849 0.000 96 137454 2.00 2.21 52 Carbon tetrachloride 117 9.860 9.860 0.000 99 604500 2.00 2.04 53 2,3-Dimethylpentane 71 10.005 10.009 -0.004 92 185272 2.00 2.01 54 Thiophene 84 10.086 10.088 -0.002 97 497891 2.00 2.12 55 Tert-amyl methyl ether 73 10.340 10.344 -0.004 97 818019 2.00 2.23 56 Isooctane 57 10.674 10.676 -0.002 99 1590579 2.00 2.22 57 1,2-Dichloropropane 63 11.062 11.062 0.000 89 361961 2.00 2.16 58 n-Heptane 71 11.068 11.070 -0.002 94 311636 2.00 2.26 59 Trichloroethene 130 11.127 11.125 0.002 92 407705 2.00 2.13 60 Dibromomethane 93 11.170 11.169 0.001 89 348124 2.00 2.03 61 Dichlorobromomethane 83 11.343 11.338 0.005 99 595404 2.00 2.12 62 1,4-Dioxane 88 11.343 11.347 -0.004 41 120354 2.00 2.07 63 Methyl methacrylate 41 11.472 11.473 -0.001 93 414504 2.00 2.17 64 Methylcyclohexane 83 11.947 11.948 -0.001 93 505199 2.00 1.76 65 4-Methyl-2-pentanone (MIBK 43 12.335 12.341 -0.006 98 768298 2.00 2.19 66 cis-1,3-Dichloropropene 75 12.389 12.389 0.000 96 484755 2.00 2.21 67 trans-1,3-Dichloropropene 75 13.111 13.112 -0.001 99 425751 2.00 2.18 68 Toluene 91 13.252 13.254 -0.002 93 1055518 2.00 2.20 69 1,1,2-Trichloroethane 83 13.305 13.308 -0.003 98 302039 2.00 2.07 70 2-Methylthiophene 97 13.403 13.402 0.000 98 849994 2.00 2.26 71 3-Methylthiophene 97 13.613 13.612 0.001 100 874002 2.00 2.37 72 2-Hexanone 58 13.731 13.736 -0.005 92 353446 2.00 2.11 73 Chlorodibromomethane 129 14.028 14.025 0.003 98 597214 2.00 2.27 74 n-Octane 85 14.044 14.045 -0.001 96 318650 2.00 2.29 75 Ethylene Dibromide 107 14.319 14.320 -0.001 97 527492 2.00 2.14 76 Tetrachloroethene 129 14.443 14.441 0.002 93 361138 2.00 2.06 77 Chlorobenzene 112 15.328 15.330 -0.002 96 831095 2.00 2.05 78 2,3-Dimethylheptane 43 15.430 15.432 -0.002 96 1068598 2.00 2.30 79 Ethylbenzene 91 15.646 15.647 -0.001 98 1302731 2.00 2.15 80 2-Ethylthiophene 97 15.743 15.744 -0.001 98 929359 2.00 2.18 81 m-Xylene & p-Xylene 91 15.818 15.819 -0.001 99 2044013 4.00 4.44 82 Bromoform 173 16.223 16.221 0.002 98 711944 2.00 2.34 83 Styrene 104 16.282 16.282 0.000 98 668862 2.00 2.20 03/21/2017Page 285 of 377 Report Date: 24-Feb-2017 16:54:27 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23LCS.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 84 n-Nonane 57 16.309 16.312 -0.003 94 732230 2.00 2.36 85 o-Xylene 91 16.347 16.347 0.000 98 1011562 2.00 2.08 86 1,1,2,2-Tetrachloroethane 83 16.660 16.658 0.002 99 712390 2.00 1.99 87 1,2,3-Trichloropropane 110 16.816 16.819 -0.003 96 209325 2.00 2.05 88 Isopropylbenzene 105 16.961 16.963 -0.002 96 1413401 2.00 2.10 89 N-Propylbenzene 120 17.538 17.540 -0.002 99 398577 2.00 2.23 90 2-Chlorotoluene 126 17.565 17.565 0.000 98 370882 2.00 2.13 91 4-Ethyltoluene 105 17.706 17.706 0.000 99 1429996 2.00 2.15 92 1,3,5-Trimethylbenzene 120 17.792 17.790 0.002 92 666995 2.00 2.18 93 Alpha Methyl Styrene 118 18.029 18.031 -0.002 88 417871 2.00 1.65 94 n-Decane 57 18.153 18.157 -0.004 89 1039052 2.00 2.53 95 tert-Butylbenzene 119 18.239 18.240 -0.001 91 1351513 2.00 2.24 96 1,2,4-Trimethylbenzene 105 18.256 18.256 0.000 96 1290525 2.00 2.27 97 1,3-Dichlorobenzene 146 18.520 18.520 0.000 97 984074 2.00 2.15 98 sec-Butylbenzene 105 18.531 18.532 -0.001 98 1934697 2.00 2.29 99 Benzyl chloride 91 18.595 18.596 -0.001 98 1008394 2.00 2.03 100 1,4-Dichlorobenzene 146 18.612 18.614 -0.002 96 1000837 2.00 2.13 101 4-Isopropyltoluene 119 18.709 18.710 -0.001 96 1593100 2.00 2.28 102 1,2,3-Trimethylbenzene 105 18.752 18.751 0.001 97 1102439 2.00 2.42 103 Butylcyclohexane 83 18.838 18.840 -0.002 93 1058740 2.00 2.26 104 1,2-Dichlorobenzene 146 18.989 18.990 -0.001 96 979176 2.00 2.18 105 2,3-Dihydroindene 117 19.000 19.001 -0.001 94 1093391 2.00 2.10 106 Indene 116 19.135 19.134 0.001 91 941496 2.00 2.47 107 n-Butylbenzene 91 19.172 19.173 -0.001 98 1694115 2.00 2.26 108 Undecane 57 19.550 19.552 -0.002 96 1132847 2.00 2.39 109 1,2-Dimethyl-4-Ethylbenzen 119 19.566 19.566 0.000 99 1464303 2.00 2.58 110 1,2-Dibromo-3-Chloropropan 157 19.620 19.620 0.000 96 387306 2.00 1.99 111 1,2,4,5-Tetramethylbenzene 119 19.970 19.970 0.000 98 1518750 2.00 2.35 112 1,2,3,5-Tetramethylbenzene 119 20.024 20.024 0.000 96 945131 2.00 2.31 113 1,2,3,4-Tetramethylbenzene 119 20.429 20.429 0.000 98 1218687 2.00 2.21 114 Dodecane 57 20.655 20.656 -0.001 95 906185 2.00 1.85 115 1,2,4-Trichlorobenzene 180 20.779 20.779 0.000 93 997002 2.00 2.07 116 Naphthalene 128 20.914 20.913 0.001 99 1687974 2.00 2.00 117 Benzo(b)thiophene 134 21.011 21.015 -0.004 100 964239 2.00 1.91 118 Hexachlorobutadiene 225 21.162 21.166 -0.004 94 964872 2.00 1.98 119 1,2,3-Trichlorobenzene 180 21.205 21.207 -0.002 95 899656 2.00 1.89 120 2-Methylnaphthalene 142 21.928 21.929 -0.001 97 122658 6.25 1.66 121 1-Methylnaphthalene 142 22.052 22.052 0.000 97 131587 6.25 2.40 A 122 C6 Range 1 7.627 (7.562-7.694) 0 2142009 2.00 2.03 S 124 Xylenes, Total 100 0 6.00 6.52 S 125 1,2-Dichloroethene, Total 1 0 4.00 3.99 Reagents: 40CV101S_00033 Amount Added: 100.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 286 of 377 Report Date: 24-Feb-2017 16:54:28 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23LCS.D Injection Date:24-Feb-2017 09:49:30 Instrument ID:MR Operator ID: Lims ID:ICV Worklist Smp#:17 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:10 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 56 Y ( X10 0 0 0 0 ) RB23LCS[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 3 1 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 8 8 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 7 9 ) $ 4 - B r o m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 7 )+ 03/21/2017Page 287 of 377 FORM VII Lab Name:Job No.: SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID: AIR - GC/MS VOA CONTINUING CALIBRATION DATA 0.32(mm) 140-7345-1 MR 03/09/2017 09:42 02/23/2017 22:59 02/24/2017 05:21 CCVIS 140-9156/2 RTX-5 TestAmerica Knoxville Lab File ID:RC09CCV.D Heated Purge: (Y/N)NConc. Units:ppb v/v ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF Chlorodifluoromethane 0.33920.3695 1.84 2.00 -8.2 30.0Ave Propene 1.5881.433 2.22 2.00 10.8 30.0Ave Dichlorodifluoromethane 2.0762.686 1.55 2.00 -22.7 30.0Ave Chloromethane 0.51830.4685 2.21 2.00 10.6 30.0Ave 1,2-Dichlorotetrafluoroethan e 2.4152.478 1.95 2.00 -2.6 30.0Ave Acetaldehyde 0.35990.4324 8.33 10.0 -16.8 30.0Ave Vinyl chloride 1.0611.118 1.90 2.00 -5.1 30.0Ave 1,3-Butadiene 0.66210.7734 1.71 2.00 -14.4 30.0Ave Butane 1.2461.466 1.70 2.00 -15.0 30.0Ave Bromomethane 0.63630.8659 1.47 2.00 -26.5 30.0Ave Chloroethane 0.28150.4131 1.36 2.00 -31.9 *30.0Ave Ethanol 0.19790.2894 6.84 10.0 -31.6 *30.0Ave Vinyl bromide 0.54930.7362 1.49 2.00 -25.4 30.0Ave 2-Methylbutane 0.55400.7689 1.44 2.00 -27.9 30.0Ave Acrolein 0.15660.2773 1.13 2.00 -43.5 *30.0Ave Trichlorofluoromethane 2.7923.269 1.71 2.00 -14.6 30.0Ave Acetonitrile 0.53070.5123 2.07 2.00 3.6 30.0Ave Acetone 0.65120.6582 5.94 6.00 -1.1 30.0Ave Isopropyl alcohol 2.0721.963 6.33 6.00 5.5 30.0Ave Pentane 0.24790.2276 2.18 2.00 8.9 30.0Ave Ethyl ether 1.8441.583 2.33 2.00 16.5 30.0Ave 1,1-Dichloroethene 1.2981.229 2.11 2.00 5.6 30.0Ave Acrylonitrile 1.0681.001 2.14 2.00 6.7 30.0Ave t-Butyl alcohol 2.3812.362 2.02 2.00 0.8 30.0Ave 1,1,2-Trichlorotrifluoroetha ne 2.8972.755 2.10 2.00 5.1 30.0Ave Methylene Chloride 1.2431.248 1.99 2.00 -0.3 30.0Ave 3-Chloropropene 1.2161.245 1.95 2.00 -2.4 30.0Ave Carbon disulfide 3.7673.545 2.13 2.00 6.3 30.0Ave trans-1,2-Dichloroethene 1.3431.260 2.13 2.00 6.6 30.0Ave 2-Methylpentane 3.3222.995 2.22 2.00 10.9 30.0Ave Methyl tert-butyl ether 3.3523.209 2.09 2.00 4.5 30.0Ave 1,1-Dichloroethane 2.5762.483 2.08 2.00 3.7 30.0Ave Vinyl acetate 4.1623.559 2.34 2.00 17.0 30.0Ave 2-Butanone 0.64260.6013 2.14 2.00 6.9 30.0Ave Hexane 1.1661.120 2.08 2.00 4.1 30.0Ave Isopropyl ether 5.4884.844 2.27 2.00 13.3 30.0Ave cis-1,2-Dichloroethene 1.3881.311 2.12 2.00 5.9 30.0Ave Ethyl acetate 3.5353.080 2.30 2.00 14.8 30.0Ave Chloroform 2.7092.688 2.02 2.00 0.8 30.0Ave Tert-butyl ethyl ether 4.1313.778 2.19 2.00 9.3 30.0Ave FORM VII TO 15 LL 03/21/2017Page 288 of 377 FORM VII Lab Name:Job No.: SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID: AIR - GC/MS VOA CONTINUING CALIBRATION DATA 0.32(mm) 140-7345-1 MR 03/09/2017 09:42 02/23/2017 22:59 02/24/2017 05:21 CCVIS 140-9156/2 RTX-5 TestAmerica Knoxville Lab File ID:RC09CCV.D Heated Purge: (Y/N)NConc. Units:ppb v/v ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF Tetrahydrofuran 1.8271.646 2.22 2.00 11.0 30.0Ave 1,1,1-Trichloroethane 2.5712.551 2.02 2.00 0.8 30.0Ave 1,2-Dichloroethane 0.36310.3718 1.95 2.00 -2.4 30.0Ave 1-Butanol 0.12910.1094 2.36 2.00 18.0 30.0Ave Benzene 0.76530.7244 2.11 2.00 5.6 30.0Ave Cyclohexane 0.12920.1154 2.24 2.00 11.9 30.0Ave Carbon tetrachloride 0.54670.5497 1.99 2.00 -0.5 30.0Ave 2,3-Dimethylpentane 0.18900.1710 2.21 2.00 10.5 30.0Ave Thiophene 0.46890.4346 2.16 2.00 7.9 30.0Ave Tert-amyl methyl ether 0.75580.6787 2.23 2.00 11.4 30.0Ave 2,2,4-Trimethylpentane 1.4891.330 2.24 2.00 12.0 30.0Ave 1,2-Dichloropropane 0.34480.3106 2.22 2.00 11.0 30.0Ave Heptane 0.29970.2559 2.34 2.00 17.1 30.0Ave Trichloroethene 0.36740.3544 2.07 2.00 3.7 30.0Ave Dibromomethane 0.33090.3182 2.08 2.00 4.0 30.0Ave 1,4-Dioxane 0.11550.1077 2.14 2.00 7.2 30.0Ave Bromodichloromethane 0.55270.5213 2.12 2.00 6.0 30.0Ave Methyl methacrylate 0.42230.3546 2.38 2.00 19.1 30.0Ave Methylcyclohexane 0.59200.5329 2.22 2.00 11.1 30.0Ave 4-Methyl-2-pentanone (MIBK)0.79530.6501 2.45 2.00 22.3 30.0Ave cis-1,3-Dichloropropene 0.45430.4066 2.24 2.00 11.7 30.0Ave trans-1,3-Dichloropropene 0.49230.4433 2.22 2.00 11.0 30.0Ave Toluene 1.2171.086 2.24 2.00 12.0 30.0Ave 1,1,2-Trichloroethane 0.35840.3302 2.17 2.00 8.5 30.0Ave 2-Methylthiophene 0.96440.8511 2.27 2.00 13.3 30.0Ave 3-Methylthiophene 0.95840.8346 2.30 2.00 14.8 30.0Ave 2-Hexanone 0.45350.3801 2.39 2.00 19.3 30.0Ave Dibromochloromethane 0.70440.5963 2.36 2.00 18.1 30.0Ave Octane 0.38850.3153 2.47 2.00 23.2 30.0Ave 1,2-Dibromoethane 0.63190.5593 2.26 2.00 13.0 30.0Ave Tetrachloroethene 0.43170.3974 2.17 2.00 8.6 30.0Ave Chlorobenzene 0.96830.9194 2.11 2.00 5.3 30.0Ave 2,3-Dimethylheptane 1.3111.055 2.49 2.00 24.3 30.0Ave Ethylbenzene 1.5221.371 2.22 2.00 11.0 30.0Ave 2-Ethylthiophene 1.0980.9674 2.27 2.00 13.5 30.0Ave m-Xylene & p-Xylene 1.1931.042 4.58 4.00 14.5 30.0Ave Bromoform 0.74890.6894 2.17 2.00 8.6 30.0Ave Styrene 0.84980.6900 2.46 2.00 23.2 30.0Ave Nonane 0.88950.7036 2.53 2.00 26.4 30.0Ave o-Xylene 1.1941.101 2.17 2.00 8.4 30.0Ave 1,1,2,2-Tetrachloroethane 0.89250.8096 2.21 2.00 10.2 30.0Ave FORM VII TO 15 LL 03/21/2017Page 289 of 377 FORM VII Lab Name:Job No.: SDG No.: Instrument ID: Calibration Date: Calib Start Date: Lab Sample ID: Calib End Date:GC Column: ID: AIR - GC/MS VOA CONTINUING CALIBRATION DATA 0.32(mm) 140-7345-1 MR 03/09/2017 09:42 02/23/2017 22:59 02/24/2017 05:21 CCVIS 140-9156/2 RTX-5 TestAmerica Knoxville Lab File ID:RC09CCV.D Heated Purge: (Y/N)NConc. Units:ppb v/v ANALYTE CURVE CALC SPIKE %D MAX TYPE AMOUNT AMOUNT %D AVE RRF RRF MIN RRF 1,2,3-Trichloropropane 0.24440.2316 2.11 2.00 5.6 30.0Ave Isopropylbenzene 1.5781.525 2.07 2.00 3.5 30.0Ave Propylbenzene 0.44240.4054 2.18 2.00 9.1 30.0Ave 2-Chlorotoluene 0.40080.3954 2.03 2.00 1.4 30.0Ave 4-Ethyltoluene 1.6791.504 2.23 2.00 11.6 30.0Ave 1,3,5-Trimethylbenzene 0.76510.6917 2.21 2.00 10.6 30.0Ave Alpha Methyl Styrene 0.67970.5727 2.37 2.00 18.7 30.0Ave Decane 1.2340.9298 2.66 2.00 32.7 *30.0Ave tert-Butylbenzene 1.5731.369 2.30 2.00 14.9 30.0Ave 1,2,4-Trimethylbenzene 1.4761.287 2.29 2.00 14.7 30.0Ave 1,3-Dichlorobenzene 1.1181.039 2.15 2.00 7.6 30.0Ave sec-Butylbenzene 2.2791.916 2.38 2.00 18.9 30.0Ave Benzyl chloride 1.3471.125 2.40 2.00 19.7 30.0Ave 1,4-Dichlorobenzene 1.1451.064 2.15 2.00 7.6 30.0Ave 4-Isopropyltoluene 1.9131.584 2.42 2.00 20.7 30.0Ave 1,2,3-Trimethylbenzene 1.1731.033 2.27 2.00 13.6 30.0Ave Butylcyclohexane 1.2841.062 2.42 2.00 21.0 30.0Ave 1,2-Dichlorobenzene 1.1201.016 2.21 2.00 10.3 30.0Ave Indane 1.2951.180 2.20 2.00 9.8 30.0Ave Indene 1.0700.8646 2.48 2.00 23.7 30.0Ave Butylbenzene 2.0831.700 2.45 2.00 22.5 30.0Ave Undecane 1.4941.072 2.79 2.00 39.3 *30.0Ave 1,2-Dimethyl-4-Ethylbenzene 1.4861.288 2.31 2.00 15.4 30.0Ave 1,2-Dibromo-3-Chloropropane 0.51440.4403 2.34 2.00 16.8 30.0Ave 1,2,4,5-Tetramethylbenzene 1.7391.462 2.38 2.00 18.9 30.0Ave 1,2,3,5-Tetramethylbenzene 1.0790.9276 2.33 2.00 16.4 30.0Ave 1,2,3,4-Tetramethylbenzene 1.4571.248 2.34 2.00 16.8 30.0Ave Dodecane 1.4471.107 2.61 2.00 30.7 *30.0Ave 1,2,4-Trichlorobenzene 1.2251.090 2.25 2.00 12.3 30.0Ave Naphthalene 2.2551.914 2.36 2.00 17.8 30.0Ave Benzo(b)thiophene 1.2801.142 2.24 2.00 12.1 30.0Ave Hexachlorobutadiene 1.1681.103 2.12 2.00 5.9 30.0Ave 1,2,3-Trichlorobenzene 1.1551.077 2.14 2.00 7.2 30.0Ave 2-Methylnaphthalene 0.13040.1675 4.87 6.25 -22.2 50.0Ave 1-Methylnaphthalene 0.11020.1240 5.56 6.25 -11.2 50.0Ave 4-Bromofluorobenzene (Surr)0.68410.6982 3.92 4.00 -2.0 30.0Ave FORM VII TO 15 LL 03/21/2017Page 290 of 377 Report Date: 09-Mar-2017 14:29:24 Chrom Revision: 2.2 08-Mar-2017 11:23:48 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09CCV.D Lims ID:CCVIS Client ID: Sample Type:CCVIS Inject. Date:09-Mar-2017 09:42:30 ALS Bottle#:15 Worklist Smp#:2 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004226-002 Misc. Info.:P32 Operator ID:Instrument ID:MR Sublist:chrom-MR_TO15*sub7 Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:09-Mar-2017 14:29:23 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK023 First Level Reviewer: tajh Date:09-Mar-2017 14:29:23 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.215 8.215 0.000 98 396885 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.377 10.377 0.000 95 1938837 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.274 15.274 0.000 89 1560294 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.961 16.961 0.000 96 1067424 4.00 3.92 6 Chlorodifluoromethane 67 3.696 3.696 0.000 96 67346 2.00 1.84 7 Propene 41 3.701 3.701 0.000 96 315388 2.00 2.22 8 Dichlorodifluoromethane 85 3.750 3.750 0.000 100 412265 2.00 1.55 9 Chloromethane 52 3.896 3.896 0.000 99 102909 2.00 2.21 10 1,2-Dichloro-1,1,2,2-tetra 135 3.928 3.928 0.000 92 479477 2.00 1.95 11 Acetaldehyde 44 4.047 4.047 0.000 98 357311 10.0 8.33 12 Vinyl chloride 62 4.047 4.047 0.000 98 210617 2.00 1.90 13 Butadiene 54 4.127 4.127 0.000 88 131458 2.00 1.71 14 Butane 43 4.133 4.133 0.000 91 247359 2.00 1.70 15 Bromomethane 94 4.392 4.392 0.000 96 126336 2.00 1.47 16 Chloroethane 64 4.516 4.516 0.000 87 55888 2.00 1.36 17 Ethanol 31 4.634 4.634 0.000 98 196500 10.0 6.84 18 Vinyl bromide 106 4.769 4.769 0.000 96 109063 2.00 1.49 19 2-Methylbutane 43 4.828 4.828 0.000 85 110001 2.00 1.44 20 Acrolein 56 5.006 5.006 0.000 29 31086 2.00 1.13 21 Trichlorofluoromethane 101 5.012 5.012 0.000 99 554281 2.00 1.71 22 Acetonitrile 40 5.060 5.060 0.000 98 105365 2.00 2.07 23 Acetone 58 5.109 5.109 0.000 98 387880 6.00 5.94 24 Isopropyl alcohol 45 5.211 5.211 0.000 82 1233998 6.00 6.33 25 Pentane 72 5.211 5.211 0.000 73 49224 2.00 2.18 26 Ethyl ether 31 5.346 5.346 0.000 92 366028 2.00 2.33 27 1,1-Dichloroethene 96 5.610 5.610 0.000 97 257802 2.00 2.11 28 Acrylonitrile 53 5.686 5.686 0.000 95 212023 2.00 2.14 29 2-Methyl-2-propanol 59 5.718 5.718 0.000 96 472676 2.00 2.02 30 1,1,2-Trichloro-1,2,2-trif 101 5.788 5.788 0.000 98 575213 2.00 2.10 31 Methylene Chloride 84 5.907 5.907 0.000 99 246890 2.00 1.99 03/21/2017Page 291 of 377 Report Date: 09-Mar-2017 14:29:24 Chrom Revision: 2.2 08-Mar-2017 11:23:48 Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09CCV.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 32 3-Chloro-1-propene 39 5.923 5.923 0.000 92 241411 2.00 1.95 33 Carbon disulfide 76 6.042 6.042 0.000 100 747994 2.00 2.13 34 trans-1,2-Dichloroethene 96 6.640 6.640 0.000 98 266590 2.00 2.13 35 2-Methylpentane 43 6.689 6.689 0.000 97 659633 2.00 2.22 36 Methyl tert-butyl ether 73 6.764 6.764 0.000 98 665477 2.00 2.09 37 1,1-Dichloroethane 63 7.007 7.007 0.000 99 511384 2.00 2.08 38 Vinyl acetate 43 7.115 7.115 0.000 100 826398 2.00 2.34 39 2-Butanone (MEK) 72 7.503 7.503 0.000 98 127586 2.00 2.14 40 Hexane 56 7.595 7.595 0.000 92 231413 2.00 2.08 41 Isopropyl ether 45 7.730 7.730 0.000 98 1089713 2.00 2.27 42 cis-1,2-Dichloroethene 96 7.913 7.913 0.000 95 275610 2.00 2.12 43 Ethyl acetate 43 8.096 8.096 0.000 98 701847 2.00 2.30 44 Chloroform 83 8.247 8.247 0.000 96 537822 2.00 2.02 45 Tert-butyl ethyl ether 59 8.360 8.360 0.000 97 820267 2.00 2.19 46 Tetrahydrofuran 42 8.598 8.598 0.000 95 362747 2.00 2.22 47 1,1,1-Trichloroethane 97 9.223 9.223 0.000 96 510498 2.00 2.02 48 1,2-Dichloroethane 62 9.299 9.299 0.000 96 352133 2.00 1.95 49 n-Butanol 31 9.779 9.779 0.000 90 125208 2.00 2.36 50 Benzene 78 9.806 9.806 0.000 97 742291 2.00 2.11 51 Cyclohexane 69 9.833 9.833 0.000 96 125275 2.00 2.24 52 Carbon tetrachloride 117 9.843 9.843 0.000 98 530257 2.00 1.99 53 2,3-Dimethylpentane 71 9.989 9.989 0.000 93 183287 2.00 2.21 54 Thiophene 84 10.075 10.075 0.000 96 454815 2.00 2.16 55 Tert-amyl methyl ether 73 10.323 10.323 0.000 96 733040 2.00 2.23 56 Isooctane 57 10.663 10.663 0.000 99 1443932 2.00 2.24 57 1,2-Dichloropropane 63 11.051 11.051 0.000 89 334458 2.00 2.22 58 n-Heptane 71 11.057 11.057 0.000 94 290654 2.00 2.34 59 Trichloroethene 130 11.111 11.111 0.000 94 356348 2.00 2.07 60 Dibromomethane 93 11.154 11.154 0.000 89 320901 2.00 2.08 61 Dichlorobromomethane 83 11.326 11.326 0.000 99 536078 2.00 2.12 62 1,4-Dioxane 88 11.326 11.326 0.000 65 111990 2.00 2.14 63 Methyl methacrylate 41 11.456 11.456 0.000 92 409633 2.00 2.38 64 Methylcyclohexane 83 11.936 11.936 0.000 92 574175 2.00 2.22 65 4-Methyl-2-pentanone (MIBK 43 12.324 12.324 0.000 98 771392 2.00 2.45 66 cis-1,3-Dichloropropene 75 12.378 12.378 0.000 96 440649 2.00 2.24 67 trans-1,3-Dichloropropene 75 13.100 13.100 0.000 98 384277 2.00 2.22 68 Toluene 91 13.246 13.246 0.000 93 949557 2.00 2.24 69 1,1,2-Trichloroethane 83 13.295 13.295 0.000 98 279756 2.00 2.17 70 2-Methylthiophene 97 13.392 13.392 0.000 98 752804 2.00 2.27 71 3-Methylthiophene 97 13.602 13.602 0.000 100 748110 2.00 2.30 72 2-Hexanone 58 13.721 13.721 0.000 91 353979 2.00 2.39 73 Chlorodibromomethane 129 14.017 14.017 0.000 98 549861 2.00 2.36 74 n-Octane 85 14.039 14.039 0.000 96 303244 2.00 2.47 75 Ethylene Dibromide 107 14.308 14.308 0.000 98 493262 2.00 2.26 76 Tetrachloroethene 129 14.432 14.432 0.000 93 336990 2.00 2.17 77 Chlorobenzene 112 15.322 15.322 0.000 95 755800 2.00 2.11 78 2,3-Dimethylheptane 43 15.424 15.424 0.000 96 1023519 2.00 2.49 79 Ethylbenzene 91 15.640 15.640 0.000 99 1188044 2.00 2.22 80 2-Ethylthiophene 97 15.737 15.737 0.000 98 856999 2.00 2.27 81 m-Xylene & p-Xylene 91 15.807 15.807 0.000 100 1862438 4.00 4.58 82 Bromoform 173 16.212 16.212 0.000 97 584596 2.00 2.17 83 Styrene 104 16.276 16.276 0.000 98 663316 2.00 2.46 03/21/2017Page 292 of 377 Report Date: 09-Mar-2017 14:29:24 Chrom Revision: 2.2 08-Mar-2017 11:23:48 Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09CCV.D Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 84 n-Nonane 57 16.303 16.303 0.000 96 694337 2.00 2.53 85 o-Xylene 91 16.341 16.341 0.000 98 931846 2.00 2.17 86 1,1,2,2-Tetrachloroethane 83 16.649 16.649 0.000 99 696645 2.00 2.21 87 1,2,3-Trichloropropane 110 16.810 16.810 0.000 96 190797 2.00 2.11 88 Isopropylbenzene 105 16.956 16.956 0.000 96 1231851 2.00 2.07 89 N-Propylbenzene 120 17.533 17.533 0.000 99 345310 2.00 2.18 90 2-Chlorotoluene 126 17.560 17.560 0.000 97 312821 2.00 2.03 91 4-Ethyltoluene 105 17.700 17.700 0.000 99 1310776 2.00 2.23 92 1,3,5-Trimethylbenzene 120 17.781 17.781 0.000 92 597222 2.00 2.21 93 Alpha Methyl Styrene 118 18.024 18.024 0.000 89 530506 2.00 2.37 94 n-Decane 57 18.148 18.148 0.000 88 963197 2.00 2.66 95 tert-Butylbenzene 119 18.234 18.234 0.000 92 1228163 2.00 2.30 96 1,2,4-Trimethylbenzene 105 18.245 18.245 0.000 96 1152315 2.00 2.29 97 1,3-Dichlorobenzene 146 18.514 18.514 0.000 97 872762 2.00 2.15 98 sec-Butylbenzene 105 18.525 18.525 0.000 99 1778996 2.00 2.38 99 Benzyl chloride 91 18.590 18.590 0.000 98 1051715 2.00 2.40 100 1,4-Dichlorobenzene 146 18.606 18.606 0.000 96 893527 2.00 2.15 101 4-Isopropyltoluene 119 18.703 18.703 0.000 96 1493016 2.00 2.42 102 1,2,3-Trimethylbenzene 105 18.746 18.746 0.000 97 915903 2.00 2.27 103 Butylcyclohexane 83 18.832 18.832 0.000 91 1002268 2.00 2.42 104 1,2-Dichlorobenzene 146 18.983 18.983 0.000 96 874598 2.00 2.21 105 2,3-Dihydroindene 117 18.994 18.994 0.000 94 1010967 2.00 2.20 106 Indene 116 19.129 19.129 0.000 91 834950 2.00 2.48 107 n-Butylbenzene 91 19.167 19.167 0.000 98 1625736 2.00 2.45 108 Undecane 57 19.544 19.544 0.000 96 1166239 2.00 2.79 109 1,2-Dimethyl-4-Ethylbenzen 119 19.560 19.560 0.000 98 1160116 2.00 2.31 110 1,2-Dibromo-3-Chloropropan 157 19.614 19.614 0.000 95 401519 2.00 2.34 111 1,2,4,5-Tetramethylbenzene 119 19.965 19.965 0.000 98 1357272 2.00 2.38 112 1,2,3,5-Tetramethylbenzene 119 20.019 20.019 0.000 96 842563 2.00 2.33 113 1,2,3,4-Tetramethylbenzene 119 20.423 20.423 0.000 98 1136969 2.00 2.34 114 Dodecane 57 20.650 20.650 0.000 94 1129352 2.00 2.61 115 1,2,4-Trichlorobenzene 180 20.774 20.774 0.000 93 956207 2.00 2.25 116 Naphthalene 128 20.903 20.903 0.000 99 1760038 2.00 2.36 117 Benzo(b)thiophene 134 21.006 21.006 0.000 100 999277 2.00 2.24 118 Hexachlorobutadiene 225 21.157 21.157 0.000 93 911481 2.00 2.12 119 1,2,3-Trichlorobenzene 180 21.200 21.200 0.000 95 901226 2.00 2.14 120 2-Methylnaphthalene 142 21.922 21.922 0.000 97 317947 6.25 4.87 121 1-Methylnaphthalene 142 22.046 22.046 0.000 97 268683 6.25 5.56 A 122 C6 Range 1 7.598 (7.530-7.640) 0 2064337 2.00 2.17 S 124 Xylenes, Total 100 0 6.00 6.75 S 125 1,2-Dichloroethene, Total 1 0 4.00 4.25 Reagents: 40CV101P_00032 Amount Added: 100.00 Units: ml 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 293 of 377 Report Date: 09-Mar-2017 14:29:24 Chrom Revision: 2.2 08-Mar-2017 11:23:48 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09CCV.D Injection Date:09-Mar-2017 09:42:30 Instrument ID:MR Operator ID: Lims ID:CCVIS Worklist Smp#:2 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:15 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 Y ( X10 0 0 0 0 ) RC09CCV[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 1 5 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 7 7 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 7 4 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 1 )+ 03/21/2017Page 294 of 377 Report Date: 03-Mar-2017 13:22:10 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GBFBC02.D Lims ID:BFB Client ID: Sample Type:BFB Inject. Date:02-Mar-2017 12:22:30 ALS Bottle#:16 Worklist Smp#:1 Injection Vol:500.0 mL Dil. Factor:1.0000 Sample Info:140-0004202-001 Misc. Info.:BFB Operator ID:7126 Instrument ID:MG Method:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:03-Mar-2017 13:22:09 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK014 First Level Reviewer: barlozhetskayaa Date:02-Mar-2017 13:20:37 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags $ 5 BFB 95 4.782 4.782 0.000 0 1291262 NR NR QC Flag Legend Processing Flags NR - Missing Quant Standard Reagents: 40MXSUR_00001 Amount Added: 40.00 Units: mL 03/21/2017Page 295 of 377 Report Date: 03-Mar-2017 13:22:10 Chrom Revision: 2.2 27-Feb-2017 12:17:18 MS Tune Report TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GBFBC02.D Injection Date:02-Mar-2017 12:22:30 Instrument ID:MG Lims ID:BFB Client ID: Operator ID:7126 ALS Bottle#:16 Worklist Smp#:1 Injection Vol:500.0 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Tune Method: BFB Method 8260 $ 5 BFB 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 3 6 9 12 15 18 21 24 27 30 33 36 Y ( X10 0 0 0 ) Tune Spec :Average 287-289( 4.78-4.79 ) Bgrd 271( 4.69) 95 174 176 75 7450 9469 96 177 m/z Ion Abundance Criteria %Relative Abundance 95 Base peak,100%relative abundance 100.0 50 15 to 40%of m/z 95 18.4 75 30 to 60%of m/z 95 55.3 96 5 to 9%of m/z 95 6.8 173 Less than 2%of m/z 174 0.5 (0.6) 174 50 to 120%of m/z 95 90.3 175 5 to 9%of m/z 174 6.1 (6.8) 176 Greater than 95%but less than 101%of m/z 174 87.4 (96.7) 177 5 to 9%of m/z 176 5.5 (6.3) 03/21/2017Page 296 of 377 Report Date: 03-Mar-2017 13:22:10 Chrom Revision: 2.2 27-Feb-2017 12:17:18 Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GBFBC02.D\MG_TO15.rslt\spectra.d Injection Date:02-Mar-2017 12:22:30 Spectrum:Tune Spec :Average 287-289( 4.78-4.79 ) Bgrd 271( 4.69) Base Peak:95.00 Minimum % Base Peak:0 Number of Points:120 m/z Y m/z Y m/z Y m/z Y 29.00 145 64.00 1215 97.00 701 139.00 175 31.00 9485 65.00 268 103.00 184 140.00 319 32.00 675 66.00 109 104.00 1911 141.00 5217 33.00 2581 67.00 912 105.00 606 142.00 483 36.00 2843 68.00 41496 106.00 2034 143.00 5399 37.00 16800 69.00 42888 107.00 409 144.00 320 38.00 15378 70.00 3367 110.00 347 145.00 500 39.00 6137 71.00 86 111.00 492 146.00 649 40.00 241 72.00 1968 112.00 312 147.00 342 41.00 117 73.00 16696 113.00 436 148.00 1047 43.00 84 74.00 70864 114.00 58 149.00 278 44.00 1920 75.00 205120 115.00 339 150.00 420 45.00 3209 76.00 17768 116.00 1701 152.00 245 46.00 378 77.00 1549 117.00 2530 153.00 355 47.00 2608 78.00 820 118.00 1929 154.00 347 48.00 1803 79.00 13761 119.00 2493 155.00 1112 49.00 13838 80.00 4338 120.00 131 156.00 231 50.00 68360 81.00 14285 123.00 56 157.00 792 51.00 19688 82.00 3090 124.00 267 158.00 58 52.00 825 83.00 446 125.00 65 159.00 551 53.00 31 85.00 137 126.00 220 161.00 566 54.00 26 86.00 231 128.00 1693 172.00 57 55.00 737 87.00 9767 129.00 780 173.00 2038 56.00 5387 88.00 10052 130.00 1599 174.00 335360 57.00 10128 91.00 1365 131.00 693 175.00 22752 58.00 513 92.00 11158 133.00 64 176.00 324288 60.00 3109 93.00 17528 134.00 58 177.00 20320 61.00 16984 94.00 46864 135.00 890 178.00 636 62.00 18152 95.00 371200 136.00 50 207.00 99 63.00 13931 96.00 25136 137.00 957 253.00 148 03/21/2017Page 297 of 377 Report Date: 03-Mar-2017 13:22:10 Chrom Revision: 2.2 27-Feb-2017 12:17:18 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GBFBC02.D Injection Date:02-Mar-2017 12:22:30 Instrument ID:MG Operator ID:7126 Lims ID:BFB Worklist Smp#:1 Client ID: Injection Vol:500.0 mL Dil. Factor:1.0000 ALS Bottle#:16 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.2 3.5 3.8 4.1 4.4 4.7 5.0 5.3 5.6 5.9 6.2 6.5 6.8 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 Y ( X10 0 0 0 0 ) GBFBC02[MS SCAN Chro]:Total $ B F B ( 4 . 7 8 2 ) 03/21/2017Page 298 of 377 Report Date: 10-Mar-2017 11:34:44 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GBFBC10.D Lims ID:BFB Client ID: Sample Type:BFB Inject. Date:10-Mar-2017 07:50:30 ALS Bottle#:16 Worklist Smp#:1 Injection Vol:500.0 mL Dil. Factor:1.0000 Sample Info:140-0004228-001 Misc. Info.:BFB Operator ID:7126 Instrument ID:MG Method:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 11:34:44 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 11:34:44 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags $ 5 BFB 95 4.717 4.717 0.000 0 1186457 NR NR QC Flag Legend Processing Flags NR - Missing Quant Standard Reagents: 40MXSUR_00001 Amount Added: 40.00 Units: mL 03/21/2017Page 299 of 377 Report Date: 10-Mar-2017 11:34:44 Chrom Revision: 2.2 05-Mar-2017 11:38:00 MS Tune Report TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GBFBC10.D Injection Date:10-Mar-2017 07:50:30 Instrument ID:MG Lims ID:BFB Client ID: Operator ID:7126 ALS Bottle#:16 Worklist Smp#:1 Injection Vol:500.0 mL Dil. Factor:1.0000 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Tune Method: BFB Method 8260 $ 5 BFB 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 m/z 0 3 6 9 12 15 18 21 24 27 30 33 36 39 42 45 Y ( X10 0 0 0 ) Tune Spec :Average 275-277( 4.71-4.72 ) Bgrd 264( 4.65) 95 174 176 75 7450 9469 9651 177 m/z Ion Abundance Criteria %Relative Abundance 95 Base peak,100%relative abundance 100.0 50 15 to 40%of m/z 95 18.6 75 30 to 60%of m/z 95 55.4 96 5 to 9%of m/z 95 7.0 173 Less than 2%of m/z 174 0.4 (0.5) 174 50 to 120%of m/z 95 88.2 175 5 to 9%of m/z 174 6.1 (6.9) 176 Greater than 95%but less than 101%of m/z 174 85.2 (96.6) 177 5 to 9%of m/z 176 5.4 (6.4) 03/21/2017Page 300 of 377 Report Date: 10-Mar-2017 11:34:44 Chrom Revision: 2.2 05-Mar-2017 11:38:00 Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GBFBC10.D\MG_TO15.rslt\spectra.d Injection Date:10-Mar-2017 07:50:30 Spectrum:Tune Spec :Average 275-277( 4.71-4.72 ) Bgrd 264( 4.65) Base Peak:95.00 Minimum % Base Peak:0 Number of Points:116 m/z Y m/z Y m/z Y m/z Y 28.00 365 63.00 17248 96.00 31368 139.00 140 30.00 68 64.00 1627 97.00 984 140.00 334 31.00 11423 65.00 273 103.00 251 141.00 5863 32.00 524 66.00 116 104.00 2396 142.00 669 33.00 2824 67.00 1259 105.00 887 143.00 6176 36.00 3409 68.00 50224 106.00 2290 144.00 314 37.00 20104 69.00 50736 107.00 492 145.00 604 38.00 18272 70.00 4308 110.00 305 146.00 657 39.00 7366 71.00 191 111.00 488 147.00 452 41.00 31 72.00 2297 112.00 364 148.00 1213 42.00 107 73.00 19896 113.00 503 149.00 429 43.00 155 74.00 83720 115.00 544 150.00 632 44.00 1763 75.00 247680 116.00 1894 152.00 287 45.00 3890 76.00 20864 117.00 2410 153.00 387 46.00 287 77.00 2135 118.00 1750 154.00 426 47.00 3371 78.00 978 119.00 2490 155.00 1372 48.00 2197 79.00 16158 120.00 213 156.00 298 49.00 16768 80.00 5241 123.00 52 157.00 1067 50.00 83000 81.00 16880 124.00 291 159.00 599 51.00 24648 82.00 3808 125.00 52 161.00 602 52.00 871 83.00 550 126.00 228 172.00 69 53.00 31 86.00 295 127.00 220 173.00 1908 55.00 1070 87.00 11463 128.00 1866 174.00 394560 56.00 6615 88.00 11446 129.00 890 175.00 27080 57.00 12838 91.00 1778 130.00 1867 176.00 381184 58.00 599 92.00 13657 131.00 819 177.00 24232 60.00 3753 93.00 20640 134.00 183 178.00 640 61.00 20264 94.00 56392 135.00 969 208.00 120 62.00 20936 95.00 447360 137.00 1043 209.00 69 03/21/2017Page 301 of 377 Report Date: 10-Mar-2017 11:34:44 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GBFBC10.D Injection Date:10-Mar-2017 07:50:30 Instrument ID:MG Operator ID:7126 Lims ID:BFB Worklist Smp#:1 Client ID: Injection Vol:500.0 mL Dil. Factor:1.0000 ALS Bottle#:16 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.2 3.5 3.8 4.1 4.4 4.7 5.0 5.3 5.6 5.9 6.2 6.5 6.8 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 Y ( X10 0 0 0 0 ) GBFBC10[MS SCAN Chro]:Total $ B F B ( 4 . 7 1 7 ) 03/21/2017Page 302 of 377 Report Date: 24-Feb-2017 17:06:11 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RXBFBB23.D Lims ID:BFB Client ID: Sample Type:BFB Inject. Date:23-Feb-2017 21:41:30 ALS Bottle#:16 Worklist Smp#:1 Injection Vol:500.0 mL Dil. Factor:1.0000 Sample Info:140-0004095-001 Misc. Info.:TUNE Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:24-Feb-2017 17:06:10 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK010 First Level Reviewer: barlozhetskayaa Date:24-Feb-2017 17:05:24 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags $ 5 BFB 95 4.569 4.569 0.000 0 859616 NR NR QC Flag Legend Processing Flags NR - Missing Quant Standard Reagents: 40MXSUR_00001 Amount Added: 40.00 Units: mL 03/21/2017Page 303 of 377 Report Date: 24-Feb-2017 17:06:11 Chrom Revision: 2.2 22-Feb-2017 11:38:16 MS Tune Report TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RXBFBB23.D Injection Date:23-Feb-2017 21:41:30 Instrument ID:MR Lims ID:BFB Client ID: Operator ID:ALS Bottle#:16 Worklist Smp#:1 Injection Vol:500.0 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Tune Method: BFB Method 8260 $ 5 BFB 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 4 8 12 16 20 24 28 32 36 40 44 48 52 Y ( X 1 0 0 0 0 ) Tune Spec :Average 342-344( 4.57-4.57 ) Bgrd 326( 4.52) 17495 176 75 50 74 94 51 96 1773738 m/z Ion Abundance Criteria %Relative Abundance 95 Base peak,100%relative abundance 100.0 50 15 to 40%of m/z 95 23.3 75 30 to 60%of m/z 95 48.6 96 5 to 9%of m/z 95 6.4 173 Less than 2%of m/z 174 0.7 (0.7) 174 50 to 120%of m/z 95 101.5 175 5 to 9%of m/z 174 6.8 (6.7) 176 Greater than 95%but less than 101%of m/z 174 98.2 (96.8) 177 5 to 9%of m/z 176 6.2 (6.3) 03/21/2017Page 304 of 377 Report Date: 24-Feb-2017 17:06:11 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RXBFBB23.D\MR_TO15.rslt\spectra.d Injection Date:23-Feb-2017 21:41:30 Spectrum:Tune Spec :Average 342-344( 4.57-4.57 ) Bgrd 326( 4.52) Base Peak:174.00 Minimum % Base Peak:0 Number of Points:141 m/z Y m/z Y m/z Y m/z Y 28.00 148 69.00 56816 115.00 561 154.00 488 29.00 15 70.00 3845 116.00 2676 155.00 1507 30.00 51 71.00 58 117.00 3525 156.00 180 31.00 18008 72.00 2970 118.00 1895 157.00 1046 32.00 726 73.00 22888 119.00 3134 158.00 128 33.00 4164 74.00 89112 120.00 40 159.00 1036 34.00 36 75.00 259328 122.00 172 160.00 145 36.00 5311 76.00 22104 123.00 146 161.00 542 37.00 30600 77.00 2721 124.00 370 165.00 39 38.00 28656 78.00 2030 125.00 134 167.00 39 39.00 10643 79.00 19736 126.00 201 168.00 189 40.00 426 80.00 6373 127.00 150 169.00 184 41.00 164 81.00 22152 128.00 1840 170.00 182 43.00 138 82.00 5895 129.00 1058 171.00 236 44.00 2821 83.00 650 130.00 1566 172.00 1812 45.00 5400 86.00 632 131.00 806 173.00 3522 46.00 698 87.00 20032 132.00 64 174.00 541376 47.00 7676 88.00 19784 133.00 80 175.00 36512 48.00 3064 89.00 290 134.00 152 176.00 523840 49.00 24840 90.00 147 135.00 903 177.00 33136 50.00 124152 91.00 2991 136.00 178 178.00 878 51.00 37240 92.00 15629 137.00 1242 179.00 82 52.00 1581 93.00 24632 139.00 137 181.00 39 54.00 199 94.00 63960 140.00 394 192.00 56 55.00 1147 95.00 533504 141.00 6735 193.00 144 56.00 9094 96.00 34064 142.00 761 195.00 254 57.00 18472 97.00 1120 143.00 6666 208.00 96 58.00 708 103.00 620 144.00 496 221.00 193 60.00 4863 104.00 3219 145.00 592 222.00 34 61.00 26448 105.00 812 146.00 1077 223.00 61 62.00 26840 106.00 2577 147.00 453 253.00 280 63.00 20128 107.00 489 148.00 946 254.00 254 64.00 2045 110.00 327 149.00 802 255.00 125 03/21/2017Page 305 of 377 Report Date: 24-Feb-2017 17:06:11 Chrom Revision: 2.2 22-Feb-2017 11:38:16 Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RXBFBB23.D\MR_TO15.rslt\spectra.d Injection Date:23-Feb-2017 21:41:30 Spectrum:Tune Spec :Average 342-344( 4.57-4.57 ) Bgrd 326( 4.52) Base Peak:174.00 Minimum % Base Peak:0 Number of Points:141 m/z Y m/z Y m/z Y m/z Y 65.00 858 111.00 446 150.00 714 67.00 1152 112.00 535 152.00 147 68.00 56904 113.00 759 153.00 510 03/21/2017Page 306 of 377 Report Date: 24-Feb-2017 17:06:11 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RXBFBB23.D Injection Date:23-Feb-2017 21:41:30 Instrument ID:MR Operator ID: Lims ID:BFB Worklist Smp#:1 Client ID: Injection Vol:500.0 mL Dil. Factor:1.0000 ALS Bottle#:16 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.5 3.7 3.9 4.1 4.3 4.5 4.7 4.9 5.1 5.3 5.5 5.7 5.9 6.1 6.3 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 Y ( X 1 0 0 0 0 0 ) RXBFBB23[MS SCAN Chro]:Total $ B F B ( 4 . 5 6 9 ) 03/21/2017Page 307 of 377 Report Date: 09-Mar-2017 14:27:20 Chrom Revision: 2.2 08-Mar-2017 11:23:48 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09BFB.D Lims ID:BFB Client ID: Sample Type:BFB Inject. Date:09-Mar-2017 09:10:30 ALS Bottle#:16 Worklist Smp#:1 Injection Vol:500.0 mL Dil. Factor:1.0000 Sample Info:140-0004226-001 Misc. Info.:TUNE Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:09-Mar-2017 14:27:20 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK023 First Level Reviewer: tajh Date:09-Mar-2017 14:27:20 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags $ 5 BFB 95 4.563 4.563 0.000 0 1098663 NR NR QC Flag Legend Processing Flags NR - Missing Quant Standard Reagents: 40MXSUR_00001 Amount Added: 40.00 Units: mL 03/21/2017Page 308 of 377 Report Date: 09-Mar-2017 14:27:20 Chrom Revision: 2.2 08-Mar-2017 11:23:48 MS Tune Report TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09BFB.D Injection Date:09-Mar-2017 09:10:30 Instrument ID:MR Lims ID:BFB Client ID: Operator ID:ALS Bottle#:16 Worklist Smp#:1 Injection Vol:500.0 mL Dil. Factor:1.0000 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Tune Method: BFB Method 8260 $ 5 BFB 20 40 60 80 100 120 140 160 180 200 220 240 260 m/z 0 5 10 15 20 25 30 35 40 45 50 55 60 65 Y ( X10 0 0 0 ) Tune Spec :Average 340-342( 4.56-4.57 ) Bgrd 324( 4.51) 95 174 176 75 50 74 94 9651 17737 m/z Ion Abundance Criteria %Relative Abundance 95 Base peak,100%relative abundance 100.0 50 15 to 40%of m/z 95 22.0 75 30 to 60%of m/z 95 46.7 96 5 to 9%of m/z 95 6.8 173 Less than 2%of m/z 174 0.5 (0.6) 174 50 to 120%of m/z 95 97.9 175 5 to 9%of m/z 174 7.1 (7.3) 176 Greater than 95%but less than 101%of m/z 174 95.2 (97.2) 177 5 to 9%of m/z 176 6.3 (6.6) 03/21/2017Page 309 of 377 Report Date: 09-Mar-2017 14:27:20 Chrom Revision: 2.2 08-Mar-2017 11:23:48 Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09BFB.D\MR_TO15.rslt\spectra.d Injection Date:09-Mar-2017 09:10:30 Spectrum:Tune Spec :Average 340-342( 4.56-4.57 ) Bgrd 324( 4.51) Base Peak:95.00 Minimum % Base Peak:0 Number of Points:140 m/z Y m/z Y m/z Y m/z Y 28.00 286 71.00 309 115.00 789 153.00 747 31.00 19680 72.00 3169 116.00 2494 154.00 479 32.00 927 73.00 26952 117.00 3885 155.00 1546 33.00 4215 74.00 101032 118.00 2655 156.00 295 36.00 6406 75.00 306880 119.00 3421 157.00 914 37.00 35992 76.00 26008 122.00 156 158.00 100 38.00 32088 77.00 3311 123.00 183 159.00 1072 39.00 12988 78.00 444 124.00 284 161.00 1037 40.00 836 79.00 19856 125.00 214 163.00 38 43.00 218 80.00 7735 126.00 233 166.00 41 44.00 3686 81.00 21648 127.00 138 168.00 101 45.00 6458 82.00 5965 128.00 1940 169.00 141 46.00 46 83.00 576 129.00 859 170.00 178 47.00 10238 86.00 496 130.00 2604 171.00 291 48.00 3336 87.00 25536 131.00 1198 172.00 1906 49.00 28416 88.00 23392 132.00 147 173.00 3607 50.00 144640 89.00 242 133.00 110 174.00 643712 51.00 42888 91.00 2211 134.00 99 175.00 46952 52.00 1332 92.00 18264 135.00 1404 176.00 625728 55.00 1184 93.00 27728 136.00 127 177.00 41408 56.00 10924 94.00 76424 137.00 1323 178.00 1200 57.00 19216 95.00 657408 139.00 246 185.00 40 58.00 1132 96.00 44448 140.00 225 191.00 321 59.00 187 97.00 1408 141.00 7209 195.00 239 60.00 5800 102.00 147 142.00 880 196.00 81 61.00 30856 103.00 178 143.00 7527 197.00 107 62.00 30136 104.00 2993 144.00 289 207.00 288 63.00 23928 105.00 802 145.00 707 208.00 156 64.00 2073 106.00 3120 146.00 894 209.00 186 65.00 498 107.00 781 147.00 430 219.00 165 66.00 68 108.00 129 148.00 1904 221.00 71 67.00 1436 110.00 563 149.00 374 249.00 54 68.00 67168 111.00 689 150.00 814 253.00 84 03/21/2017Page 310 of 377 Report Date: 09-Mar-2017 14:27:20 Chrom Revision: 2.2 08-Mar-2017 11:23:48 Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09BFB.D\MR_TO15.rslt\spectra.d Injection Date:09-Mar-2017 09:10:30 Spectrum:Tune Spec :Average 340-342( 4.56-4.57 ) Bgrd 324( 4.51) Base Peak:95.00 Minimum % Base Peak:0 Number of Points:140 m/z Y m/z Y m/z Y m/z Y 69.00 66720 112.00 655 151.00 84 254.00 190 70.00 5524 113.00 767 152.00 318 255.00 206 03/21/2017Page 311 of 377 Report Date: 09-Mar-2017 14:27:20 Chrom Revision: 2.2 08-Mar-2017 11:23:48 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09BFB.D Injection Date:09-Mar-2017 09:10:30 Instrument ID:MR Operator ID: Lims ID:BFB Worklist Smp#:1 Client ID: Injection Vol:500.0 mL Dil. Factor:1.0000 ALS Bottle#:16 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.5 3.7 3.9 4.1 4.3 4.5 4.7 4.9 5.1 5.3 5.5 5.7 5.9 6.1 6.3 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 Y ( X10 0 0 0 0 ) RC09BFB[MS SCAN Chro]:Total $ B F B ( 4 . 5 6 0 ) 03/21/2017Page 312 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: SDG No.: 140-7345-1 Lab Sample ID:MB 140-9156/4 TestAmerica Knoxville Matrix:RC09BLK.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:03/09/2017 12:38 ID:RTX-5 Analysis Batch No.:9156 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 133.4171-55-6 1,1,1-Trichloroethane ND 0.080 167.8579-34-5 1,1,2,2-Tetrachloroethan e ND 0.080 133.4179-00-5 1,1,2-Trichloroethane ND 0.080 187.3876-13-1 1,1,2-Trichlorotrifluoro ethane ND 0.080 98.9675-34-3 1,1-Dichloroethane ND 0.080 96.9475-35-4 1,1-Dichloroethene ND 0.080 181.45120-82-1 1,2,4-Trichlorobenzene ND 0.080 120.2095-63-6 1,2,4-Trimethylbenzene ND 0.080 187.87106-93-4 1,2-Dibromoethane ND 0.080 147.0095-50-1 1,2-Dichlorobenzene ND 0.080 98.96107-06-2 1,2-Dichloroethane ND 0.080 112.9978-87-5 1,2-Dichloropropane ND 0.080 170.9276-14-2 1,2-Dichlorotetrafluoroe thane ND 0.080 120.20108-67-8 1,3,5-Trimethylbenzene ND 0.080 147.00541-73-1 1,3-Dichlorobenzene ND 0.080 147.00106-46-7 1,4-Dichlorobenzene ND 0.080 88.11123-91-1 1,4-Dioxane ND 0.20 114.23540-84-1 2,2,4-Trimethylpentane ND 0.20 72.1178-93-3 2-Butanone ND 0.32 100.16108-10-1 4-Methyl-2-pentanone (MIBK) ND 0.20 78.1171-43-2 Benzene ND 0.080 126.58100-44-7 Benzyl chloride ND 0.16 163.8375-27-4 Bromodichloromethane ND 0.080 252.7575-25-2 Bromoform ND 0.080 94.9474-83-9 Bromomethane ND 0.080 153.8156-23-5 Carbon tetrachloride ND 0.040 112.56108-90-7 Chlorobenzene ND 0.080 64.5275-00-3 Chloroethane ND 0.080 119.3867-66-3 Chloroform ND 0.080 50.4974-87-3 Chloromethane ND 0.20 96.94156-59-2 cis-1,2-Dichloroethene ND 0.080 110.9710061-01-5 cis-1,3-Dichloropropene ND 0.080 84.16110-82-7 Cyclohexane ND 0.20 FORM I TO 15 LL 03/21/2017Page 313 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: SDG No.: 140-7345-1 Lab Sample ID:MB 140-9156/4 TestAmerica Knoxville Matrix:RC09BLK.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:03/09/2017 12:38 ID:RTX-5 Analysis Batch No.:9156 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 208.29124-48-1 Dibromochloromethane ND 0.080 120.9175-71-8 Dichlorodifluoromethane ND 0.080 46.0764-17-5 Ethanol ND 2.0 106.17100-41-4 Ethylbenzene ND 0.080 260.7687-68-3 Hexachlorobutadiene ND 0.080 86.17110-54-3 Hexane ND 0.20 88.151634-04-4 Methyl tert-butyl ether ND 0.16 84.9375-09-2 Methylene Chloride ND 0.20 106.17179601-23-1 m-Xylene & p-Xylene ND 0.080 106.1795-47-6 o-Xylene ND 0.080 104.15100-42-5 Styrene ND 0.080 74.1275-65-0 t-Butyl alcohol ND 0.32 165.83127-18-4 Tetrachloroethene ND 0.080 92.14108-88-3 Toluene ND 0.12 96.94156-60-5 trans-1,2-Dichloroethene ND 0.080 110.9710061-02-6 trans-1,3-Dichloropropen e ND 0.080 131.3979-01-6 Trichloroethene ND 0.040 137.3775-69-4 Trichlorofluoromethane ND 0.080 62.5075-01-4 Vinyl chloride ND 0.040 %RECCAS NO.LIMITSQSURROGATE 98 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 314 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: SDG No.: 140-7345-1 Lab Sample ID:MB 140-9156/4 TestAmerica Knoxville Matrix:RC09BLK.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:03/09/2017 12:38 ID:RTX-5 Analysis Batch No.:9156 ug/m3Units: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 133.4171-55-6 1,1,1-Trichloroethane ND 0.44 167.8579-34-5 1,1,2,2-Tetrachloroethan e ND 0.55 133.4179-00-5 1,1,2-Trichloroethane ND 0.44 187.3876-13-1 1,1,2-Trichlorotrifluoro ethane ND 0.61 98.9675-34-3 1,1-Dichloroethane ND 0.32 96.9475-35-4 1,1-Dichloroethene ND 0.32 181.45120-82-1 1,2,4-Trichlorobenzene ND 0.59 120.2095-63-6 1,2,4-Trimethylbenzene ND 0.39 187.87106-93-4 1,2-Dibromoethane ND 0.61 147.0095-50-1 1,2-Dichlorobenzene ND 0.48 98.96107-06-2 1,2-Dichloroethane ND 0.32 112.9978-87-5 1,2-Dichloropropane ND 0.37 170.9276-14-2 1,2-Dichlorotetrafluoroe thane ND 0.56 120.20108-67-8 1,3,5-Trimethylbenzene ND 0.39 147.00541-73-1 1,3-Dichlorobenzene ND 0.48 147.00106-46-7 1,4-Dichlorobenzene ND 0.48 88.11123-91-1 1,4-Dioxane ND 0.72 114.23540-84-1 2,2,4-Trimethylpentane ND 0.93 72.1178-93-3 2-Butanone ND 0.94 100.16108-10-1 4-Methyl-2-pentanone (MIBK) ND 0.82 78.1171-43-2 Benzene ND 0.26 126.58100-44-7 Benzyl chloride ND 0.83 163.8375-27-4 Bromodichloromethane ND 0.54 252.7575-25-2 Bromoform ND 0.83 94.9474-83-9 Bromomethane ND 0.31 153.8156-23-5 Carbon tetrachloride ND 0.25 112.56108-90-7 Chlorobenzene ND 0.37 64.5275-00-3 Chloroethane ND 0.21 119.3867-66-3 Chloroform ND 0.39 50.4974-87-3 Chloromethane ND 0.41 96.94156-59-2 cis-1,2-Dichloroethene ND 0.32 110.9710061-01-5 cis-1,3-Dichloropropene ND 0.36 84.16110-82-7 Cyclohexane ND 0.69 FORM I TO 15 LL 03/21/2017Page 315 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: SDG No.: 140-7345-1 Lab Sample ID:MB 140-9156/4 TestAmerica Knoxville Matrix:RC09BLK.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:03/09/2017 12:38 ID:RTX-5 Analysis Batch No.:9156 ug/m3Units: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 208.29124-48-1 Dibromochloromethane ND 0.68 120.9175-71-8 Dichlorodifluoromethane ND 0.40 46.0764-17-5 Ethanol ND 3.8 106.17100-41-4 Ethylbenzene ND 0.35 260.7687-68-3 Hexachlorobutadiene ND 0.85 86.17110-54-3 Hexane ND 0.70 88.151634-04-4 Methyl tert-butyl ether ND 0.58 84.9375-09-2 Methylene Chloride ND 0.69 106.17179601-23-1 m-Xylene & p-Xylene ND 0.35 106.1795-47-6 o-Xylene ND 0.35 104.15100-42-5 Styrene ND 0.34 74.1275-65-0 t-Butyl alcohol ND 0.97 165.83127-18-4 Tetrachloroethene ND 0.54 92.14108-88-3 Toluene ND 0.45 96.94156-60-5 trans-1,2-Dichloroethene ND 0.32 110.9710061-02-6 trans-1,3-Dichloropropen e ND 0.36 131.3979-01-6 Trichloroethene ND 0.21 137.3775-69-4 Trichlorofluoromethane ND 0.45 62.5075-01-4 Vinyl chloride ND 0.10 %RECCAS NO.LIMITSQSURROGATE 98 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 316 of 377 Report Date: 09-Mar-2017 14:29:54 Chrom Revision: 2.2 08-Mar-2017 11:23:48 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09BLK.D Lims ID:MB Client ID: Sample Type:MB Inject. Date:09-Mar-2017 12:38:30 ALS Bottle#:15 Worklist Smp#:4 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004226-004 Misc. Info.:500ML BLK Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:09-Mar-2017 14:29:23 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK023 First Level Reviewer: tajh Date:09-Mar-2017 13:22:32 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.204 8.215 -0.011 99 436115 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.372 10.377 -0.005 96 2108497 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.268 15.274 -0.006 89 1621976 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.961 16.961 0.000 95 1113159 4.00 3.93 31 Methylene Chloride 84 5.902 5.907 -0.005 98 10852 0.0798 65 4-Methyl-2-pentanone (MIBK 43 12.340 12.324 0.016 98 15782 0.0461 Reagents: 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 317 of 377 Report Date: 09-Mar-2017 14:29:54 Chrom Revision: 2.2 08-Mar-2017 11:23:48 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09BLK.D Injection Date:09-Mar-2017 12:38:30 Instrument ID:MR Operator ID: Lims ID:MB Worklist Smp#:4 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:15 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 Y ( X10 0 0 0 0 ) RC09BLK[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 0 4 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 7 2 ) * C h l o r o b e n zen e - d5 (IS )( 1 5 . 2 6 8 ) $ 4 - B r o m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 1 ) 03/21/2017Page 318 of 377 Report Date: 09-Mar-2017 14:29:54 Chrom Revision: 2.2 08-Mar-2017 11:23:48 TestAmerica Knoxville Recovery Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09BLK.D Lims ID:MB Client ID: Sample Type:MB Inject. Date:09-Mar-2017 12:38:30 ALS Bottle#:15 Worklist Smp#:4 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004226-004 Misc. Info.:500ML BLK Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:09-Mar-2017 14:29:23 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK023 First Level Reviewer: tajh Date:09-Mar-2017 13:22:32 Compound Amount Added Amount Recovered %Rec. $4 4-Bromofluorobenzene (Surr)4.00 3.93 98.30 03/21/2017Page 319 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: SDG No.: 140-7345-1 Lab Sample ID:MB 140-9158/4 TestAmerica Knoxville Matrix:GMB500C10.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:03/10/2017 10:04 ID:RTX-5 Analysis Batch No.:9158 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 46.0764-17-5 Ethanol ND 2.0 %RECCAS NO.LIMITSQSURROGATE 103 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 320 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: SDG No.: 140-7345-1 Lab Sample ID:MB 140-9158/4 TestAmerica Knoxville Matrix:GMB500C10.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:03/10/2017 10:04 ID:RTX-5 Analysis Batch No.:9158 ug/m3Units: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 46.0764-17-5 Ethanol ND 3.8 %RECCAS NO.LIMITSQSURROGATE 103 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 321 of 377 Report Date: 10-Mar-2017 11:36:48 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GMB500C10.D Lims ID:mb Client ID: Sample Type:MB Inject. Date:10-Mar-2017 10:04:30 ALS Bottle#:16 Worklist Smp#:4 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004228-004 Misc. Info.:500ML BLK Operator ID:7126 Instrument ID:MG Method:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 11:36:23 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 10:49:50 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 7.991 8.001 -0.010 86 280896 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.164 10.169 -0.005 95 1418032 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.033 15.038 -0.005 88 1398041 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.705 16.710 -0.005 94 1073193 4.00 4.12 31 Methylene Chloride 84 5.656 5.666 -0.010 90 5958 0.0880 51 n-Butanol 31 9.651 9.608 0.043 77 1998 0.0770 Reagents: 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 322 of 377 Report Date: 10-Mar-2017 11:36:48 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GMB500C10.D Injection Date:10-Mar-2017 10:04:30 Instrument ID:MG Operator ID:7126 Lims ID:mb Worklist Smp#:4 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:16 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 Y ( X10 0 0 0 0 ) GMB500C10[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 7 . 99 1) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 6 4 )* C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 3 3 ) $ 4 - B r o m o flu o r o b e n zen e (Su r r )( 1 6 . 7 0 5 ) 03/21/2017Page 323 of 377 Report Date: 10-Mar-2017 11:36:48 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Knoxville Recovery Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GMB500C10.D Lims ID:mb Client ID: Sample Type:MB Inject. Date:10-Mar-2017 10:04:30 ALS Bottle#:16 Worklist Smp#:4 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004228-004 Misc. Info.:500ML BLK Operator ID:7126 Instrument ID:MG Method:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 11:36:23 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 10:49:50 Compound Amount Added Amount Recovered %Rec. $4 4-Bromofluorobenzene (Surr)4.00 4.12 103.08 03/21/2017Page 324 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: SDG No.: 140-7345-1 Lab Sample ID:LCS 140-9156/1002 TestAmerica Knoxville Matrix:RC09CCV-LCS.dLab File ID: Date Collected:TO 15 LLAnalysis Method: Air Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:03/09/2017 09:42 ID:RTX-5 Analysis Batch No.:9156 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 133.4171-55-6 1,1,1-Trichloroethane 2.02 0.080 167.8579-34-5 1,1,2,2-Tetrachloroethan e 2.21 0.080 133.4179-00-5 1,1,2-Trichloroethane 2.17 0.080 187.3876-13-1 1,1,2-Trichlorotrifluoro ethane 2.10 0.080 98.9675-34-3 1,1-Dichloroethane 2.08 0.080 96.9475-35-4 1,1-Dichloroethene 2.11 0.080 181.45120-82-1 1,2,4-Trichlorobenzene 2.25 0.080 120.2095-63-6 1,2,4-Trimethylbenzene 2.29 0.080 187.87106-93-4 1,2-Dibromoethane 2.26 0.080 147.0095-50-1 1,2-Dichlorobenzene 2.21 0.080 98.96107-06-2 1,2-Dichloroethane 1.95 0.080 112.9978-87-5 1,2-Dichloropropane 2.22 0.080 170.9276-14-2 1,2-Dichlorotetrafluoroe thane 1.95 0.080 120.20108-67-8 1,3,5-Trimethylbenzene 2.21 0.080 147.00541-73-1 1,3-Dichlorobenzene 2.15 0.080 147.00106-46-7 1,4-Dichlorobenzene 2.15 0.080 88.11123-91-1 1,4-Dioxane 2.14 0.20 114.23540-84-1 2,2,4-Trimethylpentane 2.24 0.20 72.1178-93-3 2-Butanone 2.14 0.32 100.16108-10-1 4-Methyl-2-pentanone (MIBK) 2.45 0.20 78.1171-43-2 Benzene 2.11 0.080 126.58100-44-7 Benzyl chloride 2.40 0.16 163.8375-27-4 Bromodichloromethane 2.12 0.080 252.7575-25-2 Bromoform 2.17 0.080 94.9474-83-9 Bromomethane 1.47 0.080 153.8156-23-5 Carbon tetrachloride 1.99 0.040 112.56108-90-7 Chlorobenzene 2.11 0.080 64.5275-00-3 Chloroethane 1.36 0.080 119.3867-66-3 Chloroform 2.02 0.080 50.4974-87-3 Chloromethane 2.21 0.20 96.94156-59-2 cis-1,2-Dichloroethene 2.12 0.080 110.9710061-01-5 cis-1,3-Dichloropropene 2.24 0.080 84.16110-82-7 Cyclohexane 2.24 0.20 FORM I TO 15 LL 03/21/2017Page 325 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: SDG No.: 140-7345-1 Lab Sample ID:LCS 140-9156/1002 TestAmerica Knoxville Matrix:RC09CCV-LCS.dLab File ID: Date Collected:TO 15 LLAnalysis Method: Air Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:03/09/2017 09:42 ID:RTX-5 Analysis Batch No.:9156 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 208.29124-48-1 Dibromochloromethane 2.36 0.080 120.9175-71-8 Dichlorodifluoromethane 1.55 0.080 46.0764-17-5 Ethanol 6.84 2.0 106.17100-41-4 Ethylbenzene 2.22 0.080 260.7687-68-3 Hexachlorobutadiene 2.12 0.080 86.17110-54-3 Hexane 2.08 0.20 88.151634-04-4 Methyl tert-butyl ether 2.09 0.16 84.9375-09-2 Methylene Chloride 1.99 0.20 106.17179601-23-1 m-Xylene & p-Xylene 4.58 0.080 106.1795-47-6 o-Xylene 2.17 0.080 104.15100-42-5 Styrene 2.46 0.080 74.1275-65-0 t-Butyl alcohol 2.02 0.32 165.83127-18-4 Tetrachloroethene 2.17 0.080 92.14108-88-3 Toluene 2.24 0.12 96.94156-60-5 trans-1,2-Dichloroethene 2.13 0.080 110.9710061-02-6 trans-1,3-Dichloropropen e 2.22 0.080 131.3979-01-6 Trichloroethene 2.07 0.040 137.3775-69-4 Trichlorofluoromethane 1.71 0.080 62.5075-01-4 Vinyl chloride 1.90 0.040 %RECCAS NO.LIMITSQSURROGATE 98 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 326 of 377 Report Date: 09-Mar-2017 14:29:26 Chrom Revision: 2.2 08-Mar-2017 11:23:48 TestAmerica Laboratories Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09CCV-LCS.d Lims ID:LCS Client ID: Sample Type:LCS Inject. Date:09-Mar-2017 09:42:30 ALS Bottle#:15 Worklist Smp#:1002 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004226-002 Misc. Info.:P32 Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:09-Mar-2017 14:29:23 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK023 First Level Reviewer: tajh Date:09-Mar-2017 14:29:23 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.215 8.215 0.000 98 396885 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.377 10.377 0.000 95 1938837 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.274 15.274 0.000 89 1560294 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.961 16.961 0.000 96 1067424 4.00 3.92 6 Chlorodifluoromethane 67 3.696 3.696 0.000 96 67346 2.00 1.84 7 Propene 41 3.701 3.701 0.000 96 315388 2.00 2.22 8 Dichlorodifluoromethane 85 3.750 3.750 0.000 100 412265 2.00 1.55 9 Chloromethane 52 3.896 3.896 0.000 99 102909 2.00 2.21 10 1,2-Dichloro-1,1,2,2-tetra 135 3.928 3.928 0.000 92 479477 2.00 1.95 11 Acetaldehyde 44 4.047 4.047 0.000 98 357311 10.0 8.33 12 Vinyl chloride 62 4.047 4.047 0.000 98 210617 2.00 1.90 13 Butadiene 54 4.127 4.127 0.000 88 131458 2.00 1.71 14 Butane 43 4.133 4.133 0.000 91 247359 2.00 1.70 15 Bromomethane 94 4.392 4.392 0.000 96 126336 2.00 1.47 16 Chloroethane 64 4.516 4.516 0.000 87 55888 2.00 1.36 17 Ethanol 31 4.634 4.634 0.000 98 196500 10.0 6.84 18 Vinyl bromide 106 4.769 4.769 0.000 96 109063 2.00 1.49 19 2-Methylbutane 43 4.828 4.828 0.000 85 110001 2.00 1.44 20 Acrolein 56 5.006 5.006 0.000 29 31086 2.00 1.13 21 Trichlorofluoromethane 101 5.012 5.012 0.000 99 554281 2.00 1.71 22 Acetonitrile 40 5.060 5.060 0.000 98 105365 2.00 2.07 23 Acetone 58 5.109 5.109 0.000 98 387880 6.00 5.94 24 Isopropyl alcohol 45 5.211 5.211 0.000 82 1233998 6.00 6.33 25 Pentane 72 5.211 5.211 0.000 73 49224 2.00 2.18 26 Ethyl ether 31 5.346 5.346 0.000 92 366028 2.00 2.33 27 1,1-Dichloroethene 96 5.610 5.610 0.000 97 257802 2.00 2.11 28 Acrylonitrile 53 5.686 5.686 0.000 95 212023 2.00 2.14 29 2-Methyl-2-propanol 59 5.718 5.718 0.000 96 472676 2.00 2.02 30 1,1,2-Trichloro-1,2,2-trif 101 5.788 5.788 0.000 98 575213 2.00 2.10 31 Methylene Chloride 84 5.907 5.907 0.000 99 246890 2.00 1.99 32 3-Chloro-1-propene 39 5.923 5.923 0.000 92 241411 2.00 1.95 03/21/2017Page 327 of 377 Report Date: 09-Mar-2017 14:29:26 Chrom Revision: 2.2 08-Mar-2017 11:23:48 Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09CCV-LCS.d Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 33 Carbon disulfide 76 6.042 6.042 0.000 100 747994 2.00 2.13 34 trans-1,2-Dichloroethene 96 6.640 6.640 0.000 98 266590 2.00 2.13 35 2-Methylpentane 43 6.689 6.689 0.000 97 659633 2.00 2.22 36 Methyl tert-butyl ether 73 6.764 6.764 0.000 98 665477 2.00 2.09 37 1,1-Dichloroethane 63 7.007 7.007 0.000 99 511384 2.00 2.08 38 Vinyl acetate 43 7.115 7.115 0.000 100 826398 2.00 2.34 39 2-Butanone (MEK) 72 7.503 7.503 0.000 98 127586 2.00 2.14 40 Hexane 56 7.595 7.595 0.000 92 231413 2.00 2.08 41 Isopropyl ether 45 7.730 7.730 0.000 98 1089713 2.00 2.27 42 cis-1,2-Dichloroethene 96 7.913 7.913 0.000 95 275610 2.00 2.12 43 Ethyl acetate 43 8.096 8.096 0.000 98 701847 2.00 2.30 44 Chloroform 83 8.247 8.247 0.000 96 537822 2.00 2.02 45 Tert-butyl ethyl ether 59 8.360 8.360 0.000 97 820267 2.00 2.19 46 Tetrahydrofuran 42 8.598 8.598 0.000 95 362747 2.00 2.22 47 1,1,1-Trichloroethane 97 9.223 9.223 0.000 96 510498 2.00 2.02 48 1,2-Dichloroethane 62 9.299 9.299 0.000 96 352133 2.00 1.95 49 n-Butanol 31 9.779 9.779 0.000 90 125208 2.00 2.36 50 Benzene 78 9.806 9.806 0.000 97 742291 2.00 2.11 51 Cyclohexane 69 9.833 9.833 0.000 96 125275 2.00 2.24 52 Carbon tetrachloride 117 9.843 9.843 0.000 98 530257 2.00 1.99 53 2,3-Dimethylpentane 71 9.989 9.989 0.000 93 183287 2.00 2.21 54 Thiophene 84 10.075 10.075 0.000 96 454815 2.00 2.16 55 Tert-amyl methyl ether 73 10.323 10.323 0.000 96 733040 2.00 2.23 56 Isooctane 57 10.663 10.663 0.000 99 1443932 2.00 2.24 57 1,2-Dichloropropane 63 11.051 11.051 0.000 89 334458 2.00 2.22 58 n-Heptane 71 11.057 11.057 0.000 94 290654 2.00 2.34 59 Trichloroethene 130 11.111 11.111 0.000 94 356348 2.00 2.07 60 Dibromomethane 93 11.154 11.154 0.000 89 320901 2.00 2.08 61 Dichlorobromomethane 83 11.326 11.326 0.000 99 536078 2.00 2.12 62 1,4-Dioxane 88 11.326 11.326 0.000 65 111990 2.00 2.14 63 Methyl methacrylate 41 11.456 11.456 0.000 92 409633 2.00 2.38 64 Methylcyclohexane 83 11.936 11.936 0.000 92 574175 2.00 2.22 65 4-Methyl-2-pentanone (MIBK 43 12.324 12.324 0.000 98 771392 2.00 2.45 66 cis-1,3-Dichloropropene 75 12.378 12.378 0.000 96 440649 2.00 2.24 67 trans-1,3-Dichloropropene 75 13.100 13.100 0.000 98 384277 2.00 2.22 68 Toluene 91 13.246 13.246 0.000 93 949557 2.00 2.24 69 1,1,2-Trichloroethane 83 13.295 13.295 0.000 98 279756 2.00 2.17 70 2-Methylthiophene 97 13.392 13.392 0.000 98 752804 2.00 2.27 71 3-Methylthiophene 97 13.602 13.602 0.000 100 748110 2.00 2.30 72 2-Hexanone 58 13.721 13.721 0.000 91 353979 2.00 2.39 73 Chlorodibromomethane 129 14.017 14.017 0.000 98 549861 2.00 2.36 74 n-Octane 85 14.039 14.039 0.000 96 303244 2.00 2.47 75 Ethylene Dibromide 107 14.308 14.308 0.000 98 493262 2.00 2.26 76 Tetrachloroethene 129 14.432 14.432 0.000 93 336990 2.00 2.17 77 Chlorobenzene 112 15.322 15.322 0.000 95 755800 2.00 2.11 78 2,3-Dimethylheptane 43 15.424 15.424 0.000 96 1023519 2.00 2.49 79 Ethylbenzene 91 15.640 15.640 0.000 99 1188044 2.00 2.22 80 2-Ethylthiophene 97 15.737 15.737 0.000 98 856999 2.00 2.27 81 m-Xylene & p-Xylene 91 15.807 15.807 0.000 100 1862438 4.00 4.58 82 Bromoform 173 16.212 16.212 0.000 97 584596 2.00 2.17 83 Styrene 104 16.276 16.276 0.000 98 663316 2.00 2.46 84 n-Nonane 57 16.303 16.303 0.000 96 694337 2.00 2.53 03/21/2017Page 328 of 377 Report Date: 09-Mar-2017 14:29:26 Chrom Revision: 2.2 08-Mar-2017 11:23:48 Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09CCV-LCS.d Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 85 o-Xylene 91 16.341 16.341 0.000 98 931846 2.00 2.17 86 1,1,2,2-Tetrachloroethane 83 16.649 16.649 0.000 99 696645 2.00 2.21 87 1,2,3-Trichloropropane 110 16.810 16.810 0.000 96 190797 2.00 2.11 88 Isopropylbenzene 105 16.956 16.956 0.000 96 1231851 2.00 2.07 89 N-Propylbenzene 120 17.533 17.533 0.000 99 345310 2.00 2.18 90 2-Chlorotoluene 126 17.560 17.560 0.000 97 312821 2.00 2.03 91 4-Ethyltoluene 105 17.700 17.700 0.000 99 1310776 2.00 2.23 92 1,3,5-Trimethylbenzene 120 17.781 17.781 0.000 92 597222 2.00 2.21 93 Alpha Methyl Styrene 118 18.024 18.024 0.000 89 530506 2.00 2.37 94 n-Decane 57 18.148 18.148 0.000 88 963197 2.00 2.66 95 tert-Butylbenzene 119 18.234 18.234 0.000 92 1228163 2.00 2.30 96 1,2,4-Trimethylbenzene 105 18.245 18.245 0.000 96 1152315 2.00 2.29 97 1,3-Dichlorobenzene 146 18.514 18.514 0.000 97 872762 2.00 2.15 98 sec-Butylbenzene 105 18.525 18.525 0.000 99 1778996 2.00 2.38 99 Benzyl chloride 91 18.590 18.590 0.000 98 1051715 2.00 2.40 100 1,4-Dichlorobenzene 146 18.606 18.606 0.000 96 893527 2.00 2.15 101 4-Isopropyltoluene 119 18.703 18.703 0.000 96 1493016 2.00 2.42 102 1,2,3-Trimethylbenzene 105 18.746 18.746 0.000 97 915903 2.00 2.27 103 Butylcyclohexane 83 18.832 18.832 0.000 91 1002268 2.00 2.42 104 1,2-Dichlorobenzene 146 18.983 18.983 0.000 96 874598 2.00 2.21 105 2,3-Dihydroindene 117 18.994 18.994 0.000 94 1010967 2.00 2.20 106 Indene 116 19.129 19.129 0.000 91 834950 2.00 2.48 107 n-Butylbenzene 91 19.167 19.167 0.000 98 1625736 2.00 2.45 108 Undecane 57 19.544 19.544 0.000 96 1166239 2.00 2.79 109 1,2-Dimethyl-4-Ethylbenzen 119 19.560 19.560 0.000 98 1160116 2.00 2.31 110 1,2-Dibromo-3-Chloropropan 157 19.614 19.614 0.000 95 401519 2.00 2.34 111 1,2,4,5-Tetramethylbenzene 119 19.965 19.965 0.000 98 1357272 2.00 2.38 112 1,2,3,5-Tetramethylbenzene 119 20.019 20.019 0.000 96 842563 2.00 2.33 113 1,2,3,4-Tetramethylbenzene 119 20.423 20.423 0.000 98 1136969 2.00 2.34 114 Dodecane 57 20.650 20.650 0.000 94 1129352 2.00 2.61 115 1,2,4-Trichlorobenzene 180 20.774 20.774 0.000 93 956207 2.00 2.25 116 Naphthalene 128 20.903 20.903 0.000 99 1760038 2.00 2.36 117 Benzo(b)thiophene 134 21.006 21.006 0.000 100 999277 2.00 2.24 118 Hexachlorobutadiene 225 21.157 21.157 0.000 93 911481 2.00 2.12 119 1,2,3-Trichlorobenzene 180 21.200 21.200 0.000 95 901226 2.00 2.14 120 2-Methylnaphthalene 142 21.922 21.922 0.000 97 317947 6.25 4.87 121 1-Methylnaphthalene 142 22.046 22.046 0.000 97 268683 6.25 5.56 A 122 C6 Range 1 7.598 (7.530-7.640) 0 2064337 2.00 2.17 S 124 Xylenes, Total 100 0 6.00 6.75 S 125 1,2-Dichloroethene, Total 1 0 4.00 4.25 Reagents: 40CV101P_00032 Amount Added: 100.00 Units: ml 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 329 of 377 Report Date: 09-Mar-2017 14:29:26 Chrom Revision: 2.2 08-Mar-2017 11:23:48 TestAmerica Laboratories Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09CCV-LCS.d Injection Date:09-Mar-2017 09:42:30 Instrument ID:MR Operator ID: Lims ID:LCS Worklist Smp#:1002 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:15 Method:MR_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 Y ( X10 0 0 0 0 ) RC09CCV-LCS[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 2 1 5) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 3 7 7 ) * C h l o r o b e n zen e - d 5 (IS )( 1 5.2 7 4 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 9 6 1 )+ 03/21/2017Page 330 of 377 Report Date: 09-Mar-2017 14:29:26 Chrom Revision: 2.2 08-Mar-2017 11:23:48 TestAmerica Laboratories Recovery Report Data File:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\RC09CCV-LCS.d Lims ID:LCS Client ID: Sample Type:LCS Inject. Date:09-Mar-2017 09:42:30 ALS Bottle#:15 Worklist Smp#:1002 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004226-002 Misc. Info.:P32 Operator ID:Instrument ID:MR Method:\\ChromNA\Knoxville\ChromData\MR\20170306-4226.b\MR_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:09-Mar-2017 14:29:23 Calib Date:24-Feb-2017 05:21:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MR\20170220-4095.b\RB23IC09.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK023 First Level Reviewer: tajh Date:09-Mar-2017 14:29:23 Compound Amount Added Amount Recovered %Rec. $4 4-Bromofluorobenzene (Surr)4.00 3.92 97.99 03/21/2017Page 331 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: SDG No.: 140-7345-1 Lab Sample ID:LCS 140-9158/1002 TestAmerica Knoxville Matrix:GCCVC10-LCS.dLab File ID: Date Collected:TO 15 LLAnalysis Method: Air Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:03/10/2017 08:21 ID:RTX-5 Analysis Batch No.:9158 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RLMOLECULAR WEIGHT 46.0764-17-5 Ethanol 10.5 2.0 %RECCAS NO.LIMITSQSURROGATE 107 60-140460-00-4 4-Bromofluorobenzene (Surr) FORM I TO 15 LL 03/21/2017Page 332 of 377 Report Date: 10-Mar-2017 11:36:26 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Laboratories Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GCCVC10-LCS.d Lims ID:LCS Client ID: Sample Type:LCS Inject. Date:10-Mar-2017 08:21:30 ALS Bottle#:15 Worklist Smp#:1002 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004228-002 Misc. Info.:S31 Operator ID:7126 Instrument ID:MG Method:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 11:36:23 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 11:36:23 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.001 8.001 0.000 86 284389 4.00 4.00 * 2 1,4-Difluorobenzene 114 10.169 10.169 0.000 95 1474377 4.00 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.038 15.038 0.000 88 1473079 4.00 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.710 16.710 0.000 95 1171759 4.00 4.27 6 Chlorodifluoromethane 67 3.461 3.461 0.000 97 68770 2.00 2.47 7 Propene 41 3.472 3.472 0.000 97 152258 2.00 2.30 8 Dichlorodifluoromethane 85 3.515 3.515 0.000 100 656352 2.00 2.60 9 Chloromethane 52 3.666 3.666 0.000 98 48792 2.00 2.40 10 1,2-Dichloro-1,1,2,2-tetra 135 3.677 3.677 0.000 92 368344 2.00 2.39 11 Acetaldehyde 44 3.790 3.790 0.000 90 270105 10.0 8.90 12 Vinyl chloride 62 3.806 3.806 0.000 99 190922 2.00 2.45 13 Butadiene 54 3.882 3.882 0.000 84 128301 2.00 2.28 14 Butane 43 3.882 3.882 0.000 95 282548 2.00 2.39 15 Bromomethane 94 4.146 4.146 0.000 97 169544 2.00 2.14 16 Chloroethane 64 4.264 4.264 0.000 90 89437 2.00 2.14 17 Ethanol 31 4.361 4.361 0.000 97 328424 10.0 10.5 18 Vinyl bromide 106 4.518 4.518 0.000 95 171764 2.00 2.28 19 2-Methylbutane 43 4.566 4.566 0.000 90 186807 2.00 2.08 20 Acrolein 56 4.744 4.744 0.000 97 29598 2.00 2.54 21 Trichlorofluoromethane 101 4.750 4.750 0.000 99 616541 2.00 2.38 22 Acetonitrile 40 4.798 4.798 0.000 98 55283 2.00 1.93 23 Acetone 58 4.836 4.836 0.000 99 164609 6.00 5.42 25 Isopropyl alcohol 45 4.938 4.938 0.000 94 545409 6.00 6.05 24 Pentane 72 4.944 4.944 0.000 96 33044 2.00 2.30 26 Ethyl ether 31 5.079 5.079 0.000 92 158533 2.00 1.90 27 1,1-Dichloroethene 96 5.359 5.359 0.000 97 165768 2.00 2.25 28 Acrylonitrile 53 5.440 5.440 0.000 96 75734 2.00 2.13 29 2-Methyl-2-propanol 59 5.461 5.461 0.000 95 229289 2.00 2.11 30 1,1,2-Trichloro-1,2,2-trif 101 5.532 5.532 0.000 94 365502 2.00 2.34 31 Methylene Chloride 84 5.666 5.666 0.000 90 134673 2.00 1.97 32 3-Chloro-1-propene 39 5.683 5.683 0.000 94 157875 2.00 2.21 03/21/2017Page 333 of 377 Report Date: 10-Mar-2017 11:36:26 Chrom Revision: 2.2 05-Mar-2017 11:38:00 Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GCCVC10-LCS.d Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 33 Carbon disulfide 76 5.801 5.801 0.000 100 408738 2.00 2.08 34 trans-1,2-Dichloroethene 96 6.400 6.400 0.000 96 156647 2.00 2.09 35 2-Methylpentane 43 6.432 6.432 0.000 93 378422 2.00 2.54 36 Methyl tert-butyl ether 73 6.518 6.518 0.000 96 465949 2.00 2.38 37 1,1-Dichloroethane 63 6.783 6.783 0.000 100 319153 2.00 2.29 38 Vinyl acetate 43 6.885 6.885 0.000 100 390124 2.00 2.61 39 2-Butanone (MEK) 72 7.284 7.284 0.000 99 66822 2.00 2.12 40 Hexane 56 7.343 7.343 0.000 88 129385 2.00 2.26 41 Isopropyl ether 45 7.484 7.484 0.000 95 462987 2.00 2.31 42 cis-1,2-Dichloroethene 96 7.699 7.699 0.000 98 169047 2.00 2.16 43 Ethyl acetate 43 7.883 7.883 0.000 98 297666 2.00 2.44 44 Chloroform 83 8.028 8.028 0.000 96 424980 2.00 2.26 45 Tert-butyl ethyl ether 59 8.125 8.125 0.000 96 483346 2.00 2.59 46 Tetrahydrofuran 42 8.390 8.390 0.000 91 167033 2.00 2.43 47 1,1,1-Trichloroethane 97 9.004 9.004 0.000 95 477578 2.00 2.30 48 1,2-Dichloroethane 62 9.096 9.096 0.000 99 315424 2.00 2.41 49 Benzene 78 9.592 9.592 0.000 96 511711 2.00 2.22 50 Cyclohexane 69 9.597 9.597 0.000 87 88928 2.00 2.19 51 n-Butanol 31 9.608 9.608 0.000 70 65370 2.00 2.42 52 Carbon tetrachloride 117 9.619 9.619 0.000 97 523745 2.00 2.43 53 2,3-Dimethylpentane 71 9.748 9.748 0.000 90 113785 2.00 2.00 54 Thiophene 84 9.867 9.867 0.000 96 305806 2.00 2.31 55 Tert-amyl methyl ether 73 10.104 10.104 0.000 98 478660 2.00 2.47 56 Isooctane 57 10.422 10.422 0.000 97 814011 2.00 2.24 57 n-Heptane 71 10.821 10.821 0.000 91 190314 2.00 2.15 58 1,2-Dichloropropane 63 10.854 10.854 0.000 88 186373 2.00 2.19 59 Trichloroethene 130 10.908 10.908 0.000 95 272118 2.00 2.05 60 Dibromomethane 93 10.967 10.967 0.000 95 236523 2.00 2.18 61 Dichlorobromomethane 83 11.134 11.134 0.000 98 448339 2.00 2.36 62 1,4-Dioxane 88 11.150 11.150 0.000 95 63777 2.00 2.07 63 Methyl methacrylate 41 11.264 11.264 0.000 92 204332 2.00 2.47 64 Methylcyclohexane 83 11.711 11.711 0.000 95 323619 2.00 1.72 65 4-Methyl-2-pentanone (MIBK 43 12.137 12.137 0.000 96 288080 2.00 2.08 66 cis-1,3-Dichloropropene 75 12.180 12.180 0.000 96 347340 2.00 2.34 67 trans-1,3-Dichloropropene 75 12.903 12.903 0.000 97 343528 2.00 2.38 68 Toluene 91 13.027 13.027 0.000 93 605300 2.00 2.26 69 1,1,2-Trichloroethane 83 13.097 13.097 0.000 98 173494 2.00 2.13 70 2-Methylthiophene 97 13.178 13.178 0.000 98 540109 2.00 2.32 71 3-Methylthiophene 97 13.388 13.388 0.000 99 553596 2.00 2.40 72 2-Hexanone 58 13.518 13.518 0.000 93 138228 2.00 2.04 73 n-Octane 85 13.787 13.787 0.000 90 217215 2.00 2.21 74 Chlorodibromomethane 129 13.809 13.809 0.000 97 436836 2.00 2.42 75 Ethylene Dibromide 107 14.100 14.100 0.000 97 363011 2.00 2.23 76 Tetrachloroethene 129 14.203 14.203 0.000 94 262625 2.00 2.23 77 Chlorobenzene 112 15.087 15.087 0.000 92 520253 2.00 2.22 78 2,3-Dimethylheptane 43 15.157 15.157 0.000 93 566689 2.00 2.37 79 Ethylbenzene 91 15.394 15.394 0.000 99 813912 2.00 2.32 80 2-Ethylthiophene 97 15.497 15.497 0.000 98 649445 2.00 2.29 81 m-Xylene & p-Xylene 91 15.567 15.567 0.000 99 1324027 4.00 4.81 82 Bromoform 173 15.982 15.982 0.000 95 414448 2.00 2.36 84 Styrene 104 16.031 16.031 0.000 97 468394 2.00 2.40 83 n-Nonane 57 16.036 16.036 0.000 87 400835 2.00 2.27 03/21/2017Page 334 of 377 Report Date: 10-Mar-2017 11:36:26 Chrom Revision: 2.2 05-Mar-2017 11:38:00 Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GCCVC10-LCS.d Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response Cal Amt ppb v/v OnCol Amt ppb v/v Flags 85 o-Xylene 91 16.090 16.090 0.000 98 661156 2.00 2.34 86 1,1,2,2-Tetrachloroethane 83 16.413 16.413 0.000 98 443220 2.00 2.39 87 1,2,3-Trichloropropane 110 16.570 16.570 0.000 97 151664 2.00 2.40 88 Isopropylbenzene 105 16.694 16.694 0.000 97 969348 2.00 2.36 89 N-Propylbenzene 120 17.249 17.249 0.000 99 258398 2.00 2.36 90 2-Chlorotoluene 126 17.282 17.282 0.000 97 243807 2.00 2.31 91 4-Ethyltoluene 105 17.411 17.411 0.000 98 875761 2.00 2.26 92 1,3,5-Trimethylbenzene 120 17.497 17.497 0.000 92 435900 2.00 2.41 93 Alpha Methyl Styrene 118 17.740 17.740 0.000 87 362059 2.00 2.39 94 n-Decane 57 17.842 17.842 0.000 93 527128 2.00 2.45 95 tert-Butylbenzene 119 17.945 17.945 0.000 92 900836 2.00 2.45 96 1,2,4-Trimethylbenzene 105 17.956 17.956 0.000 96 822756 2.00 2.45 97 1,3-Dichlorobenzene 146 18.225 18.225 0.000 98 621147 2.00 2.26 98 sec-Butylbenzene 105 18.231 18.231 0.000 98 1181468 2.00 2.45 99 Benzyl chloride 91 18.306 18.306 0.000 98 802616 2.00 2.63 100 1,4-Dichlorobenzene 146 18.317 18.317 0.000 95 603053 2.00 2.22 101 4-Isopropyltoluene 119 18.403 18.403 0.000 97 1021977 2.00 2.44 102 1,2,3-Trimethylbenzene 105 18.446 18.446 0.000 98 662638 2.00 2.65 103 Butylcyclohexane 83 18.522 18.522 0.000 94 663866 2.00 2.28 104 1,2-Dichlorobenzene 146 18.694 18.694 0.000 94 581531 2.00 2.27 105 2,3-Dihydroindene 117 18.700 18.700 0.000 93 705526 2.00 2.24 106 Indene 116 18.829 18.829 0.000 91 688445 2.00 2.99 107 n-Butylbenzene 91 18.856 18.856 0.000 98 974727 2.00 2.52 108 Undecane 57 19.212 19.212 0.000 93 586142 2.00 2.54 109 1,2-Dimethyl-4-Ethylbenzen 119 19.244 19.244 0.000 97 944707 2.00 3.08 110 1,2-Dibromo-3-Chloropropan 157 19.314 19.314 0.000 96 213219 2.00 2.10 111 1,2,4,5-Tetramethylbenzene 119 19.638 19.638 0.000 96 1004245 2.00 2.69 112 1,2,3,5-Tetramethylbenzene 119 19.692 19.692 0.000 94 613908 2.00 2.76 113 1,2,3,4-Tetramethylbenzene 119 20.086 20.086 0.000 96 791749 2.00 2.58 114 Dodecane 57 20.285 20.285 0.000 93 566404 2.00 2.66 115 1,2,4-Trichlorobenzene 180 20.420 20.420 0.000 94 516115 2.00 2.32 116 Naphthalene 128 20.549 20.549 0.000 99 1055986 2.00 2.27 117 Benzo(b)thiophene 134 20.646 20.646 0.000 99 644261 2.00 2.50 118 Hexachlorobutadiene 225 20.781 20.781 0.000 95 537171 2.00 2.47 119 1,2,3-Trichlorobenzene 180 20.830 20.830 0.000 95 495900 2.00 2.45 120 2-Methylnaphthalene 142 21.622 21.622 0.000 100 788822 6.25 8.33 121 1-Methylnaphthalene 142 21.806 21.806 0.000 100 759671 6.25 9.96 A 124 Toluene Range 1 13.022 (12.987-13.057) 0 1518574 2.00 2.31 A 125 C8 Range 1 13.792 (13.777-13.807) 0 3428644 2.00 2.96 S 126 Xylenes, Total 100 0 6.00 7.15 S 127 1,2-Dichloroethene, Total 1 0 4.00 4.25 Reagents: 40CV101S_00031 Amount Added: 100.00 Units: mL 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 335 of 377 Report Date: 10-Mar-2017 11:36:26 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Laboratories Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GCCVC10-LCS.d Injection Date:10-Mar-2017 08:21:30 Instrument ID:MG Operator ID:7126 Lims ID:LCS Worklist Smp#:1002 Client ID: Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:15 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 Y ( X10 0 0 0 0 ) GCCVC10-LCS[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 0 0 7 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 6 9)* C h l o r o b e n zen e - d 5 (IS )( 1 5 . 0 3 8 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 7 1 0 ) 03/21/2017Page 336 of 377 Report Date: 10-Mar-2017 11:36:26 Chrom Revision: 2.2 05-Mar-2017 11:38:00 TestAmerica Laboratories Recovery Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\GCCVC10-LCS.d Lims ID:LCS Client ID: Sample Type:LCS Inject. Date:10-Mar-2017 08:21:30 ALS Bottle#:15 Worklist Smp#:1002 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004228-002 Misc. Info.:S31 Operator ID:7126 Instrument ID:MG Method:\\ChromNA\Knoxville\ChromData\MG\20170306-4228.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:10-Mar-2017 11:36:23 Calib Date:02-Mar-2017 20:31:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20170302-4202.b\GC02IC02R.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:10-Mar-2017 11:36:23 Compound Amount Added Amount Recovered %Rec. $4 4-Bromofluorobenzene (Surr)4.00 4.27 106.81 03/21/2017Page 337 of 377 Lab Name:Job No.: SDG No.: Instrument ID: Analysis Batch Number: AIR - GC/MS VOA ANALYSIS RUN LOG DILUTION FACTOR COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID TestAmerica Knoxville 140-7345-1 MR 8740 Start Date: End Date:02/24/2017 09:49 02/23/2017 21:41 BFB 140-8740/1 RTX-5 0.32(mm)102/23/2017 21:41 RXBFBB23.D IC 140-8740/3 RTX-5 0.32(mm)102/23/2017 22:59 RB23IC01.D 140-7244-A-2 MDLV RTX-5 0.32(mm)102/23/2017 22:59 IC 140-8740/4 RTX-5 0.32(mm)102/23/2017 23:47 RB23IC02.D 140-7244-A-3 MDLV RTX-5 0.32(mm)102/23/2017 23:47 IC 140-8740/5 RTX-5 0.32(mm)102/24/2017 00:35 RB23IC03.D 140-7244-A-4 MDLV RTX-5 0.32(mm)102/24/2017 00:35 IC 140-8740/6 RTX-5 0.32(mm)102/24/2017 01:23 RB23IC04.D 140-7244-A-5 MDLV RTX-5 0.32(mm)102/24/2017 01:23 IC 140-8740/7 RTX-5 0.32(mm)102/24/2017 02:09 RB23IC05.D 140-7244-A-6 MDLV RTX-5 0.32(mm)102/24/2017 02:09 ICIS 140-8740/8 RTX-5 0.32(mm)102/24/2017 02:57 RB23IC06.D IC 140-8740/9 RTX-5 0.32(mm)102/24/2017 03:45 RB23IC07.D IC 140-8740/10 RTX-5 0.32(mm)102/24/2017 04:33 RB23IC08.D IC 140-8740/11 RTX-5 0.32(mm)102/24/2017 05:21 RB23IC09.D ZZZZZ RTX-5 0.32(mm)102/24/2017 08:16 140-7244-A-1 MDLV RTX-5 0.32(mm)102/24/2017 09:02 ICV 140-8740/17 RTX-5 0.32(mm)102/24/2017 09:49 RB23LCS.D TO 15 LL 03/21/2017Page 338 of 377 03/21/2017Page 339 of 377 Lab Name:Job No.: SDG No.: Instrument ID: Analysis Batch Number: AIR - GC/MS VOA ANALYSIS RUN LOG DILUTION FACTOR COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID TestAmerica Knoxville 140-7345-1 MG 9079 Start Date: End Date:03/03/2017 00:46 03/02/2017 12:22 BFB 140-9079/1 RTX-5 0.32(mm)103/02/2017 12:22 GBFBC02.D IC 140-9079/3 RTX-5 0.32(mm)103/02/2017 13:34 GC02IC01.D 140-7243-A-1 MDLV RTX-5 0.32(mm)103/02/2017 13:34 IC 140-9079/5 RTX-5 0.32(mm)103/02/2017 14:57 GC02IC03.D 140-7243-A-3 MDLV RTX-5 0.32(mm)103/02/2017 14:57 IC 140-9079/6 RTX-5 0.32(mm)103/02/2017 15:39 GC02IC04.D 140-7243-A-4 MDLV RTX-5 0.32(mm)103/02/2017 15:39 IC 140-9079/7 RTX-5 0.32(mm)103/02/2017 16:20 GC02IC05.D 140-7243-A-5 MDLV RTX-5 0.32(mm)103/02/2017 16:20 ICIS 140-9079/8 RTX-5 0.32(mm)103/02/2017 17:02 GC02IC06.D IC 140-9079/9 RTX-5 0.32(mm)103/02/2017 17:44 GC02IC07.D IC 140-9079/10 RTX-5 0.32(mm)103/02/2017 18:26 GC02IC08.D IC 140-9079/11 RTX-5 0.32(mm)103/02/2017 19:08 GC02IC09.D IC 140-9079/20 RTX-5 0.32(mm)103/02/2017 20:31 GC02IC02R.D 140-7243-A-2 MDLV RTX-5 0.32(mm)103/02/2017 20:31 ICV 140-9079/15 RTX-5 0.32(mm)103/02/2017 23:17 GLCSC02.D ZZZZZ RTX-5 0.32(mm)103/03/2017 00:46 TO 15 LL 03/21/2017Page 340 of 377 03/21/2017Page 341 of 377 03/21/2017Page 342 of 377 Lab Name:Job No.: SDG No.: Instrument ID: Analysis Batch Number: AIR - GC/MS VOA ANALYSIS RUN LOG DILUTION FACTOR COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID TestAmerica Knoxville 140-7345-1 MR 9156 Start Date: End Date:03/10/2017 04:24 03/09/2017 09:10 BFB 140-9156/1 RTX-5 0.32(mm)103/09/2017 09:10 RC09BFB.D CCVIS 140-9156/2 RTX-5 0.32(mm)103/09/2017 09:42 RC09CCV.D LCS 140-9156/1002 RTX-5 0.32(mm)103/09/2017 09:42 RC09CCV-LCS.d MB 140-9156/4 RTX-5 0.32(mm)103/09/2017 12:38 RC09BLK.D ZZZZZ RTX-5 0.32(mm)103/09/2017 14:18 ZZZZZ RTX-5 0.32(mm)103/09/2017 15:11 ZZZZZ RTX-5 0.32(mm)103/09/2017 15:59 ZZZZZ RTX-5 0.32(mm)103/09/2017 16:47 ZZZZZ RTX-5 0.32(mm)1.2703/09/2017 17:35 ZZZZZ RTX-5 0.32(mm)1.2903/09/2017 18:21 ZZZZZ RTX-5 0.32(mm)1.203/09/2017 19:14 140-7345-1 RTX-5 0.32(mm)103/09/2017 20:00 RC09P107.D 140-7345-2 RTX-5 0.32(mm)103/09/2017 20:48 RC09P108.D 140-7345-3 RTX-5 0.32(mm)103/09/2017 21:35 RC09P109.D 140-7345-4 RTX-5 0.32(mm)103/09/2017 22:28 RC09P110.D ZZZZZ RTX-5 0.32(mm)103/09/2017 23:21 ZZZZZ RTX-5 0.32(mm)103/10/2017 01:45 ZZZZZ RTX-5 0.32(mm)103/10/2017 02:38 ZZZZZ RTX-5 0.32(mm)103/10/2017 03:31 ZZZZZ RTX-5 0.32(mm)103/10/2017 04:24 TO 15 LL 03/21/2017Page 343 of 377 03/21/2017Page 344 of 377 03/21/2017Page 345 of 377 Lab Name:Job No.: SDG No.: Instrument ID: Analysis Batch Number: AIR - GC/MS VOA ANALYSIS RUN LOG DILUTION FACTOR COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID TestAmerica Knoxville 140-7345-1 MG 9158 Start Date: End Date:03/10/2017 23:33 03/10/2017 07:50 BFB 140-9158/1 RTX-5 0.32(mm)103/10/2017 07:50 GBFBC10.D CCVIS 140-9158/2 RTX-5 0.32(mm)103/10/2017 08:21 GCCVC10.D LCS 140-9158/1002 RTX-5 0.32(mm)103/10/2017 08:21 GCCVC10-LCS.d MB 140-9158/4 RTX-5 0.32(mm)103/10/2017 10:04 GMB500C10.D ZZZZZ RTX-5 0.32(mm)5059.0 6 03/10/2017 10:46 ZZZZZ RTX-5 0.32(mm)4.903/10/2017 12:46 ZZZZZ RTX-5 0.32(mm)1.203/10/2017 13:28 140-7345-2 DL RTX-5 0.32(mm)103/10/2017 14:09 GC10P104.D 140-7345-3 DL RTX-5 0.32(mm)103/10/2017 14:51 GC10P105.D ZZZZZ RTX-5 0.32(mm)103/10/2017 15:34 ZZZZZ RTX-5 0.32(mm)103/10/2017 16:15 ZZZZZ RTX-5 0.32(mm)103/10/2017 16:58 ZZZZZ RTX-5 0.32(mm)103/10/2017 17:41 ZZZZZ RTX-5 0.32(mm)103/10/2017 18:24 ZZZZZ RTX-5 0.32(mm)103/10/2017 19:07 ZZZZZ RTX-5 0.32(mm)103/10/2017 19:52 ZZZZZ RTX-5 0.32(mm)103/10/2017 20:38 ZZZZZ RTX-5 0.32(mm)103/10/2017 22:07 ZZZZZ RTX-5 0.32(mm)103/10/2017 22:48 ZZZZZ RTX-5 0.32(mm)103/10/2017 23:33 TO 15 LL 03/21/2017Page 346 of 377 03/21/2017Page 347 of 377 03/21/2017Page 348 of 377 03/21/2017Page 349 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 09991 SDG No.: 140-7008-1 Lab Sample ID:140-7008-2 TestAmerica Knoxville Matrix:LOT7008.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/07/2017 11:45 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/09/2017 04:11 ID:RTX-5 Analysis Batch No.:8364 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.08071-43-2 Benzene ND 0.16100-44-7 Benzyl chloride ND 0.08074-83-9 Bromomethane ND 0.04056-23-5 Carbon tetrachloride ND 0.080108-90-7 Chlorobenzene ND 0.08075-00-3 Chloroethane ND 0.4087-61-6 1,2,3-Trichlorobenzene ND 0.08067-66-3 Chloroform ND 0.2096-18-4 1,2,3-Trichloropropane ND 0.2074-87-3 Chloromethane ND 0.08095-50-1 1,2-Dichlorobenzene ND 0.080541-73-1 1,3-Dichlorobenzene ND 0.080106-46-7 1,4-Dichlorobenzene ND 0.08075-71-8 Dichlorodifluoromethane ND 0.08075-34-3 1,1-Dichloroethane ND 0.080107-06-2 1,2-Dichloroethane ND 0.08075-35-4 1,1-Dichloroethene ND 0.080156-59-2 cis-1,2-Dichloroethene ND 0.08078-87-5 1,2-Dichloropropane ND 0.20123-91-1 1,4-Dioxane ND 0.3278-93-3 2-Butanone ND 0.08010061-01-5 cis-1,3-Dichloropropene ND 0.1695-49-8 2-Chlorotoluene ND 0.08010061-02-6 trans-1,3-Dichloropropene ND 0.08076-14-2 1,2-Dichlorotetrafluoroethane ND 0.20591-78-6 2-Hexanone ND 0.080107-05-1 3-Chloroprene ND 0.080100-41-4 Ethylbenzene ND 0.16622-96-8 4-Ethyltoluene ND 0.08075-69-4 Trichlorofluoromethane ND 0.20108-10-1 4-Methyl-2-pentanone (MIBK)ND 0.08087-68-3 Hexachlorobutadiene ND 2.067-64-1 Acetone ND 0.2075-09-2 Methylene Chloride ND 0.4075-05-8 Acetonitrile ND 0.080100-42-5 Styrene ND FORM I TO 15 LL 03/21/2017Page 350 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 09991 SDG No.: 140-7008-1 Lab Sample ID:140-7008-2 TestAmerica Knoxville Matrix:LOT7008.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/07/2017 11:45 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/09/2017 04:11 ID:RTX-5 Analysis Batch No.:8364 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.08079-34-5 1,1,2,2-Tetrachloroethane ND 0.16107-02-8 Acrolein ND 0.80107-13-1 Acrylonitrile ND 0.040127-18-4 Tetrachloroethene ND 0.1698-83-9 Alpha Methyl Styrene ND 0.12108-88-3 Toluene ND 0.080120-82-1 1,2,4-Trichlorobenzene ND 0.08071-55-6 1,1,1-Trichloroethane ND 0.08075-27-4 Bromodichloromethane ND 0.08079-00-5 1,1,2-Trichloroethane ND 0.08075-25-2 Bromoform ND 0.04079-01-6 Trichloroethene ND 0.08076-13-1 1,1,2-Trichlorotrifluoroethane ND 0.08095-63-6 1,2,4-Trimethylbenzene ND 0.16106-97-8 Butane ND 0.080108-67-8 1,3,5-Trimethylbenzene ND 0.2075-15-0 Carbon disulfide ND 0.04075-01-4 Vinyl chloride ND 0.08095-47-6 o-Xylene ND 0.08075-45-6 Chlorodifluoromethane ND 0.080179601-23-1 m-Xylene & p-Xylene ND 0.080106-93-4 1,2-Dibromoethane ND 0.20110-82-7 Cyclohexane ND 0.40124-18-5 n-Decane ND 0.080124-48-1 Dibromochloromethane ND 0.1674-95-3 Dibromomethane ND 0.40112-40-3 n-Dodecane ND 2.064-17-5 Ethanol ND 0.80141-78-6 Ethyl acetate ND 0.8060-29-7 Ethyl ether ND 0.20142-82-5 n-Heptane ND 0.20110-54-3 Hexane ND 0.8067-63-0 Isopropyl alcohol ND 0.2080-62-6 Methyl methacrylate ND 0.161634-04-4 Methyl tert-butyl ether ND 0.2091-20-3 Naphthalene ND FORM I TO 15 LL 03/21/2017Page 351 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 09991 SDG No.: 140-7008-1 Lab Sample ID:140-7008-2 TestAmerica Knoxville Matrix:LOT7008.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/07/2017 11:45 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/09/2017 04:11 ID:RTX-5 Analysis Batch No.:8364 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.16104-51-8 n-Butylbenzene ND 0.16103-65-1 N-Propylbenzene ND 0.16111-65-9 n-Octane ND 0.40109-66-0 Pentane ND 0.20115-07-1 Propene ND 0.16135-98-8 sec-Butylbenzene ND 0.2098-06-6 tert-Butylbenzene ND 0.40109-99-9 Tetrahydrofuran ND 0.080156-60-5 trans-1,2-Dichloroethene ND 0.401120-21-4 Undecane ND 0.40108-05-4 Vinyl acetate ND 0.080593-60-2 Vinyl bromide ND 0.080488-23-3 1,2,3,4-Tetramethylbenzene ND 0.080527-53-7 1,2,3,5-Tetramethylbenzene ND 0.08095-93-2 1,2,4,5-Tetramethylbenzene ND 0.080934-80-5 1,2-Dimethyl-4-Ethylbenzene ND 1.090-12-0 1-Methylnaphthalene ND 0.0803074-71-3 2,3-Dimethylheptane ND 0.080872-55-9 2-Ethylthiophene ND 0.080554-14-3 2-Methylthiophene ND 1.091-57-6 2-Methylnaphthalene ND 0.080616-44-4 3-Methylthiophene ND 0.1695-15-8 Benzo(b)thiophene ND 0.080110-02-1 Thiophene ND 0.0801678-93-9 Butylcyclohexane ND 0.080526-73-8 1,2,3-Trimethylbenzene ND 0.16106-99-0 1,3-Butadine ND 0.20540-84-1 2,2,4-Trimethylpentane ND 0.8071-36-3 1-Butanol ND 0.080565-59-3 2,3-Dimethylpentane ND 0.2078-78-4 2-Methylbutane ND 0.080107-83-5 2-Methylpentane ND 4.075-07-0 Acetaldehyde ND 0.1698-82-8 Cumene ND 0.080496-11-7 Indane ND 0.1695-13-6 Indene ND FORM I TO 15 LL 03/21/2017Page 352 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 09991 SDG No.: 140-7008-1 Lab Sample ID:140-7008-2 TestAmerica Knoxville Matrix:LOT7008.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/07/2017 11:45 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/09/2017 04:11 ID:RTX-5 Analysis Batch No.:8364 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.08099-87-6 p-Cymene ND 0.3275-65-0 tert-Butanol ND 0.080108-87-2 Methylcyclohexane ND 0.20111-84-2 n-Nonane ND FORM I TO 15 LL 03/21/2017Page 353 of 377 Report Date: 09-Feb-2017 09:25:59 Chrom Revision: 2.2 03-Feb-2017 15:35:04 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MG\20170207-3995.b\LOT7008.D Lims ID:140-7008-A-2 Client ID:09991 Sample Type:Client Inject. Date:09-Feb-2017 04:11:30 ALS Bottle#:16 Worklist Smp#:27 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0003995-027 Misc. Info.:09991 Operator ID:7126 Instrument ID:MG Method:\\ChromNA\Knoxville\ChromData\MG\20170207-3995.b\MG_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:09-Feb-2017 09:25:26 Calib Date:09-Dec-2016 12:54:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MG\20161205-3696.b\GxL08EthOxICL05.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK006 First Level Reviewer: tajh Date:09-Feb-2017 09:25:26 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.007 8.017 -0.010 93 308716 4.00 * 2 1,4-Difluorobenzene 114 10.175 10.185 -0.010 95 1352835 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.044 15.049 -0.005 87 1463352 4.00 $ 4 4-Bromofluorobenzene (Surr 95 16.721 16.721 0.000 96 943275 3.90 31 Methylene Chloride 84 5.677 5.677 0.000 94 5913 0.0900 47 1,1,1-Trichloroethane 97 9.021 9.015 0.006 92 3685 0.0174 51 n-Butanol 31 9.705 9.614 0.091 91 1780 0.0602 65 4-Methyl-2-pentanone (MIBK 43 12.175 12.148 0.027 98 9267 0.0560 Reagents: 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 354 of 377 Report Date: 09-Feb-2017 09:25:59 Chrom Revision: 2.2 03-Feb-2017 15:35:04 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MG\20170207-3995.b\LOT7008.D Injection Date:09-Feb-2017 04:11:30 Instrument ID:MG Operator ID:7126 Lims ID:140-7008-A-2 Lab Sample ID:140-7008-2 Worklist Smp#:27 Client ID:09991 Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:16 Method:MG_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 27.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Y ( X10 0 0 0 0 ) LOT7008[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 0 0 7 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 1 7 5 )+ * C h l o r o b e n zen e - d5 (IS )( 1 5 . 0 4 4 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 6 . 7 2 1 ) 03/21/2017Page 355 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 10882 SDG No.: 140-7128-1 Lab Sample ID:140-7128-11 TestAmerica Knoxville Matrix:LOT7128.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/16/2017 13:55 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/19/2017 22:46 ID:RTX-5 Analysis Batch No.:8662 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.08071-43-2 Benzene ND 0.16100-44-7 Benzyl chloride ND 0.08074-83-9 Bromomethane ND 0.04056-23-5 Carbon tetrachloride ND 0.080108-90-7 Chlorobenzene ND 0.08075-00-3 Chloroethane ND 0.4087-61-6 1,2,3-Trichlorobenzene ND 0.08067-66-3 Chloroform ND 0.2096-18-4 1,2,3-Trichloropropane ND 0.2074-87-3 Chloromethane ND 0.08095-50-1 1,2-Dichlorobenzene ND 0.080541-73-1 1,3-Dichlorobenzene ND 0.080106-46-7 1,4-Dichlorobenzene ND 0.08075-71-8 Dichlorodifluoromethane ND 0.08075-34-3 1,1-Dichloroethane ND 0.080107-06-2 1,2-Dichloroethane ND 0.08075-35-4 1,1-Dichloroethene ND 0.080156-59-2 cis-1,2-Dichloroethene ND 0.08078-87-5 1,2-Dichloropropane ND 0.20123-91-1 1,4-Dioxane ND 0.3278-93-3 2-Butanone ND 0.08010061-01-5 cis-1,3-Dichloropropene ND 0.1695-49-8 2-Chlorotoluene ND 0.08010061-02-6 trans-1,3-Dichloropropene ND 0.08076-14-2 1,2-Dichlorotetrafluoroethane ND 0.20591-78-6 2-Hexanone ND 0.080107-05-1 3-Chloroprene ND 0.080100-41-4 Ethylbenzene ND 0.16622-96-8 4-Ethyltoluene ND 0.08075-69-4 Trichlorofluoromethane ND 0.20108-10-1 4-Methyl-2-pentanone (MIBK)ND 0.08087-68-3 Hexachlorobutadiene ND 2.067-64-1 Acetone ND 0.2075-09-2 Methylene Chloride ND 0.4075-05-8 Acetonitrile ND 0.080100-42-5 Styrene ND FORM I TO 15 LL 03/21/2017Page 356 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 10882 SDG No.: 140-7128-1 Lab Sample ID:140-7128-11 TestAmerica Knoxville Matrix:LOT7128.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/16/2017 13:55 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/19/2017 22:46 ID:RTX-5 Analysis Batch No.:8662 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.08079-34-5 1,1,2,2-Tetrachloroethane ND 0.16107-02-8 Acrolein ND 0.80107-13-1 Acrylonitrile ND 0.040127-18-4 Tetrachloroethene ND 0.1698-83-9 Alpha Methyl Styrene ND 0.12108-88-3 Toluene ND 0.080120-82-1 1,2,4-Trichlorobenzene ND 0.08071-55-6 1,1,1-Trichloroethane ND 0.08075-27-4 Bromodichloromethane ND 0.08079-00-5 1,1,2-Trichloroethane ND 0.08075-25-2 Bromoform ND 0.04079-01-6 Trichloroethene ND 0.08076-13-1 1,1,2-Trichlorotrifluoroethane ND 0.08095-63-6 1,2,4-Trimethylbenzene ND 0.16106-97-8 Butane ND 0.080108-67-8 1,3,5-Trimethylbenzene ND 0.2075-15-0 Carbon disulfide ND 0.04075-01-4 Vinyl chloride ND 0.08095-47-6 o-Xylene ND 0.08075-45-6 Chlorodifluoromethane ND 0.080179601-23-1 m-Xylene & p-Xylene ND 0.080106-93-4 1,2-Dibromoethane ND 0.20110-82-7 Cyclohexane ND 0.40124-18-5 n-Decane ND 0.080124-48-1 Dibromochloromethane ND 0.1674-95-3 Dibromomethane ND 0.40112-40-3 n-Dodecane ND 2.064-17-5 Ethanol ND 0.80141-78-6 Ethyl acetate ND 0.8060-29-7 Ethyl ether ND 0.20142-82-5 n-Heptane ND 0.20110-54-3 Hexane ND 0.8067-63-0 Isopropyl alcohol ND 0.2080-62-6 Methyl methacrylate ND 0.161634-04-4 Methyl tert-butyl ether ND 0.2091-20-3 Naphthalene ND FORM I TO 15 LL 03/21/2017Page 357 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 10882 SDG No.: 140-7128-1 Lab Sample ID:140-7128-11 TestAmerica Knoxville Matrix:LOT7128.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/16/2017 13:55 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/19/2017 22:46 ID:RTX-5 Analysis Batch No.:8662 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.16104-51-8 n-Butylbenzene ND 0.16103-65-1 N-Propylbenzene ND 0.16111-65-9 n-Octane ND 0.40109-66-0 Pentane ND 0.20115-07-1 Propene ND 0.16135-98-8 sec-Butylbenzene ND 0.2098-06-6 tert-Butylbenzene ND 0.40109-99-9 Tetrahydrofuran ND 0.080156-60-5 trans-1,2-Dichloroethene ND 0.401120-21-4 Undecane ND 0.40108-05-4 Vinyl acetate ND 0.080593-60-2 Vinyl bromide ND 0.080488-23-3 1,2,3,4-Tetramethylbenzene ND 0.080527-53-7 1,2,3,5-Tetramethylbenzene ND 0.08095-93-2 1,2,4,5-Tetramethylbenzene ND 0.080934-80-5 1,2-Dimethyl-4-Ethylbenzene ND 1.090-12-0 1-Methylnaphthalene ND 0.0803074-71-3 2,3-Dimethylheptane ND 0.080872-55-9 2-Ethylthiophene ND 0.080554-14-3 2-Methylthiophene ND 1.091-57-6 2-Methylnaphthalene ND 0.080616-44-4 3-Methylthiophene ND 0.1695-15-8 Benzo(b)thiophene ND 0.080110-02-1 Thiophene ND 0.0801678-93-9 Butylcyclohexane ND 0.080526-73-8 1,2,3-Trimethylbenzene ND 0.16106-99-0 1,3-Butadine ND 0.20540-84-1 2,2,4-Trimethylpentane ND 0.8071-36-3 1-Butanol ND 0.080565-59-3 2,3-Dimethylpentane ND 0.2078-78-4 2-Methylbutane ND 0.080107-83-5 2-Methylpentane ND 4.075-07-0 Acetaldehyde ND 0.1698-82-8 Cumene ND 0.080496-11-7 Indane ND 0.1695-13-6 Indene ND FORM I TO 15 LL 03/21/2017Page 358 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 10882 SDG No.: 140-7128-1 Lab Sample ID:140-7128-11 TestAmerica Knoxville Matrix:LOT7128.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/16/2017 13:55 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/19/2017 22:46 ID:RTX-5 Analysis Batch No.:8662 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.08099-87-6 p-Cymene ND 0.3275-65-0 tert-Butanol ND 0.080108-87-2 Methylcyclohexane ND 0.20111-84-2 n-Nonane ND FORM I TO 15 LL 03/21/2017Page 359 of 377 Report Date: 20-Feb-2017 08:33:21 Chrom Revision: 2.2 03-Feb-2017 15:35:04 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MJ\20170215-4071.b\LOT7128.D Lims ID:140-7128-A-11 Client ID:10882 Sample Type:Client Inject. Date:19-Feb-2017 22:46:30 ALS Bottle#:13 Worklist Smp#:18 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004071-018 Misc. Info.:10882 Operator ID:7126 Instrument ID:MJ Method:\\ChromNA\Knoxville\ChromData\MJ\20170215-4071.b\MJ_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:20-Feb-2017 08:32:32 Calib Date:26-Nov-2016 01:58:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MJ\20161121-3656.b\JK25IC09X.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK020 First Level Reviewer: tajh Date:20-Feb-2017 08:14:52 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.574 8.581 -0.007 99 382274 4.00 * 2 1,4-Difluorobenzene 114 10.774 10.781 -0.007 94 1739525 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.551 15.552 -0.001 87 1488757 4.00 $ 4 4-Bromofluorobenzene (Surr 95 17.197 17.199 -0.002 95 855585 3.63 11 Acetaldehyde 44 3.942 3.944 -0.002 98 57625 1.21 23 Acetone 58 5.168 5.159 0.009 97 26471 0.6684 24 Isopropyl alcohol 45 5.254 5.235 0.019 93 12553 0.0681 31 Methylene Chloride 84 6.056 6.063 -0.007 97 7741 0.0687 33 Carbon disulfide 76 6.223 6.224 -0.001 95 4389 0.0129 Reagents: 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 360 of 377 Report Date: 20-Feb-2017 08:33:21 Chrom Revision: 2.2 03-Feb-2017 15:35:04 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MJ\20170215-4071.b\LOT7128.D Injection Date:19-Feb-2017 22:46:30 Instrument ID:MJ Operator ID:7126 Lims ID:140-7128-A-11 Lab Sample ID:140-7128-11 Worklist Smp#:18 Client ID:10882 Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:13 Method:MJ_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Y ( X10 0 0 0 0 ) LOT7128[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 5 7 4 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 7 7 4 )+ * C h l o r o b e n zen e - d5 (IS )( 1 5 . 5 5 1 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 7 . 1 9 7 ) 03/21/2017Page 361 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 09869 SDG No.: 140-7150-1 Lab Sample ID:140-7150-5 TestAmerica Knoxville Matrix:LOT7150.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/17/2017 14:40 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/20/2017 01:53 ID:RTX-5 Analysis Batch No.:8662 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.08071-43-2 Benzene ND 0.16100-44-7 Benzyl chloride ND 0.08074-83-9 Bromomethane ND 0.04056-23-5 Carbon tetrachloride ND 0.080108-90-7 Chlorobenzene ND 0.08075-00-3 Chloroethane ND 0.4087-61-6 1,2,3-Trichlorobenzene ND 0.08067-66-3 Chloroform ND 0.2096-18-4 1,2,3-Trichloropropane ND 0.2074-87-3 Chloromethane ND 0.08095-50-1 1,2-Dichlorobenzene ND 0.080541-73-1 1,3-Dichlorobenzene ND 0.080106-46-7 1,4-Dichlorobenzene ND 0.08075-71-8 Dichlorodifluoromethane ND 0.08075-34-3 1,1-Dichloroethane ND 0.080107-06-2 1,2-Dichloroethane ND 0.08075-35-4 1,1-Dichloroethene ND 0.080156-59-2 cis-1,2-Dichloroethene ND 0.08078-87-5 1,2-Dichloropropane ND 0.20123-91-1 1,4-Dioxane ND 0.3278-93-3 2-Butanone ND 0.08010061-01-5 cis-1,3-Dichloropropene ND 0.1695-49-8 2-Chlorotoluene ND 0.08010061-02-6 trans-1,3-Dichloropropene ND 0.08076-14-2 1,2-Dichlorotetrafluoroethane ND 0.20591-78-6 2-Hexanone ND 0.080107-05-1 3-Chloroprene ND 0.080100-41-4 Ethylbenzene ND 0.16622-96-8 4-Ethyltoluene ND 0.08075-69-4 Trichlorofluoromethane ND 0.20108-10-1 4-Methyl-2-pentanone (MIBK)ND 0.08087-68-3 Hexachlorobutadiene ND 2.067-64-1 Acetone ND 0.2075-09-2 Methylene Chloride ND 0.4075-05-8 Acetonitrile ND 0.080100-42-5 Styrene ND FORM I TO 15 LL 03/21/2017Page 362 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 09869 SDG No.: 140-7150-1 Lab Sample ID:140-7150-5 TestAmerica Knoxville Matrix:LOT7150.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/17/2017 14:40 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/20/2017 01:53 ID:RTX-5 Analysis Batch No.:8662 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.08079-34-5 1,1,2,2-Tetrachloroethane ND 0.16107-02-8 Acrolein ND 0.80107-13-1 Acrylonitrile ND 0.040127-18-4 Tetrachloroethene ND 0.1698-83-9 Alpha Methyl Styrene ND 0.12108-88-3 Toluene ND 0.080120-82-1 1,2,4-Trichlorobenzene ND 0.08071-55-6 1,1,1-Trichloroethane ND 0.08075-27-4 Bromodichloromethane ND 0.08079-00-5 1,1,2-Trichloroethane ND 0.08075-25-2 Bromoform ND 0.04079-01-6 Trichloroethene ND 0.08076-13-1 1,1,2-Trichlorotrifluoroethane ND 0.08095-63-6 1,2,4-Trimethylbenzene ND 0.16106-97-8 Butane ND 0.080108-67-8 1,3,5-Trimethylbenzene ND 0.2075-15-0 Carbon disulfide ND 0.04075-01-4 Vinyl chloride ND 0.08095-47-6 o-Xylene ND 0.08075-45-6 Chlorodifluoromethane ND 0.080179601-23-1 m-Xylene & p-Xylene ND 0.080106-93-4 1,2-Dibromoethane ND 0.20110-82-7 Cyclohexane ND 0.40124-18-5 n-Decane ND 0.080124-48-1 Dibromochloromethane ND 0.1674-95-3 Dibromomethane ND 0.40112-40-3 n-Dodecane ND 2.064-17-5 Ethanol ND 0.80141-78-6 Ethyl acetate ND 0.8060-29-7 Ethyl ether ND 0.20142-82-5 n-Heptane ND 0.20110-54-3 Hexane ND 0.8067-63-0 Isopropyl alcohol ND 0.2080-62-6 Methyl methacrylate ND 0.161634-04-4 Methyl tert-butyl ether ND 0.2091-20-3 Naphthalene ND FORM I TO 15 LL 03/21/2017Page 363 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 09869 SDG No.: 140-7150-1 Lab Sample ID:140-7150-5 TestAmerica Knoxville Matrix:LOT7150.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/17/2017 14:40 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/20/2017 01:53 ID:RTX-5 Analysis Batch No.:8662 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.16104-51-8 n-Butylbenzene ND 0.16103-65-1 N-Propylbenzene ND 0.16111-65-9 n-Octane ND 0.40109-66-0 Pentane ND 0.20115-07-1 Propene ND 0.16135-98-8 sec-Butylbenzene ND 0.2098-06-6 tert-Butylbenzene ND 0.40109-99-9 Tetrahydrofuran ND 0.080156-60-5 trans-1,2-Dichloroethene ND 0.401120-21-4 Undecane ND 0.40108-05-4 Vinyl acetate ND 0.080593-60-2 Vinyl bromide ND 0.080488-23-3 1,2,3,4-Tetramethylbenzene ND 0.080527-53-7 1,2,3,5-Tetramethylbenzene ND 0.08095-93-2 1,2,4,5-Tetramethylbenzene ND 0.080934-80-5 1,2-Dimethyl-4-Ethylbenzene ND 1.090-12-0 1-Methylnaphthalene ND 0.0803074-71-3 2,3-Dimethylheptane ND 0.080872-55-9 2-Ethylthiophene ND 0.080554-14-3 2-Methylthiophene ND 1.091-57-6 2-Methylnaphthalene ND 0.080616-44-4 3-Methylthiophene ND 0.1695-15-8 Benzo(b)thiophene ND 0.080110-02-1 Thiophene ND 0.0801678-93-9 Butylcyclohexane ND 0.080526-73-8 1,2,3-Trimethylbenzene ND 0.16106-99-0 1,3-Butadine ND 0.20540-84-1 2,2,4-Trimethylpentane ND 0.8071-36-3 1-Butanol ND 0.080565-59-3 2,3-Dimethylpentane ND 0.2078-78-4 2-Methylbutane ND 0.080107-83-5 2-Methylpentane ND 4.075-07-0 Acetaldehyde ND 0.1698-82-8 Cumene ND 0.080496-11-7 Indane ND 0.1695-13-6 Indene ND FORM I TO 15 LL 03/21/2017Page 364 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 09869 SDG No.: 140-7150-1 Lab Sample ID:140-7150-5 TestAmerica Knoxville Matrix:LOT7150.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/17/2017 14:40 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/20/2017 01:53 ID:RTX-5 Analysis Batch No.:8662 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.08099-87-6 p-Cymene ND 0.3275-65-0 tert-Butanol ND 0.080108-87-2 Methylcyclohexane ND 0.20111-84-2 n-Nonane ND FORM I TO 15 LL 03/21/2017Page 365 of 377 Report Date: 20-Feb-2017 08:33:29 Chrom Revision: 2.2 03-Feb-2017 15:35:04 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MJ\20170215-4071.b\LOT7150.D Lims ID:140-7150-A-5 Client ID:09869 Sample Type:Client Inject. Date:20-Feb-2017 01:53:30 ALS Bottle#:16 Worklist Smp#:22 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004071-022 Misc. Info.:09869 Operator ID:7126 Instrument ID:MJ Method:\\ChromNA\Knoxville\ChromData\MJ\20170215-4071.b\MJ_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:20-Feb-2017 08:32:32 Calib Date:26-Nov-2016 01:58:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MJ\20161121-3656.b\JK25IC09X.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK020 First Level Reviewer: tajh Date:20-Feb-2017 08:16:36 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.575 8.581 -0.006 98 385562 4.00 * 2 1,4-Difluorobenzene 114 10.770 10.781 -0.011 95 1549764 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.552 15.552 0.000 89 1324500 4.00 $ 4 4-Bromofluorobenzene (Surr 95 17.198 17.199 -0.001 95 769580 3.67 17 Ethanol 31 4.572 4.578 -0.006 94 39296 0.7719 21 Acrolein 56 5.051 5.046 0.005 84 3107 0.0831 24 Isopropyl alcohol 45 5.245 5.235 0.010 97 37777 0.2033 31 Methylene Chloride 84 6.063 6.063 0.000 95 7777 0.0684 49 n-Butanol 31 10.210 10.189 0.021 86 4289 0.0927 65 4-Methyl-2-pentanone (MIBK 43 12.712 12.701 0.011 96 10222 0.0479 Reagents: 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 366 of 377 Report Date: 20-Feb-2017 08:33:29 Chrom Revision: 2.2 03-Feb-2017 15:35:04 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MJ\20170215-4071.b\LOT7150.D Injection Date:20-Feb-2017 01:53:30 Instrument ID:MJ Operator ID:7126 Lims ID:140-7150-A-5 Lab Sample ID:140-7150-5 Worklist Smp#:22 Client ID:09869 Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:16 Method:MJ_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 Y ( X10 0 0 0 0 ) LOT7150[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 5 6 9 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 7 7 0 )+ * C h l o r o b e n zen e - d5 (IS )( 1 5 . 5 5 2 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 7 . 1 9 8 ) 03/21/2017Page 367 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 11059 SDG No.: 140-7194-1 Lab Sample ID:140-7194-12 TestAmerica Knoxville Matrix:LOT7194R.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/21/2017 17:20 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/23/2017 03:17 ID:RTX-5 Analysis Batch No.:8744 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.08071-43-2 Benzene ND 0.16100-44-7 Benzyl chloride ND 0.08074-83-9 Bromomethane ND 0.04056-23-5 Carbon tetrachloride ND 0.080108-90-7 Chlorobenzene ND 0.08075-00-3 Chloroethane ND 0.4087-61-6 1,2,3-Trichlorobenzene ND 0.08067-66-3 Chloroform ND 0.2096-18-4 1,2,3-Trichloropropane ND 0.2074-87-3 Chloromethane ND 0.08095-50-1 1,2-Dichlorobenzene ND 0.080541-73-1 1,3-Dichlorobenzene ND 0.080106-46-7 1,4-Dichlorobenzene ND 0.08075-71-8 Dichlorodifluoromethane ND 0.08075-34-3 1,1-Dichloroethane ND 0.080107-06-2 1,2-Dichloroethane ND 0.08075-35-4 1,1-Dichloroethene ND 0.080156-59-2 cis-1,2-Dichloroethene ND 0.08078-87-5 1,2-Dichloropropane ND 0.20123-91-1 1,4-Dioxane ND 0.3278-93-3 2-Butanone ND 0.08010061-01-5 cis-1,3-Dichloropropene ND 0.1695-49-8 2-Chlorotoluene ND 0.08010061-02-6 trans-1,3-Dichloropropene ND 0.08076-14-2 1,2-Dichlorotetrafluoroethane ND 0.20591-78-6 2-Hexanone ND 0.080107-05-1 3-Chloroprene ND 0.080100-41-4 Ethylbenzene ND 0.16622-96-8 4-Ethyltoluene ND 0.08075-69-4 Trichlorofluoromethane ND 0.20108-10-1 4-Methyl-2-pentanone (MIBK)ND 0.08087-68-3 Hexachlorobutadiene ND 2.067-64-1 Acetone ND 0.2075-09-2 Methylene Chloride ND 0.4075-05-8 Acetonitrile ND 0.080100-42-5 Styrene ND FORM I TO 15 LL 03/21/2017Page 368 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 11059 SDG No.: 140-7194-1 Lab Sample ID:140-7194-12 TestAmerica Knoxville Matrix:LOT7194R.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/21/2017 17:20 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/23/2017 03:17 ID:RTX-5 Analysis Batch No.:8744 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.08079-34-5 1,1,2,2-Tetrachloroethane ND 0.16107-02-8 Acrolein ND 0.80107-13-1 Acrylonitrile ND 0.040127-18-4 Tetrachloroethene ND 0.1698-83-9 Alpha Methyl Styrene ND 0.12108-88-3 Toluene ND 0.080120-82-1 1,2,4-Trichlorobenzene ND 0.08071-55-6 1,1,1-Trichloroethane ND 0.08075-27-4 Bromodichloromethane ND 0.08079-00-5 1,1,2-Trichloroethane ND 0.08075-25-2 Bromoform ND 0.04079-01-6 Trichloroethene ND 0.08076-13-1 1,1,2-Trichlorotrifluoroethane ND 0.08095-63-6 1,2,4-Trimethylbenzene ND 0.16106-97-8 Butane ND 0.080108-67-8 1,3,5-Trimethylbenzene ND 0.2075-15-0 Carbon disulfide ND 0.04075-01-4 Vinyl chloride ND 0.08095-47-6 o-Xylene ND 0.08075-45-6 Chlorodifluoromethane ND 0.080179601-23-1 m-Xylene & p-Xylene ND 0.080106-93-4 1,2-Dibromoethane ND 0.20110-82-7 Cyclohexane ND 0.40124-18-5 n-Decane ND 0.080124-48-1 Dibromochloromethane ND 0.1674-95-3 Dibromomethane ND 0.40112-40-3 n-Dodecane ND 2.064-17-5 Ethanol ND 0.80141-78-6 Ethyl acetate ND 0.8060-29-7 Ethyl ether ND 0.20142-82-5 n-Heptane ND 0.20110-54-3 Hexane ND 0.8067-63-0 Isopropyl alcohol ND 0.2080-62-6 Methyl methacrylate ND 0.161634-04-4 Methyl tert-butyl ether ND 0.2091-20-3 Naphthalene ND FORM I TO 15 LL 03/21/2017Page 369 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 11059 SDG No.: 140-7194-1 Lab Sample ID:140-7194-12 TestAmerica Knoxville Matrix:LOT7194R.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/21/2017 17:20 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/23/2017 03:17 ID:RTX-5 Analysis Batch No.:8744 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.16104-51-8 n-Butylbenzene ND 0.16103-65-1 N-Propylbenzene ND 0.16111-65-9 n-Octane ND 0.40109-66-0 Pentane ND 0.20115-07-1 Propene ND 0.16135-98-8 sec-Butylbenzene ND 0.2098-06-6 tert-Butylbenzene ND 0.40109-99-9 Tetrahydrofuran ND 0.080156-60-5 trans-1,2-Dichloroethene ND 0.401120-21-4 Undecane ND 0.40108-05-4 Vinyl acetate ND 0.080593-60-2 Vinyl bromide ND 0.080488-23-3 1,2,3,4-Tetramethylbenzene ND 0.080527-53-7 1,2,3,5-Tetramethylbenzene ND 0.08095-93-2 1,2,4,5-Tetramethylbenzene ND 0.080934-80-5 1,2-Dimethyl-4-Ethylbenzene ND 1.090-12-0 1-Methylnaphthalene ND 0.0803074-71-3 2,3-Dimethylheptane ND 0.080872-55-9 2-Ethylthiophene ND 0.080554-14-3 2-Methylthiophene ND 1.091-57-6 2-Methylnaphthalene ND 0.080616-44-4 3-Methylthiophene ND 0.1695-15-8 Benzo(b)thiophene ND 0.080110-02-1 Thiophene ND 0.0801678-93-9 Butylcyclohexane ND 0.080526-73-8 1,2,3-Trimethylbenzene ND 0.16106-99-0 1,3-Butadine ND 0.20540-84-1 2,2,4-Trimethylpentane ND 0.8071-36-3 1-Butanol ND 0.080565-59-3 2,3-Dimethylpentane ND 0.2078-78-4 2-Methylbutane ND 0.080107-83-5 2-Methylpentane ND 4.075-07-0 Acetaldehyde ND 0.1698-82-8 Cumene ND 0.080496-11-7 Indane ND 0.1695-13-6 Indene ND FORM I TO 15 LL 03/21/2017Page 370 of 377 FORM I AIR - GC/MS VOA ORGANICS ANALYSIS DATA SHEET Client Sample ID: Lab Name:Job No.: 11059 SDG No.: 140-7194-1 Lab Sample ID:140-7194-12 TestAmerica Knoxville Matrix:LOT7194R.DLab File ID: Date Collected:TO 15 LLAnalysis Method: Air 02/21/2017 17:20 Sample wt/vol: % Moisture: GC Column:Soil Extract Vol.: Dilution Factor:Soil Aliquot Vol:1 Level: (low/med)Low 500(mL) 0.32(mm) Date Analyzed:02/23/2017 03:17 ID:RTX-5 Analysis Batch No.:8744 ppb v/vUnits: CAS NO.COMPOUND NAME RESULT Q RL 0.08099-87-6 p-Cymene ND 0.3275-65-0 tert-Butanol ND 0.080108-87-2 Methylcyclohexane ND 0.20111-84-2 n-Nonane ND FORM I TO 15 LL 03/21/2017Page 371 of 377 Report Date: 23-Feb-2017 09:45:27 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Target Compound Quantitation Report Data File:\\ChromNA\Knoxville\ChromData\MJ\20170220-4098.b\LOT7194R.D Lims ID:140-7194-A-12 Client ID:11059 Sample Type:Client Inject. Date:23-Feb-2017 03:17:30 ALS Bottle#:15 Worklist Smp#:24 Purge Vol:500.000 mL Dil. Factor:1.0000 Sample Info:140-0004098-024 Misc. Info.:11059 Operator ID:7126 Instrument ID:MJ Method:\\ChromNA\Knoxville\ChromData\MJ\20170220-4098.b\MJ_TO15.m Limit Group:MSA TO14A_15 Routine ICAL Last Update:23-Feb-2017 09:44:30 Calib Date:26-Nov-2016 01:58:30 Integrator:RTE ID Type: Deconvolution ID Quant Method:Internal Standard Quant By:Initial Calibration Last ICal File:\\ChromNA\Knoxville\ChromData\MJ\20161121-3656.b\JK25IC09X.D Column 1 :RTX-5 ( 0.32 mm)Det: MS SCAN Process Host:XAWRK028 First Level Reviewer: tajh Date:23-Feb-2017 09:00:34 Compound Sig RT (min.) Adj RT (min.) Dlt RT (min.)Q Response OnCol Amt ppb v/v Flags * 1 Chlorobromomethane (IS) 128 8.571 8.579 -0.008 99 353659 4.00 * 2 1,4-Difluorobenzene 114 10.771 10.780 -0.009 95 1527227 4.00 * 3 Chlorobenzene-d5 (IS) 117 15.548 15.551 -0.003 87 1262067 4.00 $ 4 4-Bromofluorobenzene (Surr 95 17.199 17.197 0.002 95 714777 3.58 13 Butane 43 4.041 4.045 -0.003 90 7338 0.0344 31 Methylene Chloride 84 6.058 6.062 -0.004 98 8418 0.0808 33 Carbon disulfide 76 6.220 6.223 -0.003 96 9031 0.0288 46 Tetrahydrofuran 42 9.033 9.010 0.023 90 5338 0.0513 Reagents: 40MXISSURP_00001 Amount Added: 40.00 Units: mL Run Reagent 03/21/2017Page 372 of 377 Report Date: 23-Feb-2017 09:45:27 Chrom Revision: 2.2 22-Feb-2017 11:38:16 TestAmerica Knoxville Data File:\\ChromNA\Knoxville\ChromData\MJ\20170220-4098.b\LOT7194R.D Injection Date:23-Feb-2017 03:17:30 Instrument ID:MJ Operator ID:7126 Lims ID:140-7194-A-12 Lab Sample ID:140-7194-12 Worklist Smp#:24 Client ID:11059 Purge Vol:500.000 mL Dil. Factor:1.0000 ALS Bottle#:15 Method:MJ_TO15 Limit Group:MSA TO14A_15 Routine ICAL Column: RTX-5 ( 0.32 mm) 3.0 5.0 7.0 9.0 11.0 13.0 15.0 17.0 19.0 21.0 23.0 25.0 Min 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 Y ( X10 0 0 0 0 ) LOT7194R[MS SCAN Chro]:Total * C h l o r o b r o m o m e t h a n e (IS )( 8 . 5 7 1 ) * 1 ,4- D i flu o r o b e n zen e ( 1 0 . 7 7 1 )+ * C h l o r o b e n zen e - d5 (IS )( 1 5 . 5 4 8 ) $ 4 - Bro m o flu o r o b e n zen e (Su r r )( 1 7 . 1 9 9 ) 03/21/2017Page 373 of 377 Shipping and Receiving Documents 03/21/2017Page 374 of 377 03/21/2017Page 375 of 377 03/21/2017Page 376 of 377 Gauge ID:G5 Date:3/8/2017 Analyst Sample ID Asset # Cleaning Job Cert Size (L) Pressure @ Receipt (-in Hg or +psig) Time Comments HMT 140-7345-a-1 09869 7150 I 6 -4.0 14:00 HMT 140-7345-a-2 09991 7008 I 6 -2.8 14:01 HMT 140-7345-a-3 10882 7128 I 6 -1.2 14:02 HMT 140-7345-a-4 11059 7194 I 6 -2.9 14:03 TestAmerica Knoxville - Air Canister Initial Pressure Check 140-7345.xls MS038 r14, 6/19/1503/21/2017Page 377 of 377 Appendix C Data Review Report DATA REVIEW REPORT Sharon Cleaners Site No. 546052 Project Manager: Brian Jankauskas Analytical Laboratory: TestAmerica – Knoxville, TN Job No.: 140-7345-1 Sample Date(s): 03/06/2017 Received Date: 03/08/2017 10:10 AM Analysis Date(s): 03/09/2016, 03/10/2017 Chain-of-Custody – All samples were collected and shipped under COC record and received at TestAmerica – Knoxville, TN within two days of sampling. All samples were received intact and in good condition. Final pressures for the field sample canisters, as measured by the receiving lab were: - Sample – SS-10-2017 Canister #09869 Final Pressure – (-) 4.0 Hg - Sample – AS-10-2017 Canister #09991 Final Pressure – (-) 2.8 Hg - Sample – DUP-2017 Canister #10882 Final Pressure – (-) 1.2 Hg - Sample – OA-10-2017 Canister #11059 Final Pressure – (-) 2.9 Hg Holding Times – All samples were analyzed within the method specified holding time of 14 days from sampling. Tune Criteria – All samples were analyzed within 24 hours of a passing BFB tune. Initial Calibration – The multi-point initial calibration had a Response Factor (%RSD) of < Max % RSD for all reported analytes, except for – - acetaldehyde %RSD = 36.1 Max %RSD = 30.0 Acetaldehyde was not reported in any of the samples. All reported analytes from the multi-point calibration were within the 0.06 RRT units of the mean RRT. All reported analytes were detected at the appropriate levels in the multi-point calibration to support the reporting limits provided. The initial calibration had a concentration range of 0.0392ppbv/v to 16.00ppbv/v on column for most of the target analytes. Continuing Calibration Verification – Method TO-15LL requires that all target analytes in the continuing calibration verification standard be within 30% difference from the initial calibration. For the continuing calibration associated with analytical Batch #9156 (initial run of all samples), all reported analytes in the continuing calibration verification met the requirement of being within a maximum percent difference (%D) of < 30%, except for: - chloroethane %D = 31.9 - ethanol %D = 31.6 - acrolein %D = 43.5 - decane %D = 32.7 - undecane %D = 39.3 - dodecane %D = 30.7 The ethanol results were within the laboratory’s Standard Operating Procedure (SOP) which states that the continuing calibration is acceptable if it meets the laboratory control sample (LCS) acceptance criteria. Ethanol’s results were within the LCS acceptance limits. Any results for ethanol do not need to be qualified. The other five analytes were not reported in any of the samples. For the continuing calibration associated with analytical Batch #9158 (dilution runs of AS-10-2017 and DUP-2017), the only reported analyte – ethanol - met the requirement of being within a maximum percent difference (%D) of < 30%. The continuing calibration verifications were run at a concentration of 2.00 ppbv/v. Method Blank – A blank was run in each 24 hour window of analysis. Surrogate Recoveries were within the Method Criteria Limits of 60 – 140% Recovery. There were no target analytes at reportable levels in the blanks. Sample Data – All samples were analyzed within 24 hours of an acceptable tune and calibration or calibration verification. The Internal Standard areas are within +/- 40% of the internal standard area count of the associated calibration areas. The Internal Standard relative retention times are within + 20 seconds of the internal standard retention time in the associated calibration times. All Surrogate Recoveries are within the control limits of 60 – 140%. All reported analytes are within the calibration range of the analytical system on the primary or diluted run – - Sample AS-10-2017 included a dilution run using 25mL - Sample DUP-2017 included a dilution run using 25mL Three of the samples were run initially at a smaller volume of sample – - Sample SS-10-2017 run at 50 mL - Sample AS-10-2017 run at 100 mL - Sample DUP-2017 run at 100 mL Each of these analytical runs are reported at higher detection limits. No TICs (Tentatively Identified Compounds) were analyzed/reported. Field Duplicate precision was calculated for sample DUP-2017 which is associated with field sample AS-10-2017. The Relative Percent Difference (% RPD) between the two samples was less than 20% for all detected compounds meeting the method criteria of %RPD < 20. Canister Cleaning Data – Traceability is provided for each individual sample canister and the lab provides documentation for which analytical batch #s the sample canisters are linked. The canister cleaning data provided shows the canisters to be free of interfering compounds. The reporting limits for the canister blanks are equivalent to the reporting limits for the undiluted samples (500mL sample volume). Miscellaneous – EPA method TO-15 specifies the use of humidified “zero air” as the blank reagent for canister cleaning, instrument calibration, and sample analysis. Ultra-high purity humidified nitrogen from a cryogenic reservoir is used in place of “zero air” by Test America – Knoxville. This is an acceptable substitute. TestAmerica – Knoxville has a New York State NELAP Certification ID #10781 with an expiration date of 03-31-17. The following analytes that were included in this report, are not certified under this NELAP certification: - 1,1,2-Trichlorotrifluoroethane - Dichlorodifluoromethane - 1,2,4-Trimethybenzene - o-Xylene - 1,2-Dichlorotetrafluoroethane - Trichlorofluoromethane - 1,3,5-Trimethylbenzene The following anaytes that were included in this report, do not have a certification being offered by NELAP – Ethanol. 1,2,4-Trimethylbenzene, Ethanol, o-Xylene, Dichlorodifluoromethane, and Trichlorofluoromethane were reported in one or more of the samples. The results for these analytes should be considered as estimates and qualified with NJ – presumptive/estimated. Final Notes – This report addresses analytical performance as defined in EPA Method TO-15 and the July 2005 NYSDEC Analytical Services Protocol (ASP). All data reviewed addresses those compounds which are represented on the final laboratory reports. Results should be considered usable with qualifiers taken into consideration. Prepared by: Gail A. Dieter Environmental Chemist II Division of Environmental Remediation – Bureau E e-mail: gail.dieter@dec.ny.gov 03/30/2017